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25th Anniversary Celebration of Green Chemistry 绿色化学25周年庆典
IF 9.3 1区 化学
Green Chemistry Pub Date : 2025-07-10 DOI: 10.1039/D5GC90115D
Michael A. Rowan and Andrea Carolina Ojeda Porras
{"title":"25th Anniversary Celebration of Green Chemistry","authors":"Michael A. Rowan and Andrea Carolina Ojeda Porras","doi":"10.1039/D5GC90115D","DOIUrl":"https://doi.org/10.1039/D5GC90115D","url":null,"abstract":"<p >Launched in 1999 with the vision of advancing environmentally conscious science, <em>Green Chemistry</em> has become a leading global journal at the heart of sustainable chemistry research. This editorial celebrates 25 years of the journal's founding principles and recent initiatives aimed at supporting the next generation of green research. A global series of 25th anniversary symposia have strengthened dialogue across academia, industry, and regions. With refreshed Editorial and Advisory Boards, <em>Green Chemistry</em> remains committed to setting standards, fostering collaboration, and enabling chemistry that responds meaningfully to global challenges. As we look to the future, our mission is to empower the community to move from aspiration to action to build a more inclusive, transformative, and impactful field.</p>","PeriodicalId":78,"journal":{"name":"Green Chemistry","volume":" 29","pages":" 8686-8690"},"PeriodicalIF":9.3,"publicationDate":"2025-07-10","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"144671323","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":1,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Catalyst-free urea synthesis via plasma-driven direct coupling of CO2 and N2 under ambient conditions† 环境条件下等离子体驱动CO2和N2直接偶联的无催化剂尿素合成†
IF 9.3 1区 化学
Green Chemistry Pub Date : 2025-07-08 DOI: 10.1039/D5GC02193F
Dingwei Gan, Jingwen Huang, Longfei Hong, Haoxuan Jiang, Xiaoran Wang, Rusen Zhou, Jing Sun and Renwu Zhou
{"title":"Catalyst-free urea synthesis via plasma-driven direct coupling of CO2 and N2 under ambient conditions†","authors":"Dingwei Gan, Jingwen Huang, Longfei Hong, Haoxuan Jiang, Xiaoran Wang, Rusen Zhou, Jing Sun and Renwu Zhou","doi":"10.1039/D5GC02193F","DOIUrl":"https://doi.org/10.1039/D5GC02193F","url":null,"abstract":"<p >This work demonstrates a new catalyst-free pathway of urea synthesis <em>via</em> direct CO<small><sub>2</sub></small>/N<small><sub>2</sub></small> coupling in spatially separated dual plasma reactors. The design isolates reactive species generation, suppressing oxidative side reactions (<em>e.g.</em>, O and OH-induced NH<small><sub>3</sub></small> loss) and facilitating C–N coupling. Mechanistic studies indicate CO (from CO<small><sub>2</sub></small> dissociation) as the key intermediate, reacting with NH<small><sub><em>x</em></sub></small> to form urea, while minimizing NO<small><sub><em>x</em></sub></small> byproducts. By decoupling plasma zones, the system achieves selective nitrogen fixation under ambient conditions, advancing green urea synthesis without catalysts or extreme energy inputs. This strategy provides mechanistic insights and a scalable platform for sustainable carbon/nitrogen co-utilization.</p>","PeriodicalId":78,"journal":{"name":"Green Chemistry","volume":" 29","pages":" 8811-8817"},"PeriodicalIF":9.3,"publicationDate":"2025-07-08","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"144671295","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":1,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Closed-loop recycling of spent Li6.5La3Zr1.5Ta0.5O12: from selective lithium recovery to high-efficiency sintering-aid preparation† 废Li6.5La3Zr1.5Ta0.5O12的闭环回收:从选择性锂回收到高效助烧结制备†
IF 9.3 1区 化学
Green Chemistry Pub Date : 2025-07-07 DOI: 10.1039/D5GC02023A
Yufan Zheng, Kexin Wan, Yuancheng Chen, Chuang Ji, Hongxiang Kuai and Xunhui Xiong
