Nano Letters最新文献

Heterogenous Integration of Boron-Doped p-Diamond with Monolayer n-MoS2 for PN Junctions Operating at Room Temperature. 室温下掺杂硼的p-金刚石与单层n-MoS2在PN结中的异相集成。

IF 10.8 1区材料科学

Nano Letters Pub Date : 2025-10-03 DOI: 10.1021/acs.nanolett.5c04059

Akshay Wali,Roshan Padhan,Ralu Divan,Liliana Stan,Nihar Pradhan,Anirudha V Sumant

引用次数: 0

Subnanometer Interfacial Hydrodynamics: Spatially Resolved Viscosity and Surface Friction. 亚纳米界面流体力学：空间分辨粘度和表面摩擦。

IF 10.8 1区材料科学

Nano Letters Pub Date : 2025-10-03 DOI: 10.1021/acs.nanolett.5c03950

Shane R Carlson,Roland R Netz

引用次数: 0

Tunable Photodetection Range of GaSb Nanowires for Infrared Spectral Encryption. 用于红外光谱加密的可调GaSb纳米线光探测范围。

IF 10.8 1区材料科学

Nano Letters Pub Date : 2025-10-03 DOI: 10.1021/acs.nanolett.5c03836

Xiaoyue Wang,Zixu Sa,Zhenkai Yang,Kaixing Zhu,Yanxue Yin,Sukjoon Hong,Feng Chen,Zai-Xing Yang

引用次数: 0

Integrated Thermal-Wet Comfort Textile of Bioinspired Sweat Transportation and Triboelectric Evaporation for Personal Perspiration Management. 集成热湿舒适纺织品的生物灵感汗运输和摩擦电蒸发个人排汗管理。

IF 10.8 1区材料科学

Nano Letters Pub Date : 2025-10-03 DOI: 10.1021/acs.nanolett.5c04151

Maorong Zheng,Jiayin Yang,Bin Wang,Yalin Dong,Liming Wang,Hongnan Zhang,Xiaohong Qin

引用次数: 0

Tuning Triplet Exciton Pathways via Molecular Aggregation in a Family of Coordination Polymers. 通过配位聚合物家族中的分子聚集调节三重态激子途径。

IF 10.8 1区材料科学

Nano Letters Pub Date : 2025-10-03 DOI: 10.1021/acs.nanolett.5c03866

Rui Feng,Zi-Ying Li,Shi-Shuang Huang,Mei-Hui Yu,Fengxia Wei,Jingwei Hou,Wei Li,Xian-He Bu

{"title":"Tuning Triplet Exciton Pathways via Molecular Aggregation in a Family of Coordination Polymers.","authors":"Rui Feng,Zi-Ying Li,Shi-Shuang Huang,Mei-Hui Yu,Fengxia Wei,Jingwei Hou,Wei Li,Xian-He Bu","doi":"10.1021/acs.nanolett.5c03866","DOIUrl":"https://doi.org/10.1021/acs.nanolett.5c03866","url":null,"abstract":"Molecular aggregation is the key factor in determining the triplet exciton pathways of room-temperature phosphorescence (RTP) materials; however, controlling different aggregation forms and understanding their synergistic effects remain challenging. In this work, we report three coordination polymers (CPs) with cofacial translational stacking (H-aggregation), cofacial-staggered translational stacking (H-J aggregation) and cofacial translational-crossing stacking (H-X aggregation): [Zn(3,4-PyDC)(TPT)]·TPT (1; 3,4-PyDC = 3,4-pyridinedicarboxylate; TPT = 2,4,6-tri(4-pyridyl)-1,3,5-triazine), [Zn(IPA)(TPT)2]·H2O (2; IPA = isophthalate) and [Zn3(3,5-PyC)2(TPT)3(H2O)2] (3; 3,5-PyC = 3,5-pyrazoledicarboxylate). By changing the aggregation modes, these CPs exhibit tunable triplet exciton pathways, enabling distinct fluorescent, phosphorescent, and photochromic properties. Single-crystal X-ray diffraction, time-resolved emission spectroscopy and theoretical analysis demonstrate that enhanced charge migration in 2 with H-J aggregation promotes charge-separated photochromism, while differentiated orbital energies in 3 with H-X aggregation enables wavelength-responsive room temperature phosphorescence. These findings provide a route to hybrid CPs with designated triplet-exciton pathways and associated optical properties by manipulating molecular aggregation.","PeriodicalId":53,"journal":{"name":"Nano Letters","volume":"114 1","pages":""},"PeriodicalIF":10.8,"publicationDate":"2025-10-03","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"145209175","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":1,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

