Green Chemistry最新文献_第10页

Advances in molecular interfacial engineering of heterojunctions for photocatalytic CO2 reduction 光催化CO2还原异质结分子界面工程研究进展

IF 9.3 1区化学

Green Chemistry Pub Date : 2025-05-28 DOI: 10.1039/d5gc01228g

Haopeng Jiang , Jun Shen , Lijuan Sun , Jinhe Li , Weikang Wang , Lele Wang , Qinqin Liu

{"title":"Advances in molecular interfacial engineering of heterojunctions for photocatalytic CO2 reduction","authors":"Haopeng Jiang , Jun Shen , Lijuan Sun , Jinhe Li , Weikang Wang , Lele Wang , Qinqin Liu","doi":"10.1039/d5gc01228g","DOIUrl":"10.1039/d5gc01228g","url":null,"abstract":"<div><div>The unsustainable reliance on fossil fuels has triggered an alarming accumulation of atmospheric CO<sub>2</sub>, exacerbating global energy insecurity and environmental degradation. Photocatalytic CO<sub>2</sub> reduction, an artificial photosynthetic paradigm leveraging solar energy to convert CO<sub>2</sub> into renewable hydrocarbons (<em>e.g.</em>, CH<sub>4</sub>, C<sub>2</sub>H<sub>4</sub>, CH<sub>3</sub>COOH), has emerged as a prominent strategy in green chemistry to reconcile carbon neutrality with sustainable fuel production. This review critically examines interfacial engineering of semiconductor heterojunctions, which governs charge carrier dynamics, active site exposure, and reaction pathways by manipulating interfacial interactions (π–π stacking, coulombic forces, van der Waals forces, hydrogen bonding, covalent bonding). We articulate the mechanistic synergy between band alignment principles and green chemistry frameworks, emphasizing how interfacial effects orchestrate thermodynamics (<em>e.g.</em>, CO<sub>2</sub> activation energy barriers) and kinetics (<em>e.g.</em>, C–C coupling rates) to enhance selectivity and quantum efficiency of photocatalytic CO<sub>2</sub> reduction. By addressing critical challenges confronting scalable CO<sub>2</sub> valorization, including charge recombination and product specificity limitations, we propose forward-looking perspectives integrating atomic-scale bond modulation, circular material lifecycles, and energy-autonomous photoreactor designs. By establishing conceptual bridges between interfacial science and green process engineering, this work provides a framework to guide the rational design of interfacial interactions, advancing CO<sub>2</sub> transformation from an ecological liability to a cornerstone of circular carbon economies.</div></div>","PeriodicalId":78,"journal":{"name":"Green Chemistry","volume":"27 24","pages":"Pages 6989-7008"},"PeriodicalIF":9.3,"publicationDate":"2025-05-28","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"144291795","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":1,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

引用次数: 0

Developments in CO surrogates for base-metal-catalyzed carbonylation 碱金属催化羰基化CO代物的研究进展

IF 9.3 1区化学

Green Chemistry Pub Date : 2025-05-28 DOI: 10.1039/d5gc01579k

Wenjing Li , Shentong Xie , Renyi Shi

{"title":"Developments in CO surrogates for base-metal-catalyzed carbonylation","authors":"Wenjing Li , Shentong Xie , Renyi Shi","doi":"10.1039/d5gc01579k","DOIUrl":"10.1039/d5gc01579k","url":null,"abstract":"<div><div>Transition-metal-catalyzed carbonylation, which introduces CO into organic molecules, is one of the most important tools to synthesize carbonyl derivatives. Despite the considerable synthetic utility of carbonylation reactions, their advancement remains hindered by several critical limitations, including the use of high-loading noble metal catalysts, such as Pd, Ru, and Rh, and use of toxic and environmentally unfriendly CO or metal carbonyl complexes. Taking safety and operability into account, the base-metal-catalyzed carbonylation utilizing various CO surrogates has been identified as an ideal alternative to overcome the above-mentioned challenges. In this research field, the development of small-molecule CO surrogates occupies a central position and has achieved remarkable progress. In this review, we systematically summarize the progress in the development of CO surrogates for base-metal-catalyzed carbonylation reactions. Moreover, this review provides forward-looking perspectives to guide chemists in designing low-cost, more efficient, and environmentally benign CO surrogates, thereby establishing a robust foundation for the wider application of carbonylation reactions in organic synthesis and chemical industry.</div></div>","PeriodicalId":78,"journal":{"name":"Green Chemistry","volume":"27 24","pages":"Pages 7082-7095"},"PeriodicalIF":9.3,"publicationDate":"2025-05-28","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"144291798","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":1,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

