材料科学最新文献

{"title":"Peroxidase-catalyzed proximity labeling to survey the proteome of nanomaterial-cell interface during macropinocytosis-mediated internalization.","authors":"Yushuang Wei, Xiangyang Li, Yao Gong, Yue-Xuan Li, Jibin Guan, Bing Yuan, Yue Chen, Hong-Bo Pang","doi":"10.1016/j.nantod.2025.102865","DOIUrl":"10.1016/j.nantod.2025.102865","url":null,"abstract":"<p><p>Nanomaterials often need to interact with proteins on the plasma membrane to get cross and access their intracellular targets. Therefore, to fully understand the cell entry mechanism, it is of vital importance to gain a comprehensive insight into the proteome at the interface when nanomaterials encounter the cells. Here, we reported a peroxidase-based proximity labeling method to survey the proteome at the nanoparticle (NP)-cell interface. Horseradish peroxidase (HRP) was conjugated to a variety of NPs and other ligand types while still being able to biotinylate the proteins surrounding NP (or ligand)-receptor complexes. Using two NP-based tracers for macropinocytosis (MP), which is highly relevant to NP internalization, we performed a proteomic survey and revealed the interface proteome difference between traditional and receptor-dependent MP. Moreover, our survey found that E-cadherin (CDH1), while not serving as the primary receptor, is present at the NP-cell interface and is functionally important for the cellular uptake of a wide variety of NPs. Overall, by integrating nanotechnology with proximity labeling, our study provides an approach to map the proteome of NP-cell interface for investigating the molecular mechanism of NP and macromolecule internalization into cells.</p>","PeriodicalId":395,"journal":{"name":"Nano Today","volume":"65 ","pages":""},"PeriodicalIF":10.9,"publicationDate":"2025-12-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://www.ncbi.nlm.nih.gov/pmc/articles/PMC12410780/pdf/","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"145013639","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":1,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"OA","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

{"title":"One Stone Two Birds: Enhancing Energy Density and Temperature Adaptability for Vanadium-based Redox Flow Batteries via Dual Active Species Strategy","authors":"Jinhui Ying, Huijia Li, Xiongjie Jia, Zihan Yu, Tianshou Zhao, Haoran Jiang","doi":"10.1016/j.ensm.2025.104693","DOIUrl":"https://doi.org/10.1016/j.ensm.2025.104693","url":null,"abstract":"Vanadium-based redox flow batteries, characterized by no cross-contamination issue, are considered as one of the most promising candidates for large-scale energy storage. However, due to vanadium ions show relatively low solubility and are easy to precipitate at extreme temperatures, the battery suffers from the long challenge of low energy density and poor temperature adaptability. In this work, by introducing vanadium and bromine dual active species into the positive electrolyte, a novel V/V-Br redox flow battery (VBrRFB) is developed to boost the energy density and temperature window of vanadium-based flow batteries. The bromine, not only acts as the secondary redox couple to enhance the overall concentration of active species, but also disrupts the hydrogen bond network while optimizing the solvation structure of vanadium. As a result, the VBrRFB achieves an energy density of as high as 152.4 Wh L^-1_catholyte (38.1 Wh L^-1_{catholyte+anolyte}), which is 265.9% higher than traditional all-vanadium redox flow batteries, while maintaining stable cycling over 250 cycles with an energy efficiency of 82.5%. Additionally, the VBrRFB exhibited excellent stability and performance from -10°C to 50°C, with energy densities of 107.6 Wh L^-1_catholyte at 50 °C and 88.8 Wh L^-1_catholyte at -10 °C, demonstrating its strong potential for practical energy storage.","PeriodicalId":306,"journal":{"name":"Energy Storage Materials","volume":"116 1","pages":""},"PeriodicalIF":20.4,"publicationDate":"2025-10-19","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"145314833","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":1,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

{"title":"Production-Ready Double-Sided Fabrication of Dual-Band Infrared Metaoptics Using Deep-Ultraviolet Lithography","authors":"Kai Sun, Xingzhao Yan, Jordan Scott, Jun-Yu Ou, James N. Monks, Otto L. Muskens","doi":"10.1021/acsnano.5c11908","DOIUrl":"https://doi.org/10.1021/acsnano.5c11908","url":null,"abstract":"Metaoptics, the application of metasurfaces into optical systems, is seeing an accelerating development owing to advantages in size, weight, and cost and the ability to program optical functions beyond traditional refractive optics. The transition of metaoptics from the laboratory into applications is enabled by scalable production methods based on highly reproducible semiconductor process technology. Here, we introduce a method for the fabrication of double-sided metasurfaces through deep-UV lithography as a production-ready method for achieving high-quality metaoptics. We achieve patterning of a silicon wafer on both sides with mutual alignment of around 10 μm based on tool accuracy without requiring through-wafer alignment markers other than the wafer notch. An application highlighting the benefits of double-sided design is demonstrated in the form of a dual-band metalens with independent control over focal lengths in mid- and long-wavelength infrared bands. Using multireticle stitching, we demonstrate a 40 mm diameter, large-area metalens with excellent broadband imaging performance, showing partial canceling of chromatic dispersion when used in a hybrid configuration with a BaF₂ refractive lens. Our work establishes a production-ready approach to infrared metaoptics designs and double-sided metaoptics fabrication with direct potential for translation into scalable technology for real-world applications.","PeriodicalId":21,"journal":{"name":"ACS Nano","volume":"98 1","pages":""},"PeriodicalIF":17.1,"publicationDate":"2025-10-19","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"145314662","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":1,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