引用次数: 0

Chirality-Dependent Orbital Bulk Photovoltaic Effect in a 1D Helical Nanowire. 一维螺旋纳米线中手性相关的轨道体光伏效应。

IF 10.8 1区材料科学

Nano Letters Pub Date : 2025-10-03 DOI: 10.1021/acs.nanolett.5c03640

Lei Yang,Zhikuan Wang,Chuanhui Chen,Jinming Dong,Dongmei Li,Bing Huang,Desheng Liu,Bin Cui

引用次数: 0

High-Throughput First-Principles Design of van der Waals Stabilized Two-Dimensional Metals in Hexagonal Boron Nitride Sandwich Heterostructures. 六方氮化硼夹层结构中范德华稳定二维金属的高通量第一性原理设计。

IF 10.8 1区材料科学

Nano Letters Pub Date : 2025-10-02 DOI: 10.1021/acs.nanolett.5c04198

Qian Zhang,Lizhou Yang,Chuanjing Zeng,Jirui Lv,Jinlong Yang,Wei Hu

引用次数: 0

Temperature-Induced Morphology Control of Fe-Polydopamine Coordination Complexes and Their Derivatives for Energy Storage Applications. 铁-聚多巴胺配合物及其衍生物的温度诱导形态控制及其储能应用。

IF 10.8 1区材料科学

Nano Letters Pub Date : 2025-10-02 DOI: 10.1021/acs.nanolett.5c03768

Incheol Heo,Min Seok Kang,Jaeseong Kim,Chanyoung Lee,Hee Soo Kim,Dong-Ha Lim,Won Cheol Yoo

{"title":"Temperature-Induced Morphology Control of Fe-Polydopamine Coordination Complexes and Their Derivatives for Energy Storage Applications.","authors":"Incheol Heo,Min Seok Kang,Jaeseong Kim,Chanyoung Lee,Hee Soo Kim,Dong-Ha Lim,Won Cheol Yoo","doi":"10.1021/acs.nanolett.5c03768","DOIUrl":"https://doi.org/10.1021/acs.nanolett.5c03768","url":null,"abstract":"Controlling the morphology of organic-inorganic complexes at the nanometer scale is crucial for electrochemical applications. We present a novel method for controlling Fe-polydopamine (Fe-PD) coordination complexes into rod, urchin, and hollow structures at high (80-90 °C), medium (40-60 °C), and low (0-10 °C) synthesis temperatures, respectively. Morphological evolution was driven by the balance between oriented and random polymerization pathways, with hollow structures formed through random growth followed by selective inner-core etching. H- and U-Fe-PDs were converted to H- and U-Fe@C composites after carbonization. H-Fe@C exhibited superior performance in lithium-metal anodes, achieving stable cycling for over 2500 h with exceptional overpotentials as low as 7.4 mV and 76% capacity retention after 1000 cycles, significantly outperforming U-Fe@C due to enhanced mass transport through the thin carbon shell (∼50 nm). This temperature-controlled strategy provides a versatile approach for designing morphology-driven materials for advanced energy storage.","PeriodicalId":53,"journal":{"name":"Nano Letters","volume":"76 1","pages":""},"PeriodicalIF":10.8,"publicationDate":"2025-10-02","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"145203585","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":1,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

引用次数: 0

Multivalent Metal–Nucleotide Nanoagonists Amplify Innate Immune Activation for Cancer Metalloimmunotherapy 多价金属核苷酸纳米激动剂增强肿瘤金属免疫治疗的先天免疫激活

IF 10.8 1区材料科学

Nano Letters Pub Date : 2025-10-02 DOI: 10.1021/acs.nanolett.5c04265

Yanjuan Huang, Yike Li, Ziwei Han, Jinqi Deng, Shaokun Dong, Wenxing Lv, Chao Liu, Lele Li, Shuo Wan, Jiashu Sun

