Materials Horizons最新文献

Synergistic peptide-organic matrix enhances mineralization of biomimetic scaffolds for bone regeneration. 协同肽-有机基质增强骨再生仿生支架的矿化。

IF 12.2 2区材料科学

Materials Horizons Pub Date : 2025-07-24 DOI: 10.1039/d5mh00969c

Yawen Huang, Ziqi Zhao, Yu Yang, Ruiqi Mao, Dongxuan Li, Fengxiong Luo, Kefeng Wang, Yujiang Fan, Xingdong Zhang

{"title":"Synergistic peptide-organic matrix enhances mineralization of biomimetic scaffolds for bone regeneration.","authors":"Yawen Huang, Ziqi Zhao, Yu Yang, Ruiqi Mao, Dongxuan Li, Fengxiong Luo, Kefeng Wang, Yujiang Fan, Xingdong Zhang","doi":"10.1039/d5mh00969c","DOIUrl":"https://doi.org/10.1039/d5mh00969c","url":null,"abstract":"Biomimetic mineralized composites engineered via organic matrix templating show promise for bone repair but suffer from poor mineralization and imbalanced mechanical-biological performance. This study synergistically regulated biomolecules and organic matrix properties to enhance in situ mineralization, thereby improving mechanical strength and osteogenic potential. A nucleation-domain containing peptide (HGRGEAFDY) screened through molecular dynamics simulation was integrated into the gelatin matrix to prepare biomimetic materials with enhanced mineralization performance. The influence of peptide and organic matrix properties on mineralization capacity and saturation of in situ mineralization (SIM) was investigated. Results demonstrated that peptides with characteristic nucleation domains can boost mineralization by providing more nucleation sites and strengthening organic-inorganic interactions. Meanwhile, matrix compactness negatively correlated with mineralization capacity and SIM. Combined modulation of peptide nucleation ability and matrix compactness can enhance the SIM of the matrix, increasing the amount of minerals while improving mechanical properties. The biomimetic composites/scaffolds with mineralization enhancement by peptide-organic matrix regulation were evidenced to promote cell proliferation and osteogenic differentiation, and in vivo bone regeneration by upregulating BMP2 gene expression. This study provides valuable insights into the design of biomimetic mineralized materials and offers strategies for developing bone repair scaffolds with improved mechanical and biological performance.","PeriodicalId":87,"journal":{"name":"Materials Horizons","volume":" ","pages":""},"PeriodicalIF":12.2,"publicationDate":"2025-07-24","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"144697053","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":2,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

引用次数: 0

Thermosensitive liposomal nanomedicine-functionalized photothermal composite scaffolds for light-guided cancer therapy. 用于光导癌症治疗的热敏脂质体纳米药物功能化光热复合支架。

IF 12.2 2区材料科学

Materials Horizons Pub Date : 2025-07-24 DOI: 10.1039/d5mh00888c

Xiaohan Liu, Huajian Chen, Man Wang, Tianjiao Zeng, Toru Yoshitomi, Naoki Kawazoe, Yingnan Yang, Guoping Chen

{"title":"Thermosensitive liposomal nanomedicine-functionalized photothermal composite scaffolds for light-guided cancer therapy.","authors":"Xiaohan Liu, Huajian Chen, Man Wang, Tianjiao Zeng, Toru Yoshitomi, Naoki Kawazoe, Yingnan Yang, Guoping Chen","doi":"10.1039/d5mh00888c","DOIUrl":"https://doi.org/10.1039/d5mh00888c","url":null,"abstract":"In breast cancer treatment, the elimination of residual cancer cells in a sustainable and controllable manner to prevent recurrence remains a critical challenge in postoperative adjuvant therapy. In this study, a novel implantable in situ therapeutic composite scaffold platform (ALA@lipo/Au/Gel/PGA) was developed based on a porous scaffold composed of biocompatible gelatin and polyglutamic acid (PGA). This platform incorporated the photothermal agent Au nanorods (AuNRs) and thermosensitive liposomes encapsulated with the photosensitizer precursor 5-aminolevulinic acid (ALA). Due to the satisfactory photothermal conversion effect of the ALA@lipo/Au/Gel/PGA composite scaffold, the use of near-infrared (NIR) light not only ablated the cancer cells in the scaffold through photothermal therapy (PTT) but also induced the accelerated release of encapsulated ALA from the thermosensitive liposomes. After uptake, ALA could generate cytotoxic reactive oxygen species to increase tumour cell elimination efficiency via photodynamic therapy (PDT). Both in vitro and in vivo experiments demonstrated the synergistic anticancer effects of the composite scaffold. These results highlight the potential of this phototherapy-induced composite scaffold as a new synergistic treatment method for breast cancer.","PeriodicalId":87,"journal":{"name":"Materials Horizons","volume":" ","pages":""},"PeriodicalIF":12.2,"publicationDate":"2025-07-24","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"144697054","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":2,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