{"title":"The oxidation mechanism of heterogeneous structured Cu-316L-xMo immiscible alloys by laser powder bed fusion","authors":"Cheng Deng, Zihao Wan, Tao Xie, Xinhua Wang, Shengfeng Zhou","doi":"10.1016/j.jallcom.2025.184487","DOIUrl":"https://doi.org/10.1016/j.jallcom.2025.184487","url":null,"abstract":"Cu-316L-<em>x</em>Mo immiscible alloys were manufactured by laser powder bed fusion (LPBF) in this work. The oxidation behavior of three types Cu-316L-<em>x</em>Mo alloys at 600 °C and 700 °C were studied to reveal the influence of Mo on the oxidation kinetics, oxide scale formation and integrity. The results showed that a heterogeneous oxide layer composed of CuO and Fe₂O₃ was formed on the surface after oxidation, and locally varying oxide-thicknesses is observed due to the immiscibility of ε-Cu and γ-Fe phases. The incorporation of Mo ions into the oxide scale accelerates the oxidation rate of Cu–316L–<em>x</em>Mo alloys. The high volatility of MoO₃ compromises the integrity of the oxide scale, especially at higher temperature. Moreover, the growth and thermal stresses developed within the oxide scale during thermal cycling leads to severe cracking and spallation of the oxide scale.","PeriodicalId":344,"journal":{"name":"Journal of Alloys and Compounds","volume":"19 1","pages":""},"PeriodicalIF":6.2,"publicationDate":"2025-10-19","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"145314718","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":2,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

{"title":"Polymorph‒dependent defect chemistry of MnO2 nanorods: grain boundary and oxygen vacancy effects on burn rate enhancement in solid propellants","authors":"Santra Merin Saju, Anuj A. Vargeese","doi":"10.1016/j.apsusc.2025.164932","DOIUrl":"https://doi.org/10.1016/j.apsusc.2025.164932","url":null,"abstract":"The controlled synthesis of nanomaterials with tailored morphologies and crystal structures has emerged as a key strategy for optimizing catalytic performance through defect and interface engineering. Manganese dioxide (MnO₂), a transition-metal oxide, existing in multiple polymorphs with distinct atomic frameworks and tunable defect chemistries, is an ideal compound to investigate structure–property–performance correlations. In this study, α- and β-MnO₂ nanorods were synthesized and systematically evaluated to elucidate the influence of the crystal structure, grain boundaries, and oxygen vacancies on the catalytic behavior. The β-MnO₂ phase demonstrated superior catalytic activity, which was attributed to its abundant high-energy grain boundary interfaces, and elevated concentrations of surface oxygen vacancies, as revealed by X-ray photoelectron spectroscopy (XPS) and high-resolution transmission electron microscopy (HRTEM) analyses. Phase-dependent structural features and surface defects modulate the Mn oxidation environment and generate unsaturated coordination sites that facilitate reactant adsorption and bond activation. These sites serve as highly active centers that promote reactant adsorption and bond activation, thereby enhancing the catalytic activity and substantially accelerating the combustion dynamics of composite solid propellants. These catalytic enhancements driven by structural modifications resulted in the accelerated decomposition of ammonium perchlorate (AP) and an enhanced burn rate in AP-based composite solid propellants.","PeriodicalId":247,"journal":{"name":"Applied Surface Science","volume":"237 1","pages":""},"PeriodicalIF":6.7,"publicationDate":"2025-10-19","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"145314720","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":2,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

