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Unparalleled photocurrent and dark radical conversions of natural nano-iron oxides versus synthetic ones: thousand-fold enhanced degradation of extra antibiotic resistant genes 天然纳米氧化铁与合成氧化铁的无与伦比的光电流和暗自由基转化:对额外的抗生素抗性基因的降解增强了数千倍
IF 8.131 2区 环境科学与生态学
Environmental Science: Nano Pub Date : 2025-05-16 DOI: 10.1039/d5en00188a
Yutong Meng, Daiye Fu, Jundie Ying, Xiangliang Pan
{"title":"Unparalleled photocurrent and dark radical conversions of natural nano-iron oxides versus synthetic ones: thousand-fold enhanced degradation of extra antibiotic resistant genes","authors":"Yutong Meng, Daiye Fu, Jundie Ying, Xiangliang Pan","doi":"10.1039/d5en00188a","DOIUrl":"https://doi.org/10.1039/d5en00188a","url":null,"abstract":"Antibiotic resistant genes (ARGs) have been widely detected in global rivers, lakes and oceans. Although nanoscale natural acrisol iron oxides (NNIOs) are ubiquitous in global aquatic environments, their photoelectric conversion efficiency and bactericidal and ARG removal are not well clarified. This study evaluated the photocurrent conversion and photocatalytic degradation of antibiotic-resistant bacteria and extracellular ARGs (eARGs) of two typical NNIOs (natural hematite and goethite) in comparison with their synthetic ones. It was found that NNIOs exhibit unparalleled and persistent photocurrent conversion <em>versus</em> the synthetic ones. NNIOs also had high dark radical conversion in contrast to little conversion of the synthetic ones. Owing to these unrivalled performance, NNIOs had significant advantages of killing bacteria over the synthetic ones. What is more important, thousand-fold higher degradation rates of eARGs were obtained by NNIOs than the synthetic ones under light or light–dark conditions. The residual eARG copies after synthesized hematite treatment were up to 17 400 times that of natural hematite groups, and this difference between synthetic and natural goethite was 1612 times. These novel findings imply that enough attention should be paid to the overlooked huge contribution of NNIOs to aquatic eARG elimination and reduction of antibiotic resistance risk. The mechanisms of incomparable photoelectric and dark radical conversions of NNIOs and their ultraefficient degradation of eARGs deserve further study.","PeriodicalId":73,"journal":{"name":"Environmental Science: Nano","volume":"14 1","pages":""},"PeriodicalIF":8.131,"publicationDate":"2025-05-16","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"144066221","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":2,"RegionCategory":"环境科学与生态学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Advanced TiO2 and Al2O3 Modularized Adsorbents and Practical Application Strategies for Enhanced Arsenic Removal from Water 新型TiO2和Al2O3模块化吸附剂及强化水中砷去除的实际应用策略
IF 3.8 4区 环境科学与生态学
Water, Air, & Soil Pollution Pub Date : 2025-05-15 DOI: 10.1007/s11270-025-08094-9
Younghee Jang, Sung Su Kim, D. Duc Nguyen
{"title":"Advanced TiO2 and Al2O3 Modularized Adsorbents and Practical Application Strategies for Enhanced Arsenic Removal from Water","authors":"Younghee Jang,&nbsp;Sung Su Kim,&nbsp;D. Duc Nguyen","doi":"10.1007/s11270-025-08094-9","DOIUrl":"10.1007/s11270-025-08094-9","url":null,"abstract":"<div><p>The increasing concentration of heavy metal contamination, especially arsenic, in water resources presents significant risks to both human health and overall water quality. This study examines the adsorption efficiency of TiO<sub>2</sub> and Al<sub>2</sub>O<sub>3</sub> powders for arsenic removal from drinking water. Fourier-transform infrared spectroscopy, Brunauer–Emmett–Teller, and zeta potential were used to investigate the correlation between adsorbent properties and performance. Modularized adsorbents, specifically hollow-fiber and carbon block formats, were introduced and demonstrated outstanding arsenic removal efficiency. In particular, the TiO<sub>2</sub>-based adsorbents achieved over 99.9% arsenic removal in simulated and actual drinking water. In a pilot test, the hollow-fiber module maintained complete removal for over 16 days using real groundwater. The study emphasizes the crucial role of surface charge and hydroxyl groups in arsenic adsorption, demonstrating the practical effectiveness of these innovative adsorbents in large-scale water purification systems.</p><h3>Graphical Abstract</h3>\u0000<div><figure><div><div><picture><source><img></source></picture></div></div></figure></div></div>","PeriodicalId":808,"journal":{"name":"Water, Air, & Soil Pollution","volume":"236 7","pages":""},"PeriodicalIF":3.8,"publicationDate":"2025-05-15","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"143949474","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"环境科学与生态学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Utilizing Industrial Wastewater for Cultivation of Chlorella vulgaris NIES-227: A Study on Biodiesel Yield Optimization with Alkali Catalysts 利用工业废水培养小球藻NIES-227:碱催化剂优化生物柴油产率的研究
