Xuan Wang, Meng Li, Yawen Tang, Hao Li, Gengtao Fu
{"title":"Rare earths evoked gradient orbital coupling in electrocatalysis: Recent advances and future perspectives","authors":"Xuan Wang, Meng Li, Yawen Tang, Hao Li, Gengtao Fu","doi":"10.1016/j.pmatsci.2025.101539","DOIUrl":"https://doi.org/10.1016/j.pmatsci.2025.101539","url":null,"abstract":"Rare earths (RE) have garnered significant attention in electrocatalysis due to their unique ability to modulate electronic structure of host materials. The gradient orbital coupling (GOC) based on f-p-d orbital interaction has recently been proposed to explain the key reason for RE-enhanced electrocatalysis. However, a systematic review elaborating the critical role of GOC in electrocatalysis remains lacking. Herein, this review presents a timely and comprehensive summary of GOC breakthroughs in RE-based electrocatalysts and highlights their key role in electrocatalysis. It begins by introducing the fundamentals of GOC. We further discuss the most recent progress in tuning the electronic state of metal active centers by GOC for various electrocatalytic reactions including oxygen electrocatalysis, hydrogen evolution, carbon dioxide reduction, nitrogen oxidation and urea oxidation. From GOC insight, this discussion of electrochemical performances and intrinsic catalytic mechanisms favors the construction of RE-evoked structure-performance relationship. At the end, we discuss the challenges and potential future directions for research related to the GOC. We hope this review will inspire novel designs and a deeper understanding of RE-based electrocatalysts.","PeriodicalId":411,"journal":{"name":"Progress in Materials Science","volume":"101 1","pages":""},"PeriodicalIF":37.4,"publicationDate":"2025-07-22","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"144685120","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":1,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Deyu Wu , Hao Wang , Yingxia Nie , Haifei Wan , Shuai Liu , Song Yang , Hui Li , Heng Zhang , Chengzhou Zhu , Tianyi Ma
{"title":"When covalent organic frameworks meet metals: From opportunities toward applications","authors":"Deyu Wu , Hao Wang , Yingxia Nie , Haifei Wan , Shuai Liu , Song Yang , Hui Li , Heng Zhang , Chengzhou Zhu , Tianyi Ma","doi":"10.1016/j.pmatsci.2025.101538","DOIUrl":"10.1016/j.pmatsci.2025.101538","url":null,"abstract":"<div><div>Porous materials, particularly covalent organic frameworks (COFs), exhibit well-defined porosity, tunable structural features, and high chemical and thermal stability. These intrinsic properties render COFs highly promising candidates for the rational design of efficient functional materials, thereby attracting significant interest across diverse scientific and engineering disciplines. Nevertheless, pristine COF frameworks often suffer from an insufficient density of active sites and functional moieties, thereby constraining their practical performance. Accordingly, the incorporation of metal components into COF architectures has emerged as a promising strategy to enhance their functionalities. In this review, we introduce a novel classification scheme grounded in the interaction strength between metal species and COFs, which enables a systematic organization of existing metal-modified COF materials. This framework facilitates an in-depth analysis of this intriguing class of materials by elucidating the intrinsic relationships and distinctions among different metal-modified COF materials from the perspective of metal-COF interaction strength, thereby advancing the fundamental understanding of their structure-property correlations. Furthermore, we comprehensively summarize recent progress in metal-modified COF materials with respect to applications including adsorption and separation, photocatalysis, electrocatalysis, energy storage, sensing, and biomedicine. Emphasis is placed on structural design principles, synthetic methodologies, characterization techniques, and how different metal-modified COF materials influence reaction pathways and underlying mechanisms. Ultimately, the current challenges and future research directions pertaining to metal-modified COF materials are critically discussed.</div></div>","PeriodicalId":411,"journal":{"name":"Progress in Materials Science","volume":"155 ","pages":"Article 101538"},"PeriodicalIF":33.6,"publicationDate":"2025-07-21","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"144678008","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":1,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