引用次数: 0

Lattice plainification flattens the crystal structure of nickel-rich layered cathodes. 晶格平化使富镍层状阴极的晶体结构变平。

IF 12.2 2区材料科学

Materials Horizons Pub Date : 2025-07-24 DOI: 10.1039/d5mh00975h

Pengcheng Li, Zhuo Peng, Zhihao Sun, Chengyu Li, Jianjun Ma, Jun Wang, Run Yu, Cairong Jiang, Xiang Gao, Wenge Yang, Dongliang Chao, Yongjin Chen

{"title":"Lattice plainification flattens the crystal structure of nickel-rich layered cathodes.","authors":"Pengcheng Li, Zhuo Peng, Zhihao Sun, Chengyu Li, Jianjun Ma, Jun Wang, Run Yu, Cairong Jiang, Xiang Gao, Wenge Yang, Dongliang Chao, Yongjin Chen","doi":"10.1039/d5mh00975h","DOIUrl":"https://doi.org/10.1039/d5mh00975h","url":null,"abstract":"The extremely fast charging/discharging of nickel-rich LiNixCoyMn1-x-yO2 (NCM) cathodes has raised concerns about rapid capacity decay. The birth defects and fragile lattice result in the sluggish Li+ diffusion kinetics and unfavorable structural degradation. Moreover, lattice strain, mechanical failures, surface reconstruction, and interfacial side reactions accelerate the decay process. Here, a proof-of-principle study of the lattice plainification (LP) strategy in a high-nickel NCM cathode is reported. The introduction of Al and Zr in transition metal layers by a wet chemistry and calcination method enables the simplification of the complex lattice structures to obtain an order phase and repair the various defects of NCM, thereby enhancing the lithium-ion transport. The modified LP-NCM exhibits a high initial discharge capacity of 157.3 mAh g-1 with a capacity retention of 81% after 300 cycles at a 5C rate, significantly outperforming the pristine counterpart (50.9%). The LP-NCM/Gr pouch cells presented impressive cycling performance, achieving 80% capacity retention over 1000 cycles at 1C, which far surpasses the performance of the pristine NCM. Our method eliminates the rocksalt and disordered phases, and suppresses oxygen, lithium, and transition metal vacancies, as well as Li/Ni mixing. LP-NCM after cycling exhibits nanopores rather than cracks of pristine NCM. Our investigations reveal that the lattice plainification design approach flattens and toughens up the crystal lattice, which contributes to robust structural stability and improves the structure degradation, mechanical failures, and gas release. Our findings underscore the importance of lattice engineering and demonstrate the potential of the lattice plainification strategy for designing high-performance cathodes.","PeriodicalId":87,"journal":{"name":"Materials Horizons","volume":" ","pages":""},"PeriodicalIF":12.2,"publicationDate":"2025-07-24","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"144697050","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":2,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

引用次数: 0

Redox tunable conjugated radicals enable low threshold voltage memristors for artificial synapses. 氧化还原可调谐共轭自由基使人工突触的低阈值电压记忆电阻器。

IF 12.2 2区材料科学

Materials Horizons Pub Date : 2025-07-24 DOI: 10.1039/d5mh00886g

Kai Peng, Hanjiao Chen, Chengjia Shi, Siying Liu, Yan Hou, Yu Yan, Zhicong Li, Shuiren Liu, Li Zhang, Xiaoguang Hu, Xuying Liu

{"title":"Redox tunable conjugated radicals enable low threshold voltage memristors for artificial synapses.","authors":"Kai Peng, Hanjiao Chen, Chengjia Shi, Siying Liu, Yan Hou, Yu Yan, Zhicong Li, Shuiren Liu, Li Zhang, Xiaoguang Hu, Xuying Liu","doi":"10.1039/d5mh00886g","DOIUrl":"https://doi.org/10.1039/d5mh00886g","url":null,"abstract":"Organic molecules with reversible redox are emerging as promising materials for low power memristors. However, the structure-property relationship between the molecular structure and threshold voltage is not clear; achieving low threshold voltage memristors is still a challenge. To address this issue, a series of conjugated Blatter radicals with tunable redox were designed and synthesized by varying the functional groups. It was found that the positive redox potentials of these radicals decrease with an increase in the electron donating strength of functional groups, leading to a corresponding reduction in the threshold voltages of the fabricated memristors. Notably, methoxy and dimethylamine substituted radicals achieve low threshold voltages of 0.51 and 0.48 V, respectively, with power consumption as low as 2.04 and 6.24 nJ. Mechanistic studies confirm that resistive switching arises from the reversible radical redox transitions. The applications of these memristors in synaptic plasticity, photoimaging and image recognition are demonstrated. This work presents a promising strategy for developing low threshold voltage memristive materials.","PeriodicalId":87,"journal":{"name":"Materials Horizons","volume":" ","pages":""},"PeriodicalIF":12.2,"publicationDate":"2025-07-24","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"144697052","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":2,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

