Materials Horizons最新文献

{"title":"Thermally enhanced resistive switching in interface-engineered AgHfO_3-<i>x</i>/Al₂O₃ memristors <i>via</i> trap depopulation for neuromorphic computing.","authors":"Swaraj Mukherjee, Mubashir M Ganaie, Ayan Chatterjee, Chaitanya B Auti, Jonathan Adamu, Chittaranjan Das, Pradeep Kumar, Lavi Tyagi, Michael Saliba, Mahesh Kumar","doi":"10.1039/d6mh00879h","DOIUrl":"10.1039/d6mh00879h","url":null,"abstract":"<p><p>Thermal instability remains a fundamental bottleneck in oxide-based resistive random-access memory (RRAM), where elevated operating temperatures invariably increase the high-resistance-state (HRS) leakage current and collapse the ON/OFF switching window, severely limiting reliable deployment. Here, an Au/AgHfO_3-<i>x</i>/Al₂O₃/FTO (fluorine-doped tin oxide) memristor is reported in which this paradigm is inverted. The HRS current anomalously decreases with increasing temperature, yielding a reversible ∼25-fold enhancement in the ON/OFF ratio from 300 K to 400 K. This counter-intuitive behavior originates from trap-controlled space charge-limited conduction (SCLC) at the chemically sharp 5 nm Al₂O₃ interlayer, where thermal energy depopulates shallow trap states, suppressing hopping-assisted leakage without disrupting filamentary conduction in the low-resistance state. The optimized heterostructure achieves a room-temperature ON/OFF ratio of 349 ± 53, endurance exceeding 10³ bipolar switching cycles, retention over 25 000 s, and ten discrete analog conductance states spanning six orders of magnitude. Device-derived conductance states are directly used as synaptic weights in software-level simulations of handwritten-digit classification and image denoising on the MNIST benchmark. The handwritten-digit classification achieves 97.74% accuracy <i>via</i> transfer learning without implementation in a physical crossbar array or its associated peripheral circuitry. These results establish interface-engineered trap control as a design principle for thermally self-correcting memristors, a class where elevated temperature enhances rather than degrades performance, with direct relevance to neuromorphic hardware in thermally demanding environments.</p>","PeriodicalId":87,"journal":{"name":"Materials Horizons","volume":" ","pages":"10382-10395"},"PeriodicalIF":11.4,"publicationDate":"2026-10-19","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"148904559","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":2,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

{"title":"Correction: From the up-converting multimodal luminescent thermometer to ratiometric visual power density meter based on Er³⁺,Yb³⁺ emission.","authors":"Anam Javaid, Maja Szymczak, Lukasz Marciniak","doi":"10.1039/d6mh90097f","DOIUrl":"10.1039/d6mh90097f","url":null,"abstract":"<p><p>Correction for 'From the up-converting multimodal luminescent thermometer to ratiometric visual power density meter based on Er³⁺,Yb³⁺ emission' by Anam Javaid <i>et al.</i>, <i>Mater. Horiz.</i>, 2026, <b>13</b>, 417-429, https://doi.org/10.1039/d5mh01369k.</p>","PeriodicalId":87,"journal":{"name":"Materials Horizons","volume":" ","pages":"10432"},"PeriodicalIF":11.4,"publicationDate":"2026-10-19","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"149011653","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":2,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

{"title":"Neutron-star-inspired metamaterials: mitigating friction-strength-conductivity trade-offs.","authors":"Qi Tang, Haozhang Zhong, Hongyuan Liu, Zheda Ning, Junmei Guo, Yue Shen, Yunxiu Chao, Shiqi Li, Ke Tang, Chenqi Shi, Wenjue Yi, Yipei He, Gang Shen, Ming Wen, Jianfeng Gu","doi":"10.1039/d6mh00718j","DOIUrl":"10.1039/d6mh00718j","url":null,"abstract":"<p><p>Modern technological demands require metals to integrate structural and functional performance, yet conventional metallurgy remains constrained by intrinsic trade-offs among strength, electrical conductivity, and wear resistance. Neutron-star evolution offers a natural blueprint for overcoming this limitation: load-bearing nuclear matter forms continuous frameworks, while a permeating electron sea enables efficient charge transport, intrinsically decoupling mechanical support from transport functionality. Inspired by this principle, we designed a neutron-star-inspired metallic metamaterial that assigns load bearing to a tungsten framework and electrical transport to a silver network. Realized through sequential 3D printing and metal infiltration, the resulting Ag-W architecture delivers high strength (≈213 MPa), high electrical conductivity (>50% IACS), and ultra-low friction-reduced to ∼20% of conventional bulk metals, demonstrating an unusually favorable convergence of mechanical, electrical, and tribological performance that is difficult to achieve through composition-based alloying alone. Crucially, the performance gain goes beyond a simple composite effect, as evidenced by the ∼75% reduction in friction relative to non-neutron-star-like architected comparators. These results establish topology-guided metallic architectures as a promising complementary route for mitigating multi-property trade-offs.</p>","PeriodicalId":87,"journal":{"name":"Materials Horizons","volume":" ","pages":"10140-10156"},"PeriodicalIF":11.4,"publicationDate":"2026-10-19","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"148885597","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":2,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

