Energy & Environmental Science最新文献

{"title":"Solid-State Electrolytes Expediting Interface-Compatible Dual-Conductive Cathodes for All-Solid-State Batteries","authors":"Shumin Zhang, Feipeng Zhao, Liang Li, Xueliang Sun","doi":"10.1039/d5ee01767j","DOIUrl":"https://doi.org/10.1039/d5ee01767j","url":null,"abstract":"With the rapid development of solid-state electrolytes (SSEs), high-performance cathode materials specifically designed for all-solid-state batteries (ASSBs) are gathering increasing attention. Achieving interfacial compatibility between the continuously advancing SSEs and cathode active materials (CAMs) is crucial for the realization of advanced ASSBs. Recently, the emergence of interface-compatible dual-conductive (ICDC) cathodes has opened a novel pathway towards developing ASSBs with high energy density and cost efficiency. The ICDC cathode refers to a single cathode material engineered to simultaneously achieve mixed ionic-electronic conductivity while ensuring good compatibility with SSEs in ASSBs. This innovative research topic has been propelled by the ongoing evolution of SSEs. In this minireview, we first discuss the progress in the mutual enhancement of SSEs and cathode materials, with a focus on addressing interface compatibility and dual conductivity challenges faced by conventional layered oxide CAMs in advanced sulfide- or halide-based ASSBs. Then, we outline two primary approaches for achieving ICDC cathodes: sulfurization and halogenation. Finally, we present an outlook, highlighting unresolved questions and future research directions. This minireview serves not only a summary of advancements in ICDC cathodes, but also a fundamental guidance to inspire further exploration for cathode materials integrated with the state-of-the-art SSEs.","PeriodicalId":72,"journal":{"name":"Energy & Environmental Science","volume":"26 1","pages":""},"PeriodicalIF":32.5,"publicationDate":"2025-05-30","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"144177123","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":1,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

{"title":"Aging matrix visualizes complexity of battery aging across hundreds of cycling protocols","authors":"Bruis van Vlijmen, Vivek N. Lam, Patrick A. Asinger, Xiao Cui, Joachim Schaeffer, Alexis Geslin, Devi Ganapathi, Shijing Sun, Patrick K. Herring, Chirranjeevi Balaji Gopal, Natalie Geise, Haitao D. Deng, Henry L. Thaman, Stephen Dongmin Kang, Steven B. Torrisi, Amalie Trewartha, Abraham Anapolsky, Brian D. Storey, William E. Gent, Richard D. Braatz, William C. Chueh","doi":"10.1039/d4ee05609d","DOIUrl":"https://doi.org/10.1039/d4ee05609d","url":null,"abstract":"To reliably deploy lithium-ion batteries, a fundamental understanding of cycling aging behavior is critical. Battery aging consists of complex and highly coupled phenomena, making it challenging to develop a holistic interpretation. In this work, we generate a diverse battery cycling dataset with a broad range of degradation trajectories, consisting of 359 high energy density commercial Li(Ni,Co,Al)O<small>₂</small>/graphite + SiO<small>_<em>x</em></small> cylindrical 21 700 cells cycled across 207 unique cycling protocols. We consolidate aging <em>via</em> 16 mechanistic state-of-health (SOH) metrics, including cell-level performance metrics, electrode-specific capacities/state-of-charges (SOCs), and aging trajectory metrics. We develop a framework using interpretable machine learning and explainable features to generate an aging matrix that visually deconvolutes the complex battery degradation behavior. This generalizable data-driven mechanistic framework simplifies the complex interplay between cycling conditions, degradation modes, and SOH, acting as a hypothesis-generation tool to aid battery users in identifying key degradation regimes for further study and experimentation.","PeriodicalId":72,"journal":{"name":"Energy & Environmental Science","volume":"19 1","pages":""},"PeriodicalIF":32.5,"publicationDate":"2025-05-30","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"144177122","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":1,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

