Progress in Materials Science最新文献

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An invisible dartboard: Commercialization targets for metal and anode-free batteries 看不见的飞镖:金属和无阳极电池的商业化目标
IF 4 1区 材料科学
Progress in Materials Science Pub Date : 2025-09-11 DOI: 10.1016/j.pmatsci.2025.101580
Emily Cooper , Lingbing Ran , Ian Gentle , Ruth Knibbe
{"title":"An invisible dartboard: Commercialization targets for metal and anode-free batteries","authors":"Emily Cooper ,&nbsp;Lingbing Ran ,&nbsp;Ian Gentle ,&nbsp;Ruth Knibbe","doi":"10.1016/j.pmatsci.2025.101580","DOIUrl":"10.1016/j.pmatsci.2025.101580","url":null,"abstract":"<div><div>Alkali metal batteries (MBs) and anode-free batteries (AFBs) can offer high energy density and simple construction for future electric vehicles. The short lifespan of these batteries is regularly labelled as a significant commercialization barrier, however no clear targets have been defined. In this Snapshot Review, we determine lifespan and other targets for Li- and Na-MBs and AFBs using NMC Li-ion batteries (Li-IBs) as a benchmark. AFBs require lifespans over 1400 cycles to reach Li-IB parity, but currently last only a few hundred cycles. MBs are closer to parity, though large manufacturing challenges remain. Additionally, we assess other requirements including thermal operating ranges, fast charging thresholds, and fabrication demands which must be addressed in MB and AFB research to better match electric vehicle operation. These clear targets will align our efforts to bring these next-generation technologies out of the lab and into mainstream application.</div></div>","PeriodicalId":411,"journal":{"name":"Progress in Materials Science","volume":"156 ","pages":"Article 101580"},"PeriodicalIF":40.0,"publicationDate":"2025-09-11","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"145043628","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":1,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Fiber-based electrochemical sweat sensors toward personalized monitoring 基于纤维的电化学汗液传感器实现个性化监测
IF 4 1区 材料科学
Progress in Materials Science Pub Date : 2025-09-09 DOI: 10.1016/j.pmatsci.2025.101579
Zixu Chang , Faqiang Wang , Zongqian Wang , Jianyong Yu , Bin Ding , Zhaoling Li
{"title":"Fiber-based electrochemical sweat sensors toward personalized monitoring","authors":"Zixu Chang ,&nbsp;Faqiang Wang ,&nbsp;Zongqian Wang ,&nbsp;Jianyong Yu ,&nbsp;Bin Ding ,&nbsp;Zhaoling Li","doi":"10.1016/j.pmatsci.2025.101579","DOIUrl":"10.1016/j.pmatsci.2025.101579","url":null,"abstract":"<div><div>As skin-interfaced wearable sensors undergo rapid evolution, the real-time and non-invasive detection of health-pertinent biomarkers in human sweat has emerged as a cornerstone for gaining profound insights into our physiological status and fostering the development of tailored healthcare systems. Electrochemical sweat sensors (ECSSs) are under high pursuit for their unparalleled capabilities to enable high-performance health monitoring, movement tracking, and predictive parsing in an accurate and continuous manner. Within the realm of ECSSs fabrication, fiber materials have been served as ideal alternatives owing to their characteristic advantages. This review provides a comprehensive overview of ECSSs constructed with fiber materials for portable personalized monitoring. Initially, the recent advancements in selection of functional constructing materials, fabrication methods, and sensing mechanisms are thoughtfully demonstrated. Subsequently, hybrid multiplexed and multimodal sensors are presented, along with considerations for developing integrated electrochemical sensing systems for emerging wearable applications. Furthermore, the potential challenges and future perspectives of fiber-based ECSSs are outlined, aiming to inspire readers with insightful ideas.</div></div>","PeriodicalId":411,"journal":{"name":"Progress in Materials Science","volume":"156 ","pages":"Article 101579"},"PeriodicalIF":40.0,"publicationDate":"2025-09-09","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"145017729","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":1,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Advanced strategies to boost sustainable high-rate Ni-rich cathodes toward durable LIBs 先进的策略,促进可持续的高速率富镍阴极到耐用的锂离子电池
IF 4 1区 材料科学
Progress in Materials Science Pub Date : 2025-09-08 DOI: 10.1016/j.pmatsci.2025.101574
Parnaz Asghari , Farshad Boorboor Ajdari , Fereshteh Abbasi , Sasan Rostami , Ali Asghar Sadeghi Ghazvini , Ali Molaei Aghdam