IF 3.8 4区 环境科学与生态学
Water, Air, & Soil Pollution Pub Date : 2025-05-15 DOI: 10.1007/s11270-025-08093-w
Sonika Kumari, Vinod Kumar, Richa Kothari, Pankaj Kumar
{"title":"Utilizing Industrial Wastewater for Cultivation of Chlorella vulgaris NIES-227: A Study on Biodiesel Yield Optimization with Alkali Catalysts","authors":"Sonika Kumari,&nbsp;Vinod Kumar,&nbsp;Richa Kothari,&nbsp;Pankaj Kumar","doi":"10.1007/s11270-025-08093-w","DOIUrl":"10.1007/s11270-025-08093-w","url":null,"abstract":"<div><p>Microalgae, ubiquitous in diverse aquatic ecosystems, present a promising avenue for energy generation through cultivation. This study focused on the cultivation of indigenous <i>Chlorella vulgaris</i> using both dairy wastewater (DWW) and pharmaceutical industry wastewater (PIWW) to ascertain its viability for biodiesel production. The results showed that biodiesel yields of 78% and 76% were attained from <i>C. vulgaris</i> biomass cultivated using DWW utilizing potassium hydroxide (KOH) and sodium hydroxide (NaOH) catalysts, respectively. The results demonstrated its efficacy in wastewater treatment, with removal efficiencies of 63–60% for total dissolved solids (TDS), 82–93% for biochemical oxygen demand (BOD), 73–85% for chemical oxygen demand (COD), 80% for total Kjeldahl nitrogen (TKN), and 82–88% for total phosphorus (TP), complementing biodiesel production. This dual-purpose approach emphasizes the potential of microalgae for realizing sustainable solutions at the intersection of environmental management and bioenergy production.</p></div>","PeriodicalId":808,"journal":{"name":"Water, Air, & Soil Pollution","volume":"236 7","pages":""},"PeriodicalIF":3.8,"publicationDate":"2025-05-15","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"143949475","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"环境科学与生态学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Distribution, Characteristics, and Potential Health Risks of Microplastics in National Coastal Highway Road Dust, Northern Mindanao, Philippines 菲律宾棉兰老岛北部国家沿海公路粉尘中微塑料的分布、特征和潜在健康风险
IF 3.8 4区 环境科学与生态学
Water, Air, & Soil Pollution Pub Date : 2025-05-15 DOI: 10.1007/s11270-025-08097-6
Jeron Bet B. Tejano, Chih-Feng Chen, Yee Cheng Lim, Frank Paolo Jay B. Albarico, Ming-Huang Wang, Rodolfo A. Romarate II, Chiu-Wen Chen, Cheng-Di Dong, Hernando P. Bacosa
{"title":"Distribution, Characteristics, and Potential Health Risks of Microplastics in National Coastal Highway Road Dust, Northern Mindanao, Philippines","authors":"Jeron Bet B. Tejano,&nbsp;Chih-Feng Chen,&nbsp;Yee Cheng Lim,&nbsp;Frank Paolo Jay B. Albarico,&nbsp;Ming-Huang Wang,&nbsp;Rodolfo A. Romarate II,&nbsp;Chiu-Wen Chen,&nbsp;Cheng-Di Dong,&nbsp;Hernando P. Bacosa","doi":"10.1007/s11270-025-08097-6","DOIUrl":"10.1007/s11270-025-08097-6","url":null,"abstract":"<div><p>Microplastics (MPs) are a growing environmental problem, especially in urban areas with high human activity. Urban roads are important transport routes for MPs into aquatic and atmospheric systems, making understanding their occurrence, characteristics, and deposition in road dust is crucial. This study investigated the abundance, morphology, and polymer type of MPs in coastal road dust from three major cities in the southern Philippines: Cagayan de Oro, Iligan, and Ozamiz City. Results showed that MP abundance in road dust ranged from 180 – 780 n/kg. The MP abundance at the downtown site of each city was significantly higher than at other sites. The morphology of MP was mainly characterized by fragments (77.7%), blue color (32.5%), and small size (&lt; 1000 μm; 68%). Polyolefin polymers were the main polymers (60.9%) identified. Microplastic abundance was positively correlated with population density, but not significantly correlated with traffic volume. This reflects that MP in road dust in the study area may mainly come