Chemical Society Reviews最新文献

Scanning probe microscopy of metal–organic coordination systems: characterization of monolayers, single crystals, discrete architectures 金属-有机配位系统的扫描探针显微镜：单层，单晶，离散结构的表征

IF 46.2 1区化学

Chemical Society Reviews Pub Date : 2025-10-02 DOI: 10.1039/d4cs01303d

Antonino Cucinotta, Jack A. Davies, Kunal S. Mali, Steven De Feyter

{"title":"Scanning probe microscopy of metal–organic coordination systems: characterization of monolayers, single crystals, discrete architectures","authors":"Antonino Cucinotta, Jack A. Davies, Kunal S. Mali, Steven De Feyter","doi":"10.1039/d4cs01303d","DOIUrl":"https://doi.org/10.1039/d4cs01303d","url":null,"abstract":"Metal–organic coordination is omnipresent in a number of functional materials. Such systems are highly diverse in terms of their composition, complexity, and dimensionality. They include two-dimensional (2D) and three-dimensional (3D) structures ranging from monolayers of metal–organic coordination networks (MOCNs) physisorbed on solid surfaces, to crystalline metal–organic frameworks (MOFs), to discrete metallosupramolecular architectures (DMSAs). The use of these metal–organic materials in a wide variety of applications has been demonstrated, showing promise for their incorporation into emerging technologies. Several design strategies have been developed for the fabrication of MOCNs, MOFs, and DMSAs exhibiting a diverse array of structures, enabling precise control over their functional properties. As these strategies are designed at the molecular level, there has been considerable interest in the nanoscale resolution imaging of metal–organic coordination systems across different length scales. This review provides a glimpse of recent progress in the nanoscale characterization of metal–organic coordination systems using scanning probe microscopy (SPM). Systems ranging from surface-confined MOCN monolayers, to MOF thin films, surfaces of MOF single crystals, and DMSAs are discussed. Specifically, we discuss the contribution of scanning tunneling microscopy (STM), atomic force microscopy (AFM), and techniques that combine SPM with spectroscopic methods to obtain high-resolution chemical information, toward the nanoscale structural characterization of multinuclear metal–organic assemblies.","PeriodicalId":68,"journal":{"name":"Chemical Society Reviews","volume":"114 1","pages":""},"PeriodicalIF":46.2,"publicationDate":"2025-10-02","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"145203650","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":1,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

引用次数: 0

Spin-engineered catalysts: unlocking new frontiers in environmental and energy catalysis applications 自旋工程催化剂：解锁环境和能源催化应用的新领域

IF 46.2 1区化学

Chemical Society Reviews Pub Date : 2025-10-02 DOI: 10.1039/d5cs00216h

Bofan Zhang, Zhengyang Tong, Junhu Wang, Shiro Kubuki, Liang Zhang, Jia-Nan Zhang

{"title":"Spin-engineered catalysts: unlocking new frontiers in environmental and energy catalysis applications","authors":"Bofan Zhang, Zhengyang Tong, Junhu Wang, Shiro Kubuki, Liang Zhang, Jia-Nan Zhang","doi":"10.1039/d5cs00216h","DOIUrl":"https://doi.org/10.1039/d5cs00216h","url":null,"abstract":"Environmental catalysis is pivotal in addressing pollution and advancing energy conversion technologies. Spin, an intrinsic particle property of a material, significantly influences catalytic reactions by altering the electronic structure of active sites, radical reactions, and electron transfer behavior, all of which impact reaction selectivity and mechanisms. Understanding the spin properties within advanced materials is essential for elucidating the structure–activity relationships between the spin characteristics and the catalytic mechanism. This review begins by outlining the fundamental concepts and parameters associated with spin. It provides a comprehensive overview of the primary techniques and methodologies employed to characterize spin properties and strategies for modulating spin alignment through external fields and internal structural adjustments. The discussion then progresses to examine how spin characteristics influence various aspects of environmental catalysis, including reaction kinetics, thermodynamics, stability, pathways, and mechanisms of catalysis. In the concluding sections, the authors highlight the current challenges in applying spin concepts to environmental catalysis and propose recommendations to address these obstacles, while outlining potential directions for future research. Exploring spin properties can unveil the core mechanisms of environmental catalytic processes and facilitate the design of more efficient spin engineered catalysts, advancing the frontiers of catalytic applications and progress in environmental and energy sciences.","PeriodicalId":68,"journal":{"name":"Chemical Society Reviews","volume":"19 1","pages":""},"PeriodicalIF":46.2,"publicationDate":"2025-10-02","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"145203550","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":1,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

