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Bifunctional Tb(III)-modified Ce-MOF nanoprobe for colorimetric and fluorescence sensing of α-glucosidase activity. 用于α-葡萄糖苷酶活性比色和荧光传感的双功能锑(III)修饰 Ce-MOF 纳米探针。
IF 6.1 1区 化学
Talanta Pub Date : 2024-08-15 Epub Date: 2024-05-22 DOI: 10.1016/j.talanta.2024.126304
Yi Xiao, Pengcheng Huang, Fang-Ying Wu
{"title":"Bifunctional Tb(III)-modified Ce-MOF nanoprobe for colorimetric and fluorescence sensing of α-glucosidase activity.","authors":"Yi Xiao, Pengcheng Huang, Fang-Ying Wu","doi":"10.1016/j.talanta.2024.126304","DOIUrl":"10.1016/j.talanta.2024.126304","url":null,"abstract":"<p><p>α-Glucosidase, which directly involves in the metabolism of starch and glycogen and causes an increase in blood sugar level, is the major target enzyme for the precaution and therapy of type II diabetes. Based on the previous work, we adopted a post-synthetic modification method to encapsulate Tb<sup>3+</sup> into Ce-MOF nanozyme which owned mixed valence states. Tb@Ce-MOF displayed induced luminescence characteristic and exceptional oxidase-like activity that could oxidize colorless 3,3',5,5'-tetramethylbenzidine (TMB) to blue ox-TMB. α-Glucosidase can hydrolyze the substrate l-ascorbic acid-2-O-α-d-glucopyranosyl (AAG) to generate ascorbic acid (AA), which could increase the Ce<sup>3+</sup>/Ce<sup>4+</sup> redox valence mode in Tb@Ce-MOF, leading to the inhibition of the allochroic reaction of TMB and the decreased absorption of ox-TMB at 652 nm. The energy transfer (EnT) process from Ce<sup>3+</sup> to Tb<sup>3+</sup> will enhance due to the increased Ce<sup>3+</sup>/Ce<sup>4+</sup> mode in Tb@Ce-MOF, which will result in an enhanced fluorescence signal of Tb@Ce-MOF at 550 nm. But the addition of inhibitor acarbose will inhibit the above process. We have constructed a dual-mode detection platform of α-glucosidase and its inhibitor via colorimetric and fluorometric method. The linear range of α-glucosidase were 0.01-0.5 U/mL (colorimetric mode) and 0.8-1.5 U/mL (fluorometric mode), respectively, with a detection limit as low as 0.0018 U/mL. Furthermore, our approach was also successfully employed to the analysis of α-glucosidase in serum samples.</p>","PeriodicalId":435,"journal":{"name":"Talanta","volume":null,"pages":null},"PeriodicalIF":6.1,"publicationDate":"2024-08-15","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"141154707","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":1,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
A highly sensitive nanopore platform for measuring RNase A activity. 用于测量 RNase A 活性的高灵敏度纳米孔平台。
IF 5.6 1区 化学
Talanta Pub Date : 2024-08-15 Epub Date: 2024-05-22 DOI: 10.1016/j.talanta.2024.126276
Haiyan Zheng, Sathishkumar Munusamy, Pearl Arora, Rana Jahani, Xiyun Guan
{"title":"A highly sensitive nanopore platform for measuring RNase A activity.","authors":"Haiyan Zheng, Sathishkumar Munusamy, Pearl Arora, Rana Jahani, Xiyun Guan","doi":"10.1016/j.talanta.2024.126276","DOIUrl":"10.1016/j.talanta.2024.126276","url":null,"abstract":"<p><p>Ribonuclease A (RNase A) plays significant roles in several physiological and pathological conditions and can be used as a valuable diagnostic biomarker for human diseases such as myocardial infarction and cancer. Hence, it is of great importance to develop a rapid and cost-effective method for the highly sensitive detection of RNase A. The significance of RNase A assay is further enhanced by the growing attention from the biotechnology and pharmaceutical industries to develop RNA-based vaccines and drugs in large part as a result of the successful development of mRNA vaccines in the COVID-19 pandemic. Herein, we report a label-free method for the detection of RNase A by monitoring its proteolytic cleavage of an RNA substrate in a nanopore. The method is ultra-sensitive with the limit of detection reaching as low as 30 fg per milliliter. Furthermore, sensor selectivity and the effects of temperature, incubation time, metal ion, salt concentration on sensor sensitivity were also investigated.