European Journal of Inorganic Chemistry最新文献

Front Cover: Synthesis, Structure, and Reactivity of Ruthenium-Indane Complexes with Diphosphine Ligand (Eur. J. Inorg. Chem. 29/2024) 封面：含二膦配体的钌-茚配合物的合成、结构和反应活性（Eur.）

IF 2.2 4区化学

European Journal of Inorganic Chemistry Pub Date : 2024-10-11 DOI: 10.1002/ejic.202482901

Masumi Itazaki, Natsumi Kitani, Yukako Dobashi, Kento Okabayashi, Hiroshi Nakazawa, Toshiyuki Moriuchi

{"title":"Front Cover: Synthesis, Structure, and Reactivity of Ruthenium-Indane Complexes with Diphosphine Ligand (Eur. J. Inorg. Chem. 29/2024)","authors":"Masumi Itazaki, Natsumi Kitani, Yukako Dobashi, Kento Okabayashi, Hiroshi Nakazawa, Toshiyuki Moriuchi","doi":"10.1002/ejic.202482901","DOIUrl":"https://doi.org/10.1002/ejic.202482901","url":null,"abstract":"The Front Cover shows the molecular structures of two ruthenium–indane complexes: one is a binuclear Ru complex bridged by 1,2-bis(diphenylphosphino)ethane (dppe) ligand and the other is a mononuclear chelating 1,3-bis(diphenylphosphino)propane (dppp) complex. For the mononuclear complex, the Ru−P (P trans to In) bond distance (2.4076(11) Å) is shorter than the Ru−P (P trans to CO) one (2.4227(11) Å). It is known that both InCl3 and CO exhibit electron-withdrawing properties, but no comparison of their electron-withdrawing strengths has been reported. This result is the first to show that the InCl3 ligand withdraws electron density from Ru more strongly than the CO ligand. In addition, the mononuclear Ru−In complexes exhibit catalytic activity for the double hydrosilylation of organonitriles. More information can be found in the Research Article by M. Itazaki and co-workers.\u0000 <figure>\u0000 <div><picture>\u0000 <source></source></picture>\u0000 </div>\u0000 </figure>\u0000 ","PeriodicalId":38,"journal":{"name":"European Journal of Inorganic Chemistry","volume":null,"pages":null},"PeriodicalIF":2.2,"publicationDate":"2024-10-11","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://onlinelibrary.wiley.com/doi/epdf/10.1002/ejic.202482901","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"142438916","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"OA","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

引用次数: 0

High Performance of the Metal Organic Framework CPO-27 for Toxic Gas Capture (NO2) 高性能金属有机框架 CPO-27 用于有毒气体捕集（二氧化氮）

IF 2.2 4区化学

European Journal of Inorganic Chemistry Pub Date : 2024-10-04 DOI: 10.1002/ejic.202400253

Jannes Beihsner, Dr. Steffen Hausdorf, Prof. Dr. Ing. Jens Friedrich, Prof. Dr. Stefan Kaskel

{"title":"High Performance of the Metal Organic Framework CPO-27 for Toxic Gas Capture (NO2)","authors":"Jannes Beihsner, Dr. Steffen Hausdorf, Prof. Dr. Ing. Jens Friedrich, Prof. Dr. Stefan Kaskel","doi":"10.1002/ejic.202400253","DOIUrl":"https://doi.org/10.1002/ejic.202400253","url":null,"abstract":"Metal-organic frameworks of the CPO-27 (MOF-74) series are known for their high adsorption capacities for nitrogen oxides. On the other hand, significantly varying and partly contradictory results were reported regarding their stability to moisture. This aspect has hampered the use of these MOFs in air filtration applications. Here, we show that the stability of CPO-27 materials towards moisture and CO2 crucially depends on the synthesis parameters. By precisely adjusting the synthetic parameter-property relationship, it is possible to prepare a highly stable CPO-27(Ni) MOF by a simple precipitation in water. To demonstrate the capacity for NO2, breakthrough experiments were performed under dry and wet conditions (55% relative humidity). Extremely high values of nearly 0.74 g/g in dry conditions and 1.23 g/g under wet conditions were achieved. These results pave the way for the toxicologically safe and cost-effective preparation of a moisture-stable CPO-27(Ni), bridging the gap to a potential industrial application of the material for the selective adsorption of toxic gases, such as NO2.","PeriodicalId":38,"journal":{"name":"European Journal of Inorganic Chemistry","volume":null,"pages":null},"PeriodicalIF":2.2,"publicationDate":"2024-10-04","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://onlinelibrary.wiley.com/doi/epdf/10.1002/ejic.202400253","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"142438952","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"OA","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

