{"title":"High reliable and ultra-flexible transparent heaters composed of ZnO-Ag core–shell nanowires and PVDF films","authors":"Haoran Zheng, Shihui Yu, Jinke Bai","doi":"10.1007/s10854-025-14815-x","DOIUrl":"10.1007/s10854-025-14815-x","url":null,"abstract":"<div><p>A scalable strategy is proposed for preparing ultra-flexible transparent heaters (THs) with ZnO-Ag core–shell nanowires (ZnO@Ag NWs) embedded in polyvinylidene fluoride composite films. The obtained THs exhibit a high average transmittance of 85.8% in the visible spectral range and excellent heating performance. The maximum saturation temperature can reach 153 °C within 10 s at an input voltage of 4.0 V. Furthermore, the saturation temperature of THs has not changed significantly after 1000 bending cycles with a curvature radius of 0.5 mm, demonstrating excellent mechanical flexibility. In particular, the THs possess environmental endurance, and no significant deterioration in performance can be found after exposure to high humidity (relative humidity: 85%) and ultraviolet ozone (254 and 185 nm) irradiation for 10 h, which is attributed to the protective role provided by the covering of ZnO shells on the Ag NWs. These outstanding parameters make the fabricated THs to be promising for application in wearable systems, medical thermotherapy pads and industrial defrosters.</p></div>","PeriodicalId":646,"journal":{"name":"Journal of Materials Science: Materials in Electronics","volume":"36 12","pages":""},"PeriodicalIF":2.8,"publicationDate":"2025-04-27","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"143877751","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"工程技术","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
{"title":"OPTUNA optimization for predicting chemical respiratory toxicity using ML models","authors":"Eman Shehab, Hamada Nayel, Mohamed Taha","doi":"10.1007/s10822-025-00597-1","DOIUrl":"10.1007/s10822-025-00597-1","url":null,"abstract":"<div><p>Predicting molecular toxicity is an important stage in the process of drug discovery. It is directly related to medical destiny and human health. This paper presents an enhanced model for chemical respiratory toxicity prediction. It used a combination of molecular descriptors and term frequency – inverse document frequency (TF-IDF) based models with different machine learning algorithms. To address class imbalance, SMOTE is applied. Appropriate hyper-parameter tuning is required to generate a better system with a classifier. So, we adjusted the hyper-parameters of various models and used the adjusted parameters to train the model. We tuned hyper-parameters using OPTUNA. Internal and external validation were used to confirm the models’ performance. According to the results, the model’s internal validation accuracy and AUC using the random forest approach were 88.6% and 93.2%. For external validation, the model’s accuracy value using random forest and Gradient Boosting Classifier were 92.2% with AUC 97%. Comparing these results with previous studies shows that our model performs better compared to them.</p></div>","PeriodicalId":621,"journal":{"name":"Journal of Computer-Aided Molecular Design","volume":"39 1","pages":""},"PeriodicalIF":3.0,"publicationDate":"2025-04-26","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"143875320","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":3,"RegionCategory":"生物学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
{"title":"New method for full-process deformation of slopes subject to drying-wetting cycles","authors":"Fangyue Luo, Ga Zhang","doi":"10.1007/s10064-025-04261-8","DOIUrl":"10.1007/s10064-025-04261-8","url":null,"abstract":"<div><p>Slope deformation due to drying-wetting cycles is a great concern in both the risk warning of slopes and the design of various slope structures on the slope. A new full-process slope deformation analysis method was derived based on slice methods, with innovations in terms of the constitutive equation, displacement compatibility equation, and stress equilibrium equation. A constitutive model of the soil was proposed with defined parameters, and it was reported to perform well in the prediction of the deformation increment and strength reduction due to drying-wetting cycles. The potential slip surface was shown to be a key component of characterizing the full-process deformation of a slope and to exhibit the displacement compatibility trend in which the relative horizontal displacement along the potential slip surface was equal at various locations. A slope deformation analysis algorithm was derived to analyze the shear deformation characteristics of potential slip surfaces and the volumetric deformation characteristics of sliding bodies subjected to drying-wetting cycles. The proposed method was validated by comparing the predicted slope deformation characteristics with centrifuge model test and field observation results under drying-wetting cycles. The method was confirmed to predict the full-process deformation of soil slopes during drying-wetting cycles, including the small deformation stage, prefailure stage, failure process and postfailure stage.