</p>","PeriodicalId":435,"journal":{"name":"Talanta","volume":null,"pages":null},"PeriodicalIF":5.6,"publicationDate":"2024-08-15","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://www.ncbi.nlm.nih.gov/pmc/articles/PMC11187776/pdf/","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"141154664","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":1,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"OA","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Selection of a new aptamer targeting amoxicillin for utilization in a label-free electrochemical biosensor. 选择一种新的以阿莫西林为靶标的适配体,用于无标记电化学生物传感器。
IF 6.1 1区 化学
Talanta Pub Date : 2024-08-15 Epub Date: 2024-05-23 DOI: 10.1016/j.talanta.2024.126245
Wafaa Al Borhani, Amani Chrouda, Shimaa Eissa, Mohammed Zourob
{"title":"Selection of a new aptamer targeting amoxicillin for utilization in a label-free electrochemical biosensor.","authors":"Wafaa Al Borhani, Amani Chrouda, Shimaa Eissa, Mohammed Zourob","doi":"10.1016/j.talanta.2024.126245","DOIUrl":"10.1016/j.talanta.2024.126245","url":null,"abstract":"<p><p>Pharmaceutical pollution has received considerable attention because of the harmful effects of pharmaceutical compounds on human health, even in trace amounts. Amoxicillin is one of the frequently used antibiotics that was included in the list of emerging water pollutants. Therefore, a highly selective and rapid technique for amoxicillin detection is required. In this work, a new aptamer was selected for amoxicillin and utilized for the development of a label-free electrochemical aptasensor. Aptamer selection was performed using the systematic evolution of ligands by exponential enrichment. The selected aptamer showed good specificity against other antibiotics, including the structurally related antibiotics: ampicillin and ciprofloxacin. Among the selected aptamers, Amx3 exhibited the lowest dissociation constant value of 112.9 nM. An aptasensor was developed by immobilization of thiolated Amx3 aptamer onto gold screen-printed electrodes via self-assembly, which was characterized using cyclic voltammetry and electrochemical impedance spectroscopy. The detection was realized by monitoring the change in the differential pulse voltammetry peak current in the ferro/ferricyanide redox couple upon binding of the aptasensor to amoxicillin. The aptasensor showed very good sensitivity with an ultralow limit of detection of 0.097 nM. When the aptasensor was tested using actual spiked milk samples, excellent recovery percentages were observed. The label-free electrochemical aptasensor developed herein is a promising tool for the selective and sensitive detection of amoxicillin in environmental samples.</p>","PeriodicalId":435,"journal":{"name":"Talanta","volume":null,"pages":null},"PeriodicalIF":6.1,"publicationDate":"2024-08-15","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"141092678","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":1,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
An innovative label-free electrochemical aptamer sensor: utilizing Ti3C2Tx/MoS2/Au NPs for accurate interleukin-6 detection. 创新的无标记电化学适配体传感器:利用 Ti3C2Tx/MoS2/Au NPs 精确检测白细胞介素-6。
IF 5.6 1区 化学
Talanta Pub Date : 2024-08-15 Epub Date: 2024-05-23 DOI: 10.1016/j.talanta.2024.126281
Zhuo Shi, Kaiwen Li, Yuwei Wang, Yuhan Hu, Zhanhong Li, Zhigang Zhu