引用次数: 0

Facile and rapid access to hexafluoroisopropanol (HFIP)-group-functionalized aniline and indole derivatives using hexafluoroacetone trihydrate in HFIP† 六氟异丙醇(HFIP)-基团功能化苯胺和吲哚衍生物使用六氟丙酮三水合物HFIP†方便和快速获取

IF 9.3 1区化学

Green Chemistry Pub Date : 2025-05-28 DOI: 10.1039/d5gc00878f

Xindi Li , Yuhao Wu , Jinshan Li , Jialin Xie , Juanzu Liu , Zhenchang Wen , Zhendong Zhao , Chunman Jia

引用次数: 0

Engineering a hybrid system of Corynebacterium glutamicum and co-immobilized enzymes for efficient cadaverine production from glycerol† 设计谷氨酸棒状杆菌和共固定化酶的杂交系统，用于从甘油†中高效生产尸胺

IF 9.3 1区化学

Green Chemistry Pub Date : 2025-05-28 DOI: 10.1039/d5gc00694e

Yunpeng Lv , Simin Liu , Liang Wei , Lei Zhang , Haishan Qi

{"title":"Engineering a hybrid system of Corynebacterium glutamicum and co-immobilized enzymes for efficient cadaverine production from glycerol†","authors":"Yunpeng Lv , Simin Liu , Liang Wei , Lei Zhang , Haishan Qi","doi":"10.1039/d5gc00694e","DOIUrl":"10.1039/d5gc00694e","url":null,"abstract":"<div><div>1,5-Diaminopentane (cadaverine) is a critical raw material for producing bio-based polyamides. With growing concerns about the depletion of fossil resources and the increasing demand for sustainable industrial solutions, the biosynthesis of cadaverine has attracted significant attention. Currently, the <em>de novo</em> biosynthesis of cadaverine primarily uses glucose as the substrate, but high costs undermine its competitive advantage against other biomaterials, requiring novel production routes. Here, a cell factory coupled with co-immobilized enzymes was employed to produce cadaverine using glycerol as the sole carbon source. <em>Corynebacterium glutamicum</em> was first engineered to produce lysine from glycerol. Subsequently, the initial strain CGgly2 was engineered by regulating the lysine biosynthetic pathway and enhancing the reducing power supply pathway. The lysine yield of recombinant strain LYS10 reached 19.0 g L<sup>−1</sup> in shake flask cultures after optimizing fermentation parameters. For efficient bioconversion of cadaverine, an “EKylation” strategy was employed to engineer lysine decarboxylase. Besides, the engineered enzyme was co-immobilized with pyridoxal 5′-phosphate (PLP) using epoxy resin, resulting in the enzyme complex ER604-10EK-PLP, which exhibited significantly enhanced catalytic activity and stability. Ultimately, strain LYS10 was combined with complex ER604-10EK-PLP in a 5 L fermenter, and 90.7 g L<sup>−1</sup> cadaverine was accumulated <em>via</em> fed-batch fermentation with a yield of 0.2 g g<sup>−1</sup> glycerol, which was the highest titer of cadaverine reported from glycerol. This hybrid platform is promising for sustainable production of cadaverine, offering a viable alternative to fossil-derived chemicals.</div></div>","PeriodicalId":78,"journal":{"name":"Green Chemistry","volume":"27 24","pages":"Pages 7263-7280"},"PeriodicalIF":9.3,"publicationDate":"2025-05-28","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"144291778","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":1,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

引用次数: 0

Enhanced electrocatalytic hydrogen evolution reaction, oxygen evolution reaction and biomass oxidation over Ce-doped NiPxvia optimization of electronic modulation† 通过优化电子调制†，增强了ce掺杂nipxe上的电催化析氢反应、析氧反应和生物质氧化

IF 9.3 1区化学

Green Chemistry Pub Date : 2025-05-28 DOI: 10.1039/d5gc01605c

Shuhan Liu , Yifei Ye , Lele Gao , Zhen Yan , Haokun Pan , Zhaokun Wang , Guangrui Zhang , Xiubing Huang

