ACS Sustainable Chemistry & Engineering最新文献

{"title":"Hydroxyl Radical-Induced Calcium Phosphate Crystallization to Gain Phosphorus Fertilizers from Circulating Water","authors":"Shuqi Li, Yuru Fu, Zixuan Wang, Xinhua Wang, Shu-Guang Wang, Mei Wang, Mingming Gao","doi":"10.1021/acssuschemeng.4c06579","DOIUrl":"https://doi.org/10.1021/acssuschemeng.4c06579","url":null,"abstract":"Calcium phosphate (CaP) crystallization enables simultaneous calcium removal and phosphorus recovery during circulating water (CW) treatment. Adjusting the thermodynamic process is crucial for accelerating CaP crystallization and enhancing the energy efficiency. In this study, hydroxyl radicals (·OH) generated via an electro-Fenton-like system were employed to induce CaP crystallization. Experimental investigation and theoretical calculations revealed ·OH to be key for phosphate release and CaP crystallization. The interactions between ions and NTMP are effectively strengthened by ·OH-induced multiple hydrogen bonds, leading to intermolecular aggregation and the formation of amorphous clusters. These clusters can create thermodynamic conditions that are more conducive to crystallization. Therefore, ·OH-induced CaP crystallization predominantly proceeded through the formation of amorphous clusters as the intermediate state, representing a nonclassical crystallization process. The issue of electrode deactivation caused by surface scaling was effectively avoided when crystallization primarily occurred within the amorphous clusters, resulting in the formation of CaP crystals in bulk solution. The recovered CaP crystals showed the possibility of being used as phosphorus fertilizers based on plant experiments. Finally, ·OH-induced CaP crystallization was achieved during the authentic CW treatment. This research expanded the application of ·OH to CaP crystallization and provided a sustainable strategy for CW treatment.","PeriodicalId":25,"journal":{"name":"ACS Sustainable Chemistry & Engineering","volume":"111 1","pages":""},"PeriodicalIF":8.4,"publicationDate":"2025-01-25","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"143031475","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":1,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

{"title":"Biobased and Reprocessable Vitrimers Based on Cardanol-Derived Epoxy for More Sustainable Thermosets","authors":"Edoardo Albertini, Sara Dalle Vacche, Roberta Bongiovanni, Isabella Bianco, Gian Andrea Blengini, Alessandra Vitale","doi":"10.1021/acssuschemeng.4c09035","DOIUrl":"https://doi.org/10.1021/acssuschemeng.4c09035","url":null,"abstract":"Vitrimers, permanently cross-linked polymers with dynamic covalent bonds that allow the network to change its topology, represent an intriguing field of research as they open new ways of recycling cross-linked polymers that are usually not recyclable. The aim of this work is to prepare an innovative biobased vitrimer starting from the reaction between epoxy and acidic groups. The formulations are thermally cross-linked and then reprocessed by a transesterification reaction. The chemicals used are Cardolite NC-547, a biobased epoxy monomer synthesized from cardanol oil, and itaconic acid. Two catalysts are used: 2-ethyl-4-methylimidazole and zinc triflate. The first one mainly takes part in the cross-linking reaction, while the second one plays a role in both cross-linking and transesterification reactions. A conversion of 86% and a gel content of 82–84% are obtained when both catalysts are used. The thermal reprocessability of the cross-linked polymers is verified by mechanical tests, and the properties of the reprocessed vitrimers are compared with those of the virgin materials. Results show that a good reprocessability is obtained, with no significant change in conversion and gel content values, when a proper amount of zinc triflate is used. A slight increase in cross-linking density values and mechanical properties is observed after reprocessing. A preliminary life cycle assessment (LCA) is performed with the aim of guiding research with relevant environmental information. LCA results suggest that biobased vitrimers could lead to the production of more sustainable products compared to fossil-based ones.","PeriodicalId":25,"journal":{"name":"ACS Sustainable Chemistry & Engineering","volume":"63 1","pages":""},"PeriodicalIF":8.4,"publicationDate":"2025-01-24","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"143031477","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":1,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