引用次数: 0

Sustainable perovskite light emitters 可持续钙钛矿发光体

IF 46.2 1区化学

Chemical Society Reviews Pub Date : 2025-10-01 DOI: 10.1039/d5cs00620a

Yuxin Shi, Seong Eui Chang, Tae-Woo Lee

引用次数: 0

An AI-accelerated pathway for reproducible and stable halide perovskites 人工智能加速再生和稳定卤化物钙钛矿的途径

IF 46.2 1区化学

Chemical Society Reviews Pub Date : 2025-09-30 DOI: 10.1039/d5cs00715a

Abigail R. Hering, Carolin M. Sutter-Fella, Marina S. Leite

{"title":"An AI-accelerated pathway for reproducible and stable halide perovskites","authors":"Abigail R. Hering, Carolin M. Sutter-Fella, Marina S. Leite","doi":"10.1039/d5cs00715a","DOIUrl":"https://doi.org/10.1039/d5cs00715a","url":null,"abstract":"Halide perovskites (HPs) have remarkable optoelectronic properties, and in the last decade their photovoltaic power conversion efficiency and light-emitting diode efficiency have skyrocketed. Despite the surge in research on these burgeoning materials, two key challenges in the field remain: material irreproducibility and instability. Their behavior is especially dynamic in response to environmental stressors, due to complex interactions with the perovskite crystal lattice. In this review, we survey the latest achievements in HP materials research accomplished with the assistance of artificial intelligence (AI), through the implementation of automated experimentation and machine learning (ML) data analysis. Automated synthesis and characterization tackle problems with material irreproducibility by systematically controlling parameters with very high precision, creating massive datasets, and allowing methodical comparisons from which unbiased conclusions can be drawn. AI can reveal otherwise unnoticed trends, inform future experiments with the highest potential information gain, and forecast future performance. The review concludes with a forward viewpoint of how human-assisted closed-loop laboratories and shared databases allow halide perovskite materials’ processing, properties, and performance to be potentially optimized with AI, accelerating the development of highly reproducible and stable optoelectronic devices.","PeriodicalId":68,"journal":{"name":"Chemical Society Reviews","volume":"49 1","pages":""},"PeriodicalIF":46.2,"publicationDate":"2025-09-30","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"145189244","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":1,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

引用次数: 0

Interactions of nanoparticles with living and synthetic bio-membrane 纳米粒子与生物膜和合成生物膜的相互作用

IF 46.2 1区化学

Chemical Society Reviews Pub Date : 2025-09-30 DOI: 10.1039/d5cs00841g

Rashad Kariuki, Kalpani A. Mirihana, Rowan Penman, Andrew Hung, Nastaran Meftahi, Gary Bryant, Paul A. Ramsland, Kislon Voïtchovsky, Charlotte E. Conn, Claudia Contini, Saffron J. Bryant, Andrew J. Christofferson, Aaron Elbourne

{"title":"Interactions of nanoparticles with living and synthetic bio-membrane","authors":"Rashad Kariuki, Kalpani A. Mirihana, Rowan Penman, Andrew Hung, Nastaran Meftahi, Gary Bryant, Paul A. Ramsland, Kislon Voïtchovsky, Charlotte E. Conn, Claudia Contini, Saffron J. Bryant, Andrew J. Christofferson, Aaron Elbourne","doi":"10.1039/d5cs00841g","DOIUrl":"https://doi.org/10.1039/d5cs00841g","url":null,"abstract":"Interactions between nanomaterials and biointerfaces are of great interest across many research fields, including chemistry, physics, engineering, and biology, with applications from diagnostics to therapeutics, and in drug delivery systems. By tailoring nanomaterial properties via functionalisation, their efficacy can be enhanced for a variety of biomedical scenarios. Nanomaterial-based therapeutics, diagnostics, and theranostics display a common need to interact with biological tissue, i.e., they must make contact with, and often transverse, the external membrane of a cell or organism to elicit the desired response. As such, understanding nanoparticle (NP)–bio-membrane interactions is paramount to designing and optimising nanoparticle-based therapies and technologies for biological applications. Historically, in vivo investigations have proven to be challenging due to the complexity and intricate interactions involved with complete cell membranes. This has led researchers to employ model bio-membranes, which can be investigated using a range of in vitro experimental and theoretical techniques, to isolate the underpinning interaction mechanisms of NPs at the bio-interface. This review aims to unify the current literature regarding the biophysical interactions between inorganic and organic NPs and bio-membrane interfaces, including living and synthetic systems. The article will explore the role of membrane composition, NP morphology and chemistry, and the forces involved in interactions between the two entities. Identifying the fundamental influences of NP–membrane interactions, primarily synthetic NPs as these are more clinically applied, will allow for the more effective design of novel biomedical agents for future therapies.","PeriodicalId":68,"journal":{"name":"Chemical Society Reviews","volume":"43 1","pages":""},"PeriodicalIF":46.2,"publicationDate":"2025-09-30","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"145189243","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":1,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