{"title":"An innovative label-free electrochemical aptamer sensor: utilizing Ti<sub>3</sub>C<sub>2</sub>T<sub>x</sub>/MoS<sub>2</sub>/Au NPs for accurate interleukin-6 detection.","authors":"Zhuo Shi, Kaiwen Li, Yuwei Wang, Yuhan Hu, Zhanhong Li, Zhigang Zhu","doi":"10.1016/j.talanta.2024.126281","DOIUrl":"10.1016/j.talanta.2024.126281","url":null,"abstract":"<p><p>In the medical field, changes in interleukin-6 (IL-6) concentration serve as essential biomarkers for monitoring and diagnosing various conditions, including acute inflammatory responses such as those seen in trauma and burns, and chronic illnesses like cancer. This paper detailed a label-free electrochemical aptamer sensor designed for IL-6 quantification. A composite material consisting of Ti<sub>3</sub>C<sub>2</sub>T<sub>x</sub> and MoS<sub>2</sub> was successfully synthesized to fabricate this sensor. The synergistic effect of MoS<sub>2</sub>'s catalytic action on hydrogen peroxide (H<sub>2</sub>O<sub>2</sub>), used as a signalling marker, when combined with the exceptional conductivity and large specific surface area of Ti<sub>3</sub>C<sub>2</sub>T<sub>x</sub>, not only enables an increased loading of MoS<sub>2</sub> but also significantly boosts the electrochemical response. The in situ-reduced Au NPs provided stable immobilization sites for DNA aptamers (DNA<sub>apt</sub>) and facilitated electron transfer, ensuring accurate IL-6 recognition. Under optimal conditions, the aptamer sensor exhibited a wide linear range (5 pg/mL to 100 ng/mL) and a low limit of detection (LOD) of 2.9 pg/mL. Its sensing performance in human serum samples highlights its potential as a promising clinical analysis tool.</p>","PeriodicalId":435,"journal":{"name":"Talanta","volume":null,"pages":null},"PeriodicalIF":5.6,"publicationDate":"2024-08-15","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"141092673","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":1,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
An antagonist-based two-photon fluorogenic probe for imaging metabotropic glutamate receptor 5 in neuronal cells. 一种基于拮抗剂的双光子荧光探针,用于对神经细胞中的代谢谷氨酸受体 5 进行成像。
IF 6.1 1区 化学
Talanta Pub Date : 2024-08-01 Epub Date: 2024-05-01 DOI: 10.1016/j.talanta.2024.126167
Mingran Si, Xinyi Cai, Yani Liu, Zheng Li, Xiangjie Luo, Hai-Liang Zhu, Yong Qian
{"title":"An antagonist-based two-photon fluorogenic probe for imaging metabotropic glutamate receptor 5 in neuronal cells.","authors":"Mingran Si, Xinyi Cai, Yani Liu, Zheng Li, Xiangjie Luo, Hai-Liang Zhu, Yong Qian","doi":"10.1016/j.talanta.2024.126167","DOIUrl":"10.1016/j.talanta.2024.126167","url":null,"abstract":"<p><p>The expression of metabotropic glutamate receptor 5 (mGluR5) is subject to developmental regulation and undergoes significant changes in neuropsychiatric disorders and diseases. Visualizing mGluR5 by fluorescence imaging is a highly desired innovative technology for biomedical applications. Nevertheless, there are substantial problems with the chemical probes that are presently accessible. In this study, we have successfully developed a two-photon fluorogenic probe, mGlu-5-TP, based on the structure of mGluR5 antagonist 6-methyl-2-(phenylethynyl)pyridine (MPEP). Due to this antagonist-based probe selectively recognizes mGluR5, high expression of mGluR5 on living SH-SY5Y human neuroblastoma cells has been detected during intracellular inflammation triggered by lipopolysaccharides (LPS). Of particular significance, the probe can be employed along with two-photon fluorescence microscopy to enable real-time visualization of the mGluR5 in Aβ fiber-treated neuronal cells, thereby establishing a connection to the progression of Alzheimer's disease (AD). These results revealed that the probe can be a valuable imaging tool for studying mGluR5-related diseases in the nervous system.</p>","PeriodicalId":435,"journal":{"name":"Talanta","volume":null,"pages":null},"PeriodicalIF":6.1,"publicationDate":"2024-08-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"140849676","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":1,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Profuse color-evolution based aptasensor for mucin 1 detection utilizing urease-mediated color mixing of the mixed pH indicator. 利用脲酶介导的混合 pH 指示剂的颜色混合,基于颜色演变的粘蛋白 1 检测灵敏传感器。