{"title":"Closed-loop recycling of spent Li6.5La3Zr1.5Ta0.5O12: from selective lithium recovery to high-efficiency sintering-aid preparation†","authors":"Yufan Zheng, Kexin Wan, Yuancheng Chen, Chuang Ji, Hongxiang Kuai and Xunhui Xiong","doi":"10.1039/D5GC02023A","DOIUrl":"https://doi.org/10.1039/D5GC02023A","url":null,"abstract":"<p >Effective recycling of spent solid-state batteries (SSBs) and endowing recycled products with a “second life” show great promise for advancing the sustainable development of SSBs, which has rarely been reported in previous works. Herein, an efficient and novel strategy based on sulfur-assisted phase transformation followed by water leaching has been proposed to selectively extract Li from spent SSBs. Structural characterization indicates that the substitution of sulfur for oxygen in dodecahedral [LaO<small><sub>8</sub></small>] can promote the collapse of the garnet structure, and the Li in the crystal lattice can be fully converted into water-soluble Li salts. Under optimized conditions, the recovery ratio of Li can be as high as 99.6% with Li leaching selectivity approaching 100%. The techno-economic analysis demonstrates that the sulfur-assisted phase transformation for the selective recycling strategy holds potential economic and environmental value in battery recycling. Additionally, the lithium extraction slag can be transformed into a highly efficient solid electrolyte sintering aid through secondary roasting, which enables the SSBs to show greatly enhanced cycling stability and rate performance <em>via</em> increasing the densification of the solid-state electrolyte and improving the ionic conductivity. This work offers fresh insights into recycling spent SSBs and advancing the applications of SSBs.</p>","PeriodicalId":78,"journal":{"name":"Green Chemistry","volume":" 29","pages":" 8950-8958"},"PeriodicalIF":9.3,"publicationDate":"2025-07-07","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"144671954","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":1,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
The low-temperature selective oxidation of alcohols and a one-pot oxidative esterification using an IBS(iii/v)/oxone catalysis† IBS(iii/v)/oxone催化下醇类低温选择性氧化及一锅氧化酯化反应研究
IF 9.3 1区 化学
Green Chemistry Pub Date : 2025-07-07 DOI: 10.1039/D5GC01737H
Ryutaro Kondo, Muhammet Uyanik and Kazuaki Ishihara
{"title":"The low-temperature selective oxidation of alcohols and a one-pot oxidative esterification using an IBS(iii/v)/oxone catalysis†","authors":"Ryutaro Kondo, Muhammet Uyanik and Kazuaki Ishihara","doi":"10.1039/D5GC01737H","DOIUrl":"https://doi.org/10.1039/D5GC01737H","url":null,"abstract":"<p >The IBS/oxone catalyst system has been improved for selective alcohol oxidation at near-room temperature (30 °C), overcoming the limitations of the conventional high-temperature (70 °C) method. An NMR spectroscopy analysis identified the rate-determining step, leading to the development of optimized conditions based on the pre-generation of IBS(<small>III</small>) and a phase-transfer catalyst. These improvements enhanced the functional-group tolerance and substrate scope, including thermally unstable, acid-sensitive, or overoxidation-prone alcohols. Furthermore, the system was successfully applied to one-pot oxidative esterification reactions, demonstrating its versatility and synthetic utility in mild oxidation processes.</p>","PeriodicalId":78,"journal":{"name":"Green Chemistry","volume":" 29","pages":" 8804-8810"},"PeriodicalIF":9.3,"publicationDate":"2025-07-07","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://pubs.rsc.org/en/content/articlepdf/2025/gc/d5gc01737h?page=search","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"144671294","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":1,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"OA","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Light empowered aziridination of olefins under metal- and photocatalyst-free conditions† 无金属和无光催化剂条件下烯烃的光增强叠氮化反应
IF 9.3 1区 化学
Green Chemistry Pub Date : 2025-07-05 DOI: 10.1039/D5GC02150B
Bin Sun, Qian Zhang, Jianjie Wang, Yan Xu, Jiayin Wang, Chun Lv, Xiaohui Zhuang, Caiyun Yu and Can Jin
