NanoscalePub Date : 2025-05-08DOI: 10.1039/d5nr00660k
Longwei Xue, Li Yuan, Jixing Zhou, Junshuai Dai, Xudong Zhang, Hong Hu, Hai Liu, Tingting Zhao
{"title":"Temperature-insensitive and wide-range linear tactile electronic skins for reliable shape and texture recognition","authors":"Longwei Xue, Li Yuan, Jixing Zhou, Junshuai Dai, Xudong Zhang, Hong Hu, Hai Liu, Tingting Zhao","doi":"10.1039/d5nr00660k","DOIUrl":"https://doi.org/10.1039/d5nr00660k","url":null,"abstract":"Electronic skins, emulating the tactile functionality of the human skin, are crucial for robotic applications. The sensitivity and pressure-sensing range of current humanoid tactile sensors have performed significant advancements. However, the temperature susceptibility of conductive materials and the rapid saturation of conductive contact sites in soft polymeric materials bring about challenges for these sensors, including environmental interference and a narrow linear sensing range. These issues lead to the inconsistencies between the sensing signal and contact behavior, which eventually deteriorates both the accuracy and reliability. Here, we propose a flexible piezoresistive pressure sensor with minimized response to temperature variation but extended linear sensing range. The sensor utilizes a novel hybrid conductive material elaborated to exhibit zero temperature resistance coefficient by combining the materials with the opposite temperature coefficients, which allows for a reliable operation ranging from 20 to 70 ℃ with temperature variation induced fluctuation free. Additionally, the sensor provides a biomimetic polymer microstructure with multilevel cone-dome structural feature, which results in an ultra-wide linear pressure-sensing range from 0 up to 200 kPa. In addition, based on the simple and scalable fabrication process, a high-density sensor array (16×16) is produced to outline the spatial pressure distributions accurately even under the external temperature interferences and successfully discern the texture of the contact object.","PeriodicalId":92,"journal":{"name":"Nanoscale","volume":"17 1","pages":""},"PeriodicalIF":6.7,"publicationDate":"2025-05-08","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"143920051","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":3,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
NanoscalePub Date : 2025-05-08DOI: 10.1039/d5nr00600g
Yue Cheng, Rui Xin, Li Yu, Feiyu Mao, Xiang Li, Wenjuan Wang, Tianxin Li
{"title":"Photocarrier distribution in an InGaAs/InP avalanche photodiodes and its contribution to device performances","authors":"Yue Cheng, Rui Xin, Li Yu, Feiyu Mao, Xiang Li, Wenjuan Wang, Tianxin Li","doi":"10.1039/d5nr00600g","DOIUrl":"https://doi.org/10.1039/d5nr00600g","url":null,"abstract":"The InGaAs/InP avalanche photodiode (APD) is one of the best single photon detectors in the near-infrared wavelength range. To approach its optimal performance, it would be helpful to reveal the electrical and photoelectric properties within its core regions from a microscopic perspective. Herein, we employed cross-sectional scanning capacitance microscopy (SCM) to investigate the photocarrier behaviors in two APD devices under excitation of different light wavelengths. The grading and charge layers as well as the multiplication regions of the APDs were well resolved electrically in this study. The light-induced capacitance response in the multiplication region was found to differ by 2–4 times in the two devices, signifying a much higher photocarrier concentration under the same excitation intensity. Additionally, a sharp gradient of capacitance was observed along the core regions, which directly reflects the pronounced drifting of photocarriers in the strong built-in electric field. The findings of this study substantiate the low dark current and high gain merits of the APD device, providing an effective strategy to explore the spatial and physical origin of the device performance through nanoscopic observation of carriers in the active area.","PeriodicalId":92,"journal":{"name":"Nanoscale","volume":"56 1","pages":""},"PeriodicalIF":6.7,"publicationDate":"2025-05-08","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"143920354","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":3,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
NanoscalePub Date : 2025-05-08DOI: 10.1039/d5nr00002e
Nickie Tiwari,Qiaoli Liang,Igor Fedin