IF 6.1 1区 化学
Talanta Pub Date : 2024-08-01 Epub Date: 2024-05-01 DOI: 10.1016/j.talanta.2024.126191
Jin-Hong Sui, Zhang-Run Xu
{"title":"Profuse color-evolution based aptasensor for mucin 1 detection utilizing urease-mediated color mixing of the mixed pH indicator.","authors":"Jin-Hong Sui, Zhang-Run Xu","doi":"10.1016/j.talanta.2024.126191","DOIUrl":"10.1016/j.talanta.2024.126191","url":null,"abstract":"<p><p>Mucin 1 is a significant tumor marker, and developing portable and cost-effective methods for its detection is crucial, especially in resource-limited areas. Herein, we developed an innovative approach for mucin 1 detection using a visible multicolor aptasensor. Urease-encapsulated DNA microspheres were used to mediate multicolor change facilitated by the color mixing of the mixed pH indicator, a mixed methyl red and bromocresol green solution. Distinct color changes were exhibited in response to varying mucin 1 concentrations. Notably, the color mixing of the mixed pH indicator was used to display various hues of colors, broadening the range of color variation. And color tonality is much easier to differentiate than color intensity, improving the resolution with naked-eyes. Besides, the variation of color from red to green (a pair of complementary colors) enhanced the color contrast, heightening sensitivity for visual detection. Importantly, the proposed method was successfully applied to detect mucin 1 in real samples, demonstrating a clear differentiation of colors between the samples of healthy individuals and breast cancer patients. The use of a mixed pH indicator as a multichromatic substrate offers the merits of low cost, fast response to pH variation, and plentiful color-evolution. And the incorporation of calcium carbonate microspheres to encapsulate urease ensures stable urease activity and avoids the need for extra urease decoration. The color-mixing dependent strategy opens a new way for multicolor detection of MUC1, characterized by vivid color changes.</p>","PeriodicalId":435,"journal":{"name":"Talanta","volume":null,"pages":null},"PeriodicalIF":6.1,"publicationDate":"2024-08-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"140849811","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":1,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Non-destructive and simultaneous development and enhancement of latent fingerprints on stainless steel based on the electrochromic effect of electrodeposited manganese oxides. 基于电沉积锰氧化物的电致变色效应,对不锈钢上的潜在指纹进行无损同步显影和增强。
IF 6.1 1区 化学
Talanta Pub Date : 2024-08-01 Epub Date: 2024-05-04 DOI: 10.1016/j.talanta.2024.126148
Chuanjun Yuan, Ming Li, Meng Wang, Jiaming Lv, Yifei Sun, Tianyi Lu, Yuxin Jia, Haijun Cao, Tianchun Lin
{"title":"Non-destructive and simultaneous development and enhancement of latent fingerprints on stainless steel based on the electrochromic effect of electrodeposited manganese oxides.","authors":"Chuanjun Yuan, Ming Li, Meng Wang, Jiaming Lv, Yifei Sun, Tianyi Lu, Yuxin Jia, Haijun Cao, Tianchun Lin","doi":"10.1016/j.talanta.2024.126148","DOIUrl":"10.1016/j.talanta.2024.126148","url":null,"abstract":"<p><p>Latent fingerprints, as one of the most frequently encountered traces in crime scene investigation and also one of the largest sources of forensic evidence, can play a critical role in determining the identity of a person who may be involved in a crime. Due to the invisible characteristic of latent fingerprints, exploring efficient techniques to visualize them (especially the ones resided on metallic surfaces) while retain the biological and chemical information (e.g., touch DNA) has become a multidisciplinary research focus. Herein we reported a new and highly sensitive electrochemical interfacial strategy of simultaneously developing and