{"title":"Advanced strategies to boost sustainable high-rate Ni-rich cathodes toward durable LIBs","authors":"Parnaz Asghari ,&nbsp;Farshad Boorboor Ajdari ,&nbsp;Fereshteh Abbasi ,&nbsp;Sasan Rostami ,&nbsp;Ali Asghar Sadeghi Ghazvini ,&nbsp;Ali Molaei Aghdam","doi":"10.1016/j.pmatsci.2025.101574","DOIUrl":"10.1016/j.pmatsci.2025.101574","url":null,"abstract":"<div><div>The rapid rise in demand for high-performance lithium-ion batteries (LIBs) highlights the importance of high-rate nickel-rich cathode materials as a key step toward next-generation LIBs, offering high discharge capacity, increased energy density, stable operating voltage, and cost-effectiveness. However, issues such as cation mixing, side reactions, microcrack formation, and thermal instability limit their rate capability and long-term durability. This review provides a detailed assessment of these challenges. It outlines strategies to overcome them, including surface coating, doping, core–shell structures, full-concentration gradients, and particle or additive engineering. Surface coatings improve surface stability and ion transport, while doping methods, including pillar and gradient doping, reduce cation mixing and strengthen structural stability. Core–shell and full-concentration gradients designs relieve mechanical stress and suppress phase transitions, and advanced particle engineering reduces microcrack formation. Computational tools such as density functional theory and machine learning, together with <em>in-situ</em> characterization, provide valuable insights into degradation mechanisms, enabling more precise material optimization. Importantly, combined and modified approaches that integrate multiple strategies show the greatest potential to address these challenges while maintaining sustainability and scalability. This work clarifies operational mechanisms, aiding researchers in developing advanced high-rate Ni-rich cathode LIBs for future energy storage.</div></div>","PeriodicalId":411,"journal":{"name":"Progress in Materials Science","volume":"156 ","pages":"Article 101574"},"PeriodicalIF":40.0,"publicationDate":"2025-09-08","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"145017730","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":1,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Advancing ionic thermoelectric materials for heat recovery 热回收离子热电材料的研究进展
IF 4 1区 材料科学
Progress in Materials Science Pub Date : 2025-09-06 DOI: 10.1016/j.pmatsci.2025.101575
Yifan Wang , Ibrahim Mwamburi Mwakitawa , Hao Yang , Mingyu Song , Qian Huang , Xinzhe Li , Pengchi Zhang , Wei Fang , Lijun Hu , Yongli Zhou , Chen Li , Jianyong Ouyang , Kuan Sun
{"title":"Advancing ionic thermoelectric materials for heat recovery","authors":"Yifan Wang ,&nbsp;Ibrahim Mwamburi Mwakitawa ,&nbsp;Hao Yang ,&nbsp;Mingyu Song ,&nbsp;Qian Huang ,&nbsp;Xinzhe Li ,&nbsp;Pengchi Zhang ,&nbsp;Wei Fang ,&nbsp;Lijun Hu ,&nbsp;Yongli Zhou ,&nbsp;Chen Li ,&nbsp;Jianyong Ouyang ,&nbsp;Kuan Sun","doi":"10.1016/j.pmatsci.2025.101575","DOIUrl":"10.1016/j.pmatsci.2025.101575","url":null,"abstract":"<div><div>Ionic thermoelectrics (i-TEs) are emerging as a promising, sustainable technology for low-grade heat recovery, notable for their absence of moving mechanical parts. In recent years, significant advancements in i-TE materials and devices have been propelled by their advantages in thermal power generation, compatibility with room-temperature operation, and potential for integration into flexible, wearable devices. However, challenges remain to be addressed for practical future applications, primarily due to insufficient evaluations of innovative operational modes and materials. This review aims to bridge this gap by summarizing key existing theories and providing an in-depth analysis of ion migration mechanisms within i-TE capacitors. We also highlight significant contributions from leading studies, focusing on material selection, operational modes, performance characteristics, and pivotal discoveries. Ultimately, this review seeks to identify transformative approaches in i-TEs to foster innovative designs for practical applications.</div></div>","PeriodicalId":411,"journal":{"name":"Progress in Materials Science","volume":"156 ","pages":"Article 101575"},"PeriodicalIF":40.0,"publicationDate":"2025-09-06","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"145007200","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":1,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Elaborately designed intelligent responsive sensing materials for development of flexible gas sensors 为开发柔性气体传感器精心设计了智能响应传感材料
