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Thermally Conductive Ti3C2Tx Fibers with Superior Electrical Conductivity
IF 26.6 1区 材料科学
Nano-Micro Letters Pub Date : 2025-04-27 DOI: 10.1007/s40820-025-01752-x
Yuxiao Zhou, Yali Zhang, Yuheng Pang, Hua Guo, Yongqiang Guo, Mukun Li, Xuetao Shi, Junwei Gu
{"title":"Thermally Conductive Ti3C2Tx Fibers with Superior Electrical Conductivity","authors":"Yuxiao Zhou,&nbsp;Yali Zhang,&nbsp;Yuheng Pang,&nbsp;Hua Guo,&nbsp;Yongqiang Guo,&nbsp;Mukun Li,&nbsp;Xuetao Shi,&nbsp;Junwei Gu","doi":"10.1007/s40820-025-01752-x","DOIUrl":"10.1007/s40820-025-01752-x","url":null,"abstract":"<div><h2>Highlights</h2><div>\u0000 \u0000 <ul>\u0000 <li>\u0000 <p>The strong covalent crosslinking between trace amounts of borates and the hydroxyl groups of Ti<sub>3</sub>C<sub>2</sub>T<sub><i>x</i></sub> significantly reduces interlayer spacing, enhances orientation and compactness, leading to notable improvements in both the mechanical (tensile strength of 188.72 MPa) and electrical properties (7781 S cm<sup>−1</sup>) of Ti<sub>3</sub>C<sub>2</sub>T<sub><i>x</i></sub> fibers.</p>\u0000 </li>\u0000 <li>\u0000 <p>Trace amounts of borates can promote the regularization of interfacial structures, reduce interfacial thermal resistance, and significantly enhance the thermal conductivity (13 W m<sup>−1</sup> K<sup>−1</sup>) of Ti<sub>3</sub>C<sub>2</sub>T<sub><i>x</i></sub> fibers, thus increasing their potential for efficient heat transfer applications.</p>\u0000 </li>\u0000 </ul>\u0000 </div></div>","PeriodicalId":714,"journal":{"name":"Nano-Micro Letters","volume":"17 1","pages":""},"PeriodicalIF":26.6,"publicationDate":"2025-04-27","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://link.springer.com/content/pdf/10.1007/s40820-025-01752-x.pdf","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"143877774","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":1,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"OA","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Ultra‑Broadband and Ultra-High Electromagnetic Interference Shielding Performance of Aligned and Compact MXene Films
IF 26.6 1区 材料科学
Nano-Micro Letters Pub Date : 2025-04-27 DOI: 10.1007/s40820-025-01750-z
Weiqiang Huang, Xuebin Liu, Yunfan Wang, Jiyong Feng, Junhua Huang, Zhenxi Dai, Shaodian Yang, Songfeng Pei, Jing Zhong, Xuchun Gui
{"title":"Ultra‑Broadband and Ultra-High Electromagnetic Interference Shielding Performance of Aligned and Compact MXene Films","authors":"Weiqiang Huang,&nbsp;Xuebin Liu,&nbsp;Yunfan Wang,&nbsp;Jiyong Feng,&nbsp;Junhua Huang,&nbsp;Zhenxi Dai,&nbsp;Shaodian Yang,&nbsp;Songfeng Pei,&nbsp;Jing Zhong,&nbsp;Xuchun Gui","doi":"10.1007/s40820-025-01750-z","DOIUrl":"10.1007/s40820-025-01750-z","url":null,"abstract":"<div><p>With the rapid development of electronic detective techniques, there is an urgent need for broadband (from microwave to infrared) stealth of aerospace equipment. However, achieving effective broadband stealth primarily relies on the composite of multi-layer coatings of different materials, while realizing broadband stealth with a single material remains a significant challenge. Herein, we reported a highly compact MXene film with aligned nanosheets through a continuous centrifugal spraying strategy. The film exhibits an exceptional electromagnetic interference shielding effectiveness of 45 dB in gigahertz band (8.2–40 GHz) and 59 dB in terahertz band (0.2–1.6 THz) at a thickness of 2.25 μm, owing to the high conductivity (1.03 × 10<sup>6</sup> S m<sup>−1</sup>). Moreover, exceptionally high specific shielding effectiveness of 1.545 × 10<sup>6</sup> dB cm<sup>2</sup> g⁻<sup>1</sup> has been demonstrated by the film, which is the highest value reported for shielding films. Additionally, the film exhibits an ultra-low infrared emissivity of 0.1 in the wide-range infrared band (2.5–16.0 μm), indicating its excellent infrared stealth performance for day-/nighttime outdoor environments. Moreover, the