from the degradation of daily consumption-related products. In contrast, the contribution from road and automobile-related sources is low. Notably, road- and traffic-related MPs were found to be often extremely hazardous, leading them to be key to the high hazard risk of MPs despite their lower prevalence (&lt; 6.2%). Road dust MPs in the three cities showed moderate diversity and high hazard, among which Iligan City (industrial city) had a relatively high diversity and hazard index. Overall, this study confirms MP accumulation and hazard risks in Philippine road dust—highlighting the importance of MP studies in growing and urban cities for MP pollution management and mitigations.</p></div>","PeriodicalId":808,"journal":{"name":"Water, Air, & Soil Pollution","volume":"236 7","pages":""},"PeriodicalIF":3.8,"publicationDate":"2025-05-15","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"143949473","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"环境科学与生态学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Cellulose Acetate-nanoMOF Beads: A Safe, Sustainable and Scalable Solution for Lead Remediation in Complex Water Systems 醋酸纤维素-纳米微球:复杂水系统中铅修复的安全、可持续和可扩展的解决方案
IF 8.131 2区 环境科学与生态学
Environmental Science: Nano Pub Date : 2025-05-15 DOI: 10.1039/d5en00056d
Prathmesh Bhadane, Swaroop Chakraborty
{"title":"Cellulose Acetate-nanoMOF Beads: A Safe, Sustainable and Scalable Solution for Lead Remediation in Complex Water Systems","authors":"Prathmesh Bhadane, Swaroop Chakraborty","doi":"10.1039/d5en00056d","DOIUrl":"https://doi.org/10.1039/d5en00056d","url":null,"abstract":"Lead [Pb(II)] contamination poses a critical environmental and public health challenge, necessitating innovative and sustainable remediation strategies. This study presents cellulose acetate (CA)-BNMG-1 nanoMOF beads, synthesised via a green, water-based process without hazardous chemicals. By embedding this nanoMOF into a CA polymer matrix, the beads achieve remarkable Pb(II) removal efficiencies exceeding 80% in complex aqueous systems, including canal water and artificial seawater, even with competing ions and naturally occurring microbial contaminants in canal water. The beads exhibit significantly enhanced selectivity for Pb(II), with separation factors (SFs) improving from 2.5 to 350 for Pb/Mn, 57.4 to 220.6 for Pb/Ni, and 150.6 to 314 for Pb/Cd compared to the parent BNMG-1 nanoMOF. Structural stability is ensured, with Cu(II) leaching reduced to below 5% at higher and less than 1% at lower Pb(II) concentrations (5 bead/mL). Furthermore, the beads demonstrate outstanding reusability, retaining over 95% Pb(II) removal efficiency after three cycles. The CA matrix enhances nanoMOF stability, facilitating bead recovery via simple filtration, addressing challenges in scalability and sustainability. This work aligns with Safe and Sustainable by Design (SSbD) principles, providing an eco-friendly and scalable solution for heavy metal remediation, advancing sustainable water treatment technologies for real-world applications.","PeriodicalId":73,"journal":{"name":"Environmental Science: Nano","volume":"40 1","pages":""},"PeriodicalIF":8.131,"publicationDate":"2025-05-15","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"143979993","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":2,"RegionCategory":"环境科学与生态学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Effects of Soil Components on Microplastics Transport and Retention in Natural Soils: Various Microplastics Types and Sizes 土壤组分对天然土壤中微塑料运输和滞留的影响:不同微塑料类型和尺寸
IF 3.8 4区 环境科学与生态学
Water, Air, & Soil Pollution Pub Date : 2025-05-15 DOI: 10.1007/s11270-025-08106-8
Weiya Fan, Shunan Dong, Xiyu Chen, Xiaoting Su, Qianhui Yu, Liting Sheng
{"title":"Effects of Soil Components on Microplastics Transport and Retention in Natural Soils: Various Microplastics Types and Sizes","authors":"Weiya Fan,&nbsp;Shunan Dong,&nbsp;Xiyu Chen,&nbsp;Xiaoting Su,&nbsp;Qianhui Yu,&nbsp;Liting Sheng","doi":"10.1007/s11270-025-08106-8","DOIUrl":"10.1007/s11270-025-08106-8","url":null,"abstract":"<div><p>Microplastics (MPs) have emerged as a global concern, yet the interactions between MPs and natural soils remain poorly understood. This study aimed to investigate the transport and retention behaviors of different microplastics polymers in diverse soil environments, elucidating the critical role of soil physicochemical properties in MPs mobility. We conducted