Journal of Materials Science: Materials in Electronics最新文献

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Ultra-flexible, high-performing NAN transparent electrodes for bendable optoelectronic applications 用于可弯曲光电应用的超柔性、高性能纳米透明电极
IF 2.8 4区 工程技术
Journal of Materials Science: Materials in Electronics Pub Date : 2024-09-06 DOI: 10.1007/s10854-024-13442-2
Salih Alper Akalin, Tiago Mateus, Guilherme Ribeiro, Jonas Deuermeier, Tomas Calmeiro, Hugo Águas, Rodrigo Martins, António T. Vicente, Manuel J. Mendes, Ugur Deneb Yilmazer Menda
{"title":"Ultra-flexible, high-performing NAN transparent electrodes for bendable optoelectronic applications","authors":"Salih Alper Akalin, Tiago Mateus, Guilherme Ribeiro, Jonas Deuermeier, Tomas Calmeiro, Hugo Águas, Rodrigo Martins, António T. Vicente, Manuel J. Mendes, Ugur Deneb Yilmazer Menda","doi":"10.1007/s10854-024-13442-2","DOIUrl":"https://doi.org/10.1007/s10854-024-13442-2","url":null,"abstract":"<p>The NiO/Ag/NiO (NAN) structure, a member of the oxide/metal/oxide (OMO) structures, was developed as an alternative to conventional transparent electrodes. The fabrication process employed combination of RF-magnetron sputter and e-beam evaporation techniques, and to optimize the electrode performance, the Ag layer thickness within the NAN structures was varied between 4 and 20 nm. The resulting configurations were evaluated through the Fraser-Cook and Haacke figures of merit (FoM). The optimized structure exhibited high optical transmittance of 75% and a low sheet resistance (R<sub>S</sub>) of ∼5 Ω/□. Compared to a commercial sample of indium tin oxide (ITO) coated polyethylene terephthalate (PET), the NAN/PET structures show higher Fraser-Cook FoM, closely aligned with the Haacke FoM, owing to their lower R<sub>S</sub> values. In addition, the flexural resistance of the electrodes was assessed by subjecting the samples to 10,000 bending cycles. Following this test, the R<sub>S</sub> value of ITO/PET increased 26.3 times to 3312.89 Ω/□, while the NAN/PET only increased 1.25 times to 7.82 Ω/□. Even the least performing NAN sample, deposited on polyethylene naphthalate (NAN/PEN), experienced a moderate increase in resistance, stabilizing at 59.93 Ω/□. The obtained results highlight the great potential of the NAN structure as an electrode for flexible optoelectronic devices.</p>","PeriodicalId":646,"journal":{"name":"Journal of Materials Science: Materials in Electronics","volume":null,"pages":null},"PeriodicalIF":2.8,"publicationDate":"2024-09-06","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"142226746","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"工程技术","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Effect of BNT on piezoelectric and energy storage characteristics of piezoelectric ceramics and its application in underwater acoustic transducer BNT 对压电陶瓷压电和储能特性的影响及其在水下声换能器中的应用
IF 2.8 4区 工程技术
Journal of Materials Science: Materials in Electronics Pub Date : 2024-09-06 DOI: 10.1007/s10854-024-13446-y
Hui Lin, Fangxin Wang, Yali Ye, Chuanyi Zhuang
{"title":"Effect of BNT on piezoelectric and energy storage characteristics of piezoelectric ceramics and its application in underwater acoustic transducer","authors":"Hui Lin, Fangxin Wang, Yali Ye, Chuanyi Zhuang","doi":"10.1007/s10854-024-13446-y","DOIUrl":"https://doi.org/10.1007/s10854-024-13446-y","url":null,"abstract":"<p>Aiming at the problems such as the reduction of monitoring accuracy of ultrasonic transducer under the influence of self-heating and detection environment. In this paper, Bi, Ni and Ti elements are incorporated into manganese doped piezoelectric ceramics. xBi(Ni<sub>1/2</sub>Ti<sub>1/2</sub>)O<sub>3</sub>–(1 − <i>x</i>)[0.05Pb(Mn<sub>1/3</sub>Sb<sub>2/3</sub>)–0.95Pb(Zr<sub>0.48</sub>Ti<sub>0.52</sub>)O<sub>3</sub>] ceramics were synthesized by solid-phase sintering method. The relationship between BNT content and ceramic energy storage and piezoelectric properties was established, and a series of underwater acoustic transducers were prepared using the ceramic material as a sensitive element. The results show that the introduction of BNT reduces the volatilization of P<sub>b</sub>, promotes the grain growth, increases the piezoelectric and energy storage characteristics, and enhances the temperature stability. <i>d</i><sub><i>33</i></sub> is greater than 270 pC/N in the range of 150 °C. The prepared underwater acoustic transducer has a high emission response of about 167 dB at 100 °C. The transducer has a broad application prospects for detecting corrosion damage in high temperature oil storage tanks and other facilities.