Chemistry of Materials最新文献

{"title":"Design, Synthesis, and Evaluation of Noble Metal Nanoparticles and In Situ-Decorated Carbon-Supported Nanoparticle Electrocatalysts Using Hypergolic Reactions","authors":"Nikolaos Chalmpes, Iosif Tantis, Ahmed Wasel Alsmaeil, Athanasios B. Bourlinos, Emmanuel P. Giannelis","doi":"10.1021/acs.chemmater.4c02091","DOIUrl":"https://doi.org/10.1021/acs.chemmater.4c02091","url":null,"abstract":"We report the first synthesis of metal nanoparticles and supported metal nanoparticles on carbon by using hypergolic reactions. Specifically, we report the synthesis of noble metal nanoparticles (Pt, Ag, and Au) using sodium hydride (NaH) as both an ignition trigger and a reducing agent for the corresponding metal salt precursors. In addition, we report the one-step, in situ synthesis of Pt nanoparticles supported on carbon by adding sucrose as the carbon source. The hypergolically synthesized nanoparticles display elliptical morphology and are more crystalline compared with those conventionally synthesized in solution using sodium borohydride (NaBH₄). When tested as electrocatalysts, the hypergolic Pt nanoparticles exhibit more than 2 times higher specific electrochemical active surface area (ECSA) and a higher half-wave potential (<i>E</i>_1/2) of 0.94 V vs the reversible hydrogen electrode (RHE) compared to the conventionally synthesized ones. In addition, the electrocatalyst based on the in situ synthesized carbon that was decorated with the Pt nanoparticles synthesized hypergolically outperforms an analogous, state of the art, commercial PtC system. For example, the former shows an attractive <i>E</i>_1/2 (0.94 V) compared with 0.9 V for the commercial PtC. Accelerated durability tests (ADT) in an alkaline environment add another advantage. After 10 000 cycles, the hypergolically synthesized system shows a smaller reduction of <i>E</i>_1/2 and less degradation compared to the commercial PtC (10 mV compared to ∼30 mV). The work described here represents the first reported synthesis using hypergolic reactions of metal nanoparticles as well as supported metal nanoparticles. The properties of the resulting electrocatalysts demonstrate the versatility and promise of the new approach in materials synthesis and open new avenues for further investigation as electrocatalysts.","PeriodicalId":33,"journal":{"name":"Chemistry of Materials","volume":null,"pages":null},"PeriodicalIF":8.6,"publicationDate":"2024-10-19","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"142449947","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":2,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

{"title":"Layered and Low-Dimensional Lead, Silver, and Bismuth Halide Perovskites Directed by Halogen-Substituted Spacer Cations","authors":"Jonathan Schimmels, Willa Mihalyi-Koch, Chris R. Roy, Kyana M. Sanders, John C. Wright, Song Jin","doi":"10.1021/acs.chemmater.4c02083","DOIUrl":"https://doi.org/10.1021/acs.chemmater.4c02083","url":null,"abstract":"Hybrid organic–inorganic metal halides provide a diverse parameter space in which the optoelectronic properties can be tuned through the composition. The compositional tunability extends to the metal site, which can be expanded from single valent metals (<i>e.g</i>., Pb²⁺) to multivalent metals (<i>e.g</i>., Ag⁺ and Bi³⁺), and the dimension (2D, 1D, or 0D). However, a deeper understanding of how the organic cations template these metal halide structures is needed. Here, we synthesize and study the structures of a series of new layered and low-dimensional metal (Pb, Ag, and Bi) halides templated by the halogenated aryl spacer cations 2-chlorobenzylammonium (2ClBZ) and 3-chloro-2-fluorobenzylammonium (3Cl2FBZ). We report new lead perovskites, (3Cl2FBZ)₂PbBr₄, (2ClBZ)₃PbI₅, and (3Cl2FBZ)₂PbI₄, and compare them to their silver and/or bismuth analogs (2ClBZ)₄AgBiBr₈, (3Cl2FBZ)₄AgBiBr₈, (2ClBZ)₃Bi₂I₉, and (3Cl2FBZ)₄Bi₂I₁₀. In all structures, the halogen-substituted cations result in 2D or “pseudo-2D” layering, but the different halogen substituents introduce different distortions (tilting, octahedral distortion) and dimensional reduction to 1D or 0D depending on the metal and halide compositions. Optical absorption measurements reveal the bandgaps are tunable through metal sites, dimension, and cations to different extents. Furthermore, the 1D (3Cl2FBZ)₄Bi₂I₁₀ crystallizes in the noncentrosymmetric space group <i>Cmc</i>2₁ and exhibits second-harmonic generation (SHG). The organic–inorganic interactions and resultant structural distortions examined here provide insights toward the engineering of noncentrosymmetry and dimensional control in hybrid metal halide perovskites.","PeriodicalId":33,"journal":{"name":"Chemistry of Materials","volume":null,"pages":null},"PeriodicalIF":8.6,"publicationDate":"2024-10-19","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"142449894","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":2,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