</p></div>","PeriodicalId":500,"journal":{"name":"Bulletin of Engineering Geology and the Environment","volume":"84 5","pages":""},"PeriodicalIF":3.7,"publicationDate":"2025-04-26","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"143875459","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":2,"RegionCategory":"工程技术","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
{"title":"Enhancing Quantum Teleportation of the X-type Systems Under Pauli Channel with Memory","authors":"MeiJiao Wang, LianZhen Cao, Yang Yang, Bing Sun, Xia Liu, JiaQiang Zhao","doi":"10.1007/s10773-025-05984-w","DOIUrl":"10.1007/s10773-025-05984-w","url":null,"abstract":"<div><p>A enhancing scheme of quantum teleportation of the X-type initial state is proposed in Pauli noisy channel with memory. Compared to the noisy channels without memory, the memory coefficient improves the fidelity of quantum teleportation to a certain extent under a given damping coefficient. Among the three initial states, the memory coefficient provides the most significant enhancement in fidelity for the Bell state. For channels with full memory, the fidelity of quantum teleportation can reach the maximum value of the corresponding state, remaining unaffected by changes in the damping coefficient. This indicates that the memory factor enhances the fidelity and entanglement of the X-type system in Pauli channel, providing robust support for the realization of quantum communication.</p></div>","PeriodicalId":597,"journal":{"name":"International Journal of Theoretical Physics","volume":"64 5","pages":""},"PeriodicalIF":1.3,"publicationDate":"2025-04-26","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"143875316","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"物理与天体物理","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
N. Radhikesh Raveendran, Vinita Kumawat, E. P. Amaladass, A. T. Sathyanarayana, T. Geetha Kumary, Awadhesh Mani
{"title":"Anisotropic Upper Critical Field in Nd1.85Ce0.15CuO4±δ Superconducting Thin Films","authors":"N. Radhikesh Raveendran, Vinita Kumawat, E. P. Amaladass, A. T. Sathyanarayana, T. Geetha Kumary, Awadhesh Mani","doi":"10.1007/s10948-025-06950-7","DOIUrl":"10.1007/s10948-025-06950-7","url":null,"abstract":"<div><p>Thin films of superconducting Nd<sub>1.85</sub>Ce<sub>0.15</sub>CuO<sub>4±δ</sub> were synthesized by a pulsed laser deposition method followed by ex situ annealing in an argon atmosphere. Structural, morphological and electrical characterizations were performed using X-ray diffraction, scanning electron microscopy and temperature-dependent resistivity measurements respectively. X-ray analysis reveals preferential orientation in (001) and (110) directions for the thin films. Resistivity measurements demonstrated a pronounced superconducting behavior in the argon annealed thin films. The critical superconducting properties, the upper critical field and critical current density, were investigated using magneto-transport and magnetization measurements. The anisotropic coefficient which is the ratio of the upper critical field parallel and perpendicular to that of <i>ab</i> plane has been assessed highlighting the significant anisotropy of the Nd<sub>1.85</sub>Ce<sub>0.15</sub>CuO<sub>4±δ</sub> superconductor. The analysis of the activation energy reveals the three-dimensional nature of the vortex lattice in this system.</p></div>","PeriodicalId":669,"journal":{"name":"Journal of Superconductivity and Novel Magnetism","volume":"38 3","pages":""},"PeriodicalIF":1.6,"publicationDate":"2025-04-26","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://link.springer.com/content/pdf/10.1007/s10948-025-06950-7.pdf","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"143875384","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"物理与天体物理","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"OA","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Amna Khalid, Shazia Khurshid, Maliha Uroos, Jahangir Khan, Abid Sarwar, Ehsan ul Haq, Tariq Aziz, Fatma Alshehri, Fahad Al-Asmari, Bandar K. Baothman, Fakhria A. Al-Joufi, Maher S. Alwethaynani