{"title":"Light empowered aziridination of olefins under metal- and photocatalyst-free conditions†","authors":"Bin Sun, Qian Zhang, Jianjie Wang, Yan Xu, Jiayin Wang, Chun Lv, Xiaohui Zhuang, Caiyun Yu and Can Jin","doi":"10.1039/D5GC02150B","DOIUrl":"https://doi.org/10.1039/D5GC02150B","url":null,"abstract":"<p >Aziridines derived from biologically active compounds often exhibit distinct pharmacological properties, rendering them highly valuable in the field of pharmacology. The conversion of readily available alkenes into aziridines represents a highly valuable synthetic approach, but is predominantly achieved through either transition-metal-based catalysis or photosensitization approaches. Here, we report a catalyst-free strategy for efficient aziridination of olefins <em>via</em> visible-light-induced homolytic cleavage of the N–Cl bond in chloramine T (CAT). This strategy illustrates the broad substrate versatility of olefins and demonstrates exceptional applicability for the aziridination of important natural active molecules and pharmaceuticals. Notably, the integration of controllable photo-flow technology substantially enhances process efficiency and scalability underscoring its substantial potential for application in pharmaceutical derivatization.</p>","PeriodicalId":78,"journal":{"name":"Green Chemistry","volume":" 29","pages":" 8980-8987"},"PeriodicalIF":9.3,"publicationDate":"2025-07-05","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"144671957","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":1,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
From aspiration to action: evolving the mission of Green Chemistry 从愿望到行动:发展绿色化学的使命
IF 9.3 1区 化学
Green Chemistry Pub Date : 2025-07-04 DOI: 10.1039/D5GC90116B
Javier Pérez-Ramírez and Michael A. Rowan
{"title":"From aspiration to action: evolving the mission of Green Chemistry","authors":"Javier Pérez-Ramírez and Michael A. Rowan","doi":"10.1039/D5GC90116B","DOIUrl":"https://doi.org/10.1039/D5GC90116B","url":null,"abstract":"<p >As <em>Green Chemistry</em> moves from aspiration to action, this Editorial outlines how the journal is evolving to support a growing, global community. We highlight new tools such as the Green Foundation Box and the Methods, Models and Metrics collection, reinforce our commitment to both fundamental and applied research, and share efforts to foster collaboration, strengthen our editorial and advisory boards, and build capacity across academia and industry. Our goal is to lead not only in science, but in shaping a more inclusive, transparent and sustainability-driven research culture.</p>","PeriodicalId":78,"journal":{"name":"Green Chemistry","volume":" 28","pages":" 8357-8359"},"PeriodicalIF":9.3,"publicationDate":"2025-07-04","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"144624202","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":1,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
A mesoporous TiO2/carbon dot heterojunction photocatalyst efficiently cleaves entire types of C–O bonds in lignin under visible light† 一种介孔TiO2/碳点异质结光催化剂在可见光下能有效地切割木质素中的C-O键
IF 9.3 1区 化学
Green Chemistry Pub Date : 2025-07-03 DOI: 10.1039/D5GC01918D
Song Han, Yun Zhao, Mina Liang, Xiangxiong Zhai, Qi Zhang, Na Sun, Rong Ma, Guoling Li, Zhubing Xiao and Zhonghai Ni
{"title":"A mesoporous TiO2/carbon dot heterojunction photocatalyst efficiently cleaves entire types of C–O bonds in lignin under visible light†","authors":"Song Han, Yun Zhao, Mina Liang, Xiangxiong Zhai, Qi Zhang, Na Sun, Rong Ma, Guoling Li, Zhubing Xiao and Zhonghai Ni","doi":"10.1039/D5GC01918D","DOIUrl":"https://doi.org/10.1039/D5GC01918D","url":null,"abstract":"<p >The progress of photocatalytic biomass depolymerization under mild conditions for the production of high-value chemicals has great potential. Previous studies showed that commercial TiO<small><sub>2</sub></small> effectively cleaved α-O-4 linkages, but 4-O-5 linkages were much harder to break due to higher bond energy. Here, we successfully synthesized mesoporous TiO<small><sub>2</sub></small> with a high specific surface area, while oxygen vacancies enhanced its visible light absorption and regulated the position of the energy band. Additionally, the Z-scheme heterojunction Pt@CDs-2/TiO<small><sub>2</sub></small>-MP was successfully prepared by introducing carbon dots, thereby effectively promoting the separation and transfer of photogenerated hole–electron pairs. Pt@CDs-2/TiO<small><sub>2</sub></small>-MP was employed for the cleavage of 4-O-5 type lignin model diphenyl ether (DPE), with DPE being almost completely converted under 365 nm LED irradiation and achieving a 90.0% conversion rate under visible light. Besides, Pt@CDs-2/TiO<small><sub>2</sub></small>-MP effectively cleaved α-O-4 (benzyl phenyl ether, 77.8%) and β-O-4 (phenethoxybenzene, 99.6%) models. Even for the C–C bond with a high dissociation energy (biphenyl, 99.0%), it exhibited significant bond cleavage capability, achieving a cyclohexane yield of 10.0%. Furthermore, this photocatalytic method successfully converted different types of lignin into high-value aromatic monomers. This study presents a sustainable and efficient method for the conversion of lignin, thereby contributing significantly to the achievement of sustainable development goals.