IF 4 1区 材料科学
Progress in Materials Science Pub Date : 2025-09-04 DOI: 10.1016/j.pmatsci.2025.101565
Yonghui Deng , Luyang Liu , Yidan Chen , Yu Deng , Jichun Li , Xiaoqing Liu , Yidong Zou , Limin Wu , Wenhe Xie
{"title":"Elaborately designed intelligent responsive sensing materials for development of flexible gas sensors","authors":"Yonghui Deng ,&nbsp;Luyang Liu ,&nbsp;Yidan Chen ,&nbsp;Yu Deng ,&nbsp;Jichun Li ,&nbsp;Xiaoqing Liu ,&nbsp;Yidong Zou ,&nbsp;Limin Wu ,&nbsp;Wenhe Xie","doi":"10.1016/j.pmatsci.2025.101565","DOIUrl":"10.1016/j.pmatsci.2025.101565","url":null,"abstract":"<div><div>With the development of artificial intelligence and Internet of Things, flexible gas sensors have emerged as vital functional devices by integrating with smart wearable electronics, which exhibit irreplaceable advantages in medical diagnosis, aerospace, environmental remediation, robotics, and electronic skin. The elaborately designed sensing materials are critical to developing high-performance gas sensors in terms of sensitivity, selectivity, stability, and response/recovery dynamics. In addition, to achieve the reliable and consistent operation of the flexible sensing devices, it is essential to ensure an effective and stable integration between sensing materials and device substrates. Consequently, it is distinctly meaningful to comprehensively summarize the design principles and surface properties of gas-sensitive materials in flexible gas sensors. This review originates from the precise synthesis, regulation and structure optimization of sensing materials for flexible gas sensors, and the new concept of “chemical microenvironment” is proposed to elucidate the sensing mechanism from molecular-atomic level. Specifically, various carrier migration models (e.g., electron, proton, ion) and surface/interfacial interaction are highlighted. Finally, the emerging opportunities and challenges in flexible gas sensors are proposed and predicted, aiming to provide insight about the development of flexible gas sensors into the next-generation sensing applications and further satisfy the growing requirements of smart sensors for long-life, biocompatibility, and real-time communication capabilities.</div></div>","PeriodicalId":411,"journal":{"name":"Progress in Materials Science","volume":"156 ","pages":"Article 101565"},"PeriodicalIF":40.0,"publicationDate":"2025-09-04","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"144995178","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":1,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Peptide-based co-assembling materials: bridging fundamental science and versatile applications 肽基共组装材料:桥梁基础科学和多功能应用
IF 4 1区 材料科学
Progress in Materials Science Pub Date : 2025-09-01 DOI: 10.1016/j.pmatsci.2025.101562
Xin Su , Bingbing Yang , Liqin Chen, Qingxi Liu, Anfeng Liu, Mei-Ling Tan, Wei Ji
{"title":"Peptide-based co-assembling materials: bridging fundamental science and versatile applications","authors":"Xin Su ,&nbsp;Bingbing Yang ,&nbsp;Liqin Chen,&nbsp;Qingxi Liu,&nbsp;Anfeng Liu,&nbsp;Mei-Ling Tan,&nbsp;Wei Ji","doi":"10.1016/j.pmatsci.2025.101562","DOIUrl":"10.1016/j.pmatsci.2025.101562","url":null,"abstract":"<div><div>Inspired by biomolecular assembly in natural systems, peptides have emerged as building blocks for constructing diverse structures and materials through bottom-up self-assembly approach. However, it remains a challenge to manipulate the peptide supramolecular architectures and expand their functionality for versatile applications. Notably, co-assembly strategy provides a promising solution as it enables the integration of multiple components into extended architectural space and functional diversity of peptide-based materials. Herein, a comprehensive review is proposed to summarize the design principles and recent advances of peptide-based co-assembling materials for applications in biomedicine and nanotechnology. First, the design strategies and assembly mechanism of peptide co-assembly are introduced. Next, an overview of nanostructures formed by peptide co-assembly is summarized, ranging from nanoparticles, nanotubes, nanorods, nanoribbons to hydrogels. Subsequently, the various applications of peptide co-assembling materials are provided in details, including anticancer treatment, tissue engineering, wound healing, gene delivery, catalysis, functional electronic components, and adhesive. Finally, remaining challenges and future prospects in peptide co-assembly are discussed. It is believed that this review bridges fundamental co-assembly science with extensive applications, providing new insights for rational design and development of innovative peptide-based biomaterials in the future.