{"title":"Tailored architectures in desalination membranes with MXene: Is this the way forward?","authors":"Sutar Rani Ananda , T.M. Subrahmanya , Shambhulinga Aralekallu , Wei-Song Hung , Mahaveer D. Kurkuri","doi":"10.1016/j.pmatsci.2025.101537","DOIUrl":"10.1016/j.pmatsci.2025.101537","url":null,"abstract":"<div><div>Just with one decade of history (The discovery of Ti<sub>3</sub>C<sub>2</sub> − 2011), studies on two-dimensional (2D) transition metal carbides, carbonatites, and nitrides (comprehensively stated as MXenes) vastly expanded from fundamental to applications level. The engineered MXenes are good competitors to 2D materials like graphene, metal–organic frameworks, etc., with widespread applications such as gas sensors, water purification, EMI shielding, energy storage, and catalysts etc. Owing to the 2D layered structure, the intercalation of cations, comprising multivalent ones and polar organic molecules, allows the control of interlayer distance and enables MXenes to be used in water purification and desalination. Besides, MXenes have a high aspect ratio due to the sheet structure, which provides nanochannels as diffusion paths for these applications. In this review, we explored the MXenes as membrane materials for pressure-driven membrane-based water desalination technology and the various physico-chemical modifications of MXene’s structure to enhance desalination performance. We also highlight membrane-desalination metrics, fabrication strategies of membranes, trade-off analysis, and the mechanisms behind enhanced performances due to modifications, which provide essential insights about these materials. Ultimately, we summarize the present challenges and provide the future outlook as the foundation for early researchers.</div></div>","PeriodicalId":411,"journal":{"name":"Progress in Materials Science","volume":"155 ","pages":"Article 101537"},"PeriodicalIF":33.6,"publicationDate":"2025-07-16","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"144645626","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":1,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
{"title":"A review of recent advances in Ce3+-activated garnet phosphors for blue-chip-pumped pc-WLEDs","authors":"Xiaoyuan Chen, Xiaoyong Huang","doi":"10.1016/j.pmatsci.2025.101535","DOIUrl":"10.1016/j.pmatsci.2025.101535","url":null,"abstract":"<div><div>Inorganic luminescent materials are highly demanded for solid-state white lighting. Rare-earth Ce<sup>3+</sup> ions activated garnet phosphors, as one of the most promising luminescent materials, have received tremendous attention for their potential applications in phosphor-converted white light-emitting diodes (pc-WLEDs), due to their high absorption efficiency, remarkable multi-color emissions, broadband emission spectra, high luminescence efficiencies, and excellent thermal stability. In this paper, recent advances in the developments of Ce<sup>3+</sup>-activated garnet phosphors for pc-WLEDs are reviewed. Firstly, the working principle of pc-WLEDs, the structural composition of garnet, the photoluminescence theory of Ce<sup>3+</sup> ions, as well as the dominated factors affecting thermal stability and related thermal quenching mechanisms are highlighted. Secondly, several different synthesis methods of Ce<sup>3+</sup>-activated garnet phosphors are thoroughly elaborated, and the effects of these methods on the micro/nanoscale morphologies and luminescence properties are discussed. Thirdly, photoluminescence characteristics and thermal stability, as well as color stability of various color-emitting Ce<sup>3+</sup>-activated garnet phosphors together with their functional applications in pc-WLEDs are systematically summarized. Last, the remaining challenges and future development prospects of Ce<sup>3+</sup>-activated garnet phosphors in solid-state lighting are provided.</div></div>","PeriodicalId":411,"journal":{"name":"Progress in Materials Science","volume":"155 ","pages":"Article 101535"},"PeriodicalIF":33.6,"publicationDate":"2025-07-12","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"144611470","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":1,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Jing Bai , Baochun Guo , Ming Tian , Fei Chen , Liqun Zhang
