ChemElectroChem最新文献

Core–Shell Molecularly Imprinted Polymer@SiO2@Fe3O4 for Low-Cost and Selective Electrochemical Sensing of Paraquat 核壳分子印迹Polymer@SiO2@Fe3O4用于百草枯低成本和选择性电化学传感

IF 5.2 4区化学

ChemElectroChem Pub Date : 2026-10-14 DOI: 10.1002/celc.70332

M. Ashraful Kader, Gang Li, Yang Liu

{"title":"Core–Shell Molecularly Imprinted Polymer@SiO2@Fe3O4 for Low-Cost and Selective Electrochemical Sensing of Paraquat","authors":"M. Ashraful Kader, Gang Li, Yang Liu","doi":"10.1002/celc.70332","DOIUrl":"https://doi.org/10.1002/celc.70332","url":null,"abstract":"The widespread use of the water-soluble paraquat (PQ) herbicide has found to be linked with numerous toxic outcomes to humans as well as aquatic animals, while the on-site and rapid measurement is still challenging due to unsuitability and lack of selectivity of the existing techniques. This study presents a selective, sensitive, and low-cost electrochemical sensor for detecting residual PQ in water by combining a core–shell molecularly imprinted polymer (MIP)@SiO2@Fe3O4 material with a portable screen-printed carbon electrode (SPCE). Adsorptive stripping voltammetry (AdSV) was employed to determine PQ using the proposed MIP@SiO2@Fe3O4/SPCE, exhibiting high analytical performance with a sensitivity of 7.27 µA/µM, a two-segment linear range of 0.25–20 and 20–50 µM, and a detection limit of 0.043 µM. In addition, excellent selectivity towards PQ was achieved, even in the presence of a 20-fold excess of interfering substances commonly found in various water matrices. Recoveries of 89.72%–113.46% were obtained at the MIP@SiO2@Fe3O4/SPCE for the determination of PQ in tap water, river water, and seawater samples, and the results were validated using high-performance liquid chromatography, demonstrating its strong potential for practical applications in aquatic analysis.","PeriodicalId":142,"journal":{"name":"ChemElectroChem","volume":"13 21","pages":""},"PeriodicalIF":5.2,"publicationDate":"2026-10-14","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://onlinelibrary.wiley.com/doi/epdf/10.1002/celc.70332","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"149177390","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"OA","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

引用次数: 0

Rapid Alternating Polarity-Enabled Electrochemical Decarboxylative Borylation of Aryl Carboxylic Acids 快速交变极性催化芳基羧酸的电化学脱羧硼酸化

IF 5.2 4区化学

ChemElectroChem Pub Date : 2026-10-14 DOI: 10.1002/celc.70320

Riya Halder, Johannes L. Röckl, Anna Olsson, Eleni Lazaridi, Lutz Ackermann, Magnus J. Johansson

{"title":"Rapid Alternating Polarity-Enabled Electrochemical Decarboxylative Borylation of Aryl Carboxylic Acids","authors":"Riya Halder, Johannes L. Röckl, Anna Olsson, Eleni Lazaridi, Lutz Ackermann, Magnus J. Johansson","doi":"10.1002/celc.70320","DOIUrl":"https://doi.org/10.1002/celc.70320","url":null,"abstract":"Aromatic carboxylic acids are attractive feedstocks owing to their stability, commercial abundance, and widespread presence in pharmaceuticals and functional molecules. However, their direct decarboxylation under mild conditions has remained a longstanding challenge because of the slow fragmentation of aroyloxyl radicals and the prevalence of competing pathways. Herein, we report an electrochemical decarboxylative borylation of aryl carboxylic acids enabled by rapid alternating polarity (rAP) using reticulated vitreous carbon (RVC) electrodes. The protocol operates at ambient temperature without transition metals or external oxidants, delivering aryl boronic acid esters directly from abundant aromatic acid feedstocks. In addition to its synthetic utility, the method exhibits markedly lower energy intensity than previously reported photochemical decarboxylation platforms, highlighting its potential as a scalable and sustainable strategy for the direct conversion of abundant aromatic acid feedstocks into valuable organoboron building blocks.","PeriodicalId":142,"journal":{"name":"ChemElectroChem","volume":"13 21","pages":""},"PeriodicalIF":5.2,"publicationDate":"2026-10-14","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://onlinelibrary.wiley.com/doi/epdf/10.1002/celc.70320","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"149177392","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"OA","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