film demonstrates efficient electrothermal performance, including a high saturated temperature (over 120 °C at 1.0 V), a high heating rate (4.4 °C s<sup>−1</sup> at 1.0 V), and a stable and uniform heating distribution. Therefore, this work provides a promising strategy for protecting equipment from multispectral electromagnetic interference and inhibiting infrared detection. </p><div><figure><div><div><picture><source><img></source></picture></div></div></figure></div></div>","PeriodicalId":714,"journal":{"name":"Nano-Micro Letters","volume":"17 1","pages":""},"PeriodicalIF":26.6,"publicationDate":"2025-04-27","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://link.springer.com/content/pdf/10.1007/s40820-025-01750-z.pdf","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"143877775","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":1,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"OA","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Investigation on degradation behavior in citric acid solution for MO-Al2O3-SiO2-B2O3 (M = Ba, Sr) glass and its doped BaTiO3 ceramics
IF 2.8 4区 工程技术
Journal of Materials Science: Materials in Electronics Pub Date : 2025-04-27 DOI: 10.1007/s10854-025-14796-x
Wanlun Ren, Chun Lu, Lang Li, Yile Zhong, Baoxing Liu, Song Chen
{"title":"Investigation on degradation behavior in citric acid solution for MO-Al2O3-SiO2-B2O3 (M = Ba, Sr) glass and its doped BaTiO3 ceramics","authors":"Wanlun Ren,&nbsp;Chun Lu,&nbsp;Lang Li,&nbsp;Yile Zhong,&nbsp;Baoxing Liu,&nbsp;Song Chen","doi":"10.1007/s10854-025-14796-x","DOIUrl":"10.1007/s10854-025-14796-x","url":null,"abstract":"<div><p>This study proposes an innovative strategy for developing a type of BaTiO<sub>3</sub> ceramic, which can degrade in citric acid solution, offering the potential for harmless degradation and recycling of BaTiO<sub>3</sub> ceramics widely used in the electronics field. The degradable BaTiO<sub>3</sub> ceramic has been designed and prepared using chemically active MO-Al<sub>2</sub>O<sub>3</sub>-SiO<sub>2</sub>-B<sub>2</sub>O<sub>3</sub> (M = Ba, Sr) (MASB) glass. By adjusting the glass content, the dielectric constant of the material increases from 725 to 1480. By investigating the physical and chemical interactions between MASB glass phases and BaTiO<sub>3</sub> ceramics, we systematically evaluated the degradation behavior in citric acid solution and the dielectric properties of the BaTiO<sub>3</sub> ceramics. The results show that the ratio of [TiO<sub>6</sub>] units to [TiO<sub>4</sub>] units in glass phases is a crucial factor in determining the chemical stability of BaTiO<sub>3</sub>-doped MASB glass in citric acid solution. As the ratio of [TiO<sub>6</sub>] units to [TiO<sub>4</sub>] units increases from 0.347 to 0.464, the mass loss rate of the BaTiO<sub>3</sub>-doped BASB glasses in citric acid decreases from 70% to 36.1%. Through SEM–EDS analysis of the BaTiO<sub>3</sub> ceramics, it was found that the degradation of MASB glass phase between the BaTiO<sub>3</sub> grains in citric acid solution triggers the structural disintegration of the BaTiO<sub>3</sub> ceramics.</p></div>","PeriodicalId":646,"journal":{"name":"Journal of Materials Science: Materials in Electronics","volume":"36 12","pages":""},"PeriodicalIF":2.8,"publicationDate":"2025-04-27","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"143877704","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"工程技术","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Inhibitory effects of corylin derived from aerial part of Pueraria lobata on melanin synthesis and potential applications in skin whitening and photoaging management
IF 4.8 3区 化学
Natural Products and Bioprospecting Pub Date : 2025-04-27 DOI: 10.1007/s13659-025-00509-8
BoYoon Chang, SungYeon Kim