{"title":"Intensification of Renewable 4,4′-Dimethylbiphenyl Synthesis for Recyclable Diesters","authors":"Charles C Fields, IV, Preeti Jain, Bala Subramaniam, Alan M. Allgeier, Dionisios G. Vlachos, Raul F. Lobo","doi":"10.1021/acssuschemeng.4c09233","DOIUrl":"https://doi.org/10.1021/acssuschemeng.4c09233","url":null,"abstract":"Reducing the global dependence on petroleum-derived chemical products requires renewable alternatives to replace established materials. Recent investigations demonstrated a biobased pathway to prepare the platform chemical 4,4′-dimethylbiphenyl (4,4′-DMBP). The synthesis of 4,4′-DMBP follows a two-step process: (1) 2-methylfuran (2-MF) oxidative coupling to 5,5′-dimethyl-2,2′-bifuran (5,5′-DMBF) and (2) 5,5′-DMBF tandem Diels–Alder-dehydration with ethylene to afford 4,4′-DMBP. Here, we report the intensification of reaction conditions in step (1), improving 5,5′-DMBF space-time yield up to 1.10 mol L^–1h^–1, an 86% increase from the baseline. Scale-up of step (1) was hindered by oxygen-deprivation-induced palladium black formation and reaction exotherms decreasing yields at larger scales. Oxygen sparging, mechanical mixing, and internal cooling implemented simultaneously enabled a 108× increase in 5,5′-DMBF production to an average of 13 g/batch. In step (2), the use of a homogeneous La(OTf)₃ catalyst in the Diels–Alder-dehydration reaction─instead of heterogeneous γ-Al₂O₃─led to a 54% increase in 4,4′-DMBP yield with a 70 °C temperature reduction to 180 °C. Scale-up of the Diels–Alder-dehydration to 3 g/batch maintained <i>para</i>-selectivity for 4,4′-DMBP with full conversion to the product within 20 h. Renewable 4,4′-DMBP is achieved from the improved pathway and isolated in 96.7% purity for further utilization downstream.","PeriodicalId":25,"journal":{"name":"ACS Sustainable Chemistry & Engineering","volume":"105 1","pages":""},"PeriodicalIF":8.4,"publicationDate":"2025-01-23","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"143020155","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":1,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

{"title":"Continuous Flow Synthesis of Bismuth Nanoparticles: A Well-Controlled Nano-Object Size Thanks to Successful Scaling-Up","authors":"Gauthier Hallot, Yuen-Sim Chan, Florent Ménard, Marc Port, Catherine Gomez","doi":"10.1021/acssuschemeng.4c03619","DOIUrl":"https://doi.org/10.1021/acssuschemeng.4c03619","url":null,"abstract":"Access to reproducible, large-scale, and simple synthesis of metal nanoparticles with a well-controlled size are major challenges, given the interest in nanoparticles in many applications. In this work, the presentation of various millifluidic devices ranging from small to high throughput shows a major interest in satisfying the extensive needs of users from milligrams to several tens of milligrams and, especially, in improving stability and size distributions. The metal bismuth nanoparticles synthesis was developed using a simple procedure in a basic solution. This continuous flow process demonstrated the capacity to produce up to 7 g per day of nanoparticles with a flow rate fixed at 15 mL min^–1. This process highlighted the synthesis with an attractive <i>E</i>-factor and low energy consumption compared to conventional methods. From low scale to semi-industrial scales, access to homogeneous and eco-friendly nanoparticles is often complex but truly attractive for important applications in chemical, pharmaceutical, and biomedical industries.","PeriodicalId":25,"journal":{"name":"ACS Sustainable Chemistry & Engineering","volume":"32 1","pages":""},"PeriodicalIF":8.4,"publicationDate":"2025-01-23","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"143020154","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":1,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