{"title":"Dynamic crosslinked elastomers and rubbers","authors":"Jing Bai , Baochun Guo , Ming Tian , Fei Chen , Liqun Zhang","doi":"10.1016/j.pmatsci.2025.101536","DOIUrl":"10.1016/j.pmatsci.2025.101536","url":null,"abstract":"<div><div>Classical rubbers and elastomers are normally prepared via a crosslinking process such as vulcanization, which can produce permanent covalently crosslinked structures and endows mechanical robustness, chemical resistance and thermal stability. However, the permanent covalently crosslinked networks make rubbers and elastomers cannot be reprocessed, reshaped or recycled,<!--> <!-->causing serious pollution and negative impacts on the environment. The design of dynamic covalent crosslinked structures in polymers brings new properties to classical rubber and elastomer materials, in particular in terms of thermal responses, reprocessability and recycling abilities.<!--> <!-->In recent years, there has been a<!--> <!-->growing interest in the design and synthesis of dynamic crosslinked polymers. In this review, the designs, characterizations, and utilizations of dynamic crosslinked elastomers and rubbers are summarized, focusing on the design and synthesis of dynamic crosslinked elastomers and rubbers with sustainability and recyclability, followed by an overview of the applications of dynamic crosslinked elastomers and rubbers. Furthermore, through the tuning and controlling on the dynamic crosslinked structure variedly, some functional behaviors can be realized. To declare and promote the consequence and potential utilization of the dynamic crosslinked elastomers and rubbers, perspectives and suggestions are presented for future research on the design, synthesis, and process strategies of dynamic crosslinked elastomers and rubbers.</div></div>","PeriodicalId":411,"journal":{"name":"Progress in Materials Science","volume":"155 ","pages":"Article 101536"},"PeriodicalIF":33.6,"publicationDate":"2025-07-11","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"144611471","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":1,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Jieni Fu , Chaofeng Wang , Xiangmei Liu , Shengli Zhu , Yufeng Zheng , Zhaoyang Li , Zhenduo Cui , Yu Zhang , Hui Jiang , Yongping Cao , Paul K Chu , Shuilin Wu
{"title":"Smart responsive materials for antibacterial therapy: Progress, opportunities, and challenges","authors":"Jieni Fu , Chaofeng Wang , Xiangmei Liu , Shengli Zhu , Yufeng Zheng , Zhaoyang Li , Zhenduo Cui , Yu Zhang , Hui Jiang , Yongping Cao , Paul K Chu , Shuilin Wu","doi":"10.1016/j.pmatsci.2025.101532","DOIUrl":"10.1016/j.pmatsci.2025.101532","url":null,"abstract":"<div><div>Bacterial infections threaten global human health, driving the rapid development of antibacterial materials over the past two decades. However, the clinical application is limited due to the rapid presence of antibiotic-resistant bacteria and the brutal penetration of biofilm. ’Smart’ responsive antibacterial materials (SRAMs) that respond to endogenous/exogenous stimuli to release antibacterial factors are appealing therapeutic agents for developing next-generation antibacterial materials. Those materials can evade existing mechanisms associated with acquired drug resistance and could also provide an alternative strategy to treat biofilms due to their spatiotemporal controllability and negligible side effects. SRAMs have emerged as a promising tool to combat bacterial infections that are difficult to treat. To better understand the interaction between SRAMs and biological tissues, this review highlights the mechanisms underlying SRAM-mediated eradication of both planktonic bacteria and biofilms and recent advances in designing SRAMs that respond to internal/external stimuli. Meanwhile, we also summarize the latest progress in the development of SRAMs. Properties of internal- or external-stimuli-responsive smart antibacterial materials are outlined, and we also discuss the potential features required for antibacterial applications of various infectious diseases. Furthermore, it also discussed the current challenges and future prospects, particularly emphasizing clinical translation for these smart antimicrobial platforms.</div></div>","PeriodicalId":411,"journal":{"name":"Progress in Materials Science","volume":"155 ","pages":"Article 101532"},"PeriodicalIF":33.6,"publicationDate":"2025-07-10","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"144594796","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":1,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Zaigham Saeed Toor , Renhao Wu , Muhammad Raihan Hashmi , Jeong Ah Lee , Xiaoqing Li , Harada Yuji , Haiming Zhang , Hyoung Seop Kim