{"title":"Green synthesis of silver and gold nanoparticles using seeds extract of Cichorium intybus and their comparative analysis with commercially available ointment for wound healing activity","authors":"Amna Khalid, Shazia Khurshid, Maliha Uroos, Jahangir Khan, Abid Sarwar, Ehsan ul Haq, Tariq Aziz, Fatma Alshehri, Fahad Al-Asmari, Bandar K. Baothman, Fakhria A. Al-Joufi, Maher S. Alwethaynani","doi":"10.1007/s10735-025-10426-2","DOIUrl":"10.1007/s10735-025-10426-2","url":null,"abstract":"<div><p>Wound healing is a complicated physiological process that involves several stages including hemostasis, inflammation, proliferation and repair to rebuild the integrity of the skin and subcutaneous tissue. Millions of people around the world are affected by poor wound healing, causing increased mortality rates and related costs. Immedicable wounds are a health problem because they directly affect the person’s standard of living and produce an ultimatum to the health of people and the international economy because of the expensive medical treatment. Other schemes/approaches must be designed to achieve productive and therapeutic results. In this context, the emergence of Nano biotechnology may provide another manifesto to produce latest drugs for long-term treatment processes. This article shows that the implementation of metal nanoparticles (Au and Ag) has unbolted a brand-new gateway in the discipline of eco-friendly medicine due to their unique properties such as medicine transportation, antimicrobial activity and quick recovery. Moreover, metal nanoparticles (NPs) manufactured by green synthesis not only add the effects of nanoparticles and plant extracts but also reduce toxicity to tissues and make their use safer. In the present work, Ag and Au nanoparticles were synthesized using an aqueous seed extract of <i>Cichorium intybus</i> and their wound healing ability was assessed by performing in-vivo wound healing activity on albino mice. Till now there is no study available on the in-vivo wound healing potential of Ag and Au nanoparticles using <i>Cichorium intybus</i>. This is the first study ever to assess the ability of <i>Cichorium intybus</i> seed extract and its metal nanoparticles (AgNPs & AuNPs) to promote wound healing in animals which shows its uniqueness and novelty. The results displayed augmented and quicker wound closure with Ag as compared to the Au nanoparticles, polyfax and simple plant extract in a 21-day research work. These results illustrated that eco-friendly prepared nanoparticles provide a prominent approach to fight with the bacteria resistant against combination therapy without any lethal affair. Environment-friendly NPs declared to be the low-cost best treatment for the faster recovery of wounds. The main goal of this research is to provide aid in the creation of plant-based, durable and affordable Nano medicine for wound care, lowering dependency on synthetic techniques and encouraging environmental friendly biomedical applications.</p></div>","PeriodicalId":650,"journal":{"name":"Journal of Molecular Histology","volume":"56 3","pages":""},"PeriodicalIF":2.9,"publicationDate":"2025-04-26","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"143875313","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"生物学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Ling Wu, Jun Li, Haoyu Wang, Xu Chang, Qinglong Kong
{"title":"Identification of the oncogenic role of centromere protein M in non-small cell lung cancer via CDC20/MYBL2/Wnt signaling pathways","authors":"Ling Wu, Jun Li, Haoyu Wang, Xu Chang, Qinglong Kong","doi":"10.1007/s10735-025-10423-5","DOIUrl":"10.1007/s10735-025-10423-5","url":null,"abstract":"<div><p>Lung cancer remains the most prevalent carcinoma with a high mortality rate, yet the underlying mechanisms driving pulmonary neoplasia and disease progression are not fully understood. In our study, we conducted a comprehensive analysis of the transcriptome profiles and clinicopathological characteristics of 515 patients diagnosed with non-small cell lung cancer (NSCLC) from the TCGA database. We identified a significant upregulation of centromere protein M (CENPM) in NSCLC tissues, which was positively correlated with poor prognosis. Furthermore, overexpression of CENPM markedly promoted cell proliferation and increased the tumorigenic potential of NSCLC cell lines (A549/NCI-H1299), leading to accelerated tumor progression and reduced survival time in tumor-bearing mice. Mechanistically, CENPM activated the Wnt/β-catenin signaling pathway via the cell division cycle 20 (CDC20)/MYB proto-oncogene-like 2 (MYBL2) axis. Inhibition of either Wnt signaling or the CDC20/MYBL2 axis attenuated the tumorigenic potential and proliferative effects induced by CENPM. Our findings underscore the critical role of CENPM in driving NSCLC development and suggest that CENPM could serve as a novel biomarker for predicting NSCLC progression in clinical settings.