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Synergistic enhancement of luminescence and ferroelectricity driven by (Z)-clipping of a tetraphenylethene.
IF 12.2 2区 材料科学
Materials Horizons Pub Date : 2025-03-21 DOI: 10.1039/d4mh01620c
Sewon Lim, Donghwan Kim, Hee Jung Kim, Hwandong Jang, Sienoh Park, Eunkyoung Kim
{"title":"Synergistic enhancement of luminescence and ferroelectricity driven by (<i>Z</i>)-clipping of a tetraphenylethene.","authors":"Sewon Lim, Donghwan Kim, Hee Jung Kim, Hwandong Jang, Sienoh Park, Eunkyoung Kim","doi":"10.1039/d4mh01620c","DOIUrl":"https://doi.org/10.1039/d4mh01620c","url":null,"abstract":"<p><p>Synergistic enhancement of luminescence and ferroelectricity (SELF) was explored in a (<i>Z</i>)-isomer of tetraphenylethene derivatives containing two clipping units in (<i>Z</i>)-configuration (TPC2-(Z)). TPC2-(Z) was synthesized utilizing a 'body core' precursor, which exclusively afforded (<i>Z</i>)-configuration. High-resolution transmission electron microscopy measurements indicated that TPC2-(Z) formed a layered morphology in film, with well-ordered crystalline structures, which was ascribed to the (<i>Z</i>)-clipped self-assembled structures. The film exhibited good photoluminescence performances with 45.6% quantum yield. Simultaneously, the film exhibited high ferroelectricity as inferred from high remnant polarization (<i>P</i><sub>r</sub> = 2.54 μC cm<sup>-2</sup>) and saturated polarization (3.56 μC cm<sup>-2</sup>) along with a longitudinal piezoelectric coefficient (<i>d</i><sub>33</sub> = -23.8 pm V<sup>-1</sup>), indicating that TPC2-(Z) exhibits excellent SELF. Owing to its fluorescence and thermal stability, we fabricated light-emitting electrochemical cells (LEC) that exhibited maximum 890 cd m<sup>-2</sup> at <i>V</i><sub>on</sub> of 3.9 V. This was more than 40% enhanced performance compared to that of the (<i>E</i>)/(<i>Z</i>) mixture. A new self-powered, stimuli-sensitive electroluminescent device was demonstrated with TPC2-(Z), where the piezoelectrically tunable LECs effectively 'switched on' luminescence, showing 120-fold increased brightness after 254 bending at 1 Hz, compared to the 'off' state without bending. These results underscore that <i>Z</i>-clipping is an effective method for enhancing SELF and could create new self-powered, stimuli-sensitive electroluminescent devices.</p>","PeriodicalId":87,"journal":{"name":"Materials Horizons","volume":" ","pages":""},"PeriodicalIF":12.2,"publicationDate":"2025-03-21","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"143672926","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":2,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Self-damping photonic crystals with differentiated reversible crosslinking domains for biomimetic delayed visual perception of underwater impact stress.
IF 12.2 2区 材料科学
Materials Horizons Pub Date : 2025-03-20 DOI: 10.1039/d4mh01725k
Yong Qi, Jiahui Wang, Tong Hu, Xianfei Cao, Shi Li, Qingyu Liu, Zhaoyong Gao, Shufen Zhang
{"title":"Self-damping photonic crystals with differentiated reversible crosslinking domains for biomimetic delayed visual perception of underwater impact stress.","authors":"Yong Qi, Jiahui Wang, Tong Hu, Xianfei Cao, Shi Li, Qingyu Liu, Zhaoyong Gao, Shufen Zhang","doi":"10.1039/d4mh01725k","DOIUrl":"https://doi.org/10.1039/d4mh01725k","url":null,"abstract":"<p><p>Structural color-based impact sensors output light or electrical signals through entropic elasticity storing and releasing of the polymer network, inspiring the design of armors for underwater equipment. Designing self-damping units at the molecular and nanostructural levels will contribute to capturing and analyzing relevant impact and mechanical signals by the naked eye. Herein, inspired by the octopus' sucker, we proposed self-damping photonic crystals (SDPCs) with differentiated reversible crosslinking domains, which can delayed-release entropic elasticity in water and visually perceive stress field evolution <i>via</i> structural color. These domains are generated by weak and strong hydrogen bonds (H-bonds) assigned by differentiated copolymerization, corresponding to weak and strong crosslinking domains, respectively. The compressed network stores entropic elasticity, showing size-effect-induced blueshift structural colors. During entropic elasticity release, the weak/strong crosslinking domains are disrupted successively, resulting in temporary macropore asymmetry and forming transient Laplacian pressure difference (Δ<i>P</i>). The self-damping effect based on the continuous recombination of domains and the equilibrium iteration of Δ<i>P</i> achieves a delayed visual perception of entropy elasticity release. Given this, impact stress sensing and structural color self-erasing techniques have been developed.</p>","PeriodicalId":87,"journal":{"name":"Materials Horizons","volume":" ","pages":""},"PeriodicalIF":12.2,"publicationDate":"2025-03-20","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"143661567","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":2,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Development of highly robust polyurethane elastomers possessing self-healing capabilities for flexible sensors.