{"title":"Ionic Potential Modulation in and between Layers of Transition Metal Oxides towards Ultrahigh-Rate Sodium Storage","authors":"Ziming Wang, Riming Hu, Hao Chen, Yuxuan Ye, Qi Zhao, Zhiguo Du, Shubin Yang","doi":"10.1039/d5ee01792k","DOIUrl":"https://doi.org/10.1039/d5ee01792k","url":null,"abstract":"Although layered oxides have been considered as promising cathodes for sodium-ion batteries (SIBs), they still suffer from poor structural stability and sluggish Na+ diffusion kinetics, hampering their cycling stability at high current rates. Herein, we demonstrate an efficient ionic potential modulation strategy to produce a lattice-stable layered oxide with favorable Na+ diffusion kinetics via selective introduction of cations with different ionic potentials into transition metal (TM) layers and Na layers of layered oxides. In contrast to the implantation of cations with high ionic potentials (Φ &gt; 28.99 nm−1), introducing cations with low ionic potentials (e.g., Li+, 13.16 nm−1) into TM layers enables to facilitate the delocalization of electron clouds around lattice O2− towards TM ions, thereby constructing a unique O-TM-O interlocking configuration to simultaneously improve the stability of TM ions and lattice O2−. Meanwhile, the incorporation of cations with low ionic potentials such as K+ (7.25 nm−1) into Na layers (Na+, 9.80 nm−1) induces an attenuated K+-Na+ electrostatic interaction, thus diminishing the repulsion during Na+ diffusion process. These unique features not only strengthen the skeletal structure of TM layers, but also promote the Na+ interlayer diffusion. Consequently, an excellent rate performance of 78.7 mAh g−1 at 50 C and a long-term stability up to 2000 cycles are achieved in SIBs.","PeriodicalId":72,"journal":{"name":"Energy & Environmental Science","volume":"27 1","pages":""},"PeriodicalIF":32.5,"publicationDate":"2025-05-30","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"144177124","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":1,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

{"title":"Electrochemical reactors for the utilization of liquid-phase carbon species","authors":"Jundong Wang, Pan Zhu, Hongling Qin, Kuichang Zuo, Huazhang Zhao, Zishuai Bill Zhang","doi":"10.1039/d5ee01448d","DOIUrl":"https://doi.org/10.1039/d5ee01448d","url":null,"abstract":"Electrochemical utilization of liquid-phase carbon species presents a promising approach to reducing CO<small>₂</small> emissions while generating value-added chemicals. By bypassing energy-intensive CO<small>₂</small> liberation steps, this method enables the direct integration of carbon capture and utilization. This review highlights recent advancements in the use of concentrated carbon capture solutions (&gt;0.1 M) and seawater (∼2 mM) as feedstocks for electrochemical systems. Key developments in reaction mechanisms, catalyst design, reactor configurations, and operational strategies are explored, with a focus on enhancing selectivity, stability, and energy efficiency. Critical challenges, including system integration, impurity management, fouling, and long-term operational stability, are thoroughly analyzed. By integrating insights from technology development, reaction mechanisms, materials science, and system engineering, this review provides a comprehensive overview of this emerging field. It also outlines pathways to advance scalable and sustainable liquid-phase carbon utilization, offering a roadmap for future research and practical implementation in global carbon management efforts.","PeriodicalId":72,"journal":{"name":"Energy & Environmental Science","volume":"36 1","pages":""},"PeriodicalIF":32.5,"publicationDate":"2025-05-29","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"144165517","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":1,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