</p>","PeriodicalId":78,"journal":{"name":"Green Chemistry","volume":" 29","pages":" 8883-8900"},"PeriodicalIF":9.3,"publicationDate":"2025-07-03","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"144671929","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":1,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Selective C–O bond cleavage enhances aromatics production from lignin-derived platform molecules with ethanol as a hydrogen donor† 选择性C-O键裂解增强了以乙醇为氢供体的木质素衍生平台分子生成芳烃的能力
IF 9.3 1区 化学
Green Chemistry Pub Date : 2025-07-03 DOI: 10.1039/D5GC02104A
Hao Zhang, Qisong Yi, Huawei Geng, Zhifeng Liu, Wenhao Luo, Zichun Wang and Yuanshuai Liu
{"title":"Selective C–O bond cleavage enhances aromatics production from lignin-derived platform molecules with ethanol as a hydrogen donor†","authors":"Hao Zhang, Qisong Yi, Huawei Geng, Zhifeng Liu, Wenhao Luo, Zichun Wang and Yuanshuai Liu","doi":"10.1039/D5GC02104A","DOIUrl":"https://doi.org/10.1039/D5GC02104A","url":null,"abstract":"<p >Selective catalytic cleavage of C–O bonds during the hydrodeoxygenation (HDO) of lignin-derived phenolics is essential for producing renewable aromatics from biomass. The HDO process typically involves the use of high-pressure molecular hydrogen, which poses safety concerns and lacks sustainability. Herein, we report an effective catalytic approach that integrates the aqueous-phase reforming (APR) of ethanol with the selective HDO of lignin-derived phenol to benzene over a well-defined Pt/Al<small><sub>2</sub></small>O<small><sub>3</sub></small> catalyst. The effects of catalyst support, ethanol-to-water ratios, and reaction temperatures on <em>in situ</em> HDO processes were systematically explored and thoroughly discussed. The competitive routes of C–O bond hydrogenolysis and benzene ring hydrogenation during HDO of phenol were found to be significantly dependent on the H<small><sub>2</sub></small> produced by the APR of ethanol and variations in reaction parameters. A lower H<small><sub>2</sub></small> pressure, generated from an optimized <em>V</em><small><sub>ethanol</sub></small>/<em>V</em><small><sub>water</sub></small> of 3 : 5 and a high reaction temperature of 280 °C, favored the selective cleavage of C–O bonds rather than the hydrogenation of benzene rings, resulting in a relatively high phenol conversion of <em>ca.</em> 57% with a benzene selectivity of <em>ca.</em> 97% after 2 h of reaction. The proposed reaction pathways involved in the currently developed <em>in situ</em> HDO process provided a deep understanding of the pronounced selectivity towards benzene formation from phenol under optimized reaction conditions. The conversion of other representative lignin-derived phenolics and ethers further validated the superiority and versatility of the developed catalytic system in producing aromatic compounds from lignin biomass.</p>","PeriodicalId":78,"journal":{"name":"Green Chemistry","volume":" 29","pages":" 8959-8971"},"PeriodicalIF":9.3,"publicationDate":"2025-07-03","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"144671955","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":1,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Dual functionalization of mesoporous organosilicon nanoflowers enhances heterogeneous chemoenzymatic conversion of alkynes toward enantiopure alcohols† 介孔有机硅纳米花的双功能化增强了炔烃向对映纯醇†的非均相化学酶转化
IF 9.3 1区 化学
Green Chemistry Pub Date : 2025-07-02 DOI: 10.1039/D5GC02373D
Chen Huang, Qian Zhang, Xiaoyang Yue, Aidang Lu, Guanhua Liu, Ying He, Li Ma, Liya Zhou, Yunting Liu and Yanjun Jiang