IF 12.2 2区 材料科学
Materials Horizons Pub Date : 2025-03-20 DOI: 10.1039/d5mh00022j
Hao Tian, Wentong Lu, Caiyan Wang, Runhua Wang, Peilong Zhou, Fan Fei, Mengyang Xu, Jincheng Wang
{"title":"Development of highly robust polyurethane elastomers possessing self-healing capabilities for flexible sensors.","authors":"Hao Tian, Wentong Lu, Caiyan Wang, Runhua Wang, Peilong Zhou, Fan Fei, Mengyang Xu, Jincheng Wang","doi":"10.1039/d5mh00022j","DOIUrl":"https://doi.org/10.1039/d5mh00022j","url":null,"abstract":"<p><p>Traditional flexible electronic sensing materials have fallen short in meeting the diverse application needs and environments of modern times. Hence, we require a multi-functional elastomer material to improve the overall performance and expand the functionality of flexible electronic sensors. In this study, we fabricated a multi-block polyurethane (PU) elastomer based on semi-crystalline polycaprolactone (PCL) chain segments and highly flexible polydimethylsiloxane (PDMS) chain segments, which showcases outstanding mechanical properties, self-healing capabilities, and recyclability. By adjusting the ratio parameters of the chain segments, we were able to modulate the thermodynamic behavior, hydrophobicity, mechanical behavior, and self-healing properties of the designed PU elastomers. The optimized ratios exhibited good tensile strength (16.26 MPa), high elongation at break (3300.84%), good toughness (278.82 MJ m<sup>-3</sup>, fracture energy ≈ 234.96 KJ m<sup>-2</sup>), high self-repairing (≈100%, at room temperature for 12 h), efficient recyclability, and puncture resistance. Self-healing is accomplished through the interactions between dynamic disulfide bonds, dynamic boron-oxygen bonds, and hydrogen bonds. The conductive ink (PEDOT:PSS) was encapsulated within this elastomer to construct a flexible electronic sensor, attaining excellent sensing performance (stable output for 1000 cycles). This multi-functional polyurethane elastomer acts as an ideal matrix material for flexible electronic sensors, offering novel concepts and perspectives for the next generation of green electronic flexible materials, electronic flexible robots, and other stimulus-responsive materials.</p>","PeriodicalId":87,"journal":{"name":"Materials Horizons","volume":" ","pages":""},"PeriodicalIF":12.2,"publicationDate":"2025-03-20","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"143661647","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":2,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Weakly coupled relaxor construction in lead-free ferroelectrics with simple composition for superior energy-storage performance.
