Chemical Society Reviews最新文献

{"title":"Navigating the transitional window for organic semiconductor single crystals towards practical integration: from materials, crystallization, and technologies to real-world applications","authors":"Xianshuo Wu, Xiaoting Zhu, Lingjie Sun, Shihan Zhang, Yiwen Ren, Zhaofeng Wang, Xiaotao Zhang, Fangxu Yang, Hao-Li Zhang, Wenping Hu","doi":"10.1039/d4cs00987h","DOIUrl":"https://doi.org/10.1039/d4cs00987h","url":null,"abstract":"Organic semiconductor single crystals (OSSCs), which possess the inherent merits of long-range order, low defect density, high mobility, structural tunability and good flexibility, have garnered significant attention in the organic optoelectronic community. Past decades have witnessed the explosive growth of OSSCs. Despite numerous conceptual demonstrations, OSSCs remain in the early stages of implementation for applications that require high integration and multifunctionality. The commercialization trend of organic optoelectronic devices is driving the development of highly integrated OSSCs. Therefore, timely tracking of material requirements, crystallization demands, and key technologies for high integration, along with exploring their limitations and potential pathways, will provide critical guidance during this pivotal transition period. From the perspective of materials properties, multifunctional materials, such as ambipolar charge transport materials, high mobility emission materials and others, aiming at high integration, deserve our attention, and the material design rules are carefully discussed in the first section. Following this, we delve into the controllable growth of large-scale OSSCs based on crystallization thermodynamics and kinetics. Key technologies for achieving high integration are then discussed, with an emphasis on methods for growing wafer-scale organic single crystals and patterning single crystalline arrays. Subsequently, we outline the cutting-edge optoelectronic applications based on OSSCs, including organic logic circuits, electroluminescent displays, and image sensors. Moreover, explicitly recognizing as yet limitations and prospects on the road to ‘lab-to-fab’ transitions for OSSCs is crucial. Thus, we conclude by offering an objective assessment of key limitations and potential, encompassing aspects such as uniformity, integration density, stability, and driving capability, providing an instructive projection for future advancements.","PeriodicalId":68,"journal":{"name":"Chemical Society Reviews","volume":"27 1","pages":""},"PeriodicalIF":46.2,"publicationDate":"2024-12-24","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"142880030","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":1,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

{"title":"Surface-enhanced Raman spectroscopy: a half-century historical perspective","authors":"Jun Yi, En-Ming You, Ren Hu, De-Yin Wu, Guo-Kun Liu, Zhi-Lin Yang, Hua Zhang, Yu Gu, Yao-Hui Wang, Xiang Wang, Hao Ma, Yang Yang, Jun-Yang Liu, Feng Ru Fan, Chao Zhan, Jing-Hua Tian, Yu Qiao, Hailong Wang, Si-Heng Luo, Zhao-Dong Meng, Bing-Wei Mao, Jian-Feng Li, Bin Ren, Javier Aizpurua, Vartkess Ara Apkarian, Philip N. Bartlett, Jeremy Baumberg, Steven E. J. Bell, Alexandre G. Brolo, Louis E. Brus, Jaebum Choo, Li Cui, Volker Deckert, Katrin F. Domke, Zhen-Chao Dong, Sai Duan, Karen Faulds, Renee Frontiera, Naomi Halas, Christy Haynes, Tamitake Itoh, Janina Kneipp, Katrin Kneipp, Eric C. Le Ru, Zhi-Peng Li, Xing Yi Ling, Jacek Lipkowski, Luis M. Liz-Marzán, Jwa-Min Nam, Shuming Nie, Peter Nordlander, Yukihiro Ozaki, Rajapandiyan Panneerselvam, Jürgen Popp, Andrea E. Russell, Sebastian Schlücker, Yang Tian, Lianming Tong, Hongxing Xu, Yikai Xu, Liangbao Yang, Jianlin Yao, Jin Zhang, Yang Zhang, Yao Zhang, Bing Zhao, Renato Zenobi, George C. Schatz, Duncan Graham, Zhong-Qun Tian","doi":"10.1039/d4cs00883a","DOIUrl":"https://doi.org/10.1039/d4cs00883a","url":null,"abstract":"Surface-enhanced Raman spectroscopy (SERS) has evolved significantly over fifty years into a powerful analytical technique. This review aims to achieve five main goals. (1) Providing a comprehensive history of SERS's discovery, its experimental and theoretical foundations, its connections to advances in nanoscience and plasmonics, and highlighting collective contributions of key pioneers. (2) Classifying four pivotal phases from the view of innovative methodologies in the fifty-year progression: initial development (mid-1970s to mid-1980s), downturn (mid-1980s to mid-1990s), nano-driven transformation (mid-1990s to mid-2010s), and recent boom (mid-2010s onwards). (3) Illuminating the entire journey and framework of SERS and its family members such as tip-enhanced Raman spectroscopy (TERS) and shell-isolated nanoparticle-enhanced Raman spectroscopy (SHINERS) and highlighting the trajectory. (4) Emphasizing the importance of innovative methods to overcome developmental bottlenecks, thereby expanding the material, morphology, and molecule generalities to leverage SERS as a versatile technique for broad applications. (5) Extracting the invaluable spirit of groundbreaking discovery and perseverant innovations from the pioneers and trailblazers. These key inspirations include proactively embracing and leveraging emerging scientific technologies, fostering interdisciplinary cooperation to transform the impossible into reality, and persistently searching to break bottlenecks even during low-tide periods, as luck is what happens when preparation meets opportunity.","PeriodicalId":68,"journal":{"name":"Chemical Society Reviews","volume":"23 1","pages":""},"PeriodicalIF":46.2,"publicationDate":"2024-12-23","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"142880035","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":1,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