{"title":"Failure Mode Diagnosis and Stabilization of an Efficient Reverse-Bias Bipolar Membrane CO2 to CO Electrolyzer","authors":"Sven Brückner, Oleksandr Bondarchuk, Ana Araujo, Wen Ju, Rosalía Cid Barreno, Elvira Paz, Florian Krebs, Salomé Soares, Pierre Schröer, Peter Strasser, Isilda Amorim, Zhipeng Yu, Philipp Hauke, Manuel Fernando Pereira, Lifeng Liu","doi":"10.1039/d5ee01817j","DOIUrl":"https://doi.org/10.1039/d5ee01817j","url":null,"abstract":"Efficient and stable CO2-to-CO electrolyzers are key process components for the generation of green synthesis gas and its downstream conversion and valorization to carbonaceous e-chemicals and e-fuels. While alkaline CO2 electrolyzers suffer from low CO2 utilization due to cathodic carbonate formation and crossover, acidic CO2 electrolyzers suffer from low CO faradaic efficiency. Reverse-bias Bipolar Membrane (BPM) cell architectures have been proposed to promote cathodic proton transport, yet resulted in limited cell lifetimes due to complex degradation and failure regimes. A thorough diagnosis of BPM cell dynamics is missing to date. Here, we build and diagnose an efficient zero-gap reverse-bias BPM CO2-to-CO electrolyzer cell deploying CO-selective single Ni atom cathode catalysts. We analyzed its key cell performance parameters and diagnosed the cell stability and failure regimes over 100 hours. The electrolyzer cell showed excellent performance up to 500 mA cm-2 with CO faradaic efficiency near 100 %. The proton-controlled ion transport in the cathode was directly confirmed by an experimental carbon cross-over coefficient (CCC) of zero, suggesting minimal carbon loss due to carbonate formation. This was coupled to a high single pass conversion of ~70% at the largest current densities and 60 vol% CO in the cell outlet, ideally suited for process cascade involving electro- or thermal catalytic steps. While use of a N2 bleed for internal reference has been known to be critical for accurate evaluation of cell performance, we now propose the experimental N2 vol% in the combined cell outlet and bleed flow to be also a valuable diagnostic tool to recognize and analyze cell failure regimes.","PeriodicalId":72,"journal":{"name":"Energy & Environmental Science","volume":"33 1","pages":""},"PeriodicalIF":32.5,"publicationDate":"2025-05-29","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"144165516","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":1,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

{"title":"Interfacial Ionic and Thermal Regulation for Highly Reversible and Ultra-Reliable Zinc-Ion Batteries","authors":"Mengcheng Huang, Yaojie Lei, Yajun Hu, Wei-Hong Lai, Yun-Xiao Wang, Chunyu Liu, Shengli Zhai, Guoxiu Wang","doi":"10.1039/d5ee01635e","DOIUrl":"https://doi.org/10.1039/d5ee01635e","url":null,"abstract":"Prevalent glass fiber separators in aqueous Zn-ion batteries (ZIBs) offer inadequate control over interfacial reactions, contributing to the rapid growth of Zn dendrites and aggravated parasitic reactions. Moreover, the stability of ZIBs under extreme operating conditions remains a critical yet often overlooked issue. Here, we present a novel silane-decorated glass fiber separator with engineered physical structures and surface chemistry, facilitating highly reversible and ultra-reliable ZIBs. Silane strengthens the separator, resists stress, and forms heat-insulating char layers under flame, ensuring reliability in extreme conditions. Silane networks also function as fillers that enhance pore uniformity for even Zn2+ flux. The amino groups in silane demonstrate comprehensive management of interfacial anions, cations, water transfer and reaction kinetics. This capability induces Zn2+ to concentrate at the interface, accelerates Zn2+ transfer, reduces deposition barriers, and obstructs water molecules and sulfate ions from participating in parasitic reactions. Consequently, dendrite-free Zn plating/stripping is achieved with 99.4% Coulombic efficiency over 250 cycles, stable charge/discharge performance for 7000 hours, and remarkable cycling stability and flame resistance for Zn//V full batteries. This strategy demonstrates versatility across various separator materials and battery chemistry, offering a promising route to more reliable and higher-performing energy storage systems.","PeriodicalId":72,"journal":{"name":"Energy & Environmental Science","volume":"60 1","pages":""},"PeriodicalIF":32.5,"publicationDate":"2025-05-29","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"144165515","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":1,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