IF 12.2 2区 材料科学
Materials Horizons Pub Date : 2025-03-20 DOI: 10.1039/d5mh00261c
Minghao Liu, Chen Ming, Zhen Liu, Hongbo Liu, Bing Han, Narendirakumar Narayanan, Xuantong Liu, Kai Dai, Teng Lu, Xuefeng Chen, Zhigao Hu, Yun Liu, Genshui Wang
{"title":"Weakly coupled relaxor construction in lead-free ferroelectrics with simple composition for superior energy-storage performance.","authors":"Minghao Liu, Chen Ming, Zhen Liu, Hongbo Liu, Bing Han, Narendirakumar Narayanan, Xuantong Liu, Kai Dai, Teng Lu, Xuefeng Chen, Zhigao Hu, Yun Liu, Genshui Wang","doi":"10.1039/d5mh00261c","DOIUrl":"https://doi.org/10.1039/d5mh00261c","url":null,"abstract":"<p><p>The development of advanced environmentally friendly energy storage capacitors is critical to meet escalating demands of pulsed power systems. However, challenges persist in enhancing both the recoverable energy density (<i>W</i><sub>rec</sub>) and efficiency (<i>η</i>) simultaneously. In the present study, a strategy involving domain configuration modulation, achieved by simple single rare earth ion doping, was proposed to enhance the energy-storage performance of BaTiO<sub>3</sub>. The designed Ba<sub>1-1.5<i>x</i></sub>La<sub><i>x</i></sub>TiO<sub>3</sub> (BLT-<i>x</i>) ceramics exhibited an ultrahigh <i>W</i><sub>rec</sub> of 9.2 J cm<sup>-3</sup> and <i>η</i> of 85.0% when <i>x</i> = 0.10. Furthermore, the origin of the superior performance was revealed through first-principles calculations and atomic-scale displacement analysis. The introduction of La generated intense structural fluctuations in the ordered ferroelectric domains, leading to relaxors with weakly coupled polar nanoregions and delayed saturation polarization. Such factors, combined with enhanced <i>E</i><sub>b</sub>, contributed to elongated <i>P</i>-<i>E</i> loops and ultimately ultrahigh <i>W</i><sub>rec</sub> and <i>η</i>. Meanwhile, the BLT-0.10 ceramic demonstrated exceptional temperature stability (-40-120 °C), frequency stability (10-250 Hz) and fatigue stability (10<sup>6</sup> cycles), along with notable charging-discharging capabilities. The present research not only provides a potential candidate for advanced pulsed power systems, but also offers a novel strategy for achieving superior energy-storage performance in perovskite ferroelectrics through single rare earth ion-doping.</p>","PeriodicalId":87,"journal":{"name":"Materials Horizons","volume":" ","pages":""},"PeriodicalIF":12.2,"publicationDate":"2025-03-20","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"143661583","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":2,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Indoor light energy harvesting perovskite solar cells: from device physics to AI-driven strategies.
IF 12.2 2区 材料科学
Materials Horizons Pub Date : 2025-03-20 DOI: 10.1039/d5mh00133a
Wenning Chen, Kelvian T Mularso, Bonghyun Jo, Hyun Suk Jung
{"title":"Indoor light energy harvesting perovskite solar cells: from device physics to AI-driven strategies.","authors":"Wenning Chen, Kelvian T Mularso, Bonghyun Jo, Hyun Suk Jung","doi":"10.1039/d5mh00133a","DOIUrl":"https://doi.org/10.1039/d5mh00133a","url":null,"abstract":"<p><p>The rapid advancement of indoor perovskite solar cells (IPSCs) stems from the growing demand for sustainable energy solutions and the proliferation of internet of things (IoT) devices. With tunable bandgaps and superior light absorption properties, perovskites efficiently harvest energy from artificial light sources like LEDs and fluorescent lamps, positioning IPSCs as a promising solution for powering smart homes, sensor networks, and portable electronics. In this review, we introduce recent research that highlights advancements in material optimization under low-light conditions, such as tailoring wide-bandgap perovskites to match indoor light spectra and minimizing defects to enhance stability. Notably, our review explores the integration of artificial intelligence (AI) and machine learning (ML), which are transforming IPSC development by facilitating efficient material discovery, optimizing device architectures, and uncovering degradation mechanisms. These advancements are driving the realization of sustainable indoor energy solutions for interconnected smart technologies.</p>","PeriodicalId":87,"journal":{"name":"Materials Horizons","volume":" ","pages":""},"PeriodicalIF":12.2,"publicationDate":"2025-03-20","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"143661648","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":2,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Emerging horizons in polymer applications.
IF 12.2 2区 材料科学
Materials Horizons Pub Date : 2025-03-19 DOI: 10.1039/d5mh90026c
Calum T J Ferguson, Kostas Parkatzidis
{"title":"Emerging horizons in polymer applications.","authors":"Calum T J Ferguson, Kostas Parkatzidis","doi":"10.1039/d5mh90026c","DOIUrl":"https://doi.org/10.1039/d5mh90026c","url":null,"abstract":"<p><p>Polymers are ubiquitous in life; they are used across many length scales, from bulk engineering to precision nanomedicine. The broad applicability of polymers stems from the myriad of different architectures and chemistries that can be produced. In essence, a polymer is a large macromolecule consisting of many repeat units, a concept first proposed by Hermann Staudinger in 1920. However, the use of polymers predates this; natural polymers have been used throughout human history and synthetic polymers such as polyvinyl chloride and Bakelite were invented in the late 19th century. Throughout the 20th century, a plethora of synthetic polymers have been developed. This editorial will highlight the cutting-edge research recently reported across <i>Materials Horizons</i> and <i>Nanoscale Horizons</i>, covering four critical research areas: catalytic polymer materials, polymers in additive manufacturing, self-healing polymeric materials, and recyclable/sustainable polymers.</p>","PeriodicalId":87,"journal":{"name":"Materials Horizons","volume":" ","pages":""},"PeriodicalIF":12.2,"publicationDate":"2025-03-19","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"143655671","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":2,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Memristive neuromorphic interfaces: integrating sensory modalities with artificial neural networks.