{"title":"Inhibitory effects of corylin derived from aerial part of Pueraria lobata on melanin synthesis and potential applications in skin whitening and photoaging management","authors":"BoYoon Chang,&nbsp;SungYeon Kim","doi":"10.1007/s13659-025-00509-8","DOIUrl":"10.1007/s13659-025-00509-8","url":null,"abstract":"<div><h3>Purpose</h3><p>This study aimed to investigate the potential of corylin, a bioactive compound isolated from the aerial part of <i>Pueraria lobata</i>, as a novel skin-whitening agent. Specifically, the research sought to evaluate its effects on melanin synthesis, understand its underlying mechanisms, and validate its efficacy in mitigating hyperpigmentation.</p><h3>Methods</h3><p>Bioactive compound was isolated from <i>Pueraria lobata</i> through a systematic fractionation process involving activated carbon pigment removal, sequential solvent extraction, and resin-based chromatography. It was shown to inhibit melanin synthesis by targeting tyrosinase activation and modulating key signaling pathways. Its efficacy in reducing melanin production was validated through cellular assays and a UVB-stimulated 3D human skin model, highlighting its potential as a skin-whitening agent.</p><h3>Results</h3><p>Through fractionation, the bioactive compound was identified as corylin, which reduced melanin content and tyrosinase activity without cytotoxicity, modulated signaling pathways to downregulate MITF and melanogenic enzymes, and inhibited α-glucosidase, disrupted glycosylation. In a UVB-stimulated 3D skin model, it effectively decreased melanin production, confirming its potential to mitigate hyperpigmentation.</p><h3>Conclusion</h3><p>Corylin is a promising candidate for skin-whitening applications, effectively mitigating hyperpigmentation by targeting multiple stages of melanin synthesis, including enzymatic activity and regulatory pathways. Further clinical studies are needed to confirm its safety and therapeutic potential for dermatological use.</p><h3>Graphical Abstract</h3>\u0000<div><figure><div><div><picture><source><img></source></picture></div></div></figure></div></div>","PeriodicalId":718,"journal":{"name":"Natural Products and Bioprospecting","volume":"15 1","pages":""},"PeriodicalIF":4.8,"publicationDate":"2025-04-27","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://link.springer.com/content/pdf/10.1007/s13659-025-00509-8.pdf","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"143877692","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":3,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"OA","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
S-scheme MnS/ZnO heterojunction composites for photocatalytic degradation of tetracycline
IF 2.8 4区 工程技术
Journal of Materials Science: Materials in Electronics Pub Date : 2025-04-27 DOI: 10.1007/s10854-025-14823-x
Guangling Zuo, Yaxin Fu, Hao Zhou, Jia Du, Xin Ding, Hongyong Ye
{"title":"S-scheme MnS/ZnO heterojunction composites for photocatalytic degradation of tetracycline","authors":"Guangling Zuo,&nbsp;Yaxin Fu,&nbsp;Hao Zhou,&nbsp;Jia Du,&nbsp;Xin Ding,&nbsp;Hongyong Ye","doi":"10.1007/s10854-025-14823-x","DOIUrl":"10.1007/s10854-025-14823-x","url":null,"abstract":"<div><p>The practical applications of ZnO are somewhat limited due to its large wide band gap, requiring UV light for photocatalysis. To improve the visible-light performance of ZnO, a series of S-scheme MnS/ZnO heterojunction composites were fabricated by hydrothermal methods. Thorough characterization methods were utilized to investigate the microtopography, crystal structure, and photoelectric performance of the materials. The visible-light performance of MnS/ZnO was assessed with simulated antibiotic wastewater containing tetracycline hydrochloride (TC) as degradation object. The crystal structure of MnS/ZnO is mainly of ZnO hexagonal wurtzite structure and the overall morphology is short strip-like. MnS is tightly loaded on the ZnO surface and forms S-scheme heterojunctions at the contact sites. This structure can recombine ineffective carriers efficiently due to the existence of the internal electric field (IEF). Additionally, the presence of IEF can help retain effective