European Journal of Inorganic Chemistry最新文献

Front Cover: (Eur. J. Inorg. Chem. 18/2025) 封面：（欧元）j . Inorg。化学18/2025)

IF 2.2 4区化学

European Journal of Inorganic Chemistry Pub Date : 2025-06-25 DOI: 10.1002/ejic.202581801

引用次数: 0

Front Cover: Synthesis and Characterization of A3[ReO4][ReO3N] and A′2[ReO3N] (A = Rb, Cs; A′ = K, Cs) (Eur. J. Inorg. Chem. 17/2025) 封面：A3[ReO4][ReO3N]和A ' 2[ReO3N]的合成与表征(A = Rb, Cs；A ' = K, c)(欧元；j . Inorg。化学17/2025)

IF 2.2 4区化学

European Journal of Inorganic Chemistry Pub Date : 2025-06-18 DOI: 10.1002/ejic.202581701

Désirée Badea, Christoph Lenting, Michael Hanrath, Jörn Bruns

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Extraction of 244Cm Using 3,3′-Dibutyloxyphenyl-bis-1,2,4-Triazinyl-2,6-Pyridine as a Bipolar Complexant: A Fundamental, density functional theory, and Spectroscopic Study 以3,3′-二丁氧基苯基-双-1,2,4-三嗪基-2,6-吡啶作为双极性络合剂萃取244Cm：基本密度泛函理论和光谱研究

IF 2.2 4区化学

European Journal of Inorganic Chemistry Pub Date : 2025-06-08 DOI: 10.1002/ejic.202400818

Jessica A. Jackson, Lesta S. Fletcher, Allison A. Peroutka, Samiat O. Olayiwola, Nickolas A. Joyner, Jenifer C. Shafer, David A. Dixon, Jesse D. Carrick

{"title":"Extraction of 244Cm Using 3,3′-Dibutyloxyphenyl-bis-1,2,4-Triazinyl-2,6-Pyridine as a Bipolar Complexant: A Fundamental, density functional theory, and Spectroscopic Study","authors":"Jessica A. Jackson, Lesta S. Fletcher, Allison A. Peroutka, Samiat O. Olayiwola, Nickolas A. Joyner, Jenifer C. Shafer, David A. Dixon, Jesse D. Carrick","doi":"10.1002/ejic.202400818","DOIUrl":"https://doi.org/10.1002/ejic.202400818","url":null,"abstract":"Defining effective separation processes to extract the minor actinides from lanthanides remains a significant challenge in the expansion of nuclear power as a greener alternative to carbon-based energy. Minor actinides, Am, Cm, and Np, are routinely produced as byproducts of nuclear fission and present numerous challenges for separation from the neutron-poisoning lanthanides, including similar oxidation states, cationic radii, and coordination number. Transmutation of the minor actinides to fast-neutron reactors to decrease the radiotoxicity and volume of high-level waste stored in a geologic repository necessarily demands chemoselective isolation strategies. In this work, a comprehensive biphasic extraction, theoretical, and spectroscopic study using the recently discovered soft-N-donor, bipolar complexant, 3,3′-dibutyloxy-phenyl-bis-[1,2,4]-triazinyl-2,6,-pyridine (BOB-BTP) for 244Cm3+ extraction is described. Solvent extraction, density functional theory, and spectroscopic data are reported herein.","PeriodicalId":38,"journal":{"name":"European Journal of Inorganic Chemistry","volume":"28 18","pages":""},"PeriodicalIF":2.2,"publicationDate":"2025-06-08","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"144472892","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

引用次数: 0

Front Cover: Stabilities and Limitations in the Reactivity of Phosphorus Ylide-Based Aluminum– and Gallium–Carbon Ambiphiles: A Combined Experimental and Computational Approach (Eur. J. Inorg. Chem. 16/2025) 封面：磷基铝和镓碳双亲体反应性的稳定性和局限性：一种结合的实验和计算方法。j . Inorg。化学16/2025)

IF 2.2 4区化学

European Journal of Inorganic Chemistry Pub Date : 2025-06-05 DOI: 10.1002/ejic.202581601

Felix Krämer, Pascal Weisenburger, Israel Fernández, Frank Breher

{"title":"Front Cover: Stabilities and Limitations in the Reactivity of Phosphorus Ylide-Based Aluminum– and Gallium–Carbon Ambiphiles: A Combined Experimental and Computational Approach (Eur. J. Inorg. Chem. 16/2025)","authors":"Felix Krämer, Pascal Weisenburger, Israel Fernández, Frank Breher","doi":"10.1002/ejic.202581601","DOIUrl":"https://doi.org/10.1002/ejic.202581601","url":null,"abstract":"The Front Cover shows a sketchpad with the structure of the formal methanol activation product of an aluminum–carbon-based ambiphile that is formed by the elimination of ammonia. A water molecule is shown above the eliminated ammonia molecule, indicating that replacement by water can also be realized. On the left, other small molecules that do not react with the title compounds are shown. The product of trimerization of phenyl isocyanate, for which the ambiphiles act as catalysts, is shown on the left. To the right are shown the insertion products of carbon dioxide and acetonitrile. The ticked reaction product with carbon dioxide can be realized, the crossed-out acetonitrile product cannot. The reaction path bottom right shows that the insertion process of acetonitrile is endergonic overall and rather high activation barriers are predicted. More information can be found in the Research Article by I. Fernández, F. Breher and co-workers (DOI: 10.1002/ejic.202500165).\u0000 <figure>\u0000 <div><picture>\u0000 <source></source></picture>\u0000 </div>\u0000 </figure>","PeriodicalId":38,"journal":{"name":"European Journal of Inorganic Chemistry","volume":"28 16","pages":""},"PeriodicalIF":2.2,"publicationDate":"2025-06-05","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://onlinelibrary.wiley.com/doi/epdf/10.1002/ejic.202581601","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"144220126","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"OA","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