{"title":"Heteroatomic molecules for coordination engineering towards advanced Pb-free Sn-based perovskite photovoltaics.","authors":"Weiyin Gao, Rui Huang, He Dong, Wangyue Li, Zhongbin Wu, Yonghua Chen, Chenxin Ran","doi":"10.1039/d4cs00838c","DOIUrl":"https://doi.org/10.1039/d4cs00838c","url":null,"abstract":"<p><p>As an ideal eco-friendly Pb-free optoelectronic material, Sn-based perovskites have made significant progress in the field of photovoltaics, and the highest power conversion efficiency (PCE) of Sn-based perovskite solar cells (PSCs) has been currently approaching 16%. In the course of development, various strategies have been proposed to improve the PCE and stability of Sn-based PSCs by solving the inherent problems of Sn²⁺, including high Lewis acidity and easy oxidation. Notably, the recent breakthrough comes from the development of heteroatomic coordination molecules to control the characteristics of Sn-based perovskites, which are considered to be vital for realizing efficient PSCs. In this review, the up-to-date advances in the design of heteroatomic molecules and their key functions in the fabrication of Sn-based perovskite films are comprehensively summarized. Firstly, the design principles of heteroatomic coordination molecules and their impact on the colloidal chemistry, crystallization dynamics, and defect properties of Sn-based perovskites are introduced. Then, state-of-the-art heteroatomic coordination molecules for efficient Sn-based PSCs are discussed in terms of their heteroatom types and functional groups. Lastly, we shed some light on the current challenges and future perspectives regarding the rational design of heteroatomic coordination molecules for further boosting the performance of Sn-based PSCs.</p>","PeriodicalId":68,"journal":{"name":"Chemical Society Reviews","volume":" ","pages":""},"PeriodicalIF":40.4,"publicationDate":"2024-12-23","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"142875510","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":1,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

{"title":"Recent advances and design strategies for organic afterglow agents to enhance autofluorescence-free imaging performance.","authors":"Jieli Zhu, Liangyou Zhao, Weihao An, Qingqing Miao","doi":"10.1039/d4cs01060d","DOIUrl":"https://doi.org/10.1039/d4cs01060d","url":null,"abstract":"<p><p>Long-lasting afterglow luminescence imaging that detects photons slowly being released from chemical defects has emerged, eliminating the need for real-time photoexcitation and enabling autofluorescence-free <i>in vivo</i> imaging with high signal-to-background ratios (SBRs). Organic afterglow nano-systems are notable for their tunability and design versatility. However, challenges such as unsatisfactory afterglow intensity, short emission wavelengths, limited activatable strategies, and shallow tissue penetration depth hinder their widespread biomedical applications and clinical translation. Such contradiction between promising prospects and insufficient properties has spurred researchers' efforts to improve afterglow performance. In this review, we briefly outline the general composition and mechanisms of organic afterglow luminescence, with a focus on design strategies and an in-depth understanding of the structure-property relationship to advance afterglow luminescence imaging. Furthermore, pending issues and future perspectives are discussed.</p>","PeriodicalId":68,"journal":{"name":"Chemical Society Reviews","volume":" ","pages":""},"PeriodicalIF":40.4,"publicationDate":"2024-12-23","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"142875446","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":1,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