{"title":"Understanding the Formation of Colloidal Ferrimagnetic CuCr2Se4 Nanocrystals with Strong Room-Temperature Magnetic Circular Dichroism","authors":"Samantha Harvey, Jonathan M. DeStefano, Jiun-Haw Chu, Daniel R. Gamelin, Brandi M. Cossairt","doi":"10.1021/acs.chemmater.4c02365","DOIUrl":"https://doi.org/10.1021/acs.chemmater.4c02365","url":null,"abstract":"The ongoing development and eventual implementation of magnetic nanocrystals in devices requires not only syntheses that can bring bulk compositions down to the nanoscale but also a deep understanding of their formation such that size, morphology, and composition can be finely tuned. Chromium chalcogenide spinels are a class of materials that epitomize this dilemma; their unique magnetic and magneto-optical properties make them promising for applications in spintronics, data storage, and quantum information sciences, but only a few compositions have been synthesized as colloidal nanocrystals. Furthermore, these few existing reports lack mechanistic understanding and demonstrate little control over the physical characteristics of the final products. Here, we set forth to understand the synthesis of CuCr₂Se₄ nanocrystals by examining how the structure, composition, and magnetic properties evolve over the course of the reaction. We find that the material proceeds through binary copper selenide nanocrystal intermediates followed by Cr incorporation via diffusion. This process results in polycrystalline CuCr₂Se₄ nanocrystals that do not exhibit magnetic ordering until Cu incorporation modifies their stoichiometry and defects are annealed, which takes approximately 40 min at 340 °C to achieve. The resulting CuCr₂Se₄ nanocrystals show a strongly enhanced magnetic circular dichroism signal at the bulk plasma frequency of <i>ℏ</i>ω_pl ∼ 1.0 eV with a field dependence that reflects magnetization of the Cr³⁺ spin sublattice. These results highlight the possibility of solution processing strong near-IR magneto-optical materials for future device integration.","PeriodicalId":33,"journal":{"name":"Chemistry of Materials","volume":null,"pages":null},"PeriodicalIF":8.6,"publicationDate":"2024-10-18","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"142449948","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":2,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

{"title":"Ultrasoft Conducting Polymer Hydrogels with Large Biaxial Strain and Conformal Adhesion for Sensitive Flexible Sensors","authors":"Xiaojiao Shi, Linli Xu, Qiuli Xu, Na Li, Xinyu Li, Yubin Zhang, Zhihui Qin, Tifeng Jiao","doi":"10.1021/acs.chemmater.4c01909","DOIUrl":"https://doi.org/10.1021/acs.chemmater.4c01909","url":null,"abstract":"Conducting polymer hydrogels have been considered as promising materials for flexible sensors. The integrated performances of ultrasoftness, high deformation, mechanical robustness, conformal adhesion, and high sensitivity are of great importance for their applications in wearable sensors but still remains challenging. Herein, a highly deformable conducting polymer hydrogel with ultrasoftness, tear resistance, and self-adhesiveness is fabricated by incorporating poly(3, 4-ethylenedioxythiophene):poly(styrene sulfonic acid) (PEDOT:PSS) and silk sericin (SS) into a covalently cross-linked polyacrylamide (PAM) network. Owing to abundant noncovalent interactions among the folded SS chains, PAM chains, and PEDOT:PSS, the obtained hydrogel shows a low modulus (10.3 kPa), ultrastretchability (&gt;2000%), particularly large biaxial strain (an areal strain of 1700%), high toughness (tearing energy of 2.5 kJ/m²), and good conformal adhesion. As a result, this hydrogel demonstrates superior strain-sensitivity (gauge factor = 13.8) in a broad strain range (2000%) and excellent sensing reproducibility. The hydrogel-based wearable sensor can be used for accurately monitoring large and tiny human movements in real time and serves as bioelectrodes for precise gathering of electrocardiography and electromyography signals, showing great potential for applications in flexible sensing devices.","PeriodicalId":33,"journal":{"name":"Chemistry of Materials","volume":null,"pages":null},"PeriodicalIF":8.6,"publicationDate":"2024-10-18","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"142448648","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":2,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