引用次数: 0

Heat-resistant bio-based superhydrophobic coating from lycopodium powder skeletons for liquid food residue reduction. 石蒜粉末骨架耐热生物基超疏水涂层，用于减少液态食物残留。

IF 12.2 2区材料科学

Materials Horizons Pub Date : 2025-07-24 DOI: 10.1039/d5mh00913h

Yuanmeng Zhou, Jing Wang, Shulun Ai, Zhiguang Guo

{"title":"Heat-resistant bio-based superhydrophobic coating from lycopodium powder skeletons for liquid food residue reduction.","authors":"Yuanmeng Zhou, Jing Wang, Shulun Ai, Zhiguang Guo","doi":"10.1039/d5mh00913h","DOIUrl":"https://doi.org/10.1039/d5mh00913h","url":null,"abstract":"Facing the increasingly serious problems of plastic waste pollution and food waste, edible superhydrophobic coatings have received extensive attention from researchers because of their excellent anti-adhesion performance, which can effectively prevent liquid food from adhering to the inner wall of containers. In this study, we designed a heat-resistant and edible superhydrophobic coating by leveraging the unique and robust hierarchical structure of lycopodium spore powder (LSP) and utilizing natural low surface energy carnauba wax as the binder. The focus was to evaluate the hydrophobicity, heat resistance, and mechanical properties of the coating and to further demonstrate its application on liquid food packaging surfaces. The results confirmed that the lycopodium spore powder-carnauba wax superhydrophobic coating (LCW) exhibited excellent superhydrophobic properties (WCA > 150°, SA < 4°) and excellent self-cleaning function. It also has excellent anti-adhesion properties toward liquid foods with high viscosity and complex composition, such as honey, yogurt, etc. (it only takes 5170 ms and 2930 ms to completely slip on a surface with about 10° tilt, respectively). The incorporation of lycopodium spore powder notably enhanced the thermal stability of the coating, allowing it to retain a contact angle of 150° even after being subjected to high-temperature treatment at 120 °C for 2 hours. We posit that this Lycopodium-coated water-repellent material offers a promising avenue for the efficient production of biodegradable superhydrophobic coatings and holds significant potential for applications in functional food packaging.","PeriodicalId":87,"journal":{"name":"Materials Horizons","volume":" ","pages":""},"PeriodicalIF":12.2,"publicationDate":"2025-07-24","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"144697049","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":2,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

引用次数: 0

Microbubble-enhanced cold plasma (MB-CAP) for pathogen disinfection in water: a sustainable alternative to traditional methods. 用于水中病原体消毒的微泡增强冷等离子体（MB-CAP）：传统方法的可持续替代方案。

IF 12.2 2区材料科学

Materials Horizons Pub Date : 2025-07-24 DOI: 10.1039/d5mh00945f

Muzammil Kuddushi, Parin Dal, Chen Xiaoyun, Qian Xincong, Jiayue Luo, Huihui Gan, Dingnan Lu, David Z Zhu