引用次数: 0

Synthesis of Bi2Se3 Nanosheets on COF Surfaces as Cathode for Lithium-Sulfur Batteries: Synergistic Mechanism of Anchoring and Catalyzing Polysulfides 碳纳米管表面合成Bi2Se3纳米片作为锂硫电池正极：锚定和催化多硫化物的协同机制

IF 5.2 4区化学

ChemElectroChem Pub Date : 2026-10-14 DOI: 10.1002/celc.70321

Jin Guo, Lixuan Wang, Lihong Song, Xiaoyan Yan, Shijian Yan, Zhanlong Li, Huaying Li, Wei Kong Pang

{"title":"Synthesis of Bi2Se3 Nanosheets on COF Surfaces as Cathode for Lithium-Sulfur Batteries: Synergistic Mechanism of Anchoring and Catalyzing Polysulfides","authors":"Jin Guo, Lixuan Wang, Lihong Song, Xiaoyan Yan, Shijian Yan, Zhanlong Li, Huaying Li, Wei Kong Pang","doi":"10.1002/celc.70321","DOIUrl":"https://doi.org/10.1002/celc.70321","url":null,"abstract":"Lithium-sulfur (Li-S) batteries are one of the popular choices for the high energy storage systems due to their high theoretical energy density, cheap raw materials, and environmental friendliness. This work adopts a hydrothermal method to prepare covalent organic frameworks (COFs). Bi2Se3 nanosheets are synthesized on COFs to obtain Bi2Se3/COFs composites serving as sulfur hosts. The porous COFs accommodate active sulfur and restrain the diffusion and migration of lithium polysulfides simultaneously. Furthermore, polar Bi2Se3 immobilizes lithium polysulfides via chemical adsorption and efficiently alleviates the shuttle effect. Its layered nanostructure not only improves the structural stability of the cathode, but also endows the composites with superior electrical conductivity to accelerate the the redox reaction of sulfur. The results illustrate that the S/Bi2Se3/COFs electrode shows a remarkable initial discharge specific capacity of 961.2 mAh g−1 at 0.5 C. After 700 cycles, the capacity decay rate is 0.047% per cycle, showing excellent cycle stability. Therefore, the Bi2Se3/COFs are a desirable sulfur-loading host for high-performance Li-S batteries.","PeriodicalId":142,"journal":{"name":"ChemElectroChem","volume":"13 21","pages":""},"PeriodicalIF":5.2,"publicationDate":"2026-10-14","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://onlinelibrary.wiley.com/doi/epdf/10.1002/celc.70321","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"149177391","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"OA","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

引用次数: 0

Comparison of Different Electrochemical Setups for Noninvasive Impedance Measurements on Archeological Coins 不同电化学装置对考古钱币无创阻抗测量的比较

IF 5.2 4区化学

ChemElectroChem Pub Date : 2026-10-12 DOI: 10.1002/celc.70318

Enrico Verlato, Marco Musiani

{"title":"Comparison of Different Electrochemical Setups for Noninvasive Impedance Measurements on Archeological Coins","authors":"Enrico Verlato, Marco Musiani","doi":"10.1002/celc.70318","DOIUrl":"https://doi.org/10.1002/celc.70318","url":null,"abstract":"The electrochemical characterization of cultural heritage objects requires noninvasive approaches. In the case of patina-covered bronze objects, two essential features of the setups recently proposed to satisfy this requirement are (i) the use of gel electrolytes and (ii) the absence of metal contacts that might damage the patina (or, at least, the control of the size of the damaged area to make it invisible to the naked eye). In the present work we show how the impedance of model coins is most conveniently measured using a four-electrode setup where the sample is mounted in a symmetrical two-compartment cell filled with a gel electrolyte which contacts both coin faces. Results are presented for model coins with polished surfaces, patina-covered coins, coins pretreated with a corrosion inhibitor (benzotriazole), and coins coated with a commercial acrylate/methacrylate copolymer (Paraloid B-72(R)). Compared with alternative approaches involving two-electrode or three-electrode setups, our approach is the only one which simultaneously warrants a noninvasive character and the direct determination of the sample impedance without needing any correction. Although only model coins were used in this study, the above conclusion applies as well to true archaeological coins.","PeriodicalId":142,"journal":{"name":"ChemElectroChem","volume":"13 20","pages":""},"PeriodicalIF":5.2,"publicationDate":"2026-10-12","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://onlinelibrary.wiley.com/doi/epdf/10.1002/celc.70318","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"149205478","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"OA","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