{"title":"Hydrogen Bonds Defined Pore Windows Enable Sieving Separation of Propylene from Propane in an Ultramicroporous Metal–Organic Framework","authors":"Xiang-Jing Kong, Ming-Ming Xu, Tao He, Lin-Hua Xie, Yu-Hui Liu, Xin Zhang, Hao-Tian Wang, Jian-Rong Li","doi":"10.1021/acs.chemmater.4c02251","DOIUrl":"https://doi.org/10.1021/acs.chemmater.4c02251","url":null,"abstract":"Tailoring a MOF with suitable pore windows for the sieving C₃H₆/C₃H₈ separation is attractive but challenging, where controlling the local framework flexibility by introducing functionality provides a solution. In this work, four isoreticular ultramicroporous Zn–triazolate–dicarboxylate frameworks, <b>Zn-ATZ-IP(R)</b> (R = −F, −OH, −NH₂, and −CH₃) (HATZ = 3-amino-1,2,4-triazole; H₂IP-R = R group functionalized isophthalic acid) with variable pore apertures, were targeted as platforms to study the effect of functional groups on their separation performance. Single-component adsorption isotherms uncovered the potential of <b>Zn-ATZ-IP(OH)-a</b> with hydroxyl groups as a sieving adsorbent. Single X-ray diffraction (SXRD) measurements revealed that strong intraframework hydrogen bonds hinder the free torsion of ATZ^– ligand in <b>Zn-ATZ-IP(OH)-a</b>, defining rigid pore windows that admit C₃H₆ while exclude C₃H₈, whereas other groups give adaptive larger pores that allow both C₃H₆ and C₃H₈ in. Further, <i>in situ</i> XRD measurements suggested that temperature alters the strength of hydrogen bonds, making <b>Zn-ATZ-IP(OH)-a</b> ideal for room-temperature sieving of C₃H₆/C₃H₈. This work highlights the superiority of customizing sieving pores sustained by hydrogen bonds, which advances the rational design of smart adsorbents for energy-efficient light hydrocarbon separations.","PeriodicalId":33,"journal":{"name":"Chemistry of Materials","volume":null,"pages":null},"PeriodicalIF":8.6,"publicationDate":"2024-10-18","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"142448642","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":2,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

{"title":"Rapid Modeling of the Local Structure of Metal Oxide Nanoparticles from PDF Data: A Case Study Using TiO2 Nanoparticles","authors":"Songsheng Tao, Jonas Billet, Jonathan De Roo, Simon J. L. Billinge","doi":"10.1021/acs.chemmater.3c03002","DOIUrl":"https://doi.org/10.1021/acs.chemmater.3c03002","url":null,"abstract":"A detailed workflow is presented for applying attenuated crystal modeling (ACM) of atomic pair distribution functions from TiO₂ nanoparticles to understand the structure and morphology of the nanoparticles. We use small-box modeling approaches with the diffpy<span>-CMI</span>software program. The modeling reveals that all synthesis conditions yield nanoparticles with a majority bronze phase and a minority anatase phase, with the synthesis temperature affecting the proportion of impurity phase and the size of the nanoparticles. The fast, straightforward, and reliable workflow is widely applicable for modeling PDFs of most inorganic nanoparticles as long as hypothesized ACM models are available, providing a helpful guide for researchers to analyze the structure of nanoparticles from PDF data.","PeriodicalId":33,"journal":{"name":"Chemistry of Materials","volume":null,"pages":null},"PeriodicalIF":8.6,"publicationDate":"2024-10-18","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"142448643","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":2,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