</p>","PeriodicalId":646,"journal":{"name":"Journal of Materials Science: Materials in Electronics","volume":null,"pages":null},"PeriodicalIF":2.8,"publicationDate":"2024-09-06","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"142210153","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"工程技术","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Flexible metal foil/polymer sandwich composites for electromagnetic interference shielding with anti-wind–sand environment tolerance 用于电磁干扰屏蔽的柔性金属箔/聚合物夹层复合材料,具有抗风沙环境耐受性
IF 2.8 4区 工程技术
Journal of Materials Science: Materials in Electronics Pub Date : 2024-09-06 DOI: 10.1007/s10854-024-13427-1
Longlong Xue, Shisheng Xiong
{"title":"Flexible metal foil/polymer sandwich composites for electromagnetic interference shielding with anti-wind–sand environment tolerance","authors":"Longlong Xue, Shisheng Xiong","doi":"10.1007/s10854-024-13427-1","DOIUrl":"https://doi.org/10.1007/s10854-024-13427-1","url":null,"abstract":"<p>In the anti-wind–sand environment, it is challenging to find a single material that fulfills all the required functional application requirements, such as shielding performance, mechanical performance, chemical performance, reliability, and economic efficiency. Herein, a multi-layer electromagnetic shielding composite sheet specifically was designed for large military bases in anti-wind–sand environments. The composite material structure comprises laminated aluminum foil, PET film, and Oxford fabric, utilizing an acrylic emulsion pressure-sensitive adhesive that was modified with superior nano-SiO<sub>2</sub>. The results showed that the electromagnetic interference shielding of Al Mylar foil (0.03 mm) measured 88 dB, whereas the medium gauge foil recorded 84.7 dB after salt spray test for 288 h. The samples of Oxford fabric showed an increase in tensile and tearing strength as the fabric density increases, but the rate of increase decreases gradually. The shear and peel strengths of acrylic emulsion modified by hydrophobic nano-SiO<sub>2</sub> were 67.1 MPa and 24.3 N/m, respectively, with a blending ratio of 7 wt%. Finally, we handpicked 140 g/m<sup>2</sup> of Oxford cloth, 0.03 mm of aluminum foil with PET films, and acrylic emulsion pressure-sensitive adhesive containing 7 wt% hydrophobic nano-SiO<sub>2</sub> for the lamination. The samples have good aging performance, with electromagnetic shielding performance, shear strength, peel strength, and weight loss declining less than 10% at 85 °C and 85% RH for 1000 h.</p>","PeriodicalId":646,"journal":{"name":"Journal of Materials Science: Materials in Electronics","volume":null,"pages":null},"PeriodicalIF":2.8,"publicationDate":"2024-09-06","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"142210150","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"工程技术","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Fabrication of a PPy composite with EMD nanorods recovered from Li-ion batteries for supercapacitor 用从锂离子电池中回收的 EMD 纳米棒制造用于超级电容器的 PPy 复合材料
IF 2.8 4区 工程技术
Journal of Materials Science: Materials in Electronics Pub Date : 2024-09-05 DOI: 10.1007/s10854-024-13462-y
Erhan Karaca, Nuran Özçiçek Pekmez, Kadir Pekmez
{"title":"Fabrication of a PPy composite with EMD nanorods recovered from Li-ion batteries for supercapacitor","authors":"Erhan Karaca, Nuran Özçiçek Pekmez, Kadir Pekmez","doi":"10.1007/s10854-024-13462-y","DOIUrl":"https://doi.org/10.1007/s10854-024-13462-y","url":null,"abstract":"<p>Polypyrrole/electrolytic manganese dioxide (PPy/EMD) composite is fabricated electrochemically on a stainless-steel mesh (SSM) surface in acetonitrile containing EMD nanorods and pyrrole monomer as a supercapacitor anode electrode material. EMD is recovered with an efficiency of 96.2% from a methanesulfonic acid leached solution of spent Li-ion batteries using an iridium-tantalum-coated titanium anode. The composite-coated