引用次数: 0

Front Cover: Electrocatalytic Properties of meso- Perfluorinated Metallo Corroles for the Reduction of CO2 (Eur. J. Inorg. Chem. 28/2024) 封面：用于还原 CO2 的介-全氟金属环的电催化特性（Eur.）

IF 2.2 4区化学

European Journal of Inorganic Chemistry Pub Date : 2024-10-04 DOI: 10.1002/ejic.202482801

Chanjuan Zhang, Paul-Gabriel Julliard, Diana Dragoe, Ally Aukauloo, Gabriel Canard

引用次数: 0

Front Cover: A Novel Family of Luminescent Pyrenyl-(N-Heterocyclic Carbene)- Halogenated Coinage Metal Complexes: Synthesis, Crystal Structures, and Optical Properties (Eur. J. Inorg. Chem. 27/2024) 封面：新型发光芘-(N-杂环羰基)-卤代共价金属配合物家族：合成、晶体结构和光学特性》（Eur.）

IF 2.2 4区化学

European Journal of Inorganic Chemistry Pub Date : 2024-09-27 DOI: 10.1002/ejic.202482701

Yaping Cheng, Geoffrey Gontard, Marie Noelle Rager, Abderrahim Khatyr, Michael Knorr, Hani Amouri

引用次数: 0

Front Cover: Complexation of ThoriumIV with Fluorinated Heterocyclic β-Diketones in Aqueous Hydrochloric Solutions (Eur. J. Inorg. Chem. 26/2024) 封面：钍IV与含氟杂环β-二酮类化合物在盐酸水溶液中的络合（Eur.）

IF 2.2 4区化学

European Journal of Inorganic Chemistry Pub Date : 2024-09-19 DOI: 10.1002/ejic.202482601

Dr. Maxim A. Lutoshkin, Dr. Ilya V. Taydakov, Anastasia A. Patrusheva, Dr. Petr I. Matveev

引用次数: 0

Water Networks within Metal Organic Nanotubes: Assessment of Techniques to Understand Structure and Properties 金属有机纳米管中的水网络：评估了解结构和特性的技术

IF 2.524 4区化学

European Journal of Inorganic Chemistry Pub Date : 2024-09-19 DOI: 10.1002/ejic.202400327

Vidumini Suchintha Samarasiri, Tiron Jahinge, Tori Forbes

引用次数: 0

Isomerism in Molecular Metal Carbonyl Clusters 分子金属羰基团簇中的同分异构现象

IF 2.524 4区化学

European Journal of Inorganic Chemistry Pub Date : 2024-09-18 DOI: 10.1002/ejic.202400220

Cristiana Cesari, Cristina Femoni, Francesca Forti, Maria Carmela Iapalucci, Giorgia Scorzoni, Stefano Zacchini

{"title":"Isomerism in Molecular Metal Carbonyl Clusters","authors":"Cristiana Cesari, Cristina Femoni, Francesca Forti, Maria Carmela Iapalucci, Giorgia Scorzoni, Stefano Zacchini","doi":"10.1002/ejic.202400220","DOIUrl":"https://doi.org/10.1002/ejic.202400220","url":null,"abstract":"The present microreview focuses on different typologies of isomerism documented along the years for metal carbonyl clusters (MCCs), and outlines their analogies to other classes of ligand-protected molecular clusters and nanoclusters. Isomerism in molecular MCCs is discussed within two main categories, that is, surface isomerism and core isomerism. The first Section presents some representative examples of surface isomerism involving inorganic (carbonyls and hydrides) and organic ligands, as well as isomerism due to ML fragments decorating the cluster surface. The second Section focuses on three major categories of core isomerism, that is: (1) isomers that mainly differ on M-M distances; (2) isomers displaying different structures of the metal kernels; (3) isomers possessing almost identical metal kernels and ligand shells, but differing for the positions of different types of metal atoms within the metal kernel. The third Section briefly discusses two related and very rare cases of isomerism, that is, polymerisation and coordination isomerism. General conclusions are outlined in the final Section.","PeriodicalId":38,"journal":{"name":"European Journal of Inorganic Chemistry","volume":null,"pages":null},"PeriodicalIF":2.524,"publicationDate":"2024-09-18","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"142268680","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