{"title":"Phosphonated Inulin as an Eco-Friendly Thermally Stable Scale Inhibitor for the Oil and Gas Industry: Synthesis, Characterization, Efficacy, and Molecular Insights","authors":"Mirza T. Baig, Safwat Abdel-Azeim, Showkat Ali Ganie, Maryam Warsame, Mohamed F. Mady","doi":"10.1021/acssuschemeng.4c09241","DOIUrl":"https://doi.org/10.1021/acssuschemeng.4c09241","url":null,"abstract":"The oil and gas industry grapples with mineral scale deposits during production, which hinder efficiency and damage equipment. The need for eco-friendly scale inhibitors for high-pressure, high-temperature (HPHT) applications has risen due to offshore regulations. This study investigates phosphonated Inulin (PIn), a modified biopolymer, as an eco-friendly scale inhibitor against calcite, gypsum, and Barite in harsh environments. Inulin, a natural polysaccharide, was functionalized with phosphonate groups, achieving a degree of substitution (DS) of 48.78%. Characterization through NMR and FTIR spectroscopy confirmed the successful modification. The scale inhibition effectiveness of PIn was tested in high-pressure dynamic tube-blocking tests at 100 °C and 80 bar compared to commercial carboxymethyl inulin (CMI). PIn effectively inhibited calcite and gypsum at 5 ppm under dynamic conditions and showed excellent thermal stability after 7 days at 130 °C, along with compatibility with high calcium ion concentrations, though it had minimal impact on barite scale. Molecular simulations offered insights into the morphology of the functionalized polysaccharides with GFN2-xTB MD simulations indicating a transition to a more compact structure. DFT analysis revealed that hydrogen bonds from phosphonate groups are stronger than those from hydroxyl or carboxylic groups, explaining PIn’s higher thermal stability compared to CMI.","PeriodicalId":25,"journal":{"name":"ACS Sustainable Chemistry & Engineering","volume":"7 1","pages":""},"PeriodicalIF":8.4,"publicationDate":"2025-01-23","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"143020157","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":1,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

{"title":"Tuning Pd–In2O3 Interaction and CO2 Hydrogenation Activity for Methanol Synthesis via In2O3 Crystal Phase Engineering","authors":"Yan Shao, Jun Wan, Xiaoxia Ou, Cui Quan, Ningbo Gao, Xin Wang, Feng Zeng, Rongsheng Cai, Xiaolei Fan, Huanhao Chen","doi":"10.1021/acssuschemeng.4c08050","DOIUrl":"https://doi.org/10.1021/acssuschemeng.4c08050","url":null,"abstract":"Engineering Pd–In₂O₃ interaction is key to developing catalysts with the desired CO₂ hydrogenation activity toward methanol synthesis. Here, the crystalline phase of In₂O₃ nanospheres was tuned by changing the calcination temperature, which was found to affect the Pd–In₂O₃ interaction and thus the supported Pd states and CO₂ hydrogenation performance of the prepared Pd/In₂O₃-<i>a</i> catalysts (where <i>a</i> refers to the calcination temperature for preparing In₂O₃). The fresh Pd/In₂O₃-<i>a</i> catalysts show varied initial activities, and after the induction period, their performance stabilized though being different. During the 100 h catalysis, catalyst microstructures changed, showing Pd aggregation and Pd–In alloying, which was related to the nature of the crystalline phase of In₂O₃. The hexagonal (<i>h</i>-In₂O₃) phase in Pd/In₂O₃-400 possesses concentrated surface OH groups and limited mobility. The relatively poor mobility limits Pd–In alloying, which possibly suppresses the hydrogen spillover effect, causing low CO₂ conversion (8%) and methanol selectivity (45%) under steady-state conditions at 5 MPa and 300 °C. Conversely, the cubic In₂O₃ (<i>c</i>-In₂O₃) phase promotes Pd–In alloying and modifies Pd–In₂O₃ interaction during the reaction. The activity data show that Pd/In₂O₃-600 with the mixed phases of In₂O₃ (<i>h</i>/<i>c</i>-In₂O₃) demonstrated appropriate Pd–In₂O₃ interaction, leading to the Pd core InO_<i>x</i> shell structure with the comparatively best methanol selectivity of about 65% at steady state. Conversely, Pd/In₂O₃-800 with the pure cubic In₂O₃ (<i>c</i>-In₂O₃) phase and a relatively low specific surface area of 16 m² g^–1 encourages the sintering of Pd and thereby the formation of homogeneous Pd–In alloys, having a moderate methanol selectivity of about 50%. These findings highlight the importance of the In₂O₃ crystal phase engineering in the catalytic CO₂ hydrogenation over Pd/In₂O₃ catalysts and the dynamics of Pd–In interactions, which affect the methanol yield.","PeriodicalId":25,"journal":{"name":"ACS Sustainable Chemistry & Engineering","volume":"18 1","pages":""},"PeriodicalIF":8.4,"publicationDate":"2025-01-23","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"143020156","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":1,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