column experiments examining the transport and retention of three microplastics types (polyvinyl chloride, polymethyl methacrylate, and polypropylene) across three distinct soil types (desert, red, and black soils). Particle sizes ranging from 1–2 μm, 2–5 μm, and 10–15 μm were selected, with a focus on the impacts of soil components such as metal oxides and natural organic matter. MPs mobility generally decreased with increasing particle size, following the order PVC &gt; PMMA &gt; PP in desert soil (maximum transport mass recovery: 29.7%). The microplastics transport mass recovery approached 0% in red soil, primarily due to the high specific surface area and abundant metal oxides, which synergistically enhanced electrostatic attraction and physical retention. A non-monotonic trend observed in black soil was attributed to the interplay between natural organic matter (NOM) adsorption. Soil physicochemical properties significantly influenced MPs mobility, correlating with the soil texture, metal oxide, and organic carbon. Metal oxide typically enhanced MPs retention through decreased electrostatic repulsion and surface roughness, with the maximum observed increase in transport mass recovery being 53.2%. NOM removal exhibited biphasic effects on MPs transport, characterized by an initial promotional phase in low-NOM desert soil and an inhibitory phase in high-NOM black soil. The extended FDLVO theory and numerical modeling matched the experimental results well. The results showed that, soil physicochemical properties, particularly metal oxides and natural organic matter, significantly influenced microplastics transport and retention, with particle size, polymer type, and soil composition playing critical roles in determining microplastics mobility in natural environments.</p><h3>Graphical Abstract</h3>\u0000<div><figure><div><div><picture><source><img></source></picture></div></div></figure></div></div>","PeriodicalId":808,"journal":{"name":"Water, Air, & Soil Pollution","volume":"236 7","pages":""},"PeriodicalIF":3.8,"publicationDate":"2025-05-15","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"143949472","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"环境科学与生态学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Colorimetric Nanozyme Sensing Array based on the Interface Interaction of Platinum Nanoparticles for Discriminating Structurally Similar Triazine Pesticides in Water 基于铂纳米颗粒界面作用的比色纳米酶传感阵列识别水中结构相似的三嗪类农药
IF 8.131 2区 环境科学与生态学
Environmental Science: Nano Pub Date : 2025-05-14 DOI: 10.1039/d5en00182j
Bingqian Jing, Yuanyuan Li, Xiaofeng Liu, Zihang Zeng, Zan Long, Bingni Jia, Bo Feng, Peng Zhang, Taiping Qing
{"title":"Colorimetric Nanozyme Sensing Array based on the Interface Interaction of Platinum Nanoparticles for Discriminating Structurally Similar Triazine Pesticides in Water","authors":"Bingqian Jing, Yuanyuan Li, Xiaofeng Liu, Zihang Zeng, Zan Long, Bingni Jia, Bo Feng, Peng Zhang, Taiping Qing","doi":"10.1039/d5en00182j","DOIUrl":"https://doi.org/10.1039/d5en00182j","url":null,"abstract":"The widespread use of triazine pesticides in agricultural practices raises concerns regarding their potential harm to both humans and the environment, given their known carcinogenic and neurotoxic effects. Triazine pesticides exhibit various toxic effects on organisms, posing a significant challenge in accurately distinguishing them due to their analogous structures. Herein, we functionalized platinum nanoparticles (Pt NPs) and constructed a three-channel sensing array by modulating their oxidase-like activities through various ligands on the surface of Pt NPs. Triazine pesticides can inhibit the activity of functionalized Pt NPs, allowing the substrate TMB to show different degrees of color development reaction, which provides a solid basis for the construction of sensing arrays by platinum nanozymes. The proposed platinum nanozyme sensing array showed good performance for the identification of five kinds of triazine pesticides (atrazine, simazine, metribuzin, metamitron, and terbutryn) across a wide range of concentrations (0.5-100 µg/mL) through statistical classification using advanced algorithms like linear discriminant analysis (LDA) and hierarchical cluster analysis (HCA). Importantly, the sensing array exhibited good anti-interference ability and achieved accurate discrimination of structurally similar triazine pesticides in real water samples. This