引用次数: 0

The Rectangular Niobium Oxyiodide Cluster Nb4OI10 – A Narrow Band-Gap Semiconductor 矩形碘化铌簇 Nb4OI10 - 一种窄带隙半导体

IF 2.2 4区化学

European Journal of Inorganic Chemistry Pub Date : 2024-09-18 DOI: 10.1002/ejic.202400329

Jan Beitlberger, Dr. Markus Ströbele, Fabian Strauß, Prof. Dr. Marcus Scheele, Dr. Carl P. Romao, Prof. Dr. Hans-Jürgen Meyer

引用次数: 0

Synthesis and Reactivity of the Amino-Functionalized β-Diketiminate Ligand Stabilized Germylene and Stannylene 氨基官能化 β-二乙酰亚胺配体稳定胚芽烯和亚锡的合成与反应活性

IF 2.524 4区化学

European Journal of Inorganic Chemistry Pub Date : 2024-09-18 DOI: 10.1002/ejic.202400378

Tianyi Sun, Cheng Kong, Linlin Wu, Hao Wang

引用次数: 0

Synthesis, Characterization, and Catalysis of Planar Chiral Ferrocene-based N-Heterocyclic Carbene Ligands and Its Metal Complexes 平面手性二茂铁基 N-杂环羰基配体及其金属配合物的合成、表征和催化作用

IF 2.524 4区化学

European Journal of Inorganic Chemistry Pub Date : 2024-09-18 DOI: 10.1002/ejic.202400492

Shin-ichi Fukuzawa, Shungo Shimizu, Kazuki Osawa

{"title":"Synthesis, Characterization, and Catalysis of Planar Chiral Ferrocene-based N-Heterocyclic Carbene Ligands and Its Metal Complexes","authors":"Shin-ichi Fukuzawa, Shungo Shimizu, Kazuki Osawa","doi":"10.1002/ejic.202400492","DOIUrl":"https://doi.org/10.1002/ejic.202400492","url":null,"abstract":"This study presents the development of a novel planar chiral ferrocene-based NHC ligand and its corresponding metal complexes. The key unit of the imidazolium backbone, planar chiral ortho-isopropyl ferrocenyl amine, was synthesized starting from (R)-Ugi's amine. Imidazolium was obtained through the sequential condensation of glyoxal with ferrocenyl amine, followed by the ring-closure of 1,3-diferrocenyldiimine with chloromethylethyl ether. Chiral imidazolylidene NHC (IFcPr) metal complexes were prepared by treating imidazolium with silver oxide or base followed by transmetalation with appropriate metal salts. The steric and electronic properties of the IFcPr ligand were assessed using %Vbur and TEP, respectively. These assessments indicated that the ligand was as bulky as the adamantyl NHC ligand and exhibited strong donor ability similar to that of a triazolylidene NHC ligand. The catalytic performance of the copper and palladium complexes was evaluated in the asymmetric borylation of ethyl cinnamate and Suzuki–Miyaura coupling reactions, respectively. The IFcPr-Cu complex catalyzed the borylation of ethyl cinnamate with bis(pinacolato) diboron, followed by oxidation to yield the hydroxy ester with 58% yield and 30% ee. In contrast, the IFcPr-Pd-PEPPSI complex provided the axial chiral binaphthyl compound with 59% yield and 51% ee at a low catalyst loading (0.1 mol%, TON = 590).","PeriodicalId":38,"journal":{"name":"European Journal of Inorganic Chemistry","volume":null,"pages":null},"PeriodicalIF":2.524,"publicationDate":"2024-09-18","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"142268748","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

引用次数: 0