</p></div>","PeriodicalId":650,"journal":{"name":"Journal of Molecular Histology","volume":"56 3","pages":""},"PeriodicalIF":2.9,"publicationDate":"2025-04-26","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://link.springer.com/content/pdf/10.1007/s10735-025-10423-5.pdf","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"143875314","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"生物学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"OA","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Marta Loletti, Costanza Borghesi, Riccardo Rurali, Giacomo Giorgi
{"title":"Structural and electronic properties of CaTiO3 polymorphs and 2D-derived systems: a theoretical investigation","authors":"Marta Loletti, Costanza Borghesi, Riccardo Rurali, Giacomo Giorgi","doi":"10.1140/epjb/s10051-025-00918-1","DOIUrl":"10.1140/epjb/s10051-025-00918-1","url":null,"abstract":"<p>Oxide perovskite materials exhibit intriguing optical and electrical properties that are widely exploited in ceramics and optoelectronic devices. With particular emphasis on its application for photocatalysis, this study aims to theoretically characterize the structural and electronic features of CaTiO<sub>3</sub>, both as a stand-alone material and as a possible component in heterostructures. By means of a campaign of <i>ab-initio</i> calculations, we have revised the polymorphic nature of the material through an extensive analysis of its structural and electronic properties. Although standard DFT clearly confirms its intrinsic underestimation in predicting the excited state properties, by applying the recently introduced DFT<span>(-frac{1}{2})</span> method to the bandgap and dispersion calculations, we find very good agreement with experimental reported data. Finally, we include the investigation of dimensionally reduced CaTiO<sub>3</sub>-based surfaces and nanosheets, opening the way to interesting possibilities for additional novel supports and photocatalysts with unique features.</p>","PeriodicalId":787,"journal":{"name":"The European Physical Journal B","volume":"98 4","pages":""},"PeriodicalIF":1.6,"publicationDate":"2025-04-26","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://link.springer.com/content/pdf/10.1140/epjb/s10051-025-00918-1.pdf","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"143877716","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"物理与天体物理","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"OA","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Mariangela Carlucci, Pompea Gabriella Lucchese, Cinzia Benincasa, Rosa Nicoletti, Andrea Pacifico, Enzo Perri, Franco Nigro
{"title":"Unveiling the occurrence and role of Methylobacterium endophytes in olive trees: insights into potential interactions with Xylella fastidiosa subsp. pauca","authors":"Mariangela Carlucci, Pompea Gabriella Lucchese, Cinzia Benincasa, Rosa Nicoletti, Andrea Pacifico, Enzo Perri, Franco Nigro","doi":"10.1186/s40538-025-00770-6","DOIUrl":"10.1186/s40538-025-00770-6","url":null,"abstract":"<div><h3>Background</h3><p>Olive quick decline syndrome (OQDS), caused by <i>Xylella fastidiosa</i> subsp. <i>pauca</i> (<i>Xfp</i>), is a destructive vascular disease affecting olive trees, particularly in Apulia, Southeastern Italy. Control measures rely on containment and replanting with resistant cultivars. Endophytic bacteria, including <i>Methylobacterium</i> spp., have shown potential in mitigating vascular diseases. These facultative methylotrophic bacteria inhabit xylem vessels and compete with pathogens like <i>Xfp</i> by producing siderophores that limit iron availability.