引用次数: 0

Front Cover: Theoretical Study of Local Environmental Effect on Electronic Structure of M-Cluster (Eur. J. Inorg. Chem. 15/2025) 封面：局部环境对m -簇电子结构影响的理论研究。j . Inorg。化学15/2025)

IF 2.2 4区化学

European Journal of Inorganic Chemistry Pub Date : 2025-05-28 DOI: 10.1002/ejic.202581501

Kazuki Honjo, Taigo Kamimura, Kohei Tada, Ryohei Kishi, Yasutaka Kitagawa

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Front Cover: Complexes of d- and f-metal Ions with a Redox-Active and Highly Symmetric Truxenone Ligand: Effect of Cations and Coordination on Distortions of Radical Anions and Singlet-Triplet Transitions in Dianions (Eur. J. Inorg. Chem. 14/2025) 封面：d-和f-金属离子与氧化还原活性和高度对称的Truxenone配体的配合物：阳离子和配位对自由基阴离子畸变和diions中单重态-三重态转变的影响。j . Inorg。化学14/2025)

IF 2.2 4区化学

European Journal of Inorganic Chemistry Pub Date : 2025-05-24 DOI: 10.1002/ejic.202581401

Kira D. Krivenko, Alexander F. Shestakov, Maxim A. Faraonov, Alexey V. Kuzmin, Salavat S. Khasanov, Akihiro Otsuka, Hideki Yamochi, Hiroshi Kitagawa, Dmitri V. Konarev

{"title":"Front Cover: Complexes of d- and f-metal Ions with a Redox-Active and Highly Symmetric Truxenone Ligand: Effect of Cations and Coordination on Distortions of Radical Anions and Singlet-Triplet Transitions in Dianions (Eur. J. Inorg. Chem. 14/2025)","authors":"Kira D. Krivenko, Alexander F. Shestakov, Maxim A. Faraonov, Alexey V. Kuzmin, Salavat S. Khasanov, Akihiro Otsuka, Hideki Yamochi, Hiroshi Kitagawa, Dmitri V. Konarev","doi":"10.1002/ejic.202581401","DOIUrl":"https://doi.org/10.1002/ejic.202581401","url":null,"abstract":"The Front Cover shows truxenone (Tr), which has high C3h symmetry and degenerated LUMO. It forms salts and complexes. Calculations predict Jahn–Teller distortions for Tr⋅− that are enhanced by the asymmetric approach of Cp*2Co+ to Tr⋅−. The dianions should have a triplet state, but the asymmetric approach of Cs+ to the oxygen atoms of Tr2− stabilizes the singlet ground state. Radical anions of Tr⋅− coordinate with TbIII(TMHD)3 and MnII(acac)2 providing asymmetric spin density localization on the coordinated oxygen atom and strong magnetic exchange of the ligand and paramagnetic metal spins. More information can be found in the Research Article by D. V. Konarev and co-workers (DOI: 10.1002/ejic.202400760).\u0000 <figure>\u0000 <div><picture>\u0000 <source></source></picture>\u0000 </div>\u0000 </figure>\u0000 ","PeriodicalId":38,"journal":{"name":"European Journal of Inorganic Chemistry","volume":"28 14","pages":""},"PeriodicalIF":2.2,"publicationDate":"2025-05-24","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://onlinelibrary.wiley.com/doi/epdf/10.1002/ejic.202581401","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"144131513","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"OA","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

引用次数: 0

Cover Feature: Photocatalytic Efficiency Improvement of Porous TiO2 Immobilized by a Pd-Te Complex for H2 Production by Water Splitting (Eur. J. Inorg. Chem. 13/2025) 封面特征：Pd-Te配合物固定化多孔TiO2水裂解制氢光催化效率的提高j . Inorg。化学13/2025)

IF 2.2 4区化学

European Journal of Inorganic Chemistry Pub Date : 2025-05-22 DOI: 10.1002/ejic.202581302

Camila N. Cechin, Tanize Bortolotto, Andressa Lunardi, Renaldo M. da Silva Jr., Robert A. Burrow, Bernardo A. Iglesias, Ernesto S. Lang, Bárbara Tirloni, Shirley Nakagaki

