{"title":"Quantum dots@layered double hydroxides: Emerging nanocomposites for multifaceted applications","authors":"Garima Rathee , Antonio Puertas-Segura , Jeniffer Blair , Jyotsna Rathee , Tzanko Tzanov","doi":"10.1016/j.pmatsci.2024.101403","DOIUrl":"10.1016/j.pmatsci.2024.101403","url":null,"abstract":"<div><div>Nanomaterials have fascinated experts across numerous fields owing to their intriguing properties and wide-ranging applications. Layered double hydroxides (LDHs) and quantum dots (QDs) are fascinating nanomaterials renowned for their versatility in various consumer products. LDHs are multifunctional two-dimensional nanostructures, whereas QDs are semiconductor nanocrystals with exceptional electronic features. This review explores the synergistic combination of LDHs and QDs in QDs@LDH nanocomposites exploitable across numerous applications. Diverse technologies have been used to customize their morphological and structural features, including ultrasonication, LbL self-assembly, chemical reduction, photochemical processing, microwave-assisted synthesis, and hydro/solvothermal methods. We emphasize the increased surface area, tunable optical properties, improved stability, and enhanced catalytic performance of QDs@LDH nanocomposites that unlock a myriad of biomedical, sensor, energy storage and conversion, optoelectronic, catalytic, environmental, flame retardant, anti-fake detection, paper protection and forensic applications. Mechanistic insights into defect engineering, charge transfer mechanisms, and QD-LDH interactions are provided, elucidating the underlying principles of these nanocomposites’ behavior and functionality.</div></div>","PeriodicalId":411,"journal":{"name":"Progress in Materials Science","volume":"150 ","pages":"Article 101403"},"PeriodicalIF":33.6,"publicationDate":"2024-11-13","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"142642833","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":1,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"OA","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
{"title":"Thermoelectric materials and applications in buildings","authors":"Qi Sun, Chunyu Du, Guangming Chen","doi":"10.1016/j.pmatsci.2024.101402","DOIUrl":"10.1016/j.pmatsci.2024.101402","url":null,"abstract":"<div><div>Thermoelectric materials are functional materials that utilize the movements of charge carriers to achieve the direct interconversions between heat and electricity. Recently, high-performance thermoelectric materials and multifunctional devices have witnessed explosive progresses to alleviate energy burdens. As the energy consumption in buildings continues to increase, the integration of thermoelectric materials with buildings provides a promising solution to improve the energy utilization efficiency. However, despite the rapid progress in thermoelectric technology, there remains a scarcity of comprehensive reviews and systematic assessments focused on the integration and applications of thermoelectric materials in building environments. This timely paper provides a thorough introduction to the research landscape, encompassing applications of thermoelectric materials, a brief historical overview of building technologies, and recent research trends in thermoelectric materials pertinent to buildings. We systematically elucidate the principles of thermoelectric materials and outlines the specific properties required for their application across various building components. Following this, the focus is on representative thermoelectric materials across four critical domains: energy harvesting, building cooling, temperature monitoring, and corrosion prevention. The discussion is structured according to the positioning and functional roles of devices integrated within buildings. Finally, we summarize the key findings and underscore the challenges and the future prospects for thermoelectric materials and devices in building applications.</div></div>","PeriodicalId":411,"journal":{"name":"Progress in Materials Science","volume":"149 ","pages":"Article 101402"},"PeriodicalIF":33.6,"publicationDate":"2024-11-04","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"142579966","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":1,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Sadaf Siddique , Abdul Waheed , Muhammad Iftikhar , Muhammad Taqi Mehran , Muhammad Zafar Zarif , Hassan A. Arafat , Sajjad Hussain , Faisal Shahzad