{"title":"Hierarchically porous carbon supports enable efficient syngas production in electrified reactive capture","authors":"Hengzhou Liu, Heejong Shin, Xiao-Yan Li, Guangcan Su, Pengfei Ou, Yong Wang, Lihaokun Chen, Jiaqi Yu, Yuanjun Chen, Rong Xia, Geonhui Lee, Kug-Seung Lee, Christine Yu, Peiying Wang, Deokjae Choi, Daojin Zhou, Cong Tian, Issam Gereige, Ammar Alahmed, Aqil Jamal, Omar K. Farha, Shannon W. Boettcher, Jennifer B. Dunn, Ke Xie, Edward H. Sargent","doi":"10.1039/d5ee00094g","DOIUrl":"https://doi.org/10.1039/d5ee00094g","url":null,"abstract":"Direct-air capture (DAC) of CO<small>₂</small> often uses alkali hydroxides (<em>e.g.</em> KOH) as sorbent, and relies on an energy-intensive thermal CaCO<small>₃</small>/Ca(OH)<small>₂</small> step to release CO<small>₂</small> and regenerate the alkali hydroxide. Reactive capture instead uses alkali carbonate post-capture liquid as feedstock, seeking to convert the captured CO<small>₂</small> to value-added products while regenerating the capture liquid. Here we investigate the origins of low prior performance in electrochemical reactive capture systems, finding that the catalyst becomes starved of CO<small>₂</small> even at moderate current densities leading to a rapid decline in faradaic efficiency (FE). We then study how the catalyst support can be redesigned to tackle this problem, and construct hierarchical carbon supports featuring interconnected mesopores and micropores, our purpose to increase the interaction between <em>in situ</em> generated CO<small>₂</small>, <em>i</em>-CO<small>₂</small> – the limiting reagent – and the catalyst. We find that the attachment chemistry of the catalyst to the support is critical: only when we disperse and tether the molecular catalyst do we prevent catalyst aggregation and deactivation under bias. We report as a result carbonate electrolysis at 200 mA cm<small>⁻²</small> at 2.9 V with FE of 47 ± 1% for CO, this corresponding to an energy efficiency (EE) to 2 : 1 syngas of 50% at 200 mA cm<small>⁻²</small> when H<small>₂</small> is added using a water electrolyzer. This represents a 1.5× improvement in EE at this current density relative to the most efficient prior carbonate electrolysis reports. The CO FE remains above 40% at current densities as high as 500 mA cm<small>⁻²</small>, and all systems studied herein achieve &lt; 1% CO<small>₂</small> in the outlet stream. The cradle-to-gate carbon intensity is lowered to −1.49 tonCO<small>₂</small> per tonsyngas as a result of the increase in EE, and a CO<small>₂</small>-free tailgas stream is provided that minimizes separation costs.","PeriodicalId":72,"journal":{"name":"Energy & Environmental Science","volume":"3 1","pages":""},"PeriodicalIF":32.5,"publicationDate":"2025-05-29","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"144165514","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":1,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

{"title":"Precision N-Species Engineering in Pt–N4 via Ring-Reconstruction towards Efficient Alkaline Water Electrolysis","authors":"Zhenyu Liu, Junyi Du, Jin Yang, Yuanyuan Yan, Yatong Wang, Meiling Wang, Tian Wang, Lixing Kang, Dingsheng Wang","doi":"10.1039/d5ee01449b","DOIUrl":"https://doi.org/10.1039/d5ee01449b","url":null,"abstract":"Pyridinic-N (N[6]) and pyrrolic-N (N[5]) are vital for the performance of metal-nitrogen-carbon (M–N–C) catalysts, yet precise control over them remains elusive. Here we theoretically explore the impact of N[5]/N[6] atomic ratios on stabilities and activities of Pt–N4–C, a leading hydrogen evolution catalyst. Guided by the insight, we successfully synthesize the Pt–N4–C with an optimized 1:1 N[5]/N[6] ratio via hydrogen-assisted pyrolysis of ZIF-8@ZIF-67, followed by Pt coordination. In-situ generated Co nanoparticles convert partial N[6] to N[5], inducing a ring-reconstruction and fine-tuning of N ratios. The internal N-engineering of Pt1 coordinated with N[5]/[6]C and external OH adsorption on Con significantly reduce the alkaline water splitting energy barrier, achieving an exceptionally low voltage (1.82 V) and excellent stability (400 h @ 1 A cm-2) in membrane electrode assemblies. This work offers crucial insights into optimizing N[5]/N[6] ratios to enhance the performance of M–N–C catalyst.","PeriodicalId":72,"journal":{"name":"Energy & Environmental Science","volume":"16 1","pages":""},"PeriodicalIF":32.5,"publicationDate":"2025-05-28","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"144154181","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":1,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