{"title":"Cover Feature: Photocatalytic Efficiency Improvement of Porous TiO2 Immobilized by a Pd-Te Complex for H2 Production by Water Splitting (Eur. J. Inorg. Chem. 13/2025)","authors":"Camila N. Cechin, Tanize Bortolotto, Andressa Lunardi, Renaldo M. da Silva Jr., Robert A. Burrow, Bernardo A. Iglesias, Ernesto S. Lang, Bárbara Tirloni, Shirley Nakagaki","doi":"10.1002/ejic.202581302","DOIUrl":"https://doi.org/10.1002/ejic.202581302","url":null,"abstract":"The Cover Feature shows the preparation of solids based on a Pd--Te complex, [Pd2(μ-TePh)2(bipy)2](PF6)2, immobilized over porous TiO2 and over commercial TiO2 to be used as photocatalysts for H2 production by water splitting under sunlight. All the solids enhanced H2 production compared to pure titania supports by up to 69-fold. This outcome inspires the investigation of metal complexes combined with semiconductors to improve their photocatalytic ability for H2 production. More information can be found in the Research Article by S. Nakagaki and co-workers (DOI: 10.1002/ejic.202400806).\u0000 <figure>\u0000 <div><picture>\u0000 <source></source></picture>\u0000 </div>\u0000 </figure>","PeriodicalId":38,"journal":{"name":"European Journal of Inorganic Chemistry","volume":"28 13","pages":""},"PeriodicalIF":2.2,"publicationDate":"2025-05-22","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://onlinelibrary.wiley.com/doi/epdf/10.1002/ejic.202581302","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"144108701","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"OA","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

引用次数: 0

Front Cover: Heterometallic Coordination Compounds with Amino-Acid Dithiocarbamate Ligands (Eur. J. Inorg. Chem. 13/2025) 封面：氨基酸二硫代氨基甲酸酯配体的杂金属配位化合物。j . Inorg。化学13/2025)

IF 2.2 4区化学

European Journal of Inorganic Chemistry Pub Date : 2025-05-22 DOI: 10.1002/ejic.202581301

Dr. Phil Köhler

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Expanding the Chemical Space of Allyl Palladates with Anticancer Properties 拓展具有抗癌特性的丙烯酸酯的化学空间

IF 2.2 4区化学

European Journal of Inorganic Chemistry Pub Date : 2025-05-21 DOI: 10.1002/ejic.202500146

Alessia Schiavo, Giacomo Baio, Francis Bru, Irene Guerra, Victoria Mechrouk, Thierry Achard, Sara Baldissin, Stéphane Bellemin-Laponnaz, Catherine S. J. Cazin, Cristina Tubaro, Fabiano Visentin, Isabella Caligiuri, Flavio Rizzolio, Steven P. Nolan, Thomas Scattolin

{"title":"Expanding the Chemical Space of Allyl Palladates with Anticancer Properties","authors":"Alessia Schiavo, Giacomo Baio, Francis Bru, Irene Guerra, Victoria Mechrouk, Thierry Achard, Sara Baldissin, Stéphane Bellemin-Laponnaz, Catherine S. J. Cazin, Cristina Tubaro, Fabiano Visentin, Isabella Caligiuri, Flavio Rizzolio, Steven P. Nolan, Thomas Scattolin","doi":"10.1002/ejic.202500146","DOIUrl":"https://doi.org/10.1002/ejic.202500146","url":null,"abstract":"Allyl palladates are emerging as promising anticancer agents due to their unique mechanisms of action, including thioredoxin reductase inhibition and immunogenic cell death activation. However, their lack of selectivity toward cancer cells has hindered their therapeutic potential. Herein, a library of ten novel allyl palladates featuring diverse azolium ligands is synthesized via a solvent-free approach, including 1) ring-expanded azolium salts; 2) azolium salts functionalized with phosphonium, thioether, selenoether, or sulfoxide groups; 3) 12-membered cyclic alkyl groups; or 4) bulky or methoxy-functionalized aryl groups. The newly synthesized compounds are tested against A2780, A2780cis, and U87 cancer cell lines, as well as MRC-5 non-cancerous cells. Results reveal a general excellent cytotoxicity (in the micromolar or submicromolar range), with allyl palladates 2c–d showing the greatest activity but limited selectivity. Compounds 2f and 2h, however, demonstrate improved selectivity toward cancer cells, highlighting the influence of thioether and selenoether functional groups.","PeriodicalId":38,"journal":{"name":"European Journal of Inorganic Chemistry","volume":"28 18","pages":""},"PeriodicalIF":2.2,"publicationDate":"2025-05-21","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://onlinelibrary.wiley.com/doi/epdf/10.1002/ejic.202500146","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"144472843","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"OA","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

引用次数: 0

Preparation and Reactions of (Hydrosilyl)diarylborane （氢硅基）二乙基硼烷的制备及反应

IF 2.2 4区化学

European Journal of Inorganic Chemistry Pub Date : 2025-05-21 DOI: 10.1002/ejic.202500068

Ryota Koyanagi, Mutsuki Tanaka, Yuki Nonaka, Kyoka Mori, Shogo Morisako, Yohsuke Yamamoto, Atsushi Kawachi

引用次数: 0