{"title":"Fluorine-free MXenes via molten salt Lewis acidic etching: Applications, challenges, and future outlook","authors":"Sadaf Siddique , Abdul Waheed , Muhammad Iftikhar , Muhammad Taqi Mehran , Muhammad Zafar Zarif , Hassan A. Arafat , Sajjad Hussain , Faisal Shahzad","doi":"10.1016/j.pmatsci.2023.101183","DOIUrl":"10.1016/j.pmatsci.2023.101183","url":null,"abstract":"<div><p><span>MXenes, a family of two-dimensional (2D) transition metal carbides, </span>nitrides<span><span>, and carbonitrides, have garnered a global attention for their diverse applications in energy storage, electromagnetic interference shielding, sensing, catalysis, biomedicine, and more. Traditionally, MXenes have been prepared by dissolving </span>Al<span> from the MAX phase using fluorine-based etching solutions. However, a greener alternative approach, that is, Lewis acidic etching via molten salt has recently emerged which avoids the use of harmful fluorine-based etchants and allows for the production of MXenes with tunable surface functionalities. In this comprehensive review article, the authors delve into the drawbacks of traditional fluorine-based MXene fabrication methods and showcase the advantages of the greener and more efficient approach of Lewis acid etching via molten salt. The chemical processes involved in the conventional and Lewis acid etching methods are discussed and a special emphasis is given on the structure–property relationship that can be tuned by using the later approach. This article is expected to be a valuable resource for researchers interested in the MXene fabrication and to inspire further development and innovation in this exciting and rapidly evolving field.</span></span></p></div>","PeriodicalId":411,"journal":{"name":"Progress in Materials Science","volume":"139 ","pages":"Article 101183"},"PeriodicalIF":37.4,"publicationDate":"2023-10-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"46985411","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":1,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
{"title":"Nanogels: Synthesis, properties, and recent biomedical applications","authors":"Qiu-Yi Duan, Ya-Xuan Zhu, Hao-Ran Jia, Shi-Hao Wang, Fu-Gen Wu","doi":"10.1016/j.pmatsci.2023.101167","DOIUrl":"10.1016/j.pmatsci.2023.101167","url":null,"abstract":"<div><p>Nanogels, also termed hydrogel nanoparticles<span>, have the properties and functions of both nanomaterials and hydrogels. Till date, a considerable number of nanogels have been developed to satisfy increasing requirements from different fields. Therefore, it is crucial to summarize the existing preparation methods, physicochemical and biological properties, and recent applications of nanogels, which may be beneficial for seeking new developmental directions of nanogels. In this review, we first introduce the history, ingredients, and classification of nanogels, and the differences of nanogels from macro-sized hydrogels and other kinds of nanoparticles. Second, we focus on the synthetic methods of nanogels from the aspects of physical crosslinking approaches and chemical crosslinking reactions, and discuss the pros and cons of these methods. Third, the common properties of nanogels are introduced, including the reasons why nanogels possess these properties and some representative examples illustrating the merits brought about by these properties. Fourth, we elaborate on the current applications of nanogels in drug delivery, imaging, detection, and regenerative medicine. Fifth, we also summarize the clinical trials and clinical applications in the nanogel field. Finally, the current problems and challenges in the nanogel field are raised. This review is expected to inspire researchers to develop more functional nanogels and promote their practical applications in a variety of fields.</span></p></div>","PeriodicalId":411,"journal":{"name":"Progress in Materials Science","volume":"139 ","pages":"Article 101167"},"PeriodicalIF":37.4,"publicationDate":"2023-10-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"47012632","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":1,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
{"title":"High temperature liquid thermal conductivity: A review of measurement techniques, theoretical understanding, and energy applications","authors":"Andrew Z. Zhao , Javier E. Garay","doi":"10.1016/j.pmatsci.2023.101180","DOIUrl":"10.1016/j.pmatsci.2023.101180","url":null,"abstract":"<div><p><span>High temperature heat transfer fluids like molten salts and molten metals<span> will unlock the higher efficiency and lower cost of next generation grid scale energy sources such as concentrated solar power and advanced nuclear power plants. Their thermal conductivity will help determine how much heat power can be extracted from high temperature systems to do useful work. However, there is a large spread in liquid thermal conductivity data at high temperatures, and well-established, general models of liquid thermal conductivity across liquid classes and temperature ranges are lacking. In this work, we review experimental techniques used to measure liquid thermal conductivity – various steady-state, time-domain, and frequency-domain techniques – and we discuss strategies to minimize errors from convection, radiation, and corrosion that are amplified at high temperature. We classify liquids based on their dominant intermolecular interaction (simple, molecular, coulombic, or metallic) and examine their resulting short-range order that will inform models of </span></span>heat conduction<span><span> in liquids. Through the lens of intermolecular interactions and short-range order in liquids, we review previous analytical models