引用次数: 0

Injectable nanorobots for precision cancer therapy: motion-enhanced drug delivery. 用于精确癌症治疗的可注射纳米机器人：运动增强药物输送。

IF 46.2 1区化学

Chemical Society Reviews Pub Date : 2025-09-29 DOI: 10.1039/d5cs00596e

Zhixue Gao,Zili Yang,Wentao Xu,Ming Luo,Jianguo Guan

{"title":"Injectable nanorobots for precision cancer therapy: motion-enhanced drug delivery.","authors":"Zhixue Gao,Zili Yang,Wentao Xu,Ming Luo,Jianguo Guan","doi":"10.1039/d5cs00596e","DOIUrl":"https://doi.org/10.1039/d5cs00596e","url":null,"abstract":"Cancer remains a major global health challenge, demanding innovative strategies to overcome the limitations of conventional therapies. While nanoparticle-based drug delivery systems show potential, their clinical translation is hindered by low targeting efficiency and insufficient tissue penetration. Injectable nanorobots, capable of autonomous movement driven by external fields or endogenous fuels, offer a transformative technology to enhance drug delivery precision. Following the brief discussion of propulsion mechanisms, design and fabrication of injectable nanorobots, this review provides a comprehensive summary of injectable nanorobots designed for precision cancer therapy. It focuses on their dynamic performance across six critical stages: circulation, targeting, penetration, internalization, release, and treatment (CTPIRT process). Compared to passive nanoparticles, self-propelled nanorobots demonstrate superior tumor accumulation, deeper tissue penetration, and enhanced cellular internalization. Furthermore, they can substantially amplify therapeutic efficacy by enabling stimulus-responsive drug release and integrating diverse treatment strategies. Finally, this review delves into the unresolved challenges in scalable fabrication, biosafety, and clinical translation of injectable nanorobots. Interdisciplinary strategies are proposed to help bridge the gap between laboratory research and clinical translation. Together, this review highlights injectable nanorobots as a paradigm shift in precision drug delivery, promising a path toward surmounting the long-standing barriers in cancer therapy.","PeriodicalId":68,"journal":{"name":"Chemical Society Reviews","volume":"39 1","pages":""},"PeriodicalIF":46.2,"publicationDate":"2025-09-29","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"145182575","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":1,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

引用次数: 0

High energy density lithium battery systems: from key cathode materials to pouch cell design. 高能量密度锂电池系统：从关键正极材料到袋式电池设计。

IF 46.2 1区化学

Chemical Society Reviews Pub Date : 2025-09-26 DOI: 10.1039/d5cs00641d

Chengrong Xu,Bo Peng,Wujie Yang,Jiaming Tian,Haoshen Zhou

{"title":"High energy density lithium battery systems: from key cathode materials to pouch cell design.","authors":"Chengrong Xu,Bo Peng,Wujie Yang,Jiaming Tian,Haoshen Zhou","doi":"10.1039/d5cs00641d","DOIUrl":"https://doi.org/10.1039/d5cs00641d","url":null,"abstract":"The ongoing energy revolution and technological development of energy storage require high-energy-density lithium battery systems beyond 500 Wh kg-1. However, the commercialized lithium-ion batteries using graphite as the anode with a limited theoretical energy density of about 350 Wh kg-1 are far from this goal. Promisingly, the lithium metal batteries (LMBs) matched with a variety of cathode materials have great potential to achieve ultra-high-energy-densities in practice. Nevertheless, the energy density of LMBs depends greatly on the energy density of different types of cathodes. Therefore, research on how to improve the output energy density and durability of various cathode materials under practical working conditions is essential for realizing the ultra-high-energy-density LMBs. In this review, we systematically explore the pathway to achieving high-energy and durable LMBs from the perspective of key cathode materials to pouch cell configuration design. We discuss the fundamental characteristics and key challenges of five promising cathode materials, including a lithium cobalt oxide cathode, a high-nickel oxide cathode, a Li-rich oxide cathode, a sulfur cathode, and an oxygen cathode, and also summarize the feasible solutions and recent progress in addressing the key bottlenecks. Furthermore, using pouch cell configurations as a typical pattern, we precisely summarize the impact of each component in pouch cells on energy density and provide detailed routes for acquiring the maximum practical energy density by using different cathode materials in pouch cells. This review offers guidelines for promoting the practical applications of high-energy-density LMBs.","PeriodicalId":68,"journal":{"name":"Chemical Society Reviews","volume":"18 1","pages":""},"PeriodicalIF":46.2,"publicationDate":"2025-09-26","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"145140346","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":1,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