{"title":"Lattice-reinforced polyurethane foam with stable thermal and mechanical performance under repeated vacuum cycling.","authors":"Sooyeon Ji, Jaemin Lee, Beomjun Choi, Jeongwoo Lee, Youngseok Oh, Ki Jun Kim, Wonjoon Choi, Dahyun Daniel Lim","doi":"10.1039/d6mh01447j","DOIUrl":"10.1039/d6mh01447j","url":null,"abstract":"<p><p>Developing thermally and mechanically robust insulation capable of maintaining performance under repeated vacuum cycling remains a critical challenge for aircraft, aerospace and cryogenic systems, where both thermal efficiency and structural integrity are required. This study focuses on overcoming the trade-off between low thermal conductivity and mechanical stability in polymer-based insulating materials that are prone to structural degradation under pressure fluctuations. Herein, we present a Kelvin lattice-reinforced foam that preserves intrinsic insulation properties of closed-cell polyurethane (PU). The lattice framework suppresses structural collapse during vacuum cycling, while the PU foam region preserves low thermal conductivity. As a result, the hybrid structure exhibits a peak stress enhancement of up to 25 times compared to pristine PU foam. Furthermore, after 50 vacuum cycles, the hybrid structure retains thermal conductivity to within 10%, and peak-to-plateau ratio by less than 20% from their initial values, demonstrating excellent retention of both thermal and mechanical properties. These results establish the PU-Kelvin hybrid as a viable insulation architecture for environments subject to repeated pressure fluctuations, including aircraft cabins, aerospace structures, and cryogenic applications.</p>","PeriodicalId":87,"journal":{"name":"Materials Horizons","volume":" ","pages":"10113-10123"},"PeriodicalIF":11.4,"publicationDate":"2026-10-19","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"148862710","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":2,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

{"title":"Water-soluble conjugated molecular materials toward biomedical translational applications.","authors":"Huanxiang Yuan, Zhiqiang Gao, Yuqing Dong, Hao Zhao","doi":"10.1039/d6mh00944a","DOIUrl":"10.1039/d6mh00944a","url":null,"abstract":"<p><p>Water-soluble conjugated molecular materials (WSCMs) have exhibited hierarchical light harvesting, energy transfer, photosensitization, and photoconversion capabilities, thus achieving remarkable breakthroughs in disease-related biosensing, biotheranostics, and biophotoconversion. In contrast to the basic investigations, rare efforts have been devoted to truly realizing their biomedical translational applications toward industrialization. This review concisely summarizes the state-of-the-art applications of WSCMs in clinical gene detection, disease theranostics, and green biosynthesis of high-value chemicals. Furthermore, challenges and development directions of WSCMs toward biomedical translations in precise diagnosis kits, <i>in vivo</i> theranostics, and large-scale photobiocatalysis are discussed, clearly mapping future industrialization trajectories for personalized medicine, veterinary drugs, and industrial bio-related fermentation.</p>","PeriodicalId":87,"journal":{"name":"Materials Horizons","volume":" ","pages":"10064-10081"},"PeriodicalIF":11.4,"publicationDate":"2026-10-19","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"148785648","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":2,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