of liquid thermal conductivity – modified kinetic gas, quasi-crystalline, and electron dominated models – and we compare their results with reliable experimental measurements of various types of liquids. The results suggest that modified kinetic gas models do not match experimental data for liquids. Quasi-crystalline models can accurately match some available experimental results of molten salts. We explore underlying similarities between various quasi-crystalline models that may be explained by frequency dependent vibrational modes in liquids. Electron transport is the dominant mechanism for thermal conductivity in molten metals. However </span>electrical conductivity measurements cannot be used directly for molten metal thermal conductivity measurement using the Wiedemann-Franz law because the Lorentz number varies with pressure, temperature and metal composition. In addition to analytical models we review molecular dynamics simulations, using equilibrium and non-equilibrium methods. The results show that MD simulations for molten salt thermal conductivity slightly overpredict experimentally measured reference values. These simulations can provide insights into the frequency-dependent behavior of vibrational modes in liquids. Lastly, we discuss future research directions of high temperature liquid thermal conductivity research and provide an outlook for applications for high temperature heat transfer fluids including use in power generation.</span></p></div>","PeriodicalId":411,"journal":{"name":"Progress in Materials Science","volume":"139 ","pages":"Article 101180"},"PeriodicalIF":37.4,"publicationDate":"2023-10-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"54898839","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":1,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Prithu Bhatnagar , Sadeq Hooshmand Zaferani , Nassim Rafiefard , Bardia Baraeinejad , Amir Reza Vazifeh , Raheleh Mohammadpour , Reza Ghomashchi , Harald Dillersberger , Douglas Tham , Daryoosh Vashaee
{"title":"Advancing personalized healthcare and entertainment: Progress in energy harvesting materials and techniques of self-powered wearable devices","authors":"Prithu Bhatnagar , Sadeq Hooshmand Zaferani , Nassim Rafiefard , Bardia Baraeinejad , Amir Reza Vazifeh , Raheleh Mohammadpour , Reza Ghomashchi , Harald Dillersberger , Douglas Tham , Daryoosh Vashaee","doi":"10.1016/j.pmatsci.2023.101184","DOIUrl":"10.1016/j.pmatsci.2023.101184","url":null,"abstract":"<div><p>The emergence of self-powered wearable devices has revolutionized health and wellness monitoring by effortlessly integrating it into daily life. This article explores the recent advancements and challenges in energy efficiency and harvesting technologies, which have been instrumental in the development of these wearables. These self-powered systems encompass sensors, energy harvesting mechanisms, power management units, energy storage, data transmission, and processing platforms. This article emphasizes the energy harvesting aspect, providing a concise overview of core techniques, and critically analyzing their application in state-of-the-art wearable devices. Furthermore, we investigate ongoing research and industry efforts to establish networks of self-powered wearables for sustained, long-term operation. Through this analysis, the article aims to provide insights into leveraging current knowledge and technology to accelerate the growth and potential of self-powered wearable devices in healthcare and entertainment.</p></div>","PeriodicalId":411,"journal":{"name":"Progress in Materials Science","volume":"139 ","pages":"Article 101184"},"PeriodicalIF":37.4,"publicationDate":"2023-10-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"41847541","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":1,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
{"title":"Solid-state lithium batteries-from fundamental research to industrial progress","authors":"Dengxu Wu , Liquan Chen , Hong Li , Fan Wu","doi":"10.1016/j.pmatsci.2023.101182","DOIUrl":"10.1016/j.pmatsci.2023.101182","url":null,"abstract":"<div><p><span>In recent years, solid-state lithium batteries (SSLBs) using </span>solid electrolytes<span> (SEs) have been widely recognized as the key next-generation energy storage technology due to its high safety, high energy density, long cycle life, good rate performance and wide operating temperature range. However, SSLBs still suffer from many obstacles that hinder their practical application. This review discusses typical lithium-ion conductors and their in-depth lithium-ion conduction mechanism. The key interfacial problems of electrolytes and electrodes for SSLBs are comprehensively elaborated and several possible solution methods are proposed. Furthermore, three viable manufacturing strategies for free-standing thin SE membranes are discussed in details. Moreover, for the first time, the government policies and latest company industrialization process relative to SSLBs worldwide are systematically summarized. Finally, several potential strategies are identified for the future development of high-energy-density SSLBs.</span></p></div>","PeriodicalId":411,"journal":{"name":"Progress in Materials Science","volume":"139 ","pages":"Article 101182"},"PeriodicalIF":37.4,"publicationDate":"2023-10-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"45589472","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":1,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