{"title":"Cd3P2 QDs emitting in the SWIR through overgrowth of cadmium phosphide clusters.","authors":"Nickie Tiwari,Qiaoli Liang,Igor Fedin","doi":"10.1039/d5nr00002e","DOIUrl":"https://doi.org/10.1039/d5nr00002e","url":null,"abstract":"Cd3P2 quantum dots (QDs) are promising candidates for short-wave infrared (SWIR) applications. Producing QDs with SWIR emission and sharp spectral features is challenging. In this study, we show that overgrowth of Cd3P2 clusters extends the emission of Cd3P2 QDs into the SWIR. The resulting QDs are promising for imaging and telecom applications.","PeriodicalId":92,"journal":{"name":"Nanoscale","volume":"3 1","pages":""},"PeriodicalIF":6.7,"publicationDate":"2025-05-08","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"143921103","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":3,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
NanoscalePub Date : 2025-05-08DOI: 10.1039/d5nr00483g
Yuxia Wang, Juan Xiao, Tingting Huang, Ying Wang, Hui Ding, Qimeng Zhu, Guan-Cheng Xu, Li Zhang
{"title":"Pairing Ru-doped NiCo-layered double hydroxides and selenide derivatives as self-supporting electrocatalyst for alkaline overall water splitting","authors":"Yuxia Wang, Juan Xiao, Tingting Huang, Ying Wang, Hui Ding, Qimeng Zhu, Guan-Cheng Xu, Li Zhang","doi":"10.1039/d5nr00483g","DOIUrl":"https://doi.org/10.1039/d5nr00483g","url":null,"abstract":"The pursuit of a catalyst exhibiting exceptional efficacy and an optimal cost-performance ratio currently composes a prominent research focus. Herein, Ru-NiCo LDH/NF-4 (4 represents 4 mg mL-1 RuCl3⋅xH2O soultion) is prepared by impregnating NiCo layered double hydroxides (NiCo LDH) grown on nickel foam (NF) with RuCl3⋅xH2O soultion. The Ru-NiSe2/CoSe/NF-4 is prepared by selenization of Ru-NiCo LDH/NF-4. Benefiting from the three-dimensional flower-like nanosheet arrays, the synergistic effect between Ru and non-precious metal materials and the change of Ru electron valence state, Ru-NiCo LDH/NF-4 and Ru-NiSe2/CoSe/NF-4 exhibit low HER and OER with achieving overpotentials of 45 mV and 238 mV, respectively, with a current density of 10 mA cm-2 in 1.0 M KOH. Furthermore, when utilizing Ru-NiCo LDH/NF-4 as the cathode electrode and Ru-NiSe2/CoSe/NF-4 as the anode electrode, a voltage of 1.53 V is required to achieve overall water splitting at a current density of 10 mA cm-2, gaining exceptional stability for over 300 hours in 1.0 M KOH. This work presents a novel approach for integrating precious metals and non-precious metal material to reduce costs and optimize performance, offering a fresh perspective on the novel combination for water electrolysis.","PeriodicalId":92,"journal":{"name":"Nanoscale","volume":"63 1","pages":""},"PeriodicalIF":6.7,"publicationDate":"2025-05-08","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"143920050","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":3,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
NanoscalePub Date : 2025-05-08DOI: 10.1039/d5nr00717h
Cai-Pan Zhang, Chenjie Zhang, Yaxian Yuan, Jianlin Yao
{"title":"Fabrication on AFM Tips for Tip-Enhanced Raman Spectroscopy by Au Nanoparticles Monolayer Film and Electrodeposition","authors":"Cai-Pan Zhang, Chenjie Zhang, Yaxian Yuan, Jianlin Yao","doi":"10.1039/d5nr00717h","DOIUrl":"https://doi.org/10.1039/d5nr00717h","url":null,"abstract":"The tip-enhanced Raman spectroscopy integrates the high spatial resolution of scanning probe microscopy (SPM) with the remarkable sensitivity on chemical information recognition of surface-enhanced Raman spectroscopy (SERS), enabling simultaneous acquisition of morphological and chemical imaging of samples. It is well known that the quality of tips become the crucial issue of TERS technology. Therefore, the development on the cost-effective and feasible method for fabricating AFM-TERS tips with stable TERS imaging capabilities is high desired. Herein, a facial approach combining the nanoparticles assembly with electrodeposition has been developed to fabricate AFM-TERS tips. The different fabrication recipes were carefully compared to identify the most suitable approach. Utilizing p-nitrobenzenethiol (pNTP) as the probe molecule, the results revealed that annealing treatment, coupled with the electrochemical deposition of additional outer layers of gold, significantly improved the stability and cleanness of the tips. Annealing at 105°C followed by the electrodeposition of a 10 nm outer layer of gold brought tips with a controllable morphology, featuring a radius of curvature (ROC) of approximately 35 nm, and an enhancement factor of roughly 3.2 × 10<small><sup>4</sup></small>. The present results suggested that the approach become one of the promising tools and can be served as a general routine for the cost-effective fabrication of AFM-TERS tips for extending the practical application of TERS technology.","PeriodicalId":92,"journal":{"name":"Nanoscale","volume":"286 1","pages":""},"PeriodicalIF":6.7,"publicationDate":"2025-05-08","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"143920049","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":3,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
NanoscalePub Date : 2025-05-08DOI: 10.1039/d4nr05435k