IF 12.2 2区 材料科学
Materials Horizons Pub Date : 2025-03-19 DOI: 10.1039/d5mh00038f
Ji Eun Kim, Keunho Soh, Su In Hwang, Do Young Yang, Jung Ho Yoon
{"title":"Memristive neuromorphic interfaces: integrating sensory modalities with artificial neural networks.","authors":"Ji Eun Kim, Keunho Soh, Su In Hwang, Do Young Yang, Jung Ho Yoon","doi":"10.1039/d5mh00038f","DOIUrl":"https://doi.org/10.1039/d5mh00038f","url":null,"abstract":"<p><p>The advent of the Internet of Things (IoT) has led to exponential growth in data generated from sensors, requiring efficient methods to process complex and unstructured external information. Unlike conventional von Neumann sensory systems with separate data collection and processing units, biological sensory systems integrate sensing, memory, and computing to process environmental information in real time with high efficiency. Memristive neuromorphic sensory systems using memristors as their basic components have emerged as promising alternatives to CMOS-based systems. Memristors can closely replicate the key characteristics of biological receptors, neurons, and synapses by integrating the threshold and adaptation properties of receptors, the action potential firing in neurons, and the synaptic plasticity of synapses. Furthermore, through careful engineering of their switching dynamics, the electrical properties of memristors can be tailored to emulate specific functions, while benefiting from high operational speed, low power consumption, and exceptional scalability. Consequently, their integration with high-performance sensors offers a promising pathway toward realizing fully integrated artificial sensory systems that can efficiently process and respond to diverse environmental stimuli in real time. In this review, we first introduce the fundamental principles of memristive neuromorphic technologies for artificial sensory systems, explaining how each component is structured and what functions it performs. We then discuss how these principles can be applied to replicate the four traditional senses, highlighting the underlying mechanisms and recent advances in mimicking biological sensory functions. Finally, we address the remaining challenges and provide prospects for the continued development of memristor-based artificial sensory systems.</p>","PeriodicalId":87,"journal":{"name":"Materials Horizons","volume":" ","pages":""},"PeriodicalIF":12.2,"publicationDate":"2025-03-19","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"143655672","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":2,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Simulating open quantum systems with molecular spin qudits.
IF 12.2 2区 材料科学
Materials Horizons Pub Date : 2025-03-19 DOI: 10.1039/d4mh01512f
Sebastián Roca-Jerat, Emilio Macaluso, Alessandro Chiesa, Paolo Santini, Stefano Carretta
{"title":"Simulating open quantum systems with molecular spin qudits.","authors":"Sebastián Roca-Jerat, Emilio Macaluso, Alessandro Chiesa, Paolo Santini, Stefano Carretta","doi":"10.1039/d4mh01512f","DOIUrl":"https://doi.org/10.1039/d4mh01512f","url":null,"abstract":"<p><p>Noise affecting quantum processors still limits quantum simulations to a small number of units and operations. This is especially true for the simulation of open quantum systems, which involve additional units and operations to map environmental degrees of freedom. Hence, finding efficient approaches for the simulation of open quantum systems is an open issue. In this work, we demonstrate how using units with <i>d</i> > 2 levels (qudits) results in a reduction of up to two orders of magnitude in the number of operations (gates) required to implement state-of-the-art algorithms. We explore two conceptually distinct families of these algorithms that were initially designed for qubits and discuss the gate complexity scaling that different platforms (qubit-based <i>vs.</i> qudit-based) offer. Additionally, we present realistic simulations of an experimental platform based on molecular spin qudits coupled to superconducting resonators, where the main hardware error sources are included. We show that, in all cases considered, the use of qudits leads to a remarkable reduction in circuit complexity and that molecular nanomagnets are ideal qudit hosts.</p>","PeriodicalId":87,"journal":{"name":"Materials Horizons","volume":" ","pages":""},"PeriodicalIF":12.2,"publicationDate":"2025-03-19","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"143661571","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":2,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Development of novel multi-responsive 4D printed smart nanocomposites with polypyrrole coated iron oxides for remote and adaptive transformation. 利用聚吡咯涂层铁氧化物开发新型多响应 4D 印刷智能纳米复合材料,实现远程自适应转换。