study provided a simple and effective method for the identification of triazine pesticides, with potential for discriminating other related pollutants such as antibiotics and biotoxins for environmental monitoring and food safety.","PeriodicalId":73,"journal":{"name":"Environmental Science: Nano","volume":"87 1","pages":""},"PeriodicalIF":8.131,"publicationDate":"2025-05-14","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"143945684","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":2,"RegionCategory":"环境科学与生态学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Advances in Membrane Technologies for Heavy Metal Removal from Polluted Water: A Comprehensive Review
IF 3.8 4区 环境科学与生态学
Water, Air, & Soil Pollution Pub Date : 2025-05-14 DOI: 10.1007/s11270-025-08035-6
Mohamed Dawam, Mohamed Gobara, Hussein Oraby, Mahmoud Y. Zorainy, Islam M. Nabil
{"title":"Advances in Membrane Technologies for Heavy Metal Removal from Polluted Water: A Comprehensive Review","authors":"Mohamed Dawam,&nbsp;Mohamed Gobara,&nbsp;Hussein Oraby,&nbsp;Mahmoud Y. Zorainy,&nbsp;Islam M. Nabil","doi":"10.1007/s11270-025-08035-6","DOIUrl":"10.1007/s11270-025-08035-6","url":null,"abstract":"<div><p>Heavy metals and other hazardous substances contaminating water have harmful effects on plants, animals, and potentially human health. Therefore, it is essential to explore ways to extract toxic materials from polluted water. Removing mineral contaminants from water is crucial for promoting a healthy environment and protecting human health. Among the existing methods, membrane-based techniques are particularly effective in reducing pollutants, especially heavy metals, in water systems. Membrane filtration is extensively researched and known for its high efficiency, although cost factors limit its broader application. Reverse osmosis technology achieves the highest heavy metal removal efficiency, ranging from 98.0% to 99.9%. While reverse osmosis boasts high operational efficiency, it demands a significant amount of energy. To maintain the sustainability of reverse osmosis efficiency, suitable and intermediate conditions must be established. Polymeric membranes provide an energy-efficient water purification solution, although they face fouling issues during filtration. Membrane fouling, a prevalent challenge for all membrane-based water and wastewater treatment technologies, refers to the accumulation of dissolved or suspended solids on or within the membrane pores, which deteriorates membrane performance. Surface modification of membranes is one strategy to alleviate fouling and sustain high water productivity levels. Two main methods have been extensively explored: grafting polymer chains onto the membrane surface and applying a thin film to the membrane surface. The objectives of these membrane modifications include increased fouling resistance, improved selectivity, and extended membrane lifespan. This study thoroughly analyzes results from various experiments conducted over the past two decades to identify the most relevant membrane filtration processes for different contaminant profiles.</p></div>","PeriodicalId":808,"journal":{"name":"Water, Air, & Soil Pollution","volume":"236 7","pages":""},"PeriodicalIF":3.8,"publicationDate":"2025-05-14","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://link.springer.com/content/pdf/10.1007/s11270-025-08035-6.pdf","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"143944214","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"环境科学与生态学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"OA","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Air Quality Forecasting Using Machine Learning: Comparative Analysis and Ensemble Strategies for Enhanced Prediction
IF 3.8 4区 环境科学与生态学
Water, Air, & Soil Pollution Pub Date : 2025-05-14 DOI: 10.1007/s11270-025-08122-8
Yıldırım Özüpak, Feyyaz Alpsalaz, Emrah Aslan