Youngseul Cho, Se Hun Lee, Yongyeol Park, Tianyu Chen, Kyu Sang Lee, Su Eun Park, Ok Sung Jeon, Dongpyo Hong, Young Pyo Jeon, Young Joon Yoo, Sang Yoon Park, Yuanzhe Piao
{"title":"A rice husk-derived SiOx/C composite for effective lithium-sulfur battery separator modification","authors":"Youngseul Cho, Se Hun Lee, Yongyeol Park, Tianyu Chen, Kyu Sang Lee, Su Eun Park, Ok Sung Jeon, Dongpyo Hong, Young Pyo Jeon, Young Joon Yoo, Sang Yoon Park, Yuanzhe Piao","doi":"10.1039/d4nr05435k","DOIUrl":"https://doi.org/10.1039/d4nr05435k","url":null,"abstract":"Lithium–sulfur (Li–S) batteries offer several advantages including high specific capacity, high energy density, cost-effectiveness, and non-toxicity. However, challenges such as the shuttle effect and low electrical conductivity hinder the reversibility during cycling. Herein, we introduce a sustainable rice husk-derived SiO<small><sub><em>x</em></sub></small>/porous carbon composite (S-MRH) for separator modification in high-performance Li–S batteries. The S-MRH composite, synthesized <em>via</em> a salt-assisted method without toxic chemicals, features amorphous polar SiO<small><sub><em>x</em></sub></small> and porous carbon working synergistically. SiO<small><sub><em>x</em></sub></small> promotes a catalytic effect that suppresses polysulfide dissolution, while porous carbon provides an open conductive network. An S-MRH-coated polypropylene (S-MRH/PP) separator exhibited a high specific capacity of 1507.7 mA h g<small><sup>−1</sup></small> at 0.1C, which is attributed to improved sulfur utilization. Compared to different separators, the S-MRH/PP separator demonstrated a superior rate performance of 766.5 mA h g<small><sup>−1</sup></small> at 3C. Even under high sulfur loading and lean electrolyte conditions, S-MRH/PP exhibited good cycling stability with high capacities. This study highlights the potential of biomass-derived materials in Li–S batteries and offers insights into SiO<small><sub><em>x</em></sub></small>/C synthesis applicable to various energy storage systems.","PeriodicalId":92,"journal":{"name":"Nanoscale","volume":"125 1","pages":""},"PeriodicalIF":6.7,"publicationDate":"2025-05-08","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"143920356","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":3,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
{"title":"A highly-ordered close-packed metallic nanotube array for surface-enhanced Raman scattering","authors":"Ting-Hao Chang, Alfreda Krisna Altama, Jun-Ting Wang, Pakman Yiu, Jinn P. Chu","doi":"10.1039/d4nr05150e","DOIUrl":"https://doi.org/10.1039/d4nr05150e","url":null,"abstract":"This study reports on a rhombic metallic nanotube array (MeNTA) for surface-enhanced Raman scattering (SERS) applications. The close-packed structure of the MeNTA is made of silver and comprises over one hundred million rhombic nanotubes per 1 cm<small><sup>2</sup></small>. The space-efficient arrangement was developed using finite difference time domain simulations, and fabrication was performed using a top-down lithographic method developed for semiconductors, followed by sputtering at room temperature, making it suitable for SERS applications. Scanning electron microscopy images confirmed the highly ordered periodic structure of the rhombic MeNTA substrate. In experiments, the rhombic MeNTAs demonstrated excellent SERS effects in the detection of rhodamine 6G (R6G), crystal violet (CV), folic acid, malachite green, and methyl parathion. The detection limit for R6G was 10<small><sup>−11</sup></small> M, with an enhancement factor of 1.35 × 10<small><sup>8</sup></small> and a relative standard deviation of 6.98%. The detection limit for CV was 10<small><sup>−12</sup></small> M, with an enhancement factor of 3.23 × 10<small><sup>8</sup></small> and a relative standard deviation of 5.92%. The high reproducibility of our findings can be attributed to the uniformly dense distribution of the periodic MeNTA.","PeriodicalId":92,"journal":{"name":"Nanoscale","volume":"37 1","pages":""},"PeriodicalIF":6.7,"publicationDate":"2025-05-08","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"143920048","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":3,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