{"title":"Bioinspired Electrocatalyst for CO2 Electroreduction to Ethanol via Secondary-Sphere Synergy in Fe Porphyrinic-Based Metal-Organic Frameworks","authors":"Kaian Sun, Shaohui Xie, Ping Guan, Zewen Zhuang, Xin Tan, Wei Yan, Jiujun Zhang, Chen Chen","doi":"10.1039/d5ee01388g","DOIUrl":"https://doi.org/10.1039/d5ee01388g","url":null,"abstract":"Carbon dioxide electroreduction reaction (CO2RR) to ethanol (C2H5OH) represents a sustainable route toward carbon neutrality. Herein, we present the design of enzyme-inspired zirconium-Fe porphyrinic-based metal-organic framework (MOF) nanosheets functionalized with 5-benzimidazolecarboxylic acid (FeTCPP-NSs-BAA) for CO2RR. Electrochemical performances in H-cell reveal that FeTCPP-NSs-BAA achieves C2H5OH Faradaic efficiencies (FEs) of 79.8% under neutral and 89.2% under acidic conditions, with C2H5OH FEs exceeding 60% over wide potential windows of –0.3 to –0.6 V and –0.3 to –0.8 V, respectively. In flow cell tests under acidic conditions, FeTCPP-NSs-BAA delivers a highest C2H5OH partial current density of 8.1 mA cm–2 with pure CO2, and a C2H5OH partial current density of 5.6 mA cm–2 when using 30% low-concentration CO2. Operando spectroscopic characterizations and theoretical calculations reveal that the superior C2H5OH performance of FeTCPP-NSs-BAA arises from the enzyme-like non-covalent synergistic effects between FeTCPP and the secondary-sphere functionalities of BAA and Zr6 clusters. Specifically, BAA enhances CO2 enrichment and facilitates the formation of tilted *CO adsorption at Fe centers on FeTCPP, which significantly reduces energy barriers for *CO-CO coupling compared to linearly adsorbed *CO. Meanwhile, the subsequent hydrogenation of *CO-CO to C2H5OH can be further accelerated by proton shuttling mediated through hydrogen-bonding networks introduced by Zr6 clusters.","PeriodicalId":72,"journal":{"name":"Energy & Environmental Science","volume":"10 1","pages":""},"PeriodicalIF":32.5,"publicationDate":"2025-05-28","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"144154182","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":1,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

{"title":"High-areal-capacity Na-ion battery electrode with high energy and power densities by simultaneous electrospinning-spraying fabrication","authors":"Mengzheng Ouyang, Zhenyu Guo, Luis E Salinas-Farran, Siyu Zhao, Mengnan Wang, Feiran Li, Yan Zhao, Kaitian Zheng, Hao Zhang, Guangdong Li, Xinhua Liu, Shichun Yang, Fei Xie, Paul Shearing, Maria Magdalena Titirici, Nigel Brandon","doi":"10.1039/d5ee01444a","DOIUrl":"https://doi.org/10.1039/d5ee01444a","url":null,"abstract":"Sodium-ion batteries (SIBs) are cost-effective alternatives to lithium-ion batteries (LIBs), but their low energy density remains a challenge. Current electrode designs fail to simultaneously achieve high areal loading, high active content, and superior performance. In response, this work introduces an ideal electrode structure, featuring a continuous conductive network with active particles securely trapped in the absence of binder, fabricated using a universal technique that combines electrospinning and electrospraying (co-ESP). We found that the particle size must be larger than the network's pores for optimised performance, an aspect overlooked in previous research. The free-standing co-ESP Na2V3(PO4)3 (NVP) cathodes demonstrated state-of-the-art 296 mg cm-2 areal loading with 97.5 wt.% active content, as well as remarkable rate-performance and cycling stability. Co-ESP full cells showed uncompromised energy and power densities (231.6 Wh kg-1/7152.6 W kg-1), leading among reported SIBs with industry-relevant areal loadings. The structural merit is analysed using multi-scale X-ray computed tomography, providing valuable design insights. Finally, the superior performance is validated in the pouch cells, highlighting the electrode’s scalability and potential for commercial application.","PeriodicalId":72,"journal":{"name":"Energy & Environmental Science","volume":"33 1","pages":""},"PeriodicalIF":32.5,"publicationDate":"2025-05-27","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"144145759","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":1,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}