carriers, leading to a significant promotion of the visible-light photocatalytic performance of MnS/ZnO. The trapping experiments indicate that hydroxyl radical (OH) and superoxide radical (O<sub>2</sub><sup>−</sup>) are the main active species in the photocatalytic reaction. MnS/ZnO composite photocatalysts exhibit better degradation efficiency of TC than pure MnS and ZnO, especially when the loading amount of MnS is 6 wt%. Under optimized experimental conditions, the MnS/ZnO composite catalyst (0.67 g/L) was employed to treat TC solution with an initial concentration of 20 mg/L. When the pH of the system was adjusted to approximately 7, a remarkable degradation efficiency of 97.8% was achieved after 100 min under visible light irradiation. Additionally, after four cycles of usage, MnS/ZnO can still degrade 90.3% of the TC, demonstrating the stability of this composite catalyst.</p></div>","PeriodicalId":646,"journal":{"name":"Journal of Materials Science: Materials in Electronics","volume":"36 12","pages":""},"PeriodicalIF":2.8,"publicationDate":"2025-04-27","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"143877753","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"工程技术","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Construction and performance of a novel perylene diimide/AgI S-scheme heterojunction photocatalyst for various pollutants degradation
IF 2.8 4区 工程技术
Journal of Materials Science: Materials in Electronics Pub Date : 2025-04-27 DOI: 10.1007/s10854-025-14833-9
Shuo Ji, Shuting Zhang, Chengyuan Qi, Chunwei Shi, Lei Shi
{"title":"Construction and performance of a novel perylene diimide/AgI S-scheme heterojunction photocatalyst for various pollutants degradation","authors":"Shuo Ji,&nbsp;Shuting Zhang,&nbsp;Chengyuan Qi,&nbsp;Chunwei Shi,&nbsp;Lei Shi","doi":"10.1007/s10854-025-14833-9","DOIUrl":"10.1007/s10854-025-14833-9","url":null,"abstract":"<div><p>A series of novel self-assembled perylene diimide (SAPDI) attached AgI photocatalysts (SAPDI/AgI) were successfully prepared by the chemical precipitation method. Different characterizations were used to test their chemical structures, appearance and morphology, and optical properties. The results showed that rod-shaped SAPDI tight loaded on the surface of granular AgI. The prepared SAPDI/AgI composites not only could greatly improve the light absorption capacity and broaden the light absorption range, but also could effectively reduce the recombined probability of photogenerated charge and improve the photodegradation efficiency. The mass ratio of AgI and SAPDI was 60:1, as-prepared SAPDI/AgI-60 had the largest degradation rate of Rhodamine B (RhB) under visible light. The degradation rate constant was 0.0695 min<sup>−1</sup>, which was 2.59 times of that of AgI (0.02687 min<sup>−1</sup>). And SAPDI/AgI-60 maintained good degradation effect after 3 cycles of degradation experiments. In addition to RhB, the SAPDI/AgI-60 also showed good photodegradation of methylene blue (MB), methyl orange (MO), and tetracycline hydrochloride (TC). Obviously, a photocatalyst with visible-light-induced various pollutants degradation ability is synthesized. Finally, based on the work functions of SAPDI and AgI, the S-scheme heterojunction photocatalytic mechanism is proposed.</p></div>","PeriodicalId":646,"journal":{"name":"Journal of Materials Science: Materials in Electronics","volume":"36 12","pages":""},"PeriodicalIF":2.8,"publicationDate":"2025-04-27","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"143877765","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"工程技术","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
A Janus Smart Window for Temperature-Adaptive Radiative Cooling and Adjustable Solar Transmittance
IF 26.6 1区 材料科学
Nano-Micro Letters Pub Date : 2025-04-27 DOI: 10.1007/s40820-025-01740-1
Zuowei Zhang, Meina Yu, Cong Ma, Longxiang He, Xian He, Baohua Yuan, Luoning Zhang, Cheng Zou, Yanzi Gao, Huai Yang