引用次数: 0

Bromine Retention Versus Electrochemical Accessibility in a Ferri-/Ferrocyanide–Bromine Flow Battery 铁/氰化铁-溴液流电池中溴的保留与电化学可及性

IF 5.2 4区化学

ChemElectroChem Pub Date : 2026-10-11 DOI: 10.1002/celc.70319

Jungmyung Kim, Joseph B. Russell, Shaan Bibi Jaffri, Edward Brightman, Stuart D. Robertson, Jaewoo Seo, Dowon Bae

{"title":"Bromine Retention Versus Electrochemical Accessibility in a Ferri-/Ferrocyanide–Bromine Flow Battery","authors":"Jungmyung Kim, Joseph B. Russell, Shaan Bibi Jaffri, Edward Brightman, Stuart D. Robertson, Jaewoo Seo, Dowon Bae","doi":"10.1002/celc.70319","DOIUrl":"https://doi.org/10.1002/celc.70319","url":null,"abstract":"Bromine retention in aqueous redox flow batteries can be improved by complexation, but the resulting gain in stability is often accompanied by losses in electrochemical accessibility and transport. Here, we investigate a ferri-/ferrocyanide–bromine flow battery based on soluble ferri-/ferrocyanide and bromine/bromide redox electrolytes. Three bromine/bromide positive-electrolyte conditions were compared: a pristine bromide electrolyte, an electrolyte containing the bromine-complexing agent (BCA) N-ethyl-N-methylpyrrolidinium bromide ([EMPyrr]Br), and the same electrolyte after nitrogen presparging. Charge–capacity retention after 70 cycles increased from 23.4% for the pristine electrolyte to 34.9% with [EMPyrr]Br and 66.0% with [EMPyrr]Br and nitrogen presparging. Because neither a nitrogen-pre-sparged BCA-free control nor an alternative inert-gas control was examined, the higher retention cannot be attributed uniquely to nitrogen; deaeration and sparging-induced redistribution of bromine-rich phases may also contribute. Improved retention was accompanied by increased polarization, higher ex situ electrolyte impedance, and an initial voltage rise associated with bromine-rich phase formation. Postcycling cyclic voltammetry provides qualitative evidence of bromine crossover, while Raman spectroscopy shows condition-dependent bromine-related signatures in the sampled liquid phase. These findings show that improved charge–capacity retention does not necessarily translate into better cell performance unless the retained bromine remains electrochemically accessible.","PeriodicalId":142,"journal":{"name":"ChemElectroChem","volume":"13 20","pages":""},"PeriodicalIF":5.2,"publicationDate":"2026-10-11","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://onlinelibrary.wiley.com/doi/epdf/10.1002/celc.70319","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"149205315","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"OA","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