enhancing latent fingerprints on stainless steel based on synchronous electrodeposition and electrochromism of manganese oxides in a neutral aqueous electrolyte. By utilizing a specially designed device for electrochemical testing and image capture, a series of electrochemical measurements, physical characterization and image analysis have been applied to evaluate the feasibility, development accuracy and enhancement efficacy of the proposed electrochemical system. The qualitative and quantitative analysis on the in situ and ex situ fingerprint images indicates that the three levels of fingerprint features can be precisely developed and effectively enhanced. Forensic DNA typing has also been performed to reveal actual impact of the proposed electrochemical system on subsequent analysis of touch DNA in fingerprint residues. The ratio of detected loci after electrochemical treatment reaches up to 98.5 %, showing non-destructive nature of this fingerprint development and enhancement technique.</p>","PeriodicalId":435,"journal":{"name":"Talanta","volume":null,"pages":null},"PeriodicalIF":6.1,"publicationDate":"2024-08-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"140847811","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":1,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Automated H2O2 monitoring during photo-Fenton processes using an Arduino self-assembled automatic system. 利用 Arduino 自组装自动系统对光-芬顿过程中的 H2O2 进行自动监测。
IF 6.1 1区 化学
Talanta Pub Date : 2024-08-01 Epub Date: 2024-05-03 DOI: 10.1016/j.talanta.2024.126195
Kevin U Antela, Davide Palma, Angel Morales-Rubio, M Luisa Cervera, Alessandra Bianco Prevot
{"title":"Automated H<sub>2</sub>O<sub>2</sub> monitoring during photo-Fenton processes using an Arduino self-assembled automatic system.","authors":"Kevin U Antela, Davide Palma, Angel Morales-Rubio, M Luisa Cervera, Alessandra Bianco Prevot","doi":"10.1016/j.talanta.2024.126195","DOIUrl":"10.1016/j.talanta.2024.126195","url":null,"abstract":"<p><p>A cheap and easy to use Arduino self-assembled automatic system was employed to continuously monitor the hydrogen peroxide consumption during the photo-Fenton degradation of caffeine, selected as model target compound. The automatic system made it possible to measure the H<sub>2</sub>O<sub>2</sub> concentration in the reaction cell via a colorimetric reaction and to take samples for HPLC analysis minimising the operator manual intervention and exposure to UV radiation. The obtained results were compared in terms of LOD and LOQ with H<sub>2</sub>O<sub>2</sub> measurements manually performed using UV-Vis spectrophotometry, evidencing better analytical performance when using the automatic system; LOD and LOQ were respectively 0.032 mM and 0.106 mM for the automatic system against 0.064 mM and 0.213 mM for UV-Vis spectrophotometry. Furthermore, the photo-Fenton treatment was optimised by means of a Design of Experiments (DoE) investigating the effect of added H<sub>2</sub>O<sub>2</sub> concentration, iron concentration and caffeine initial concentration on system performances. The use of the automatic device for such monitoring provided several advantages: automation (with consequent reduction of the workload), measurement increased precision, reduced reagents consumption and waste production in agreement with the principles of Green Analytical Chemistry.</p>","PeriodicalId":435,"journal":{"name":"Talanta","volume":null,"pages":null},"PeriodicalIF":6.1,"publicationDate":"2024-08-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"140846459","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":1,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Detection of acetaminophen and P-aminophenol simultaneously by an electrochemical sensor based on Fe-NC derivatives attached with Ti3C2 QDs. 基于附着有 Ti3C2 QD 的 Fe-NC 衍生物的电化学传感器同时检测对乙酰氨基酚和对氨基苯酚。
IF 6.1 1区 化学