{"title":"Computation- and process-based design for advanced structural high-entropy alloy development and analyses: A critical review","authors":"Zaigham Saeed Toor , Renhao Wu , Muhammad Raihan Hashmi , Jeong Ah Lee , Xiaoqing Li , Harada Yuji , Haiming Zhang , Hyoung Seop Kim","doi":"10.1016/j.pmatsci.2025.101534","DOIUrl":"10.1016/j.pmatsci.2025.101534","url":null,"abstract":"<div><div>Over the past decades, high-entropy alloys (HEAs) have been rapidly designed, developed, prepared, and tested to achieve superior performance across a multitude of applications. Computational materials science driven design techniques, including molecular dynamics, density functional theory, calculation of phase diagrams, phase-field modeling, crystal plasticity modelling, and artificial intelligence, combined with additive manufacturing and severe plastic deformation, present unprecedented opportunities to tailor microstructural features with remarkable flexibility and feasibility. This integration significantly enhances material properties. This review paper focuses on the computation-driven and processing-guided designs for structural HEAs (SHEAs), focusing on the relationship among materials, processing, microstructures, and properties. A succinct introduction to the computational design of SHEAs is first presented. Following this, we delve into the complex interplay between computational microstructures at various scales and the mechanical properties of SHEAs, revealing the underlying mechanisms. Additionally, we explore the distinctive features, advantages, and practical applications of these promising materials have been further explored. In conclusion, we address the prevailing challenges and anticipate future prospects in this burgeoning field.</div></div>","PeriodicalId":411,"journal":{"name":"Progress in Materials Science","volume":"155 ","pages":"Article 101534"},"PeriodicalIF":33.6,"publicationDate":"2025-07-09","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"144594738","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":1,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Di Shi , Xiang Wang , Yulin Deng , Huaijuan Zhou , Yilong Wang , Paul K. Chu , Jinhua Li
{"title":"Smart micro/nanorobots for drug delivery in the brain","authors":"Di Shi , Xiang Wang , Yulin Deng , Huaijuan Zhou , Yilong Wang , Paul K. Chu , Jinhua Li","doi":"10.1016/j.pmatsci.2025.101533","DOIUrl":"10.1016/j.pmatsci.2025.101533","url":null,"abstract":"<div><div>Pharmacotherapy is the core approach for treating various brain diseases. However, the intricate anatomical structure and the blood–brain barrier (BBB) of the brain present challenges for intracerebral drug delivery and therapeutic efficacy. Although systemic administration and surgical interventions can alleviate symptoms, they are limited by low therapeutic effects and potential adverse side effects. Moreover, due to their complex pathogenesis, insidious development, and deep-seated lesions, brain diseases are difficult to diagnose accurately. To address these challenges, there is an urgent need to develop intelligent nanocarriers that can efficiently load drugs and penetrate the BBB for precise therapy of brain diseases. In this connection, micro/nanorobots (MNRs) are multifunctional drug carriers at the micro-nano scale, which possess exceptional penetration and targeting capabilities. Employing externally powered propulsion or chemical self-propulsion, MNRs can navigate in the brain and cross the BBB. This review comprehensively summarizes the recent advances and future outlook of smart MNR drug delivery systems for brain disease treatment. It covers broad topics from nanocarriers to active smart MNRs. Furthermore, it elucidates the therapeutic mechanisms of these smart MNR drug delivery systems in brain diseases based on pathogenesis and pathology. Our aim is to provide a reference for designing and developing novel smart MNRs for drug delivery in the brain, paving the way for their clinical applications in treating brain diseases.</div></div>","PeriodicalId":411,"journal":{"name":"Progress in Materials Science","volume":"155 ","pages":"Article 101533"},"PeriodicalIF":33.6,"publicationDate":"2025-07-06","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"144568882","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":1,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Linchao Sun , Zhong Li , Yan Zhang , Yao Lu , Shiguo Zhang