{"title":"Multivalent Metal–Nucleotide Nanoagonists Amplify Innate Immune Activation for Cancer Metalloimmunotherapy","authors":"Yanjuan Huang, Yike Li, Ziwei Han, Jinqi Deng, Shaokun Dong, Wenxing Lv, Chao Liu, Lele Li, Shuo Wan, Jiashu Sun","doi":"10.1021/acs.nanolett.5c04265","DOIUrl":"https://doi.org/10.1021/acs.nanolett.5c04265","url":null,"abstract":"Metalloimmunotherapy represents a new paradigm in cancer immunotherapy by leveraging the immune-modulatory functions of metal ions, either alone or in combination with agonists. However, the low bioavailability of free metal ions and agonists limits robust stimulation of antitumor immune responses. Here we developed multivalent metal–nucleotide nanoagonists (Mn-MNAs) through aqueous coordination of multiple nucleotide-based innate immune agonists with Fe<sup>2+</sup> and Mn<sup>2+</sup>, which not only enhanced the stability and cellular uptake of the agonists but also amplified the antitumor immunity by concurrently activating the stimulator of interferon genes (STING) and toll-like receptor 9 (TLR9) pathways. Intratumoral injection of Mn-MNAs significantly inhibited tumor growth and fostered an immune-supportive tumor microenvironment in the CT26 tumor model. Intravenous administration of Mn-MNAs achieved remarkable therapeutic efficacy in the B16F10 melanoma model, which was further enhanced upon combination with a checkpoint blockade. Overall, multivalent nanoagonists open new avenues for cancer metalloimmunotherapy.","PeriodicalId":53,"journal":{"name":"Nano Letters","volume":"11 1","pages":""},"PeriodicalIF":10.8,"publicationDate":"2025-10-02","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"145209671","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":1,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

引用次数: 0

Engineering Low-Coordinated Pt Sites through Supported Polyhedral Nanoparticles for Enhanced Low-Temperature Toluene Catalytic Oxidation. 通过负载多面体纳米颗粒工程低协调Pt位点增强低温甲苯催化氧化。

IF 10.8 1区材料科学

Nano Letters Pub Date : 2025-10-02 DOI: 10.1021/acs.nanolett.5c04170

Xiangwei Zhang,Qingze Chen,Haoyang Fu,Peng Liu,Jieyang Xie,Xun Geng,Zhihao Lei,Shuzhou Li,Runliang Zhu

{"title":"Engineering Low-Coordinated Pt Sites through Supported Polyhedral Nanoparticles for Enhanced Low-Temperature Toluene Catalytic Oxidation.","authors":"Xiangwei Zhang,Qingze Chen,Haoyang Fu,Peng Liu,Jieyang Xie,Xun Geng,Zhihao Lei,Shuzhou Li,Runliang Zhu","doi":"10.1021/acs.nanolett.5c04170","DOIUrl":"https://doi.org/10.1021/acs.nanolett.5c04170","url":null,"abstract":"Engineering low-coordinated Pt sites represents a promising strategy to boost catalysis, yet their precise control to optimize structure-activity relationships for volatile organic compounds oxidation remains challenging. Herein, we achieved abundant low-coordinated Pt sites by constructing highly dispersed and well-defined polyhedral Pt nanoparticles on a porous silica support (Pt-APSiO2) for toluene oxidation. The amino-functionalized silica provides coordination environments for [PtCl6]2- precursors that regulate the reduction kinetics to favor polyhedral morphology formation. The resulting Pt-APSiO2 catalyst showed exceptional performance in toluene oxidation with an extremely low T90 of 148 °C. Structural characterization revealed that the polyhedral Pt nanoparticles possessed a reduced coordination number of 7.38, leading to an upward shift in the d-band center to -1.88 eV. This shifts endowed Pt sites with stronger adsorption and activation for both toluene and O2. This work demonstrates the feasibility of morphology-directed synthesis for tailoring active site coordination environments, advancing rational design principles for environmental catalysis.","PeriodicalId":53,"journal":{"name":"Nano Letters","volume":"6 1","pages":""},"PeriodicalIF":10.8,"publicationDate":"2025-10-02","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"145203480","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":1,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

引用次数: 0