{"title":"Enhanced electrocatalytic hydrogen evolution reaction, oxygen evolution reaction and biomass oxidation over Ce-doped NiPxvia optimization of electronic modulation†","authors":"Shuhan Liu , Yifei Ye , Lele Gao , Zhen Yan , Haokun Pan , Zhaokun Wang , Guangrui Zhang , Xiubing Huang","doi":"10.1039/d5gc01605c","DOIUrl":"10.1039/d5gc01605c","url":null,"abstract":"<div><div>Electrocatalytic oxidation of 5-hydroxymethylfurfural (HMFOR) to 2,5-furandicarboxylic acid (FDCA) using highly efficient electrocatalysts is currently a research hotspot. In this study, nickel foam-supported Ce-doped transition metal phosphide (<em>i.e.</em>, Ce-NiP<sub><em>x</em></sub>/NF) was synthesized using a one-step electrochemical deposition method. The Lewis acidity of the Ce species offered adsorption sites for oxygen-containing substrates, and the electronic structure of Ni could be effectively adjusted due to its variable valence state. In addition, the charge modulation of Ce and P promoted the rapid valorization of Ni, and the escape of P during the reaction formed many oxygen vacancies, which facilitated the adsorption of HMF. The hydrogen evolution reaction (HER) and oxygen evolution reaction (OER) required overpotentials of only 116 mV and 276 mV for a current density of 10 mA cm<sup>−2</sup>, respectively. For HMFOR, the HMF conversion reached almost 100%, and the FDCA yield and Faraday efficiency were 98.69% and 98.38% at 1.40 V<sub>RHE</sub>, respectively, and both remained above 95% after 20 cycles. This study presents a facile method for constructing heteroatomic electrodes for electrocatalytic oxidation and reduction and provides a method for designing high-performance electrocatalysts.</div></div>","PeriodicalId":78,"journal":{"name":"Green Chemistry","volume":"27 24","pages":"Pages 7307-7318"},"PeriodicalIF":9.3,"publicationDate":"2025-05-28","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"144291782","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":1,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

引用次数: 0

Production of high-carbon-number hydrocarbon bio-aviation fuels via catalytic hydrogenation of vanillin and non-catalytic condensation: a mechanistic study with DFT and experimental insights† 通过香兰素催化加氢和非催化缩合生产高碳数碳氢化合物生物航空燃料：用DFT和实验见解进行的机理研究

IF 9.3 1区化学

Green Chemistry Pub Date : 2025-05-28 DOI: 10.1039/d5gc00281h

Jina Eun , Jeonghun Kim , Han Byeol Kim , Do Heui Kim , Jae-Wook Choi , Kwang Ho Kim , Chun-Jae Yoo , Seongmin Jin , Kyeongsu Kim , Hyunjoo Lee , Chang Soo Kim , Kwan-Young Lee , Jong Suk Yoo , Seo-Jung Han , Keunhong Jeong , Jeong-Myeong Ha

{"title":"Production of high-carbon-number hydrocarbon bio-aviation fuels via catalytic hydrogenation of vanillin and non-catalytic condensation: a mechanistic study with DFT and experimental insights†","authors":"Jina Eun , Jeonghun Kim , Han Byeol Kim , Do Heui Kim , Jae-Wook Choi , Kwang Ho Kim , Chun-Jae Yoo , Seongmin Jin , Kyeongsu Kim , Hyunjoo Lee , Chang Soo Kim , Kwan-Young Lee , Jong Suk Yoo , Seo-Jung Han , Keunhong Jeong , Jeong-Myeong Ha","doi":"10.1039/d5gc00281h","DOIUrl":"10.1039/d5gc00281h","url":null,"abstract":"<div><div>Lignocellulose or lignin present significant potential as sustainable feedstocks to replace petroleum-derived resources through catalytic upgrading. Hydrodeoxygenation of phenolic molecules derived from lignocellulose or lignin can produce cycloalkanes, but often forms low-carbon-number hydrocarbons, which are more suitable for gasoline rather than high-carbon-number diesel or aviation fuels. This study investigates the production of high-carbon-number hydrocarbons in the aviation fuel range from lignin-derived compounds, using vanillin as a model. A two-step process was performed to achieve this: selective hydrogenation of vanillin to vanillyl alcohol and creosol using 1 wt% ruthenium on carbon, followed by non-catalytic condensation and subsequent hydrodeoxygenation of the condensates to cycloalkanes using 3 wt% ruthenium on HZSM-5. This process yielded C14 aviation fuel precursor (19%) and C14 deoxygenated hydrocarbon (5%) whereas the one-step process without the condensation step did not yield any C14 compounds. The reaction pathway was elucidated through density functional theory calculations and control experiments with intermediates, providing insights into the mechanisms of upgrading lignin-derived compounds for sustainable aviation fuel production.</div></div>","PeriodicalId":78,"journal":{"name":"Green Chemistry","volume":"27 24","pages":"Pages 7147-7159"},"PeriodicalIF":9.3,"publicationDate":"2025-05-28","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"144291819","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":1,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