{"title":"Biomimetic hierarchical structure for high-performance implantable fiber sensors.","authors":"Hao Guo, Wang Li, Tao Huang, Songlin Zhang, Huisheng Peng, Xuemei Sun","doi":"10.1039/d6mh00883f","DOIUrl":"10.1039/d6mh00883f","url":null,"abstract":"<p><p>Implantable fiber sensors are emerging as viable platforms for continuous <i>in situ</i> monitoring of physiological signals, yet their clinical translation remains limited. The core challenge lies not only in balancing mechanical compliance, electrical reliability, analytical specificity, and long-term stability but also in maintaining these properties at the tissue-device interface throughout chronic implantation. Biomimetic hierarchical architectures, which are common in living systems, have provided a practical route by enabling structural and functional integration across multiple scales. In this review, we summarize recent progress in biomimetic design principles for improving the performance of implantable fiber sensors. We first discuss bioinspired hierarchically structured conductive fiber substrates that combine conductivity, flexibility, and resistance to cyclic deformation. We then focus on bioinspired interfaces, membranes, and surface coatings to improve sensitivity, regulate mass transport, and suppress biofouling. Finally, we address mechanically adaptive and self-stabilizing interphases and discuss biosafety, biocompatibility evaluation, and postprocessing compatibility for the clinical translation of these sensing systems. Overall, this review aims to provide actionable biomimetic design insights that can accelerate the development of next-generation implantable fiber sensors with improved long-term performance and clinical applicability.</p>","PeriodicalId":87,"journal":{"name":"Materials Horizons","volume":" ","pages":"9982-10000"},"PeriodicalIF":11.4,"publicationDate":"2026-10-19","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"148785599","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":2,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

{"title":"Bioinspired plant-derived extracellular vesicles enabling dual-targeting therapy for primary ovarian insufficiency.","authors":"Yaoqin Mu, Xinyi Zhang, Keyi Ye, Qiuyue Liao, Wei Yang, Jun Dai, Fan Xia, Kezhen Li","doi":"10.1039/d6mh01330a","DOIUrl":"10.1039/d6mh01330a","url":null,"abstract":"<p><p>Extracellular vesicles (EVs) have emerged as promising therapeutic agents for restoring ovarian function and fertility in chemotherapy-induced premature ovarian insufficiency (POI). However, their limited ovarian targeting capacity and inefficient mitochondrial delivery have substantially constrained their therapeutic efficacy. Here, we present a biomimetic, dual-targeted EV platform derived from <i>Lycium barbarum</i> (TPP-GCM-LBEVs) and demonstrate its therapeutic potential in a mouse POI model. Hybridization with granulosa cell membranes (GCMs) confers intrinsic ovarian-homing capability, whereas subsequent surface conjugation with triphenylphosphonium (TPP) promotes mitochondrial targeting following cellular uptake. TPP-GCM-LBEVs efficiently target granulosa cells and their mitochondria <i>in vitro</i> and <i>in vivo</i>, with cellular internalization mediated predominantly by caveolae- and lipid-raft-dependent endocytosis. Subsequently, TPP-GCM-LBEVs restore mitochondrial ultrastructure and bioenergetic function in granulosa cells, thereby re-establishing ovarian redox and metabolic homeostasis. This mitochondrial rescue enhances the paracrine metabolic support provided to oocytes, thereby improving oocyte quality and developmental competence. Consistent with these effects, treatment with TPP-GCM-LBEVs rescues follicular development, ovarian endocrine function, and natural fertility in POI mice. Collectively, this cross-species, dual-targeted, plant-derived EV strategy provides a translatable and effective therapeutic framework for POI, with broader implications for mitochondria-associated reproductive ageing.</p>","PeriodicalId":87,"journal":{"name":"Materials Horizons","volume":" ","pages":"10207-10221"},"PeriodicalIF":11.4,"publicationDate":"2026-10-19","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"148910339","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":2,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

{"title":"Bioinspired tri-state optical gels with a thermally tunable modulus for 3D morphing.","authors":"Ying Shen, Melissa Yazhen-Pang Yan, Chengcheng Jia, Xiaoxia Le, Tao Chen","doi":"10.1039/d6mh01181k","DOIUrl":"10.1039/d6mh01181k","url":null,"abstract":"<p><p>Shape-reconfigurable optical materials are promising for camouflage, sensing, and anti-counterfeiting, yet most existing systems produce only a single optical output and suffer from optical instability during deformation. Herein, a bioinspired tri-state optical gel (TOG) is fabricated by photopolymerization, incorporating SiO₂ photonic nanoparticles, SrAl₂O₄:Eu²⁺,Dy³⁺ phosphors and phase-change polymers. Phase-change components enable the gel to fix its geometry at low temperatures and to undergo programmable 2D-to-3D reshaping upon heating. Notably, the thermally tunable gel displays three distinct optical states under different illumination conditions: structural color under natural light, UV-triggered fluorescence and persistent phosphorescence. This work integrates programmable shape morphing and triple optical signals in a single gel, offering a facile route toward advanced dynamic optical composites.</p>","PeriodicalId":87,"journal":{"name":"Materials Horizons","volume":" ","pages":"10173-10180"},"PeriodicalIF":11.4,"publicationDate":"2026-10-19","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"148885659","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":2,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