{"title":"Tuning Optical and Electrical Properties of Vanadium Oxide with Topochemical Reduction and Substitutional Tin","authors":"Lance M. Wheeler, Thanh Luan Phan, Michelle A. Smeaton, Swagata Acharya, Shruti Hariyani, Marlena E. Alexander, Miranda I. Gonzalez, Elisa M. Miller, David W. Mulder, Sarbajit Banerjee, Katherine L. Jungjohann, Andrew J. Ferguson, Jeffrey L. Blackburn","doi":"10.1021/acs.chemmater.4c01557","DOIUrl":"https://doi.org/10.1021/acs.chemmater.4c01557","url":null,"abstract":"Vanadium oxides are widely tunable materials, with many thermodynamically stable phases suitable for applications spanning catalysis to neuromorphic computing. The stability of vanadium in a range of oxidation states enables mixed-valence polymorphs of kinetically accessible metastable materials. Low-temperature synthetic routes to, and the properties of, these metastable materials are poorly understood and may unlock new optoelectronic and magnetic functionalities for expanded applications. In this work, we demonstrate topochemical reduction of α-V₂O₅ to produce metastable vanadium oxide phases with tunable oxygen vacancies (&gt;6%) and simultaneous substitutional tin incorporation (&gt;3.5%). The chemistry is carried out at low temperature (65 °C) with solution-phase SnCl₂, where Sn²⁺ is oxidized to Sn⁴⁺ as V⁵⁺ sites are reduced to V⁴⁺ during oxygen vacancy formation. Despite high oxygen vacancy and tin concentrations, the transformations are topochemical in that the symmetry of the parent crystal remains intact, although the unit cell expands. Band structure calculations show that these vacancies contribute electrons to the lattice, whereas substitutional tin contributes holes, yielding a compensation doping effect and control over the electronic properties. The SnCl₂ redox chemistry is effective on both solution-processed V₂O₅ nanoparticle inks and mesoporous films cast from untreated inks, enabling versatile routes toward functional films with tunable optical and electronic properties. The electrical conductance rises concomitantly with the SnCl₂ concentration and treatment time, indicating a net increase in density of free electrons in the host lattice. This work provides a valuable demonstration of kinetic tailoring of electronic properties of vanadium–oxygen systems through top-down chemical manipulation from known thermodynamic phases.","PeriodicalId":33,"journal":{"name":"Chemistry of Materials","volume":null,"pages":null},"PeriodicalIF":8.6,"publicationDate":"2024-10-17","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"142444423","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":2,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

{"title":"In Operando Evaluation of Heterogeneity Development in Fast-Cycled Single-Layer Pouch Cells","authors":"Daniel Risskov Sørensen, Ronald Gordon, Anna Smith, Innokenty Kantor, Mads Ry Vogel Jørgensen","doi":"10.1021/acs.chemmater.4c01483","DOIUrl":"https://doi.org/10.1021/acs.chemmater.4c01483","url":null,"abstract":"Investigating Li-ion batteries during high current rates is becoming increasingly important to advance fast charging of electric vehicles. Here, we use a state-of-the-art synchrotron instrument and detector to measure spatially resolved X-ray diffraction in operando on single-layer pouch cells at 1C and 3C. Using batch refinement on the hundreds of thousands of obtained diffractograms, the electrode lithiation inhomogeneity across the cells induced by cell cycling could be probed. The inhomogeneity was found to depend significantly on C-rate, and the cells were generally more electrochemically active in the center than close to the edges. At high current rates, the expected sequence of lithiated stages in the graphite anode was found to no longer hold. Areas of the electrodes were also found to behave very differently from others, probably due to local differences in resistance. These behaviors are detectable only at high C-rates using in operando methods. Using the methods developed in this work allows for investigating pouch cells that are close to commercial sizes.","PeriodicalId":33,"journal":{"name":"Chemistry of Materials","volume":null,"pages":null},"PeriodicalIF":8.6,"publicationDate":"2024-10-17","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"142448646","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":2,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