引用次数: 0

A general strategy for strengthening and toughening physical hydrogels via anti-Hofmeister sequence solid salting-out† 通过反霍夫迈斯特序列固盐析出法强化和增韧物理水凝胶的一般策略

IF 9.3 1区化学

Green Chemistry Pub Date : 2025-05-28 DOI: 10.1039/d5gc00826c

En-Jiang Liu , Ding-Ding Lü , Bai-Chuan Lu , Run-Ze Hu , Shi-Wen Guo , Chen-Man Zong , Xiao-Hui Yao , Xue-Yang Wang , Tao Chen , Ai-Jun Wan , Dong-Yang Zhang

{"title":"A general strategy for strengthening and toughening physical hydrogels via anti-Hofmeister sequence solid salting-out†","authors":"En-Jiang Liu , Ding-Ding Lü , Bai-Chuan Lu , Run-Ze Hu , Shi-Wen Guo , Chen-Man Zong , Xiao-Hui Yao , Xue-Yang Wang , Tao Chen , Ai-Jun Wan , Dong-Yang Zhang","doi":"10.1039/d5gc00826c","DOIUrl":"10.1039/d5gc00826c","url":null,"abstract":"<div><div>In recent years, many strategies have been developed to enhance the mechanical properties of hydrogels. However, due to the complex process, the addition of non-green crosslinking agents and the use of high concentration salt solutions these strategies lead to increased costs, resource waste and environmental pollution. In addition, the synergistic improvement of strength and toughness of hydrogels is still challenging. Herein, a general green strategy of solid salting-out to improve the strength and toughness of physical hydrogels is reported. This strategy can induce the directional transfer of water molecules in the hydrogel, promoting the close layer-by-layer self-assembly of the PVA molecular chain. Compared with liquid salting-out, solid salting-out has a more significant improvement in the strength of hydrogels, and solid salt blocks can be recycled and reused. A PVA hydrogel prepared by the solid salting-out method showed both high strength and toughness that were 1962- and 1900-fold those from before solid salting-out, respectively. The strength and toughness of the hydrogel can be further improved to 109.06 MPa and 125.73 MJ m<sup>−3</sup>, respectively, by inducing the collaborative self-assembly of cellulose nanofibers and PVA molecular chains. As a general strategy, solid salting-out could enhance various physical hydrogels composed of materials such as silk, gelatin, and cotton staple cellulose. Thus, this study not only provides a simple method for the strengthening and toughening of physical hydrogels but also has potential applications in the field of biological implants because of the favorable biocompatibility of the prepared hydrogels.</div></div>","PeriodicalId":78,"journal":{"name":"Green Chemistry","volume":"27 24","pages":"Pages 7208-7219"},"PeriodicalIF":9.3,"publicationDate":"2025-05-28","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"144291824","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":1,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

引用次数: 0

The hydrogen economy fairytale† 氢经济的童话

IF 9.3 1区化学

Green Chemistry Pub Date : 2025-05-27 DOI: 10.1039/D5GC00946D

Tycho Ehrhardt and Gadi Rothenberg

引用次数: 0

Mechanochemical approach to polymer-functionalized black phosphorus nanomaterials for precious metal recovery† 用于贵金属回收的聚合物功能化黑磷纳米材料的机械化学方法