引用次数: 0

From halide perovskite nanocrystals to supercrystals: fundamentals and applications. 从卤化物钙钛矿纳米晶体到超晶体：基本原理和应用。

IF 46.2 1区化学

Chemical Society Reviews Pub Date : 2025-09-26 DOI: 10.1039/d5cs00937e

S L Aneesha,Yifei Xia,Takuya Okamoto,Deepika Gaur,Sudipta Seth,Johan Hofkens,Lakshminarayana Polavarapu,Vasudevanpillai Biju

{"title":"From halide perovskite nanocrystals to supercrystals: fundamentals and applications.","authors":"S L Aneesha,Yifei Xia,Takuya Okamoto,Deepika Gaur,Sudipta Seth,Johan Hofkens,Lakshminarayana Polavarapu,Vasudevanpillai Biju","doi":"10.1039/d5cs00937e","DOIUrl":"https://doi.org/10.1039/d5cs00937e","url":null,"abstract":"Halide perovskite supercrystals, also known as superlattices, are electronically coupled low-dimensional materials, such as nanocrystals, quantum dots, or nanoplatelets that offer collective optical and electronic properties distinct from those of their constituents. The intrinsic dielectric properties and defect tolerance of halide perovskites make their supercrystals superior to metal chalcogenide supercrystals. The physicochemical properties of ligands and the shape and size uniformity of the constituents determine the overall size, shape, and electronic and optical properties of these supercrystals, where excitons interact across long distances through phase coherence and dipole coupling, inducing enhanced and narrow-band emission, including superfluorescence, superradiance, amplified spontaneous emission, and lasing. These emergent optical and electronic properties make halide perovskite supercrystals promising for brilliant LEDs, low-threshold lasers, high-efficiency solar cells, and broadband photodetectors. This article provides a state-of-the-art overview of halide perovskite supercrystals, addressing the critical gap between their structure-property relationship and linking the fundamental mechanism of electronic coupling with their emergent optoelectronic properties.","PeriodicalId":68,"journal":{"name":"Chemical Society Reviews","volume":"42 1","pages":""},"PeriodicalIF":46.2,"publicationDate":"2025-09-26","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"145140345","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":1,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

引用次数: 0

Defining, designing and determining the structure of supramolecular frameworks. 定义、设计和确定超分子框架的结构。

IF 46.2 1区化学

Chemical Society Reviews Pub Date : 2025-09-26 DOI: 10.1039/d5cs00550g

Nicholas G White,C Michael McGuirk

引用次数: 0

Optimizing CO2 electroreduction: theoretical insights for enhancing efficiency across elementary steps 优化二氧化碳电还原：提高基本步骤效率的理论见解

IF 46.2 1区化学

Chemical Society Reviews Pub Date : 2025-09-25 DOI: 10.1039/d5cs00780a

Hengan Wang, Xinchen Kang, Buxing Han

{"title":"Optimizing CO2 electroreduction: theoretical insights for enhancing efficiency across elementary steps","authors":"Hengan Wang, Xinchen Kang, Buxing Han","doi":"10.1039/d5cs00780a","DOIUrl":"https://doi.org/10.1039/d5cs00780a","url":null,"abstract":"The electrochemical CO2 reduction reaction (CO2RR) can convert CO2 emissions into valuable fuels and chemicals, offering a promising pathway to close the carbon cycle. However, existing CO2RR systems face challenges in holistically optimizing interdependent elementary processes, such as adsorption, electron–proton transfer, and mass transport, resulting in unavoidable trade-offs between selectivity, activity, and stability. To address these limitations, a thorough analysis of these elementary steps is essential, supported by theoretical frameworks to guide the design of electrocatalytic systems. By systematically optimizing each process, CO2RR performance can be significantly enhanced. This review provides a comprehensive overview of the theories and applications governing elementary steps in CO2RR systems for fine-tuning both catalysts and their near-catalyst environments. The deactivation mechanisms of electrocatalysts are discussed, along with strategies to enhance their stability. Furthermore, alternative anodic reactions that enhance the energy efficiency of the associated system are outlined, along with experimental methodologies for investigating CO2RR mechanisms. Finally, the review critically assesses the challenges and future prospects in CO2RR research. Through this in-depth analysis, the review advances the understanding of key theoretical principles and their practical applications in CO2RR, offering valuable insights for the design and industrial implementation of electrocatalytic CO2RR systems.","PeriodicalId":68,"journal":{"name":"Chemical Society Reviews","volume":"28 1","pages":""},"PeriodicalIF":46.2,"publicationDate":"2025-09-25","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"145133546","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":1,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

引用次数: 0