{"title":"Simple Molecular Synthetic Approach to Dinuclear Titanium Sites in Ti-Containing Silica-Based Catalysts","authors":"Takuya Hikino, Yuka Kawakubo, Takamichi Matsuno, Seiji Yamazoe, Kazuyuki Kuroda, Atsushi Shimojima","doi":"10.1021/acs.chemmater.4c01454","DOIUrl":"https://doi.org/10.1021/acs.chemmater.4c01454","url":null,"abstract":"Ti-containing silica-based catalysts are widely used for various organic oxidation reactions. Recently, increasing attention has been paid to the catalytic role of dinuclear (SiO)₃Ti–O–Ti(OSi)₃ sites in titanosilicate zeolite TS-1. A promising experimental approach for elucidating the active sites is to use model compounds with dinuclear Ti sites. In this study, we report the synthesis and catalytic properties of a μ-oxo-bridged dinuclear titanosiloxane compound with a (SiO)₃Ti–O–Ti(OSi)₃ site. A Ti-containing cage siloxane compound (^<i>i</i>Bu₇Si₇O₁₂)TiO^<i>i</i>Pr (mononuclear Ti-polyhedral oligomeric silsesquioxane (POSS)) is prepared by the reaction of incompletely condensed POSS with titanium tetraisopropoxide. Then, it is converted to the dinuclear species (^<i>i</i>Bu₇Si₇O₁₂)₂Ti₂(μ-O) (dinuclear Ti-POSS) by the simple hydrolytic condensation of the TiO^<i>i</i>Pr groups. The addition of H₂O₂ to dinuclear Ti-POSS leads to the formation of a bishydroperoxo complex, as revealed by Ti K-edge X-ray absorption fine structure analysis. Dinuclear Ti-POSS possesses high catalytic activity in the cyclohexene epoxidation reaction, indicating that the (SiO)₃Ti–O–Ti(OSi)₃ sites can function as efficient catalytically active sites. These findings contribute to the comprehension of the catalytic properties exhibited by dinuclear titanium sites within titanosilicate zeolite catalysts.","PeriodicalId":33,"journal":{"name":"Chemistry of Materials","volume":null,"pages":null},"PeriodicalIF":8.6,"publicationDate":"2024-10-17","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"142444422","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":2,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

{"title":"Liquid Phase-Made Aluminum Nanoparticles and Their Hydrogen Sorption as Aluminum/LiH Composite","authors":"Sven Riegsinger, Radian Popescu, Dagmar Gerthsen, Claus Feldmann","doi":"10.1021/acs.chemmater.4c01533","DOIUrl":"https://doi.org/10.1021/acs.chemmater.4c01533","url":null,"abstract":"Aluminum nanoparticles, Al(0), are prepared in toluene at room temperature (25 °C) by reduction of AlH₃ with dilithium naphthalenide ([Li₂Naph]). To dissolve the starting materials in toluene, AlH₃ and [Li₂Naph] are coordinated by <i>N</i>,<i>N</i>,<i>N</i>′,<i>N</i>′-tetramethylethylendiamin (TMEDA). The as-prepared Al(0) nanoparticles are monocrystalline and exhibit a uniform size of 11 ± 3 nm with narrow size distribution. They are highly reactive, as indicated by reaction in air and even with nitrogen. Besides the formation of Al(0) nanoparticles, the [Li₂Naph]-driven reduction of AlH₃ results in the formation of LiAlH₄ as a side phase, which can be removed but is difficult to remove due to its low solubility in solvents that do not react with the Al(0) nanoparticles (e.g., toluene, THF). The presence of LiAlH₄ and the formation of a Al(0) nanoparticle/LiAlH₄ composite, however, turned out to be advantageous in regard to H₂ sorption. After thermal transition of LiAlH₄ to LiH (250 °C, vacuum), the resulting Al(0) nanoparticle/LiH composite shows promising H₂ sorption and H₂ uptake at 250 °C and 100 bar of H₂ with a gravimetric capacity of 3.8%. After modification of the Al(0) nanoparticles with 1 wt % Pd for activation, the H₂ uptake occurs at even a reduced temperature of 150 °C.","PeriodicalId":33,"journal":{"name":"Chemistry of Materials","volume":null,"pages":null},"PeriodicalIF":8.6,"publicationDate":"2024-10-16","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"142440534","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":2,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}