electrode is characterized using electrochemical impedance spectroscopy (EIS) and cyclic voltammetry (CV) by comparison with those of its components: the electrode with a mass loading of 10 mg.cm<sup>-2</sup> has the highest specific capacitance (72 F g<sup>-1</sup>) and pseudocapacitive contribution (95% at 50 mV s<sup>-1</sup>) and the lowest resistance (1.85 Ω cm<sup>2</sup>). Spectroscopic studies of the composite coating are carried out using energy-dispersive X-ray spectroscopy (EDX) and X-ray photoelectron spectroscopy (XPS), while the morphological and structural analyses are performed using field emission scanning electron microscopy (FESEM), transmission electron microscopy (TEM), and X-ray diffraction (XRD). EMD nanoparticles with ε-MnO<sub>2</sub> and oxygen-deficient structure are homogeneously distributed in the composite at 8.4 wt% and encapsulated within the growing PPy clusters. Thus, due to the pseudocapacitive behavior, EMD recovered from batteries contributes significantly to the capacitance of the composite. PPy/EMD- and C- coated electrodes are combined in polyvinyl alcohol/Li<sub>2</sub>SO<sub>4</sub> gel electrolyte to construct an asymmetric supercapacitor cell: it has a 23.2 Wh.kg<sup>-1</sup> energy density and a 0.31 kW.kg<sup>-1</sup> power density at 0.50 A.g<sup>-1</sup> from the galvanostatic charge-discharge (GCD) test. After 5000 cycles, cycle life is 74.0% with a coulombic efficiency of 77.7%.</p>","PeriodicalId":646,"journal":{"name":"Journal of Materials Science: Materials in Electronics","volume":null,"pages":null},"PeriodicalIF":2.8,"publicationDate":"2024-09-05","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"142226747","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"工程技术","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Exploring the dual functionality of copper oxide for enhanced supercapacitor performance and photocatalysis application 探索氧化铜的双重功能以增强超级电容器性能和光催化应用
IF 2.8 4区 工程技术
Journal of Materials Science: Materials in Electronics Pub Date : 2024-09-05 DOI: 10.1007/s10854-024-13378-7
Swapnil N. Pawar, Shankar G. Randive, Prathamesh B. Dahivade, Yugen A. Kullkarni, Prashant P. Chikode, Balkrishna J. Lokhande
{"title":"Exploring the dual functionality of copper oxide for enhanced supercapacitor performance and photocatalysis application","authors":"Swapnil N. Pawar, Shankar G. Randive, Prathamesh B. Dahivade, Yugen A. Kullkarni, Prashant P. Chikode, Balkrishna J. Lokhande","doi":"10.1007/s10854-024-13378-7","DOIUrl":"https://doi.org/10.1007/s10854-024-13378-7","url":null,"abstract":"<p>In this study, CuO thin films were deposited onto stainless steel substrates using the SILAR (Successive Ionic Layer Adsorption and Reaction) technique. The samples underwent annealing at various temperatures: room temperature (300 K, 500 K, 700 K, and 900 K). We investigated the impact of annealing temperature on the crystal structure, electrochemical properties, and morphology of the CuO thin film electrodes. These aspects were correlated with electrochemical analyses, namely cyclic voltammetry and chronopotentiometry, as well as physical characterizations including contact angle measurements, X-ray diffraction and field emission scanning electron microscopy. Additionally, atomic force microscopy provided 3D images along with parameters such as average roughness, root mean square roughness, and average grain diameter. The CuO thin film electrodes exhibited a notable enhancement in capacitive behaviour. Specifically, the specific capacitance reached a significant value of 946 F/g at 5 mV/sec. Moreover, the highest observed specific power was recorded at 42 kW/kg during scans at 1 mV/sec. Notably, the CuO films also demonstrated commendable photo-catalytic activity in the degradation of methylene blue dye.</p>","PeriodicalId":646,"journal":{"name":"Journal of Materials Science: Materials in Electronics","volume":null,"pages":null},"PeriodicalIF":2.8,"publicationDate":"2024-09-05","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"142226748","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"工程技术","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Modified nanosphere lithography: application to the fabrication of ordered arrays of gold nanopyramids 改良纳米层光刻技术:应用于制造有序的金纳米金字塔阵列