{"title":"Microbubble-enhanced cold plasma (MB-CAP) for pathogen disinfection in water: a sustainable alternative to traditional methods.","authors":"Muzammil Kuddushi, Parin Dal, Chen Xiaoyun, Qian Xincong, Jiayue Luo, Huihui Gan, Dingnan Lu, David Z Zhu","doi":"10.1039/d5mh00945f","DOIUrl":"https://doi.org/10.1039/d5mh00945f","url":null,"abstract":"Ensuring access to safe drinking water is a key global priority. However, conventional disinfection methods often produce toxic disinfection byproducts (DBPs) such as trihalomethanes (THMs) and haloacetic acids (HAAs), which pose significant carcinogenic and environmental risks. Cold atmospheric plasma (CAP) has emerged as a promising alternative disinfection approach that generates reactive species in situ, without the need for added chemical reagents. It utilizes reactive oxygen and nitrogen species (RONS), ultraviolet (UV) radiation, and transient electric fields to effectively inactivate a wide range of waterborne pathogens. CAP disrupts microbial membranes, damages nucleic acids, and induces oxidative stress, rapidly inactivating bacteria, viruses, and fungi. A notable advancement in plasma-based water disinfection is microbubble-enhanced cold atmospheric plasma (MB-CAP), which significantly improves plasma-liquid interactions. Microbubbles (MBs) act as efficient carriers for RONS, greatly increasing the gas-liquid interfacial area and enhancing the mass transfer of RONS. This results in faster removal of pathogens compared to conventional CAP systems. Furthermore, MB-CAP offers localized and targeted treatment capabilities, making it particularly suitable for decentralized water systems, hospital wastewater, and high-load industrial effluents. This review thoroughly examines the mechanisms of microorganism inactivation by MB-CAP, reactor configurations, MB generation techniques, and disinfection performance. This review also discusses key challenges such as energy efficiency, scalability, and regulatory compliance. Future research should focus on developing hybrid CAP systems, integrating renewable energy sources, and implementing real-time monitoring tools to optimize treatment efficacy. Overall, the review highlights the transformative potential of MB-CAP as a next-generation sustainable water disinfection technology.","PeriodicalId":87,"journal":{"name":"Materials Horizons","volume":" ","pages":""},"PeriodicalIF":12.2,"publicationDate":"2025-07-24","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"144697051","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":2,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

引用次数: 0

Polyimide-driven innovations as "inert" components in high-performance lithium-ion batteries. 聚酰亚胺驱动的创新作为高性能锂离子电池的“惰性”组件。

IF 12.2 2区材料科学

Materials Horizons Pub Date : 2025-07-23 DOI: 10.1039/d5mh00822k

Yayue He, Zhenxi Li, Shilun Gao, Yinkui He, Yurong Liang, Yan Zhai, Yuxuan Li, Huabin Yang, Peng-Fei Cao

{"title":"Polyimide-driven innovations as \"inert\" components in high-performance lithium-ion batteries.","authors":"Yayue He, Zhenxi Li, Shilun Gao, Yinkui He, Yurong Liang, Yan Zhai, Yuxuan Li, Huabin Yang, Peng-Fei Cao","doi":"10.1039/d5mh00822k","DOIUrl":"https://doi.org/10.1039/d5mh00822k","url":null,"abstract":"The rapid proliferation of lithium-ion batteries (LIBs) across portable electronics and electrified transportation systems has propelled unprecedented requirements for high energy density, prolonged cycle life, and improved safety protocols. Polyimides (PIs), attributed to the excellent thermal stability, mechanical robustness, chemical stability, and flame retardant properties, have been widely researched as \"inert\" materials to address critical challenges in advancing LIBs. Herein, this review provides design principles for employing PIs' inherent characteristics to develop next-generation high-performance LIBs with balanced energy density, rate capability, and operational reliability. PI-based \"inert\" components, including PI-based separators, solid-state electrolytes, protective layers, and binders, overcome the limitations of conventional materials by enhancing the safety of liquid batteries, reinforcing the mechanical properties, stabilizing the electrolyte/electrode interface, and maintaining the electrode integrity. Key challenges and optimization pathways for practical implementation are discussed and proposed. Finally, prospective research directions of PIs in LIBs are also outlined to provide critical orientation for research fields.","PeriodicalId":87,"journal":{"name":"Materials Horizons","volume":" ","pages":""},"PeriodicalIF":12.2,"publicationDate":"2025-07-23","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"144688405","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":2,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

引用次数: 0

A photothermal-driven hydrovoltaic-pyroelectric hybrid system for efficient energy harvesting and self-powered disinfection. 一种光热驱动的水力发电-热释电混合系统，用于高效的能量收集和自供电消毒。