{"title":"A Janus Smart Window for Temperature-Adaptive Radiative Cooling and Adjustable Solar Transmittance","authors":"Zuowei Zhang,&nbsp;Meina Yu,&nbsp;Cong Ma,&nbsp;Longxiang He,&nbsp;Xian He,&nbsp;Baohua Yuan,&nbsp;Luoning Zhang,&nbsp;Cheng Zou,&nbsp;Yanzi Gao,&nbsp;Huai Yang","doi":"10.1007/s40820-025-01740-1","DOIUrl":"10.1007/s40820-025-01740-1","url":null,"abstract":"<div><h2>Highlights</h2><div>\u0000 \u0000 <ul>\u0000 <li>\u0000 <p>Using polymer-stabilized liquid crystal as the active control layer and KCWO-PNIPAM (KPP) as the passive control layer, a KPP smart window was constructed, successfully achieving dual electro-thermal collaborative control.</p>\u0000 </li>\u0000 <li>\u0000 <p>The window can adjust incident light across three bands: visible light, near-infrared light, and mid-far infrared light (especially 8–13 µm).</p>\u0000 </li>\u0000 <li>\u0000 <p>Combination of active and passive control to meet the diverse weather conditions.</p>\u0000 </li>\u0000 </ul>\u0000 </div></div>","PeriodicalId":714,"journal":{"name":"Nano-Micro Letters","volume":"17 1","pages":""},"PeriodicalIF":26.6,"publicationDate":"2025-04-27","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://link.springer.com/content/pdf/10.1007/s40820-025-01740-1.pdf","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"143877776","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":1,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"OA","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
An electrochemiluminescence sensor based on Ru(bpy)32+@Au and GO@CdS for detection of tartrazine
IF 5.3 2区 化学
Microchimica Acta Pub Date : 2025-04-27 DOI: 10.1007/s00604-025-07144-7
Li Tian, Huiling Li, Pengfei Han, Guangping Ma, Wenzhuo Wang, Hanyue Jiang, Juan Lu
{"title":"An electrochemiluminescence sensor based on Ru(bpy)32+@Au and GO@CdS for detection of tartrazine","authors":"Li Tian,&nbsp;Huiling Li,&nbsp;Pengfei Han,&nbsp;Guangping Ma,&nbsp;Wenzhuo Wang,&nbsp;Hanyue Jiang,&nbsp;Juan Lu","doi":"10.1007/s00604-025-07144-7","DOIUrl":"10.1007/s00604-025-07144-7","url":null,"abstract":"<div><p>An electrochemiluminescence (ECL) sensor was constructed based on Ru(bpy)<sub>3</sub><sup>2+</sup>@Au and GO@CdS for the detection of tartrazine (TTZ). In the presence of the co-reactant TPrA, Ru(bpy)<sub>3</sub><sup>2+</sup> and CdS quantum dots (QDs) were used as dual luminophores to synergistically amplify the ECL signal of the sensor. Gold nanoparticles (Au NPs) enhanced the electron transport capability of the system and thereby amplified the ECL intensity. Graphene oxide (GO), as a carrier, has a special wrinkle-like structure that not only adsorbed a substantial amount of CdS QDs but also prevented their agglomeration. Additionally, a more sensitive detection method was established based on the quenching of the ECL signal, which occurred due to the interaction between Ru(bpy)<sub>3</sub><sup>2+</sup> and TTZ. A low detection limit (1.3 × 10<sup>–13</sup> mol·L<sup>−1</sup>, S/N = 3) was obtained for TTZ concentrations ranging from 4.0 × 10<sup>–13</sup> to 4.0 × 10<sup>–8</sup> mol·L<sup>−1</sup>. Finally, actual measurement results from three beverage samples demonstrated that the prepared sensors possess excellent practical capabilities for TTZ detection.</p><h3>Graphical Abstract</h3>\u0000<div><figure><div><div><picture><source><img></source></picture></div></div></figure></div></div>","PeriodicalId":705,"journal":{"name":"Microchimica Acta","volume":"192 5","pages":""},"PeriodicalIF":5.3,"publicationDate":"2025-04-27","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"143877718","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":2,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Electrospun mesoporous lead oxide nanofibers as anode material for Li-ion batteries
IF 2.8 4区 工程技术
Journal of Materials Science: Materials in Electronics Pub Date : 2025-04-27 DOI: 10.1007/s10854-025-14824-w
V. Mamatha Rani, Hari Prasad Kamatam, CH. V. K. N. S. N. Moorthy, B. M. Pratima, Satish Kumar