IF 12.2 2区 材料科学
Materials Horizons Pub Date : 2025-03-18 DOI: 10.1039/d4mh01804d
Shengbo Guo, Tarun Agarwal, Shuaiqi Song, Kausik Sarkar, Lijie Grace Zhang
{"title":"Development of novel multi-responsive 4D printed smart nanocomposites with polypyrrole coated iron oxides for remote and adaptive transformation.","authors":"Shengbo Guo, Tarun Agarwal, Shuaiqi Song, Kausik Sarkar, Lijie Grace Zhang","doi":"10.1039/d4mh01804d","DOIUrl":"https://doi.org/10.1039/d4mh01804d","url":null,"abstract":"<p><p>Four-dimensional (4D) printing, a state-of-the-art additive manufacturing technology, enables the creation of objects capable of changing shape, properties, or functionality over time in response to external stimuli. However, the lack of effective remote control and reliance on a single actuation method pose significant challenges, limiting its applications in various fields. This study aims to address these limitations by developing a novel multi-responsive nanocomposite. By coating near-infrared light (NIR)-responsive polypyrrole (PPy) onto the surface of magnetic iron oxide (Fe<sub>2</sub>O<sub>3</sub>) nanoparticles (NPs), multi-responsive PPy@Fe<sub>2</sub>O<sub>3</sub> NPs were synthesized. Doping PPy@Fe<sub>2</sub>O<sub>3</sub> into a thermo-responsive shape memory polymer (SMP) matrix created a nanocomposite with excellent NIR and magnetic responsiveness, enabling dynamic, remote-controlled shape transformation of printed objects with precise timing and positioning using NIR and a magnetic field. Using the nanocomposite, a proof-of-concept semi-tubular construct was fabricated to evaluate its controllable transformation capability and assess the potential for modulating neural stem cell (NSC) behaviors. Furthermore, three proof-of-concept smart robots with distinct features were designed and fabricated for cargo delivery in diverse scenarios and different purposes. Importantly, all complex operations of these robots were remotely controlled using NIR illumination and an external magnetic field. This novel approach demonstrates significant progress in addressing the key challenges of remote control and actuation in 4D printing, highlighting its potential for enhanced versatility and functionality across various applications.</p>","PeriodicalId":87,"journal":{"name":"Materials Horizons","volume":" ","pages":""},"PeriodicalIF":12.2,"publicationDate":"2025-03-18","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"143646769","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":2,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Polyimide nanocomposites for next generation spacesuits.
IF 12.2 2区 材料科学
Materials Horizons Pub Date : 2025-03-17 DOI: 10.1039/d4mh01816h
Priyanka Prakash, Janith Weerasinghe, Igor Levchenko, Karthika Prasad, Katia Alexander
{"title":"Polyimide nanocomposites for next generation spacesuits.","authors":"Priyanka Prakash, Janith Weerasinghe, Igor Levchenko, Karthika Prasad, Katia Alexander","doi":"10.1039/d4mh01816h","DOIUrl":"https://doi.org/10.1039/d4mh01816h","url":null,"abstract":"<p><p>Polyimides have a long history of use in space missions, with Kapton® being the first polymer material to touch the surface of the Moon. Polyimides offer remarkable mechanical strength, superior thermal stability, and resistance to radiation, chemicals, and wear, and as such are often serve as a thermal barrier and a protective layer against extreme radiation and temperatures in multi-layer insulation systems. While the use of Kapton® in spacesuits dates back to the two aluminised Kapton® layers used in the spacesuits in the Apollo 11 mission, the potential uses of polyimides in the design of spacesuits remain underexplored, particularly considering the advancement made in the development of high-performance polyimide-based composites. This review explores the opportunities that emerge when the desirable properties of polyimides are combined with that of nanomaterials, specifically carbon nanomaterials, to produce strategic material combinations that promise to achieve enhanced thermal and mechanical properties, improved resistance to abrasion and puncture, and potentially reduced weight compared to traditional spacesuit materials. In turn, these advancements will contribute to the development of next-generation spacesuits that offer superior comfort, protection, and astronaut mobility during extravehicular activities.</p>","PeriodicalId":87,"journal":{"name":"Materials Horizons","volume":" ","pages":""},"PeriodicalIF":12.2,"publicationDate":"2025-03-17","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"143646361","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":2,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
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