引用次数: 0

Finite Element Analysis of Programmable Chemical Actuators 可编程化学执行器的有限元分析

IF 5.2 4区化学

ChemElectroChem Pub Date : 2026-10-11 DOI: 10.1002/celc.70322

J. Parker Evans, Vishnu B. Sundaresan, Katrina Cornish

{"title":"Finite Element Analysis of Programmable Chemical Actuators","authors":"J. Parker Evans, Vishnu B. Sundaresan, Katrina Cornish","doi":"10.1002/celc.70322","DOIUrl":"https://doi.org/10.1002/celc.70322","url":null,"abstract":"Spatiotemporal modulation of electrochemical gradients to control enzyme activity in biological systems has been achieved using programmable chemical actuators (PCAs). The electronic-ionic coupling by polypyrrole is the operational physics foundation of PCAs. In a previous study, pH-indicating dyes were used to measure the effects of potential application techniques on the temporal control over the gradient. Also, when PCAs were operated under duplex pulse amperometry, the duty cycle was studied as a control variable over soluble alkaline phosphatase activity. The data were used here to develop numerical models of the ion transport mechanisms in three PCAs differing in size and geometry based on finite element analysis. The models considered electric fields, ion flux, diffusion, and Coulombic repulsion and were implemented and solved with COMSOL Multiphysics using the Secondary Current Distribution and Transport of Diluted Species predefined application modes. The new models were able to accurately predict ion transport patterns induced by PCAs in a 6-well plate and a 10 mL beaker but were less accurate for a PCA in a semi-microcuvette, probably due to the dependence of current density on the surface roughness of the working electrode. Nonetheless, these models provide a good foundation to design PCAs for new applications.","PeriodicalId":142,"journal":{"name":"ChemElectroChem","volume":"13 20","pages":""},"PeriodicalIF":5.2,"publicationDate":"2026-10-11","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://onlinelibrary.wiley.com/doi/epdf/10.1002/celc.70322","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"149205314","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"OA","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

引用次数: 0

Molten Salt-Derived Double Transition Metal MXene (Ti2NbC2Tx) as a Capacitive Material for Energy Storage Applications 熔盐衍生的双过渡金属MXene （Ti2NbC2Tx）作为储能应用的电容材料

IF 5.2 4区化学

ChemElectroChem Pub Date : 2026-10-07 DOI: 10.1002/celc.70259

Kawthar Shaheen, Kangkang Ge, Pierre-Louis Taberna, Patrice Simon

引用次数: 0

Rational Engineering of Cellobiose Dehydrogenase via Substrate Pocket Redesign and Electron Transfer Optimization for Efficient Bioelectrosynthesis of Lactobionic Acid 纤维素二糖脱氢酶的底物口袋设计和电子转移优化在乳酸生物电合成中的应用

IF 5.2 4区化学

ChemElectroChem Pub Date : 2026-10-06 DOI: 10.1002/celc.70296

Xinyu Cui, Haiyan Song, Yuanming Wang, Zepeng Kang, Hao Su, Lingling Zhang, Zhiguang Zhu

{"title":"Rational Engineering of Cellobiose Dehydrogenase via Substrate Pocket Redesign and Electron Transfer Optimization for Efficient Bioelectrosynthesis of Lactobionic Acid","authors":"Xinyu Cui, Haiyan Song, Yuanming Wang, Zepeng Kang, Hao Su, Lingling Zhang, Zhiguang Zhu","doi":"10.1002/celc.70296","DOIUrl":"https://doi.org/10.1002/celc.70296","url":null,"abstract":"Cellobiose dehydrogenase (CDH) is a fungal extracellular flavocytochrome crucial for biomass degradation and promising for bioelectrocatalytic applications. However, its practical application remains limited by suboptimal catalytic efficiency and inefficient electron transfer. Here, an integrated engineering strategy was developed that couples substrate-pocket modification with electron-transfer optimization to enhance overall catalytic cycle simultaneously. Structure-guided engineering identified beneficial substrate-pocket mutations, which were subsequently combined with the previously validated electron-transfer-enhancing mutations (W316H and A165C), yielding the triple mutant A165C-N313D-W316H. This variant exhibited a fourfold increase in catalytic specific activity and an 8.5-fold enhancement in electron transfer rate relative to the WT. Molecular dynamics simulations further revealed that the mutation improves the hydrogen-bonding network within the substrate-binding pocket. Moreover, the mutant retained high thermostability, displayed enhanced specificity toward lactose, and reduced hydrogen peroxide generation by 82% compared with the WT. When immobilized on electrodes, A165C-N313D-W316H showed substantially improved electrocatalytic performance. Under optimized conditions, the MET-based bioelectrocatalytic system achieved a 94% conversion yield of lactobionic acid within 18 h. This study demonstrates that the integration of substrate-pocket and electron-transfer engineering effectively improves the overall catalytic cycle of CDH and provides a promising approach for engineering multidomain redox enzymes.","PeriodicalId":142,"journal":{"name":"ChemElectroChem","volume":"13 20","pages":""},"PeriodicalIF":5.2,"publicationDate":"2026-10-06","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://onlinelibrary.wiley.com/doi/epdf/10.1002/celc.70296","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"149145808","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"OA","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