{"title":"Construction of Bifunctional UCST-Responsive Claw-Shaped Cellulase Traps for Enzyme-Recyclable Lignocellulosic Hydrolysis","authors":"Feiyun Li, Jinxian Shan, Helin Li, Hongming Lou, Yanjun Tang","doi":"10.1021/acssuschemeng.4c10037","DOIUrl":"https://doi.org/10.1021/acssuschemeng.4c10037","url":null,"abstract":"Adding additives to improve lignocellulosic enzymatic hydrolysis and recycling of cellulase effectively reduced hydrolysis costs. Herein, we derived several thermoresponsive claw-type strong binding cellulase traps (PSTP) using triallylamine to cross-link the prepolymer of sulfobetaine and vinylpyrrolidone (NVP). The product improved lignocellulosic enzymatic hydrolysis and recycled cellulase. The high NVP molar ratio of PSTP significantly enhanced the enzymatic hydrolysis of corncob residues (CCR). Specifically, CCR’s substrate enzymatic digestibility of 72 h (SED@72 h) improved twice by adding 8.0 g/L PSTP₅. PSTP with a moderate NVP molar proportion and a large molecular weight significantly enhanced enzymatic hydrolysis and recovered cellulase properties. When a mere 0.12 g/L PSTP₂ was added to the CCR high-solid system, SED@48 h increased by 1.1 times. After hydrolysis, 60% of the cellulase dosage was saved. Conclusively, we report a new method for enhanced hydrolysis and recovering cellulase using a cellulase trap. This new strategy efficiently reduces the enzymolysis cost of the lignocellulose-based sugar platform and separates proteins.","PeriodicalId":25,"journal":{"name":"ACS Sustainable Chemistry & Engineering","volume":"33 1","pages":""},"PeriodicalIF":8.4,"publicationDate":"2025-01-22","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"143020200","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":1,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

{"title":"How to Engineer the Best Possible Ionic Liquid?─Scrutinizing Structure–Property Relationships in Ammonium Ionic Liquids for Anti-Crystal Engineering","authors":"Volodymyr Smetana, Magdalena Wilk-Kozubek, Guillaume Bousrez, Anja-Verena Mudring","doi":"10.1021/acssuschemeng.4c06407","DOIUrl":"https://doi.org/10.1021/acssuschemeng.4c06407","url":null,"abstract":"A set of IL-forming ion combinations has been studied to gain a deeper understanding of how, aside from obvious electrostatic interactions and ion size effects, secondary bonding such as hydrogen as well as halogen bonding and van der Waals interactions along with conformational and structural flexibility influence the crystallization behavior of potentially IL forming salts. The scrutinized ions have been specifically chosen to allow for unraveling preferential interactions of functional groups that may favor or disfavor crystallization with respect to secondary bonding interactions, i.e., primary and quaternary ammonium cations of variable alkyl chain lengths, which were also endowed with hydroxy groups, combined with formate and bis(trifluoromethanesulfonyl)amide anions. The background is to provide a deeper fundamental understanding of how to intentionally pair cations and anions that will not support the formation of a crystalline solid but rather IL formation, an approach described as “anti-crystal engineering”. This concept is based on the idea to avoid combining ions that are strong supramolecular synthons for crystallization. To this avail, the crystallization behavior of salts constituted of combinations of selected ions bearing different structural, supramolecular crystallization motifs has been studied in detail by low-temperature differential scanning calorimetry (DSC). Single crystal X-ray structure analysis has been used to elucidate ion packing and preferential interactions whenever crystalline solid formation is observed. The study reveals that the lowest melting points are supported by cation–anion combinations that have the least hydrogen bonding. However, if there are multiple possibilities of H-bonding for an ion with its counteranion, this bonding frustration leads as well to low melting points–albeit they are still higher compared to ion combinations with no H-bonding capacity. Through a careful balance of primary and secondary, directional and nondirectional interactions, it was possible to rationally identify a record class of ionic liquids, which combine exceptionally high decomposition points (440–450 °C) with an enormously high liquid range around of more than 500 °C and no tendency for solidification down to well below ambient temperature (−90 °C). These ILs are formed by bis(trifluoromethane)sulfonylamides with quaternary ammonium ions that bear an −OH group in the side chain.","PeriodicalId":25,"journal":{"name":"ACS Sustainable Chemistry & Engineering","volume":"74 1","pages":""},"PeriodicalIF":8.4,"publicationDate":"2025-01-22","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"143020159","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":1,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