{"title":"Polymerization-induced ordering and liquid-crystalline ordered melts of semicrystalline homopolymers with dynamic properties.","authors":"Aizezi Maimaitiming, Kun Cui, Feng Tian, Yonggang Zhang","doi":"10.1039/d6mh01033d","DOIUrl":"10.1039/d6mh01033d","url":null,"abstract":"<p><p>Melts of semicrystalline homopolymers are classically described as disordered random coils that crystallize into folded-chain lamellar nanocrystals. Here, using ultrahigh-molecular-weight polyethylene (UHMWPE) as a model system, we show that polymerization induces hierarchical ordering that evolves into liquid-crystalline ordered melts, two-dimensional self-assembled mesocrystals, and intelligent, photonic, and dynamic nanocomposites. Upon static melting, an unusual conformationally ordered orthorhombic phase is retained in the melts of less-crosslinked meso-granules and physically intra-crosslinked meso-fibrils of as-polymerized nascent powders up to a universal order-disorder transition temperature (<i>T</i>_O-D) of approximately 190 °C, after which it transformed into a disorder globular melt. During dynamic shearing, a less-entangled columnar (hexagonal) liquid-crystalline phase forms at 153-176 °C, followed by chain explosion at <i>T</i>_O-D and the formation of temperature-responsive, recoverable, non-equilibrium entangled networks above <i>T</i>_O-D. Isothermal crystallization of these ordered melts generates macroscale and microscale 2D-ordered and randomly 3D organized nanofibrillar superstructures, which impart self-toughening behaviour and ultrahigh impact resistance to UHMWPE. In addition, shape-memory and transparent photonic sheets were fabricated through mesoscale 2D self-assembly from preserved, heterogeneously entangled, intercrosslinked ordered melts under pressure. We further developed self-reinforced monomaterial \"eplastomers\" with tensile responses ranging from elastomeric to plastic-like through complete nanofibrillation of only 5 wt% less-crosslinked mesoparticles in a polyolefin elastomer matrix and reversible exchange between 1D-ordered nanofibrillar networks and disordered 3D mesogranules. Together, these findings deepen the understanding of semicrystalline polymers and provide a foundation for ultrahigh-performance, 3D-printable intelligent and photonic crystals and sustainable monomaterial dynamic nanocomposites based on reversible entangled nanofibrillar networks.</p>","PeriodicalId":87,"journal":{"name":"Materials Horizons","volume":" ","pages":"10278-10292"},"PeriodicalIF":11.4,"publicationDate":"2026-10-19","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"148862705","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":2,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

{"title":"Biofabrication of osteochondral composite scaffolds: advances in multi-material bioprinting, functional microenvironment engineering and orthopedic translation.","authors":"Jingtao Huang, Haojian Wang, Yaohang Yue, Rongji Liang, Quan Lin, Jiayou Chen, Haochi Lun, Shun Li, Jianjing Lin, Xintao Zhang","doi":"10.1039/d6mh01311b","DOIUrl":"10.1039/d6mh01311b","url":null,"abstract":"<p><p>Osteochondral defects are challenging to repair due to the complex structure of the osteochondral unit. Current clinical methods often fail to achieve long-term cartilage-bone integration. Recent advances in multi-material bioprinting enable the construction of biomimetic scaffolds with graded architectures and region-specific functions. This review summarizes progress in biofabricating osteochondral composite scaffolds, focusing on multi-material bioprinting and zonal microenvironment engineering. Key topics include bioink design, gradient scaffold architectures, hybrid manufacturing, spatiotemporal delivery systems, multicellular biofabrication, vascularization, immunomodulation, and stimuli-responsive biomaterials. We also discuss <i>in vitro</i> and <i>in vivo</i> evaluation approaches and major translational barriers such as mechanical mismatch, long-term stability, scalability, and regulatory issues. The integration of multimaterial bioprinting, adaptive biomaterials, and programmable microenvironments may facilitate the development of osteochondral implants with improved tissue integration and translational potential. Future studies should prioritize long-term osteochondral integration, vascular coordination, manufacturing reproducibility, and clinically relevant validation.</p>","PeriodicalId":87,"journal":{"name":"Materials Horizons","volume":" ","pages":"9932-9981"},"PeriodicalIF":11.4,"publicationDate":"2026-10-19","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"149068681","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":2,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}