IF 2.8 4区 工程技术
Journal of Materials Science: Materials in Electronics Pub Date : 2024-09-05 DOI: 10.1007/s10854-024-13289-7
Cecilia Salinas-Fuentes, Angélica Hernández-Zanabria, Juan-Carlos Cheang-Wong, Yuriy Kudriavtsev
{"title":"Modified nanosphere lithography: application to the fabrication of ordered arrays of gold nanopyramids","authors":"Cecilia Salinas-Fuentes, Angélica Hernández-Zanabria, Juan-Carlos Cheang-Wong, Yuriy Kudriavtsev","doi":"10.1007/s10854-024-13289-7","DOIUrl":"https://doi.org/10.1007/s10854-024-13289-7","url":null,"abstract":"<p>In this work a modified approach to improve the capabilities of nanosphere lithography was performed to obtain ordered arrays of gold nanopyramids that can be used as Surface-Enhanced Raman Scattering (SERS) substrates. Specifically, shadow sphere lithography in combination with nanosphere lithography was used to fabricate metallic nanostructures of different sizes starting from the same mask of silica microspheres. An extensive study of the obtained samples with scanning electron microscopy, atomic force microscopy and Raman characterizations confirms that indeed this modification of the standard nanosphere lithography is an excellent candidate to produce ordered arrays of Au nanopyramids with good control on their geometric properties. Rhodamine 6G dye was used as a probe molecule to test our SERS substrates. These features can be used in turn to optimize the SERS substrates for several potential applications. Remarkably, it is shown that by this simple technique one can achieve enhancement factors and detection capabilities of dyes that are comparable with those obtained by using more sophisticated techniques as proposed recently in the literature.</p>","PeriodicalId":646,"journal":{"name":"Journal of Materials Science: Materials in Electronics","volume":null,"pages":null},"PeriodicalIF":2.8,"publicationDate":"2024-09-05","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"142210195","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"工程技术","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
A photonic insight of NiO–GO nanocomposites synthesized by Adhatoda vasica extracts 从光子角度看阿达朵达藤提取物合成的 NiO-GO 纳米复合材料
IF 2.8 4区 工程技术
Journal of Materials Science: Materials in Electronics Pub Date : 2024-09-05 DOI: 10.1007/s10854-024-13452-0
Hiral M. Mistry, M. P. Deshpande, Anilkumar B. Hirpara, Nidhishree M. Suchak, Sunil H. Chaki, Sandip V. Bhatt
{"title":"A photonic insight of NiO–GO nanocomposites synthesized by Adhatoda vasica extracts","authors":"Hiral M. Mistry, M. P. Deshpande, Anilkumar B. Hirpara, Nidhishree M. Suchak, Sunil H. Chaki, Sandip V. Bhatt","doi":"10.1007/s10854-024-13452-0","DOIUrl":"https://doi.org/10.1007/s10854-024-13452-0","url":null,"abstract":"<p>The low-cost, simple, and environmentally friendly green synthesis of nickel oxide nanoparticles (NiO) and related hybrids through plant extracts has gained a lot of interest nowadays. In this work, a one-step green synthesis of hybrid Nickel Oxide-Graphene oxide nanocomposites (NiO–GO NCs) utilizing an Adhatoda vasica extract was undertaken. Numerous analytical techniques, such as EDX, XPS, FESEM, HRTEM, XRD, Raman spectroscopy, FTIR, and UV–visible spectroscopy, were employed to assess the formation of NiO on GO. The study explored the light responsiveness of NiO–GO NCs by obtaining current–voltage (I–V) measurements under visible light exposure. The synthesized NiO–GO NCs exhibited remarkable and extensive sensitivity to light over a variety of wavelengths. Furthermore, responsivity and detectivity were maximum at 480 nm (9.83 mA/W, 2.53<b> × </b>10<sup><b>9</b></sup> Jones), followed by 7.54 mA/W, 1.94<b> × </b>10<sup><b>9</b></sup> Jones, and 3.98 mA/W, 1.02<b> × </b>10<sup><b>9</b></sup> Jones, at 520 and 670 nm respectively. At 480 nm, with a biasing voltage as low as 1 nV, we got a responsivity of 6.91 µA/W and a detectivity of 5.15<b> × </b>10<sup><b>7</b></sup> Jones. The photodetector showed a positive photoresponse between 5–30 V and a negative one between 1–100 nanovolts. This controllable approach for switching between positive and negative photoconductivity adds an extra functionality to conventional optoelectronic devices.</p>","PeriodicalId":646,"journal":{"name":"Journal of Materials Science: Materials in Electronics","volume":null,"pages":null},"PeriodicalIF":2.8,"publicationDate":"2024-09-05","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"142210152","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"工程技术","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Flexible airflow-strain dual response sensor with high sensitivity based on polyurethane conductive fiber flocked carbon fibers 基于聚氨酯导电纤维植绒碳纤维的高灵敏度柔性气流-应变双响应传感器