</p><h3>Results</h3><p>Analysis of endophytic bacterial populations in olive trees identified <i>Methylobacterium</i> spp. in both healthy and <i>Xfp</i>-infected plants, with variable isolation frequencies. Molecular identification based on 16S rDNA and <i>mxaF</i> gene sequences classified isolates as <i>M. radiotolerans</i> (70%) and <i>M. mesophilicum</i> (30%). Phylogenetic analysis showed limited genetic variation, clustering isolates with reference strains. In vitro experiments revealed that culture supernatants from <i>Methylobacterium</i> spp., grown in siderophore-inducing media, affected <i>Xfp</i> growth in a concentration-dependent manner. At low concentrations (up to 2%), supernatants stimulated <i>Xfp</i> growth, while higher concentrations (20% and 50%) inhibited growth. Selected strains of <i>M. radiotolerans</i> and <i>M. mesophilicum</i> were confirmed as siderophore producers through CAS blue agar tests and targeted LC–MS/MS analysis. LC–MS/MS identified ferrioxamine E and ferrichrome in all <i>Methylobacterium</i> strains, with the highest levels in <i>M. organophilum</i> and <i>M. aminovorans</i>. Deferoxamine was absent, whereas <i>Xfp</i> exhibited elevated production of ferrioxamine E, deferoxamine, and ferrichrome.</p><h3>Conclusions</h3><p>This study underscores the biocontrol potential of <i>Methylobacterium</i> spp. against <i>Xfp</i>, suggesting an ability to compete with the pathogen through siderophore-mediated mechanisms. The dual effect of <i>Methylobacterium</i> supernatants—stimulatory at low concentrations and inhibitory at higher levels—highlights the complexity of plant–microbe–pathogen interactions. The production of ferrioxamine E and ferrichrome suggests a possible role in modulating iron availability in vivo, potentially reducing <i>Xfp</i>'s growth and virulence. These findings provide a basis for developing <i>Methylobacterium</i> spp. as sustainable biocontrol agents to manage <i>Xfp</i> in olive production systems.</p><h3>Graphical Abstract</h3>\u0000<div><figure><div><div><picture><source><img></source></picture></div></div></figure></div></div>","PeriodicalId":512,"journal":{"name":"Chemical and Biological Technologies in Agriculture","volume":"12 1","pages":""},"PeriodicalIF":5.2,"publicationDate":"2025-04-26","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://chembioagro.springeropen.com/counter/pdf/10.1186/s40538-025-00770-6","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"143877691","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":2,"RegionCategory":"农林科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"OA","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
{"title":"Thin Film-Formation Mechanisms of Aqueous Lubricant in Elastohydrodynamic Lubrication","authors":"Ashley Mungroo, Denis Mazuyer, Juliette Cayer-Barrioz","doi":"10.1007/s11249-025-01998-x","DOIUrl":"10.1007/s11249-025-01998-x","url":null,"abstract":"<div><p>Aqueous lubricants are increasingly used in industry due to their excellent cooling capability and to environmental considerations. However, the film forming mechanisms in high-pressure contacts, such as in EHL regime, differ from those, well-known, of classical piezoviscous oil lubricants. This work investigated the role of the molecular architecture of polyalkylene glycol (PAG) molecules dispersed in water, with co-solvent monopropylene glycol, on the film forming capability in elastohydrodynamic lubrication regime by means of <i>in situ in-operando</i> chemical distribution mapping of the contact. These mappings were based on infrared hyperspectral images. A specific focus was made on the analysis of the area absorbance ratio of the ether stretching band, characteristic of PAG polymer, and the O–H stretching band of continuous water media, in order to identify the relative contribution of the solvent and of the polymer additives. Linear and branched PAG molecules were used as well as mixtures of different molecular weight PAGs. The penetration capability of the polymers in the high-pressure zone of the contact under pure rolling conditions, was discussed in terms of molar mass, architecture and polarity.</p><h3>Graphical Abstract</h3>\u0000<div><figure><div><div><picture><source><img></source></picture></div></div></figure></div></div>","PeriodicalId":806,"journal":{"name":"Tribology Letters","volume":"73 2","pages":""},"PeriodicalIF":2.9,"publicationDate":"2025-04-26","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://link.springer.com/content/pdf/10.1007/s11249-025-01998-x.pdf","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"143877701","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":3,"RegionCategory":"工程技术","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"OA","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}