{"title":"From text to insight: large language models for chemical data extraction","authors":"Mara Schilling-Wilhelmi, Martiño Ríos-García, Sherjeel Shabih, María Victoria Gil, Santiago Miret, Christoph T. Koch, José A. Márquez, Kevin Maik Jablonka","doi":"10.1039/d4cs00913d","DOIUrl":"https://doi.org/10.1039/d4cs00913d","url":null,"abstract":"The vast majority of chemical knowledge exists in unstructured natural language, yet structured data is crucial for innovative and systematic materials design. Traditionally, the field has relied on manual curation and partial automation for data extraction for specific use cases. The advent of large language models (LLMs) represents a significant shift, potentially enabling non-experts to extract structured, actionable data from unstructured text efficiently. While applying LLMs to chemical and materials science data extraction presents unique challenges, domain knowledge offers opportunities to guide and validate LLM outputs. This tutorial review provides a comprehensive overview of LLM-based structured data extraction in chemistry, synthesizing current knowledge and outlining future directions. We address the lack of standardized guidelines and present frameworks for leveraging the synergy between LLMs and chemical expertise. This work serves as a foundational resource for researchers aiming to harness LLMs for data-driven chemical research. The insights presented here could significantly enhance how researchers across chemical disciplines access and utilize scientific information, potentially accelerating the development of novel compounds and materials for critical societal needs.","PeriodicalId":68,"journal":{"name":"Chemical Society Reviews","volume":"27 1","pages":""},"PeriodicalIF":46.2,"publicationDate":"2024-12-20","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"142858162","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":1,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

{"title":"Mixed-valence metal–organic frameworks: concepts, opportunities, and prospects","authors":"Farzaneh Afshariazar, Ali Morsali","doi":"10.1039/d4cs01061b","DOIUrl":"https://doi.org/10.1039/d4cs01061b","url":null,"abstract":"Owing to increasing global demand for the development of multifunctional advanced materials with various practical applications, great attention has been paid to metal–organic frameworks due to their unique properties, such as structural, chemical, and functional diversity. Several strategies have been developed to promote the applicability of these materials in practical fields. The induction of mixed-valency is a promising strategy, contributing to exceptional features in these porous materials such as enhanced charge delocalization, conductivity, magnetism, <em>etc.</em> The current review provides a detailed study of mixed-valence MOFs, including their fundamental properties, synthesis challenges, and characterization methods. The outstanding applicability of these materials in diverse fields such as energy storage, catalysis, sensing, gas sorption, separation, <em>etc.</em> is also discussed, providing a roadmap for future design strategies to exploit mixed valency in advanced materials. Interestingly, mixed-valence MOFs have demonstrated fascinating features in practical fields compared to their homo-valence MOFs, resulting from an enhanced synergy between mixed-valence states within the framework.","PeriodicalId":68,"journal":{"name":"Chemical Society Reviews","volume":"76 1","pages":""},"PeriodicalIF":46.2,"publicationDate":"2024-12-20","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"142858161","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":1,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

{"title":"Catalysis under electric-/magnetic-/electromagnetic-field coupling","authors":"Canyu Hu, Yueyue Dong, Qianqi Shi, Ran Long, Yujie Xiong","doi":"10.1039/d4cs00869c","DOIUrl":"https://doi.org/10.1039/d4cs00869c","url":null,"abstract":"The ultimate goal of catalysis is to control the cleavage and formation of chemical bonds at the molecular or even atomic level, enabling the customization of catalytic products. The essence of chemical bonding is the electromagnetic interaction between atoms, which makes it possible to directly manipulate the dynamic behavior of molecules and electrons in catalytic processes using external electric, magnetic and electromagnetic fields. In this tutorial review, we first introduce the feasibility and importance of field effects in regulating catalytic reaction processes and then outline the basic principles of electric-/magnetic-/electromagnetic-field interaction with matter, respectively. In each section, we further summarize the relevant important advances from two complementary perspectives: the macroscopic molecular motion (including translation, vibration and rotation) and the microscopic intramolecular electron state alteration (including spin polarization, transfer or excitation, and density of states redistribution). Finally, we discuss the challenges and opportunities for further development of catalysis under electric-/magnetic-/electromagnetic-field coupling.","PeriodicalId":68,"journal":{"name":"Chemical Society Reviews","volume":"88 1","pages":""},"PeriodicalIF":46.2,"publicationDate":"2024-12-19","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"142849328","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":1,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