IF 9.3 1区化学

Green Chemistry Pub Date : 2025-05-27 DOI: 10.1039/D5GC00274E

Obida Bawadkji, Peng Tang, Christian Müller and Rainer Haag

{"title":"Mechanochemical approach to polymer-functionalized black phosphorus nanomaterials for precious metal recovery†","authors":"Obida Bawadkji, Peng Tang, Christian Müller and Rainer Haag","doi":"10.1039/D5GC00274E","DOIUrl":"https://doi.org/10.1039/D5GC00274E","url":null,"abstract":"<p >Rapid and sustainable methods for precious metal recovery are urgently needed to support circular economy initiatives. Herein, we introduce a one-pot mechanochemical route to synthesize a black phosphorus–polyglycerol (BP–PG) nanohybrid with enhanced interfacial reactivity for selective gold ion reduction. The process transforms inexpensive red phosphorus directly into amorphous BP and, subsequently, into BP–PG <em>via</em> planetary ball milling, thereby eliminating high temperatures, extended reaction times, and toxic solvents commonly used in conventional functionalized-BP nanomaterial syntheses. This “grafting-from” polymerization of glycidol onto BP yields a uniform, hydrophilic hybrid that can rapidly and selectively reduce gold ions to stabilized gold nanoparticles. Notably, BP–PG recovers more than three times its own weight in gold, far surpassing previously reported materials, while leveraging a scalable, cost-effective, and green production method. These findings underscore the critical role of synthetic strategy and material architecture in achieving high-performance nanohybrids, offering promising opportunities for precious metal recovery and broader interface-driven applications.</p>","PeriodicalId":78,"journal":{"name":"Green Chemistry","volume":" 23","pages":" 6813-6824"},"PeriodicalIF":9.3,"publicationDate":"2025-05-27","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://pubs.rsc.org/en/content/articlepdf/2025/gc/d5gc00274e?page=search","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"144243958","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":1,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"OA","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

引用次数: 0

A self-adhesive glutenin-based coating cross-linked by genipin for suppressing microplastic shedding in harsh environments† 一种由genipin交联的自粘面筋蛋白涂层，用于抑制恶劣环境下的微塑料脱落

IF 9.3 1区化学

Green Chemistry Pub Date : 2025-05-23 DOI: 10.1039/d4gc06154c

Yulun Chen , Qingrun Liu , Jianjun Ding , Shaofeng Yuan , Hang Yu , Yahui Guo , Yuliang Cheng , He Qian , Weirong Yao

{"title":"A self-adhesive glutenin-based coating cross-linked by genipin for suppressing microplastic shedding in harsh environments†","authors":"Yulun Chen , Qingrun Liu , Jianjun Ding , Shaofeng Yuan , Hang Yu , Yahui Guo , Yuliang Cheng , He Qian , Weirong Yao","doi":"10.1039/d4gc06154c","DOIUrl":"10.1039/d4gc06154c","url":null,"abstract":"<div><div>The large-scale application of plastic packaging has raised concerns on the generation of microplastics (MPs). The presence of MPs in food has been increasingly reported, and plastic packaging is one of the main sources. However, few studies have focused on strategies to inhibit shedding of MPs. Herein, a simple, green, and durable coating, which was inspired from soybean milk skin, was developed to suppress MP shedding from food-grade plastics in seven harsh simulation environments (considering the five factors of heat, acid, alkali, salt, and oil). This coating was formed <em>via</em> the phase transition of glutenin after treatment with tris(2-carboxyethyl)phosphine, and it spontaneously adhered to any plastic surfaces under mild conditions. To improve its physical properties, genipin was used as a cross-linking coating. The performance of the cross-linked coating improved in the following aspects: (1) increase in its contact angle from 84.7° to 96.1°; (2) improvement in its tightness; (3) reduction in its roughness from 0.59 μm to 0.31 μm; (4) improvement in its elastic modulus from 19.85 GPa to 30.87 GPa; (5) improvement in its gas barrier permeance by 24.46%; and (6) and decrease in the shedding abundance of MPs by 61.14%. Notably, the inhibition rate of the cross-linked coating on MP shedding under any harsh conditions ranged from 92% to 98%. After coating, MPs with sizes exceeding 100 μm were not observed through fluorescence and micro-Raman microscopies. Moreover, the covalent crosslinking mechanism of genipin on the coating was investigated using Fourier transform infrared and X-ray photoelectron spectroscopies. Furthermore, cell proliferation was used to demonstrate the safety of the coating. Overall, this work provides new insights into the control of MPs, inspiring researchers to focus more on the front-end source and design new materials to defend against the threat of MPs to human health.</div></div>","PeriodicalId":78,"journal":{"name":"Green Chemistry","volume":"27 25","pages":"Pages 7518-7531"},"PeriodicalIF":9.3,"publicationDate":"2025-05-23","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"144339057","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":1,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

引用次数: 0