{"title":"MetaMode Deposition of Niobium Oxide Thin Films Using a Broad-Beam Ion Source","authors":"Junwoo Lee, Yifan Liu, Carson Malhado, Ming Xu, Keliang Wang, Zhen Qiu, Shi-You Ding, Richard R. Lunt, Qi Hua Fan","doi":"10.1016/j.jallcom.2025.184505","DOIUrl":"https://doi.org/10.1016/j.jallcom.2025.184505","url":null,"abstract":"Niobium oxide (Nb₂O₅) thin films were deposited under MetaMode using a new broad-beam ion source-enhanced magnetron sputtering. The ion source significantly reduced the required oxygen concentration from over 20% to ~7.5% to form fully stoichiometric Nb₂O₅ films. The MetaMode deposition rates were over three times higher than conventional reactive magnetron sputtering, which requires significantly higher oxygen concentrations. The film properties were characterized using UV-Vis spectroscopy, atomic force microscopy (AFM), scanning electron microscope (SEM), x-ray diffraction (XRD), x-ray photoelectron spectroscopy (XPS), four-point probe, and spectroscopic ellipsometry. The MetaMode deposited Nb₂O₅ thin films exhibited smoother surfaces, better optical transmittance, and denser morphology, while overcoming the disappearing anode effect in conventional reactive sputtering.","PeriodicalId":344,"journal":{"name":"Journal of Alloys and Compounds","volume":"40 1","pages":""},"PeriodicalIF":6.2,"publicationDate":"2025-10-19","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"145314732","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":2,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

{"title":"Effect of 0.5 wt.% Cr on Precipitation Evolution and Recrystallization Behavior in Cu-Ni-Co-Si-Zn Alloys","authors":"Liusen Yang, Haozhi Ao, Fangxin Yu, Yongqiang Zhou, Jianyi Cheng, Linnian Zhang, Jian Zhou, Jiaqiang Ding","doi":"10.1016/j.jallcom.2025.184502","DOIUrl":"https://doi.org/10.1016/j.jallcom.2025.184502","url":null,"abstract":"This study investigates the effects of 0.5<!-- --> <!-- -->wt.% Cr on precipitates, texture, recrystallization, and properties in Cu-Ni-Co-Si-Zn alloys. During melting, Cr promotes the formation of (Cr, Co)₃Si primary phases, which contribute to the refinement of the initial grains. The addition of Cr significantly increases the activation energy for second-phase precipitation by 46%, thereby retarding the precipitation kinetics by raising the nucleation energy barrier. However, in the early stage of aging, the co-precipitation of BCC-Cr (three variants) and δ-(Ni, Co, Cr)₂Si results in a multi-phase strengthening effect, markedly enhancing the peak hardness. Cr promotes the transformation of δ-(Ni, Co)₂Si into the more stable δ-(Ni, Co, Cr)₂Si phase and induces the precipitation of fully coherent β-(Ni, Co)₃Si, significantly delaying over-aging and enhancing hardness retention. The formation enthalpies of δ-(Ni, Co, Cr)₂Si and β-(Ni, Co)₃Si are lower than those of δ-(Ni, Co)₂Si and β-Ni₃Si, indicating that the Cr-containing precipitates exhibit stronger thermodynamic driving force and higher structural stability after overcoming the precipitation activation energy. The effect of Cr on grain exhibits a pronounced time-dependent behavior: during short-term aging (2<!-- --> <!-- -->h), Cr suppresses the precipitation of secondary phases, thereby increasing lattice distortion (KAM value increases by 3.4%), promoting the formation of Cube recrystallization texture (1.82), and weakening the Brass texture (from 5.89 to 4.29). After prolonged aging (20<!-- --> <!-- -->h), the 0.5Cr alloy retains a high precipitate density through suppressed coarsening, strengthening grain boundary pinning. As a result, the Brass texture (1.92) is retained, and the recrystallization fraction (2.0%) remains significantly lower than that of the 0Cr alloy (23.6%), ultimately leading to a mixed microstructure composed of recrystallization textures (Rt-C: 1.70, R: 2.43) and deformation textures inherited from cold rolling.","PeriodicalId":344,"journal":{"name":"Journal of Alloys and Compounds","volume":"15 1","pages":""},"PeriodicalIF":6.2,"publicationDate":"2025-10-19","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"145314734","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":2,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