{"title":"N-Heterocyclic carbene (NHC) organocatalysis: from fundamentals to frontiers","authors":"Sukriyo Chakraborty, Soumen Barik, Akkattu T. Biju","doi":"10.1039/d4cs01179a","DOIUrl":"https://doi.org/10.1039/d4cs01179a","url":null,"abstract":"N-Heterocyclic carbenes (NHCs) have been used as organocatalysts for a multitude of C–C and C–heteroatom bond-forming reactions. They enable diverse modalities of activating a wide range of structurally distinct substrate classes and allow access to electronically distinct intermediates. The easy tunability of the NHC scaffold contributes to its versatility. Recent years have witnessed a surge of interest in various organocatalytic reactions of NHCs, leading to the forays of NHC catalysis into the relatively newer domains such as reactions involving radical intermediates, atroposelective synthesis, umpolung of electrophiles other than aldehydes, and the use of NHCs as non-covalent templates for enantioinduction. This tutorial review provides an overview of various important structural features and reactivity modes of NHCs and delves deep into some frontiers of NHC-organocatalysis.","PeriodicalId":68,"journal":{"name":"Chemical Society Reviews","volume":"24 1","pages":""},"PeriodicalIF":46.2,"publicationDate":"2024-12-18","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"142841658","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":1,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

{"title":"Toward synergetic reduction of pollutant and greenhouse gas emissions from vehicles: a catalysis perspective","authors":"Yan Zhang, Jinpeng Du, Yulong Shan, Fei Wang, Jingjing Liu, Meng Wang, Zhi Liu, Yong Yan, Guangyan Xu, Guangzhi He, Xiaoyan Shi, Zhihua Lian, Yunbo Yu, Wenpo Shan, Hong He","doi":"10.1039/d4cs00140k","DOIUrl":"https://doi.org/10.1039/d4cs00140k","url":null,"abstract":"It is a great challenge for vehicles to satisfy the increasingly stringent emission regulations for pollutants and greenhouse gases. Throughout the history of the development of vehicle emission control technology, catalysts have always been in the core position of vehicle aftertreatment. Aiming to address the significant demand for synergistic control of pollutants and greenhouse gases from vehicles, this review provides a panoramic view of emission control technologies and key aftertreatment catalysts for vehicles using fossil fuels (gasoline, diesel, and natural gas) and carbon-neutral fuels (hydrogen, ammonia, and green alcohols). Special attention will be given to the research advancements in catalysts, including three-way catalysts (TWCs), NO<small>_<em>x</em></small> selective catalytic reduction (SCR) catalysts, NO<small>_<em>x</em></small> storage-reduction (NSR) catalysts, diesel oxidation catalysts (DOCs), soot oxidation catalysts, ammonia slip catalysts (ASCs), methane oxidation catalysts (MOCs), N<small>₂</small>O abatement catalysts (DeN<small>₂</small>O), passive NO<small>_<em>x</em></small> adsorbers (PNAs), and cold start catalysts (CSCs). The main challenges for industrial applications of these catalysts, such as insufficient low-temperature activity, product selectivity, hydrothermal stability, and poisoning resistance, will be examined. In addition, the future development of synergistic control of vehicle pollutants and greenhouse gases will be discussed from a catalysis perspective.","PeriodicalId":68,"journal":{"name":"Chemical Society Reviews","volume":"30 1","pages":""},"PeriodicalIF":46.2,"publicationDate":"2024-12-17","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"142831932","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":1,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

{"title":"Interface engineering for photoelectrochemical oxygen evolution reaction","authors":"Yequan Xiao, Jie Fu, Yuriy Pihosh, Keshab Karmakar, Beibei Zhang, Kazunari Domen, Yanbo Li","doi":"10.1039/d4cs00309h","DOIUrl":"https://doi.org/10.1039/d4cs00309h","url":null,"abstract":"Photoelectrochemical (PEC) water splitting provides a promising approach for solving sustainable energy challenges and achieving carbon neutrality goals. The oxygen evolution reaction (OER), a key bottleneck in the PEC water-splitting system occurring at the photoanode/electrolyte interface, plays a fundamental role in sustainable solar fuel production. Proper surface or interface engineering strategies have been proven to be necessary to achieve efficient and stable PEC water oxidation. This review summarizes the recent advances in interface engineering, including junction formation, surface doping, surface passivation or protection, surface sensitization, and OER cocatalyst modification, while highlighting the remarkable research achievements in the field of PEC water splitting. The benefits of each interface engineering strategy and how it enhances the device performance are critically analyzed and compared. Finally, the outlook for the development of interface engineering for efficient PEC water splitting is briefly discussed. This review illustrates the importance of employing rational interface engineering in realizing efficient and stable PEC water splitting devices.","PeriodicalId":68,"journal":{"name":"Chemical Society Reviews","volume":"1 1","pages":""},"PeriodicalIF":46.2,"publicationDate":"2024-12-16","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"142825658","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":1,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}