{"title":"Dual functionalization of mesoporous organosilicon nanoflowers enhances heterogeneous chemoenzymatic conversion of alkynes toward enantiopure alcohols†","authors":"Chen Huang, Qian Zhang, Xiaoyang Yue, Aidang Lu, Guanhua Liu, Ying He, Li Ma, Liya Zhou, Yunting Liu and Yanjun Jiang","doi":"10.1039/D5GC02373D","DOIUrl":"https://doi.org/10.1039/D5GC02373D","url":null,"abstract":"<p >A tandem chemoenzymatic cascade for the direct synthesis of chiral alcohols from bulk alkynes is promising but challenging, as it couples the gold-catalysed alkyne hydration with an alcohol dehydrogenase-driven asymmetric reduction of the resulting ketones. Herewith two heterogeneous bifunctional catalysts are fabricated for chemocatalytic and biocatalytic steps, respectively. The bi-functionalized chemocatalyst (Au@HS/SO<small><sub>3</sub></small>H-DON), which possesses both Au NPs and Brønsted acid catalytic sites, exhibits superior catalytic performance and better reusability compared to those of homogeneous Au(<small>III</small>) catalysts. The bi-functionalized biocatalyst (ADH@QA-DON) exhibits enhanced reusability over free ADH and enriches NADH, enhancing the overall catalytic performance. Various chiral alcohols are directly obtained from alkynes with high yields (73%–92%) and enantioselectivity (&gt;99% ee) <em>via</em> tandem cascade reactions catalyzed by bifunctional chemo- and biocatalysts. By fabricating a continuous-flow system, a space–time yield (STY) of 4.69 g L<small><sup>−1</sup></small> h<small><sup>−1</sup></small> for (<em>S</em>)-1-phenylethanol can be achieved, which is 6.7-fold higher than that obtained in batch.</p>","PeriodicalId":78,"journal":{"name":"Green Chemistry","volume":" 29","pages":" 8858-8866"},"PeriodicalIF":9.3,"publicationDate":"2025-07-02","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"144671926","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":1,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Sustainable approaches in vat photopolymerization: advancements, limitations, and future opportunities† 还原光聚合的可持续方法:进展、限制和未来机遇
IF 9.3 1区 化学
Green Chemistry Pub Date : 2025-07-02 DOI: 10.1039/D5GC02299A
Mirko Maturi, Erica Locatelli, Alberto Sanz de Leon, Mauro Comes Franchini and Sergio Ignacio Molina
{"title":"Sustainable approaches in vat photopolymerization: advancements, limitations, and future opportunities†","authors":"Mirko Maturi, Erica Locatelli, Alberto Sanz de Leon, Mauro Comes Franchini and Sergio Ignacio Molina","doi":"10.1039/D5GC02299A","DOIUrl":"https://doi.org/10.1039/D5GC02299A","url":null,"abstract":"<p >Vat photopolymerization (VP) is reshaping advanced manufacturing, yet its dependence on petrochemical-derived resins poses significant sustainability challenges. This review critically evaluates conventional photocurable formulations, highlighting the limitations of standard metrics such as the biobased carbon content (BCC%), and introduces the sustainable formulation score (SFS) as a comprehensive alternative. By integrating factors like atom economy, hazardous reagent usage, solvent selection, and end-of-life considerations, SFS offers a more holistic measure of environmental impact. The analysis encompasses diverse resin systems, including (meth)acrylated vegetable oil derivatives, biobased small molecules from lignin and other renewable sources, non-isocyanate urethanes, and thiol–ene formulations. For vegetable oil-based systems, a key trade-off is observed between achieving high biobased content and maintaining optimal mechanical properties, driven by variations in the degree of acrylation and processing conditions. In contrast, the synthesis of small biobased molecules often involves toxic reagents and less favorable atom economies, reducing their overall green appeal. Moreover, non-isocyanate urethanes and thiol–ene systems emerge as promising routes for improving sustainability while preserving performance. Overall, this review underscores the need for unified green metrics and optimized synthesis strategies to bridge the gap between environmental sustainability and material performance in photopolymer formulations, paving the way for more responsible and efficient additive manufacturing technologies.</p>","PeriodicalId":78,"journal":{"name":"Green Chemistry","volume":" 29","pages":" 8710-8754"},"PeriodicalIF":9.3,"publicationDate":"2025-07-02","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://pubs.rsc.org/en/content/articlepdf/2025/gc/d5gc02299a?page=search","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"144671292","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":1,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"OA","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
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