{"title":"Electrospun mesoporous lead oxide nanofibers as anode material for Li-ion batteries","authors":"V. Mamatha Rani,&nbsp;Hari Prasad Kamatam,&nbsp;CH. V. K. N. S. N. Moorthy,&nbsp;B. M. Pratima,&nbsp;Satish Kumar","doi":"10.1007/s10854-025-14824-w","DOIUrl":"10.1007/s10854-025-14824-w","url":null,"abstract":"<div><p>Our investigation into synthesizing one-dimensional (1-D) mesoporous lead monoxide (PbO) nanofibers and their application as an anode material in lithium-ion batteries holds considerable practical significance. The PbO nanofibers were synthesized via electrospinning and subsequent calcination. We meticulously examined their properties using several techniques, including XRD, BET surface area analysis, FT-IR, Raman spectroscopy, FE-SEM, TEM, and EDX. The XRD measurements validate the presence of a pure orthorhombic PbO phase, whereas the FTIR and Raman spectroscopy results suggest a structurally coordinated PbO sample. The PbO nanofibers possess a BET-specific surface area of 61.23 m<sup>2</sup> g⁻<sup>1</sup>, and FE-SEM and TEM images indicate that their diameter ranges from 90 to 150 nm. The electrical conductivity of the PbO nanofiber sample at 423 K is 3.38 × 10⁻⁶ S/cm. Subsequently, we evaluated the PbO nanofibers as an anode material in half-coin CR-2032 lithium batteries and performed electrochemical assessments. The initial discharge capacity of the PbO nanofiber was 1270 mAh g<sup>−1</sup>. After 50 charge - discharge cycles, the PbO nanofibers exhibit a capacity of 372 mAh g⁻<sup>1</sup> as an anode material for lithium-ion batteries, indicating their viability for practical applications.</p></div>","PeriodicalId":646,"journal":{"name":"Journal of Materials Science: Materials in Electronics","volume":"36 12","pages":""},"PeriodicalIF":2.8,"publicationDate":"2025-04-27","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"143877752","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"工程技术","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Multi-Energy Conversion and Electromagnetic Shielding Enabled by Carbonized Polyimide/Kevlar/Graphene Oxide@ZIF-67 Bidirectional Complex Aerogel-Encapsulated Phase-Change Materials
IF 26.6 1区 材料科学
Nano-Micro Letters Pub Date : 2025-04-27 DOI: 10.1007/s40820-025-01761-w
Tao Shi, Xing Gao, Huan Liu, Xiaodong Wang
{"title":"Multi-Energy Conversion and Electromagnetic Shielding Enabled by Carbonized Polyimide/Kevlar/Graphene Oxide@ZIF-67 Bidirectional Complex Aerogel-Encapsulated Phase-Change Materials","authors":"Tao Shi,&nbsp;Xing Gao,&nbsp;Huan Liu,&nbsp;Xiaodong Wang","doi":"10.1007/s40820-025-01761-w","DOIUrl":"10.1007/s40820-025-01761-w","url":null,"abstract":"<div><h2>Highlights</h2><div>\u0000 \u0000 <ul>\u0000 <li>\u0000 <p>A “five-in-one” multifunctional phase-change composite is developed for magnetothermal, electrothermal, solar-thermal, and thermoelectric energy conversion and electromagnetic shielding applications.</p>\u0000 </li>\u0000 <li>\u0000 <p>The developed composite is based on an innovative combination of carbonized polyimide/Kevlar/graphene oxide@ZIF-67 complex aerogel as a supporting material and paraffin wax as a phase-change material.</p>\u0000 </li>\u0000 <li>\u0000 <p>The developed composite exhibits excellent solar-thermal, thermoelectric, electrothermal, and magnetothermal energy conversion performance along with high electromagnetic interference shielding effectiveness.</p>\u0000 </li>\u0000 </ul>\u0000 </div></div>","PeriodicalId":714,"journal":{"name":"Nano-Micro Letters","volume":"17 1","pages":""},"PeriodicalIF":26.6,"publicationDate":"2025-04-27","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://link.springer.com/content/pdf/10.1007/s40820-025-01761-w.pdf","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"143877773","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":1,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"OA","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
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