{"title":"Air Quality Forecasting Using Machine Learning: Comparative Analysis and Ensemble Strategies for Enhanced Prediction","authors":"Yıldırım Özüpak,&nbsp;Feyyaz Alpsalaz,&nbsp;Emrah Aslan","doi":"10.1007/s11270-025-08122-8","DOIUrl":"10.1007/s11270-025-08122-8","url":null,"abstract":"<div><p>Air pollution poses a critical challenge to environmental sustainability, public health, and urban planning. Accurate air quality prediction is essential for devising effective management strategies and early warning systems. This study utilized a dataset comprising hourly measurements of pollutants such as PM2.5, NO<sub>x</sub>, CO, and benzene, sourced from five metal oxide sensors and a certified analyzer in a polluted urban area, totaling 9,357 records collected over one year (March 2004–February 2005) from the Kaggle Air Quality Data Set. A comprehensive comparison of ten machine learning regression models XGBoost, LightGBM, Random Forest, Gradient Boosting, CatBoost, Support Vector Regression (SVR) with Bayesian Optimization, Decision Tree, K-Nearest Neighbors (KNN), Elastic Net, and Bayesian Ridge was conducted. Model performance was enhanced through Bayesian optimization and randomized cross-validation, with stacking employed to leverage the strengths of base models. Experimental results showed that hyperparameter optimization and ensemble strategies significantly improved accuracy, with the SVR model optimized via Bayesian optimization achieving the highest performance: an R<sup>2</sup> score of 99.94%, MAE of 0.0120, and MSE of 0.0005. These findings underscore the methodology’s efficacy in precisely capturing the spatial and temporal dynamics of air pollution.</p></div>","PeriodicalId":808,"journal":{"name":"Water, Air, & Soil Pollution","volume":"236 7","pages":""},"PeriodicalIF":3.8,"publicationDate":"2025-05-14","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://link.springer.com/content/pdf/10.1007/s11270-025-08122-8.pdf","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"143944249","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"环境科学与生态学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"OA","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Adsorption of Cr(III) on Areca Nut Fibers – An Environmentally Friendly Approach
IF 3.8 4区 环境科学与生态学
Water, Air, & Soil Pollution Pub Date : 2025-05-14 DOI: 10.1007/s11270-025-08105-9
Mishantha Kanishka, Hasanka Rathnayaka, Namal Priyantha
{"title":"Adsorption of Cr(III) on Areca Nut Fibers – An Environmentally Friendly Approach","authors":"Mishantha Kanishka,&nbsp;Hasanka Rathnayaka,&nbsp;Namal Priyantha","doi":"10.1007/s11270-025-08105-9","DOIUrl":"10.1007/s11270-025-08105-9","url":null,"abstract":"<div><p>Development of pollutant removal methodologies based on biosorption has become attractive due to many desirable characteristics. However, practical applications of biosorption have not been much attended to. On the other hand, the use of chromium and its compounds has been steadily increased in the ever-expanding industrial sector. Consequently, there is a necessity to remove chromium from the environment, especially from water bodies. The methodologies to be adopted for pollutant removal should not only be cost-effective and environmentally friendly but also be efficient. In this respect, the study reported herein is on the use of areca nut fibers (ARF), leading to an excellent Cr(III) removal of &gt; 90% from 10 ppm solution under optimized conditions of biosorbent dosage, shaking time, settling time, and solution pH. However, adsorption characteristics of ARF, which are not desirable at higher Cr(III) concentrations, can be significantly strengthened by surface modification, which is feasible due to the fibrous nature of the biosorbent. This is evidenced by obtaining &gt; 90% Cr(III) removal from 25 ppm solution with NaOH-treated ARF, which is approximately 130% increment as compared to the situation before any treatment. Adsorption of Cr(III) on ARF is a monolayer process, as determined by the validity of the Langmuir adsorption isotherm model. X-ray fluorescence spectroscopic studies confirm the biosorption of Cr(III) on the fibers, while Fourier transform infrared spectroscopic investigation indicates the presence of carboxylic acid groups in the biosorbent, which could be deprotonated during NaOH treatment, leading to stronger affinity toward positively charged Cr(III) species. Results of static experiments performed could be extended toward dynamic experiments and proto-type studies to apply ARF for industrial applications.</p></div>","PeriodicalId":808,"journal":{"name":"Water, Air, & Soil Pollution","volume":"236 7","pages":""},"PeriodicalIF":3.8,"publicationDate":"2025-05-14","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"143944247","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"环境科学与生态学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
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