IF 2.8 4区 工程技术
Journal of Materials Science: Materials in Electronics Pub Date : 2024-09-04 DOI: 10.1007/s10854-024-13443-1
Wanrong Xu, Jin Luo, Weiwei Zhang, Tao Sun, Jun Sun, Jianjun Wang, Chuanxiang Qin, Lixing Dai
{"title":"Flexible airflow-strain dual response sensor with high sensitivity based on polyurethane conductive fiber flocked carbon fibers","authors":"Wanrong Xu, Jin Luo, Weiwei Zhang, Tao Sun, Jun Sun, Jianjun Wang, Chuanxiang Qin, Lixing Dai","doi":"10.1007/s10854-024-13443-1","DOIUrl":"https://doi.org/10.1007/s10854-024-13443-1","url":null,"abstract":"<p>Fluffy airflow sensors have unique advantages in the field of non-contact sensing, while strain sensors have more advantages in the field of contact sensing. However, it remains a challenge for a sensor to simultaneously detect both airflow and strain with fast response time and high sensitivity. Combining of strain sensing and airflow sensing allows for a simultaneous response to both contact and non-contact stimuli. Herein, we demonstrate for the first time a facile approach for creating flexible airflow and strain dual response sensors based on polyurethane substrate flocked with carbon fibers. The effective transduction of airflow and cyclic strain stimuli into the electrical resistance signals enables instantaneous sensing with an high sensitivity (157.5% s m<sup>− 1</sup>) and an fast response time (37 ms). Furthermore, the sensor can easily detect subtle strain (0.1%) and low velocity airflow (0.117 m s<sup>− 1</sup>) from the perceived object. With their outstanding sensing performance, these dual response sensors are more sensitive to sound waves than airflow response sensors. Particularly, they can effectively distinguish faint signals from detected objects. Taking the advantage of the sensor, precise control and monitoring in wearable device, industrial process, aerospace, medical equipment and intelligent home furnishing system are expected.</p>","PeriodicalId":646,"journal":{"name":"Journal of Materials Science: Materials in Electronics","volume":null,"pages":null},"PeriodicalIF":2.8,"publicationDate":"2024-09-04","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"142210155","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"工程技术","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Zn site substituting effects on structural evolution and microwave dielectric properties of rutile Zn0.15Nb0.3Ti0.55O2 ceramics 锌位点置换对金红石型 Zn0.15Nb0.3Ti0.55O2 陶瓷结构演化和微波介电性能的影响
IF 2.8 4区 工程技术
Journal of Materials Science: Materials in Electronics Pub Date : 2024-09-04 DOI: 10.1007/s10854-024-13450-2
Juan Gao, Juncheng Ma, Dafang Zhong, Hongyu Yang, Peidong Li, Zhe Xiong, Bin Tang
{"title":"Zn site substituting effects on structural evolution and microwave dielectric properties of rutile Zn0.15Nb0.3Ti0.55O2 ceramics","authors":"Juan Gao, Juncheng Ma, Dafang Zhong, Hongyu Yang, Peidong Li, Zhe Xiong, Bin Tang","doi":"10.1007/s10854-024-13450-2","DOIUrl":"https://doi.org/10.1007/s10854-024-13450-2","url":null,"abstract":"<p>In this work, the structure–property relationship of four types of divalent ions doped rutile Zn<sub>0.15</sub>Nb<sub>0.3</sub>Ti<sub>0.55</sub>O<sub>2</sub> microwave dielectric ceramics, including Co<sup>2+</sup>, (Cu<sub>0.5</sub>Co<sub>0.5</sub>)<sup>2+</sup>, (Cu<sub>0.5</sub>Ba<sub>0.5</sub>)<sup>2+</sup>, and Ca<sup>2+</sup>, were studied. It is found that impurity phases with contents less than 1.5% were identified in Ca<sup>2+</sup> and (Cu<sub>0.5</sub>Ba<sub>0.5</sub>)<sup>2+</sup> doped systems. There are decreased trends of axis length and cell volume along with the decrease of radius of doped ions. The extrinsic factors, including amounts of grain boundaries, and uniformity of