Talanta Pub Date : 2024-08-01 Epub Date: 2024-05-01 DOI: 10.1016/j.talanta.2024.126192
Jinjin Zhang, Sumin Xu, Wenjing Liu, Qi Wang, Jianying Qu
{"title":"Detection of acetaminophen and P-aminophenol simultaneously by an electrochemical sensor based on Fe-NC derivatives attached with Ti<sub>3</sub>C<sub>2</sub> QDs.","authors":"Jinjin Zhang, Sumin Xu, Wenjing Liu, Qi Wang, Jianying Qu","doi":"10.1016/j.talanta.2024.126192","DOIUrl":"10.1016/j.talanta.2024.126192","url":null,"abstract":"<p><p>In this paper, Ti<sub>3</sub>C<sub>2</sub> QDs and Fe-ZIF-8 were synthesized by a straightforward hydrothermal method. Fe-ZIF-8 was pyrolyzed at high temperatures to obtain Fe-nanoclusters (Fe-NC). Then Fe-NC is mixed with Ti<sub>3</sub>C<sub>2</sub> QDs to form a new composite material (Ti<sub>3</sub>C<sub>2</sub> QDs/Fe-NC), and its microstructure and composition were analyzed by technology. The proposed material can detect acetaminophen (PA) and P-aminophenol (4-AP) simultaneously with excellent detection performance. With the best conditions, the linear ranges and detection limits were 0.50-210.00 μM, 0.03 μM (S/N = 3) and 0.50-150.00 μM, 0.06 μM (S/N = 3) for PA and 4-AP, respectively. The sensor has lower detection limits and wider linear ranges, and can successfully detect 4-AP and PA in river water and acetaminophen tablets at the same time, showing potential practical application prospects. Especially, this study reports the modification of MOF derivatives with Ti<sub>3</sub>C<sub>2</sub> QDs for the first time, which expands the application scope of Quantum Dots and MOF derivatives.</p>","PeriodicalId":435,"journal":{"name":"Talanta","volume":null,"pages":null},"PeriodicalIF":6.1,"publicationDate":"2024-08-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"140846834","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":1,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Development of an atmospheric pressure plasma-based OES device for in-situ mapping of Cd and related elements in plants. 开发基于常压等离子体的 OES 设备,用于植物中镉及相关元素的原位绘图。
IF 6.1 1区 化学
Talanta Pub Date : 2024-08-01 Epub Date: 2024-05-01 DOI: 10.1016/j.talanta.2024.126196
Chaoqun Geng, Tiantian Zhang, Zheng Dong, Yuan Lu, Biao Ma, Yuan Xu, Zhao Yang, Shuai Liang, Xuelu Ding
{"title":"Development of an atmospheric pressure plasma-based OES device for in-situ mapping of Cd and related elements in plants.","authors":"Chaoqun Geng, Tiantian Zhang, Zheng Dong, Yuan Lu, Biao Ma, Yuan Xu, Zhao Yang, Shuai Liang, Xuelu Ding","doi":"10.1016/j.talanta.2024.126196","DOIUrl":"10.1016/j.talanta.2024.126196","url":null,"abstract":"<p><p>We have developed an innovative optical emission spectrometry imaging device integrating a diode laser for sample introduction and an atmospheric pressure plasma based on dielectric barrier discharge for atomization and excitation. By optimizing the device parameters and ensuring appropriate leaf moisture, we achieved effective imaging with a lateral resolution as low as 50 μm. This device allows for tracking the accumulation of Cd and related species such as K, Zn, and O<sub>2</sub><sup>+∙</sup>, in plant leaves exposed to different Cd levels and culture times. The results obtained are comparable to established in-lab imaging and quantitative methods. With its features of compact construction, minimal sample preparation, ease of operation, and low limit of detection (0.04 μg/g for Cd), this novel methodology shows promise as an in-situ elemental imaging tool for interdisciplinary applications.</p>","PeriodicalId":435,"journal":{"name":"Talanta","volume":null,"pages":null},"PeriodicalIF":6.1,"publicationDate":"2024-08-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"140848173","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":1,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
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