IF 12.2 2区材料科学

Materials Horizons Pub Date : 2025-07-23 DOI: 10.1039/d5mh00815h

Hui Cheng, Hiang Kwee Lee, Haitao Li

{"title":"A photothermal-driven hydrovoltaic-pyroelectric hybrid system for efficient energy harvesting and self-powered disinfection.","authors":"Hui Cheng, Hiang Kwee Lee, Haitao Li","doi":"10.1039/d5mh00815h","DOIUrl":"https://doi.org/10.1039/d5mh00815h","url":null,"abstract":"Capturing energy from water phase transitions holds great promise in emerging energy technologies due to its green, sustainable, and abundant nature. However, effectively harvesting this energy remains challenging, largely due to the inherently slow evaporation of water. Here, we present a high-performance hybrid generator that efficiently extracts water-phase transition energy through a multiscale structural design. The system integrates an arched multifunctional film with a polarized PVDF layer, enabling simultaneous photothermal, hydrovoltaic, and pyroelectric energy harvesting. Under optimized conditions, the device achieves a photothermal evaporation rate of ∼1.53 kg m-2 h-1 with a conversion efficiency of ∼96% enabled by rational microcomponent regulation, which is ∼30% higher than its planar counterpart. The hydrovoltaic output reaches a VOC value of ∼1.13 V and an ISC value of ∼6.46 μA, delivering a power density of ∼611 μW m-2 that is 8.5-fold higher than previous designs under 1 sun illumination in seawater. The generator also yields a pyroelectric VOC value of ∼143 V and an ISC value of ∼694 nA, with a peak power density of ∼13.58 mW m-2. Notably, these electrical outputs surpass earlier reports by >80%, attributed to enhanced interfacial temperature oscillations driven by the arched geometry. This platform reliably powers small electronic devices and enables a self-driven electrocatalytic system for seawater disinfection, achieving sodium hypochlorite production by coupling the generator with commercial Pt electrodes. Our multiscale design offers new insights for developing self-sustaining energy systems capable of harvesting and converting water-based energy for practical applications.","PeriodicalId":87,"journal":{"name":"Materials Horizons","volume":" ","pages":""},"PeriodicalIF":12.2,"publicationDate":"2025-07-23","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"144688373","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":2,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

引用次数: 0

Effect of physicochemical congestion on the catalytic conversion of arylboronic acids to phenols. 理化堵塞对芳基硼酸催化转化为酚的影响。

IF 12.2 2区材料科学

Materials Horizons Pub Date : 2025-07-23 DOI: 10.1039/d5mh00744e

Mrityunjoy Dey, Mithu Roy, Partha Pratim Borah, Sonali Roy, Amlan Jyoti Gogoi, Kalishankar Bhattacharyya, Kalyan Raidongia

引用次数: 0

Phosphorylation-assisted cell wall engineering enables ultra-strong, highly ion-conductive bio-membranes for high-power salinity gradient energy harvesting. 磷酸化辅助细胞壁工程实现了超高强度、高离子导电性的生物膜，用于高功率盐度梯度能量收集。

IF 12.2 2区材料科学

Materials Horizons Pub Date : 2025-07-23 DOI: 10.1039/d5mh01003a

Kaihuang Chen, Jie Zhou, Chunbao Charles Xu, Zhiqiang Fang, Le Yu, Chaoji Chen, Xueqing Qiu

{"title":"Phosphorylation-assisted cell wall engineering enables ultra-strong, highly ion-conductive bio-membranes for high-power salinity gradient energy harvesting.","authors":"Kaihuang Chen, Jie Zhou, Chunbao Charles Xu, Zhiqiang Fang, Le Yu, Chaoji Chen, Xueqing Qiu","doi":"10.1039/d5mh01003a","DOIUrl":"https://doi.org/10.1039/d5mh01003a","url":null,"abstract":"Nanofluidic membranes derived from cellulose-based biomaterials have garnered increasing attention for ion transport and regulation due to their modifiable nature, ordered structures, sustainability, and excellent compatibility. However, their practical applications in ionic circuits, energy conversion, and sensing have been limited by insufficient mechanical strength and suboptimal ion transport properties. In this study, we report ultra-strong, highly ion-conductive bio-membranes fabricated through phosphorylation-assisted cell wall engineering. This process introduces high-density anionic phosphate groups onto cellulose chains while preserving their natural hierarchical alignment across macroscopic to molecular scales. The resulting PhosWood-40 membrane (bio-membranes phosphorylated for 40 minutes) shows exceptional performance, with a record-high ion conductivity of 21.01 mS cm-1 in 1.0 × 10-5 mol L-1 KCl aqueous solution, an ionic selectivity of 0.95, and a high tensile strength up to 241 MPa under dry conditions and 66 MPa under wet conditions. Phosphorylation enhances the membrane's ionic conductivity by 100-fold and improves cation/anion ratio by 38-fold compared to the unmodified membrane, primarily due to the increased surface charge density and optimized ion channel accessibility. Under simulated conditions of artificial seawater (0.5 mol L-1) and river water (0.01 mol L-1), the phosphorylated PhosWood-40 membranes achieve a remarkable output power density of 6.4 W m-2, surpassing unmodified membranes by 30-fold and outperforming other bio-based nanofluidic systems. This work highlights the potential of renewable and easily modifiable cellulose-based biomaterials for developing high-performance nanofluidic systems.","PeriodicalId":87,"journal":{"name":"Materials Horizons","volume":" ","pages":""},"PeriodicalIF":12.2,"publicationDate":"2025-07-23","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"144688376","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":2,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

引用次数: 0