{"title":"Metal–organic frameworks: a biomimetic odyssey in cancer theranostics","authors":"Soji Soman, Sanjay Kulkarni, Jahnavi Kulkarni, Namdev Dhas, Amrita Arup Roy, Rahul Pokale, Anoushka Mukharya, Srinivas Mutalik","doi":"10.1039/d5nr00794a","DOIUrl":"https://doi.org/10.1039/d5nr00794a","url":null,"abstract":"This review comprehensively explores biomimetic metal–organic frameworks (MOFs) and their significant applications in cancer theranostics. Although MOFs have promising features such as adjustable porosity, improved surface area, and multifunctionality, they are limited by factors like low biocompatibility and specificity. Biomimetic strategies involving biological membranes and materials are proposed to address these challenges. The review begins by examining the unique characteristics and preparation methods of biomimetic carriers used in MOF-based nanoplatforms, with a comparative analysis of each method. It then delves into the various biomedical applications of biomimetic MOFs, including biosensing, bioimaging, immunotherapy, gene therapy, and multimodal therapies. The review also discusses the bio-interaction of these nanoplatforms, including their immunogenicity and interactions with fluids and tissues. Toxicity perspectives are also critically assessed. Overall, the article emphasizes the need for continued research into biomimetic MOFs, highlighting their potential to overcome current obstacles and provide safe, effective, and targeted therapeutic options.","PeriodicalId":92,"journal":{"name":"Nanoscale","volume":"12 1","pages":""},"PeriodicalIF":6.7,"publicationDate":"2025-05-08","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"143920357","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":3,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
{"title":"Sliding ferroelectricity in bilayer phosphorus-analogue compounds: mechanisms and applications","authors":"Dongdong Wang, Xinyi Gao, Yandong Guo, Yuting Guo, Zhipeng Huan, Liyan Lin, Yue Jiang, Zengyun Gu, Hong-Li Zeng, Xiaohong Yan","doi":"10.1039/d5nr00415b","DOIUrl":"https://doi.org/10.1039/d5nr00415b","url":null,"abstract":"Two-dimensional (2D) van der Waals (vdW) ferroelectric structures have attracted much attention due to their superior properties and broad application prospects. For many systems, although there have been plenty of studies on the monolayer ferroelectrics, the bilayer or multilayer ferroelectricity has been rarely investigated. Here, we focus on the sliding ferroelectricity of bilayer <em>α</em>- and <em>β</em>-phase MX (M = Si, Ge, Sn and Pb; X = S, Se and Te) structures. Bilayer <em>α</em>-SiS is found to exhibit a quite large out-of-plane polarization that is not present in the monolayer configuration. Interestingly, the polarization of bilayer <em>β</em>-MX shows a periodic variation with the change of X atoms, where the charge transfer is found to play an important role. Furthermore, both strain and multilayer stacking are found to be able to effectively modulate the polarization. With those structures, field-effect transistors (FETs) are constructed and their performances are found to satisfy the International Technology Roadmap for Semiconductors (ITRS) requirements for the year of 2028. Moreover, four kinds of logic operators are proposed and also demonstrated to operate quite well, showing great application potential. We believe our findings will be quite beneficial to the development of sliding ferroelectrics.","PeriodicalId":92,"journal":{"name":"Nanoscale","volume":"36 1","pages":""},"PeriodicalIF":6.7,"publicationDate":"2025-05-08","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"143920355","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":3,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
{"title":"A Fluorenone-Based Conjugated Polymer Nanoparticle Applied in Drug Delivery with Real-Time Detection (Color Change) via the AILE Mechanism","authors":"Shouhui Huang, Lili Li, Weihao Chen, Shuo Zhu, Tsz Sen Zhu, Genbao Zhu, Bizhu Chu, Xinlong Pang, Yuyang Jiang","doi":"10.1039/d5nr00540j","DOIUrl":"https://doi.org/10.1039/d5nr00540j","url":null,"abstract":"Based on the self-assembly of conjugated polymers (CPs) with paclitaxel constructed as nanoparticles (NPs) with luminescent property of AILE mechanism, a novel type of pH-responsive nanoparticle was developed, featuring a color change that indicated the drug molecule release. The nanoparticles (NPs) characterized by their AILE luminescence were straightforward to prepare, exhibited exceptional stability, and demonstrated a high drug loading capacity and a sensitive drug release profile under acidic conditions. These NPs could release drugs within cellular lysosomes in response to acidic environments, thereby triggering apoptosis in cancer cells. Furthermore, the release of the drug can be monitored by observing changes in fluorescence color, which serves as an indicator signal. Additionally, by investigating the molecular interactions between PFOP-NEt3(+) and paclitaxel, we have proposed a novel mechanism for the induction of AILE luminescence.","PeriodicalId":92,"journal":{"name":"Nanoscale","volume":"95 1","pages":""},"PeriodicalIF":6.7,"publicationDate":"2025-05-07","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"143915773","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":3,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}