grain size distribution, contribute to the development of microwave dielectric properties. More importantly, based on the P–V–L bond theory, it is shown that the variations of bond ionicity, lattice energy, and bond energy are responsible for the dielectric constant, quality factor, and temperature coefficient of resonance frequency, where Nb–O bonds own the largest bond ionicity and bond energy among all the types of bonds, and Ti–O bonds provide about 52% of the total lattice energy. This study provides an idea for further improving the microwave dielectric properties of rutile Zn<sub>0.15</sub>Nb<sub>0.3</sub>Ti<sub>0.55</sub>O<sub>2</sub> ceramics by moderating the bond characteristics.</p>","PeriodicalId":646,"journal":{"name":"Journal of Materials Science: Materials in Electronics","volume":null,"pages":null},"PeriodicalIF":2.8,"publicationDate":"2024-09-04","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"142210196","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"工程技术","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Investigation of structural, thermal, magnetic, and dielectric properties of Yb+3 doped nickel cobalt ferrite nanomaterial for electro-magnetic applications 用于电磁应用的 Yb+3 掺杂镍钴铁氧体纳米材料的结构、热、磁和介电特性研究
IF 2.8 4区 工程技术
Journal of Materials Science: Materials in Electronics Pub Date : 2024-09-04 DOI: 10.1007/s10854-024-13389-4
Smita Patil, Sunil Meti, Mallikarjun Anandalli, Hanamanta Badiger, Rajashekhar F. Bhajantri, L. Pratheek, Mohammad Muhiuddin, Mohammad Rizwanur Rahman, Balachandra G. Hegde
{"title":"Investigation of structural, thermal, magnetic, and dielectric properties of Yb+3 doped nickel cobalt ferrite nanomaterial for electro-magnetic applications","authors":"Smita Patil, Sunil Meti, Mallikarjun Anandalli, Hanamanta Badiger, Rajashekhar F. Bhajantri, L. Pratheek, Mohammad Muhiuddin, Mohammad Rizwanur Rahman, Balachandra G. Hegde","doi":"10.1007/s10854-024-13389-4","DOIUrl":"https://doi.org/10.1007/s10854-024-13389-4","url":null,"abstract":"<p>Herein, we report the synthesis of ytterbium (Yb) (with concentration <i>x</i> = 0.01, 0.015, 0.02, 0.025 and 0.03) doped in to nickel cobalt ferrite (NCYFO: Yb<sub><i>x</i></sub>Ni<sub>0.5</sub>Co<sub>0.5</sub>Fe<sub>2-<i>x</i></sub>O<sub>4</sub>) nanoparticles at temperature 500 °C with phase pure spinel using solution combustion technique. The phase purity and effect of doping on NCYFO complex oxide on structural, thermal, magnetic and dielectric properties have been determined by various characterization techniques. The FTIR data reveal that strong metal oxide linkages can be observed in the tetrahedral and octahedral sites at wavenumbers 460 to 410 cm<sup>−1</sup> and 595 to 540 cm<sup>−1</sup>. The X-ray diffraction (XRD) studies confirmed the spinel structure. The crystallite sizes and lattice parameters were estimated to be in the range of 31 to 22 nm and 8.32 to 8.35 Å, respectively. The X-ray photoelectron spectroscopy (XPS) study confirmed that the increase in Yb concentration results in accumulation of Yb in the grain boundaries of NCYFO in the form of Yb<sub>2</sub>O<sub>3</sub>. The thermal stability of nanoparticles were investigated using TGA/DSC method. Transmission Electron microscopy (TEM) studies and Field emission scanning electron microscopy (FESEM) used to study the particle size distribution and elemental composition within the nanomaterial. In addition, the dielectric properties, such as, dielectric constant and dielectric loss were investigated for all the NCYFO nanomaterial. The saturation magnetization of the NCYFO is determined using vibrating sample magnetometer (VSM) analysis and is maximum for <i>x</i> = 0.03 (<i>Ms</i> = 97.56 emu/g) sample. The high magnetic behaviour and better dielectric properties of the NCYFO nanomaterials are suitable for electro-magnetic applications.</p>","PeriodicalId":646,"journal":{"name":"Journal of Materials Science: Materials in Electronics","volume":null,"pages":null},"PeriodicalIF":2.8,"publicationDate":"2024-09-04","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"142210193","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"工程技术","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
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