{"title":"On Pipe Diffusion of Rhenium along Misfit-Dislocation-Networks in Ni-base Single Crystal Superalloys","authors":"Rico Zehl, Nicolas Karpstein, Aparna Saksena, Oliver Martin Horst, Aleksander Kostka, Baptiste Gault, Alfred Ludwig, Suzana G. Fries, Erdmann Spiecker, Guillaume Laplanche, Gunther Eggeler","doi":"10.1016/j.actamat.2025.121656","DOIUrl":"https://doi.org/10.1016/j.actamat.2025.121656","url":null,"abstract":"This study explores whether the diffusion of Re in the γ-phase of Ni-base superalloy single crystals is accelerated along fine dislocation networks that have formed at γ/γʹ-interfaces during high-temperature and low-stress creep. Diffusion couples of Re-enriched superalloy thin films were sputter deposited onto (100) planes of two Re-free single-crystalline nickel-base superalloys with different microstructures. One consisted of an as-processed microstructure with cuboidal γʹ-particles separated by thin γ-channels, with a low dislocation density. The other featured continuous γʹ-rafts parallel to the [100] direction with fine dislocation networks at the γ/γʹ-interfaces. The rafted structure was produced by 2% creep deformation along the [001] direction at 1000°C and 240 MPa. Analytical transmission electron microscopy and atom probe tomography revealed that the diffusion of Re into the γ-phase was not accelerated by the presence of dislocation networks at the γ/γʹ-interfaces of the rafted microstructure.","PeriodicalId":238,"journal":{"name":"Acta Materialia","volume":"100 1","pages":""},"PeriodicalIF":9.4,"publicationDate":"2025-10-19","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"145314736","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":1,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

{"title":"Influence of Ar-assisted pulsed laser ablation on structural and magnetic properties of Fe₈0B20 thin films","authors":"Jimena Soler-Morala, Rubén Fernández-Jiménez, Verónica Braza, Luis Vázquez, Daniel F. Reyes, Sergio Jiménez-Fernández, David González, Juan Rubio-Zuazo, Jesús M. González, F. Javier Palomares","doi":"10.1016/j.apsusc.2025.164936","DOIUrl":"https://doi.org/10.1016/j.apsusc.2025.164936","url":null,"abstract":"We report on the chemical, structural and morphological modifications introduced in nanothick Fe₈₀B₂₀ films by the use of Ar assistance (at different pressures) during their pulsed laser ablation deposition process. As a reference, a film deposited in absence of Ar and under ultra-high vacuum conditions was also prepared. Samples were characterized from the measurement of X-ray photoelectron spectroscopy depth profiles, atomic force microscopy, and transmission electron microscopy as well as from the standpoint of their dc angular dependence of the hysteresis, high applied field magnetization and tens of GHz dynamics. Our results include i) the induction of surface roughening that increases with the assisting gas pressure, ii) the amorphousness of the ultra-high vacuum film, iii) the induction, by the Ar assistance, of partial crystallization, yielding Fe-rich columns whose transverse dimension increased with the Ar pressure, iv) the progressive isotropization of the in-plane hysteresis parameters associated to the increase of Ar pressure, v) the occurrence on the samples deposited with the largest Ar pressures of spin waves stiffness constant having a magnitude 20 times larger than the value measured in the reference sample, and vi) the decrease of the ferromagnetic resonance damping parameter with regard to the reference sample.","PeriodicalId":247,"journal":{"name":"Applied Surface Science","volume":"160 1","pages":""},"PeriodicalIF":6.7,"publicationDate":"2025-10-19","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"145314755","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":2,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

{"title":"Dual-wavelength solar blind photodetectors based on GeTiO2 vertical and lateral heterojunctions","authors":"Chen Guo, Lingdong Wang, Jiabao Hu, Shuxian Zang, Xingyu Liu, Yang Chen, Xueyao Lu, Hongguang Duan, Ziyang Hu, Feifei Qin, Xu Wang","doi":"10.1016/j.apsusc.2025.164937","DOIUrl":"https://doi.org/10.1016/j.apsusc.2025.164937","url":null,"abstract":"Wide bandgap heterojunction solar blind photodetectors (SBPDs) are actively being explored to achieve widespread applications in the military and civilian fields. However, interface defects induced during the stacking process of the vertical heterostructure reduce the SBPD performance. Here, GeTiO₂ vertical and lateral heterojunction SBPDs have been fabricated by using the radio frequency magnetron sputtering strategy and exhibit obvious dual-wavelength solar-blind photoresponses. Compared to the vertical heterojunction SBPD, the GeTiO₂ lateral heterojunction SBPD has been demonstrated substantially enhanced performances including good photoresponsivity of 2.01 × 10⁻² and 4.5 × 10⁻⁴ A/W, high detectivity of 2.07 × 10¹⁰ and 5.7 × 10⁸ Jones, and large external quantum efficiency of 11.7 and 0.22 % at 213 and 254 nm due to the decreased interface defect and adjusted band arrangement. Besides, benefiting from their short response time, GeTiO₂ lateral heterojunction SBPDs successfully achieve binary-encoded information transmissions and optoelectronic logic device applications<em>.</em> Our work presents a feasible strategy for fabricating high-performance lateral heterojunction SBPDs, offering new insights into the design of oxide semiconductor heterostructures for developing optoelectronic applications.","PeriodicalId":247,"journal":{"name":"Applied Surface Science","volume":"40 1","pages":""},"PeriodicalIF":6.7,"publicationDate":"2025-10-19","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"145314721","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":2,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}