{"title":"Switchable Hydrophilicity Amine Product Extraction: Efficient Separation of Tertiary Amines via Carbon Dioxide-Induced Polarity Switch in Homogeneous Catalysis","authors":"Tim Benjamin Riemer, Milan Danilo Kulaš, Ma-Azou Baba, Dieter Vogt, Thomas Seidensticker","doi":"10.1021/acssuschemeng.4c07757","DOIUrl":"https://doi.org/10.1021/acssuschemeng.4c07757","url":null,"abstract":"A combined approach is presented for the homogeneously catalyzed synthesis of tertiary amines and their subsequent carbon dioxide (CO₂)-induced separation. After production, the nonpolar tertiary amines are reacted with carbon dioxide to the corresponding polar ammonium carbonates and separated from the nonpolar reaction phase by water extraction. Subsequently, the nonpolar tertiary amines reform upon CO₂-stripping the loaded aqueous phase, enabling their straightforward isolation by decantation. For this <b>S</b>witchable <b>H</b>ydrophilicity <b>A</b>mine <b>P</b>roduct <b>E</b>xtraction (<b>SHAPE</b>) concept, the influence of various nonpolar solvents on the separation efficiency was investigated using <i>N</i>,<i>N</i>-dimethylbenzylamine (DMBA) as the model amine. After examination of all operating parameters of SHAPE in anisole as the best-performing solvent, homogeneously Ru-catalyzed alcohol amination of benzyl alcohol was identified as the most suitable model reaction for the production of DMBA, which was successfully isolated in 84.9% yield using SHAPE methodology. Moreover, only 0.09 wt % of Ru was lost in the separated product phase. This SHAPE concept was successfully combined with catalysis in thermomorphic multiphase systems (TMS). Four different tertiary amines were efficiently separated from the nonpolar solvent and the other reaction components, achieving high product purities of up to 97.3 wt %.","PeriodicalId":25,"journal":{"name":"ACS Sustainable Chemistry & Engineering","volume":"50 1","pages":""},"PeriodicalIF":8.4,"publicationDate":"2025-01-22","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"143020158","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":1,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

{"title":"Closing the Loop on Lithium-Ion Battery Cathodes: A Green Electrometallurgical Recycling Approach","authors":"Zhengping Ding, Jing Li, Yanqing Huang, Huahui Lin, Peng Wei, Jianbin Li, Xiangqun Zhuge, Zhenzhong Yang, Ke Qu, Yurong Ren","doi":"10.1021/acssuschemeng.4c07920","DOIUrl":"https://doi.org/10.1021/acssuschemeng.4c07920","url":null,"abstract":"The burgeoning use of lithium-ion batteries (LIBs) creates a growing challenge: spent battery management. Traditional hydrometallurgical recycling with coprecipitation generates massive Na₂SO₄ wastewater, posing a significant environmental burden. This work presents a novel, closed-loop recycling method for LIB cathode materials that merges electrolysis and hydrometallurgy. Using Na₂SO₄ electrolysis, we produced high-purity sulfuric acid and sodium hydroxide solutions, which served as the key reagents for leaching and resynthesizing waste cathodes. Optimized leaching conditions ensure near-complete recovery of valuable metals. Li₂CO₃ and a precursor (Ni_0.8Co_0.1Mn_0.1(OH)₂) are subsequently precipitated and regenerated into a new LiNi_0.8Co_0.1Mn_0.1O₂ cathode material, which demonstrates excellent electrochemical performance. The spent Na₂SO₄ solution undergoes a simple treatment before re-electrolysis, achieving a closed-loop system with minimal waste generation and reduced reliance on external reagents. Moreover, the acid-leaching carbon residue is repurposed as a bifunctional carbon-based catalyst for hydrogen peroxide production. This innovative approach offers both economic and environmental benefits, paving the way for sustainable LIBs recycling and a circular economy for battery materials.","PeriodicalId":25,"journal":{"name":"ACS Sustainable Chemistry & Engineering","volume":"62 1","pages":""},"PeriodicalIF":8.4,"publicationDate":"2025-01-22","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"143020196","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":1,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}