{"title":"Deformation twinning in body-centered cubic metals and alloys","authors":"Xiyao Li , Ze Zhang , Jiangwei Wang","doi":"10.1016/j.pmatsci.2023.101160","DOIUrl":"10.1016/j.pmatsci.2023.101160","url":null,"abstract":"<div><p><span>Deformation twinning is an important plastic carrier competing with the ordinary dislocation slip in a broad class of crystalline solids, which critically controls the mechanical properties, plasticity, and fracture of crystalline materials across different length scales. Compared with the well-established twinning theories in their close-packed metallic counterparts, a comprehensive understanding of twinning dynamics and twinning mechanisms in body-centered cubic (BCC) metals and alloys remains largely elusive, though some important progresses have been made in past few decades. In this review, we systematically summarize recent advances of deformation twinning in BCC metals and alloys in past few decades, by focusing on the various aspects of the most common {1</span> <!-->1<!--> <!-->2}〈11<span><math><mrow><mover><mrow><mtext>1</mtext></mrow><mrow><mo>¯</mo></mrow></mover></mrow></math></span>〉 twins, including the atomic structures of twin boundaries, twin nucleation and growth mechanisms, asymmetry of twinning and anti-twinning, factors influencing the deformation twins, twin-induced fractures and some other unique properties. {3<!--> <!-->3<!--> <!-->2}〈11<span><math><mrow><mover><mrow><mtext>3</mtext></mrow><mrow><mo>¯</mo></mrow></mover></mrow></math></span>〉 and other types of high-index deformation twins that have been extensively observed in BCC alloys are also summarized and discussed. The comprehensive understanding of deformation twinning in BCC metals and alloys not only advances our knowledge of twinning in metallic materials, but also has broad implications for the design of high-performance BCC metals and alloys by regulating deformation twins.</p></div>","PeriodicalId":411,"journal":{"name":"Progress in Materials Science","volume":"139 ","pages":"Article 101160"},"PeriodicalIF":37.4,"publicationDate":"2023-10-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"42158583","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":1,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
{"title":"Recent advances in bio-based functional additives for polymers","authors":"Valentina Marturano , Angela Marotta , Sarai Agustin Salazar , Veronica Ambrogi , Pierfrancesco Cerruti","doi":"10.1016/j.pmatsci.2023.101186","DOIUrl":"10.1016/j.pmatsci.2023.101186","url":null,"abstract":"<div><p>In recent decades, the strong global concern on depletion of fossil fuel and the environmental impact of oil-based compounds has pushed towards more sustainable approaches in the development of polymer-based materials. This interest is driven by the need of a more sustainable economy and a lower dependency on fossil fuels. In this frame, the replacement of synthetic additives with natural compounds in polymer commodities is progressively taking place. Additionally, according to forecasts, the production of bio-plastics will grow exponentially in the near future. However, these materials may exhibit poor physical and mechanical properties regarding processability and end-use, which can limit their potential for applications. Therefore, academic and industrial communities are pushing their interest in fully bio-based formulations with improved performance, and tailored for specific applications, ranging from packaging to biomedicine.</p><p>This review presents the most recent advances in research and development of bio-based functional additives for polymeric materials. For each type of additive, both the scientific fundamentals and the technological aspects are encompassed, with an emphasis on the current commercially available bio-based additives and their role in market uptake of environmentally friendly products. Finally, considerations about environmental, health, regulatory, and economic issues related to the use of bio-additives in plastic materials are also addressed.</p></div>","PeriodicalId":411,"journal":{"name":"Progress in Materials Science","volume":"139 ","pages":"Article 101186"},"PeriodicalIF":37.4,"publicationDate":"2023-10-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://www.sciencedirect.com/science/article/pii/S0079642523001184/pdfft?md5=80d6f31c73fba93a9c3cc1494a94d42e&pid=1-s2.0-S0079642523001184-main.pdf","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"47146310","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":1,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"OA","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}