引用次数: 0

Wireless Electrochemical Palladium Membrane Reactor 无线电化学钯膜反应器

IF 5.2 4区化学

ChemElectroChem Pub Date : 2026-10-06 DOI: 10.1002/celc.70324

Hossein Bemana, Jost Heise, Shuai Yan, Hariprasad Ranganathan, Abolfazl Kiani, Nikolay Kornienko

{"title":"Wireless Electrochemical Palladium Membrane Reactor","authors":"Hossein Bemana, Jost Heise, Shuai Yan, Hariprasad Ranganathan, Abolfazl Kiani, Nikolay Kornienko","doi":"10.1002/celc.70324","DOIUrl":"https://doi.org/10.1002/celc.70324","url":null,"abstract":"Electrochemical palladium membrane reactors traditionally rely on direct cathodic polarization of the palladium membrane to drive hydrogen permeation. This work introduces the wireless electrochemical palladium membrane reactor (wPMR), a design that utilizes bipolar electrochemistry to actuate hydrogen transport without direct electrical connections to the membrane. By redefining the palladium membrane as an “ajar” bipolar electrode, we demonstrate that it functions similarly to a diode, requiring a voltage threshold to initiate selective hydrogen transport along an induced external electric field. As a proof-of-concept, we integrated the wPMR with lithium-mediated nitrogen reduction, successfully synthesizing ammonia using hydrogen atoms derived directly from water. Unlike conventional systems that suffer from structural deformation due to lattice expansion, the wPMR maintains membrane integrity by avoiding the lattice-expanded β-PdH. Through isotope labeling and operando monitoring, we confirm the synchronous operation of four Faradaic reactions within this reaction geometry. The wPMR thus emerges as a high-voltage electrosynthetic platform capable of directly delivering hydrogen from water to organic reactions.","PeriodicalId":142,"journal":{"name":"ChemElectroChem","volume":"13 20","pages":""},"PeriodicalIF":5.2,"publicationDate":"2026-10-06","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://onlinelibrary.wiley.com/doi/epdf/10.1002/celc.70324","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"149145807","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"OA","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

引用次数: 0

Performance Optimization and Prospects of Double Network Hydrogels for Flexible Electronic Devices 柔性电子器件用双网络水凝胶的性能优化与展望

IF 5.2 4区化学

ChemElectroChem Pub Date : 2026-10-06 DOI: 10.1002/celc.70270

Liu Xing, Feng Ailing, Peng Yue, Guo Yating, Liu Yuhui, Li Lanfen, Zu Yanqing, Liu Peitao, Li Xiaodong

{"title":"Performance Optimization and Prospects of Double Network Hydrogels for Flexible Electronic Devices","authors":"Liu Xing, Feng Ailing, Peng Yue, Guo Yating, Liu Yuhui, Li Lanfen, Zu Yanqing, Liu Peitao, Li Xiaodong","doi":"10.1002/celc.70270","DOIUrl":"https://doi.org/10.1002/celc.70270","url":null,"abstract":"Dual-network (DN) hydrogels possess tunable polymer network architectures, exceptional mechanical robustness, and superior water retention capability. They demonstrate substantial potential in structural optimization and performance stabilization, thus garnering widespread attention from both the academic and industrial sectors in the field of flexible devices such as supercapacitors, temperature sensors, and zinc-air batteries. Focusing on the gelation mechanisms of DN hydrogels, this review systematically classifies them into three categories according to different cross-linking interactions, namely Chemical crosslinking, physical crosslinking, and hybrid crosslinking. Notably, this review details optimization strategies for the electrical conductivity, temperature resistance, and mechanical properties of DN hydrogels, including porosity enhancement, conductive filler incorporation, the salt-in-water strategy, and network structure modulation. Finally, it elaborates on the applications of DN hydrogels in flexible devices (supercapacitors, temperature sensors, zinc-air batteries). Based on the aforementioned findings, an innovative and feasible strategic outlook is put forward, with the aim of facilitating the further advancement of these flexible devices.","PeriodicalId":142,"journal":{"name":"ChemElectroChem","volume":"13 20","pages":""},"PeriodicalIF":5.2,"publicationDate":"2026-10-06","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://onlinelibrary.wiley.com/doi/epdf/10.1002/celc.70270","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"149145841","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"OA","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

引用次数: 0