{"title":"Stimuli-responsive shape-morphing soft actuators: metrics, materials, mechanism, design and applications","authors":"Linchao Sun , Zhong Li , Yan Zhang , Yao Lu , Shiguo Zhang","doi":"10.1016/j.pmatsci.2025.101531","DOIUrl":"10.1016/j.pmatsci.2025.101531","url":null,"abstract":"<div><div>The rapid development of flexible wearable devices and the integration of artificial intelligence (AI) in robotics have driven the evolution of soft actuators, positioning soft shape-morphing actuators at the forefront of cutting-edge research in soft robotics, intelligent devices, and bio-inspired engineering. Stimuli-responsive soft actuators are intelligent devices constructed from flexible materials capable of precise and controllable deformation in response to external stimuli, attracting growing scientific and technological interest. This review systematically delineates and evaluates critical performance metrics essential for evaluating actuator functionality. It offers a comprehensive analysis of the predominant stimuli-responsive actuating materials, elucidating their actuation mechanisms while critically examining their inherent advantages, limitations, and emerging research trajectories. Fundamental design principles are meticulously articulated to guide the development of next-generation shape-morphing actuators. Furthermore, this review extensively surveys diverse practical applications, underscoring the versatility and broad technological impact of stimuli-responsive soft actuators across multiple domains. Finally, key challenges in the current state-of-the-art and prospective research pathways are thoroughly discussed, aiming to foster the development and widespread adoption of soft actuators in both academic research and industrial applications.</div></div>","PeriodicalId":411,"journal":{"name":"Progress in Materials Science","volume":"155 ","pages":"Article 101531"},"PeriodicalIF":33.6,"publicationDate":"2025-07-05","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"144566676","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":1,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Hanpeng Gao , Zetian Xing , Siyu Chang , Fangyi Zhao , Honglin Zhang , Zong Meng , Zhiwu Han , Yan Liu
{"title":"Bioinspired multifunctional antifogging surfaces: Progress, AI design and challenges","authors":"Hanpeng Gao , Zetian Xing , Siyu Chang , Fangyi Zhao , Honglin Zhang , Zong Meng , Zhiwu Han , Yan Liu","doi":"10.1016/j.pmatsci.2025.101530","DOIUrl":"10.1016/j.pmatsci.2025.101530","url":null,"abstract":"<div><div>Over the past few decades, various antifogging strategies and preparation methods have been proposed. Unfortunately, a surface with a single antifogging function cannot achieve a wide range of practical applications. For example, medical endoscopes require antifogging and antibacterial capabilities to improve diagnostic accuracy and safety. Inspired by the near-perfect multifunctional properties of natural creatures, antifogging materials with specific functions have drawn more and more attention owing to their promising and wide applications. However, the design of bioinspired antifogging surfaces with broad applicability still presents some challenges, such as the integration of multifunctional properties, and the optimization of preparation routes. In this review, beginning with the fogging mechanism and wettability theory, the latest antifogging surface materials and pattern designs are analyzed in detail and critically evaluated. The natural biomaterials with multifunctional characteristics are summarized, and the integration mechanism and design difficulties of the four multifunctional characteristics are then emphatically analyzed. Based on artificial intelligence (AI) assisted design optimization, we introduce the neural network into the bionic multifunction antifogging path realization for the first time and summarize the antifogging prototype and antifogging multifunction database. Finally, the challenges and future trends of bioinspired multifunction antifogging surfaces (MF-AFS) are presented.</div></div>","PeriodicalId":411,"journal":{"name":"Progress in Materials Science","volume":"155 ","pages":"Article 101530"},"PeriodicalIF":33.6,"publicationDate":"2025-07-02","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"144533707","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":1,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}