</div></div>","PeriodicalId":411,"journal":{"name":"Progress in Materials Science","volume":"156 ","pages":"Article 101562"},"PeriodicalIF":40.0,"publicationDate":"2025-09-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"144928481","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":1,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Recent advances and remaining challenges of solid-state electrolytes for lithium batteries 锂电池固态电解质的最新进展与挑战
IF 4 1区 材料科学
Progress in Materials Science Pub Date : 2025-08-30 DOI: 10.1016/j.pmatsci.2025.101559
Qing Qiao , Yingxue Li , Chang Song , Mariyam Niyaz , Yang Zhang , Songqiang Zhu , Tengfei Zhang , Weiming Teng , Hongge Pan , Xuebin Yu
{"title":"Recent advances and remaining challenges of solid-state electrolytes for lithium batteries","authors":"Qing Qiao ,&nbsp;Yingxue Li ,&nbsp;Chang Song ,&nbsp;Mariyam Niyaz ,&nbsp;Yang Zhang ,&nbsp;Songqiang Zhu ,&nbsp;Tengfei Zhang ,&nbsp;Weiming Teng ,&nbsp;Hongge Pan ,&nbsp;Xuebin Yu","doi":"10.1016/j.pmatsci.2025.101559","DOIUrl":"10.1016/j.pmatsci.2025.101559","url":null,"abstract":"<div><div>All-solid-state lithium batteries (ASSLBs) have garnered significant attention as a next-generation energy storage technology, providing superior safety, enhanced stability, and high energy density. However, current research predominantly remains confined to laboratory-scale demonstrations, with limited translation into scalable technological solutions. Addressing this academia-industry disconnect is critical to unlocking the commercial viability of ASSLBs. This review focuses on bridging this gap by systematically analyzing advancements in solid-state electrolytes (SSEs)—the cornerstone of ASSLB technology. We delve into the structural characteristics, ion transport mechanisms, and performance metrics of various SSEs, alongside a comprehensive summary of modification strategies. Beyond theoretical advancements, we emphasize the practical implications of these strategies in addressing energy density limitations, interfacial instability, and safety concerns. A distinctive feature of this review lies in its multidimensional analysis of early-stage ASSLB industrialization hurdles, integrating perspectives from materials synthesis scalability, electrode processing innovations, device-level performance validation, advanced characterization methodologies, and application-specific requirements. This work not only maps current research frontiers but also establishes actionable guidelines for academia–industry collaboration, offering scientists a roadmap for targeted innovation and equipping enterprises with evidence-based insights to streamline technology development and commercialization strategies.</div></div>","PeriodicalId":411,"journal":{"name":"Progress in Materials Science","volume":"156 ","pages":"Article 101559"},"PeriodicalIF":40.0,"publicationDate":"2025-08-30","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"144920904","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":1,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Advanced fast-charging anode designs for sodium-ion batteries 用于钠离子电池的先进快速充电阳极设计
IF 4 1区 材料科学
Progress in Materials Science Pub Date : 2025-08-29 DOI: 10.1016/j.pmatsci.2025.101564
Jiaxin Wang , Yanling Yang , Jingeng Chen , Xiao-Lei Shi , Yu Sun , Xuefeng Tian , Hao Che , Yuefeng Chen , Zhi-Gang Chen
{"title":"Advanced fast-charging anode designs for sodium-ion batteries","authors":"Jiaxin Wang ,&nbsp;Yanling Yang ,&nbsp;Jingeng Chen ,&nbsp;Xiao-Lei Shi ,&nbsp;Yu Sun ,&nbsp;Xuefeng Tian ,&nbsp;Hao Che ,&nbsp;Yuefeng Chen ,&nbsp;Zhi-Gang Chen","doi":"10.1016/j.pmatsci.2025.101564","DOIUrl":"10.1016/j.pmatsci.2025.101564","url":null,"abstract":"<div><div>Sodium-ion batteries (SIBs) are emerging as a promising next-generation fast-charging technology due to their abundant raw resources, low cost, and low desolvation energy advantages that are especially beneficial under low-temperature conditions. However, achieving ultra-fast charging (i.e., charging times under 15 min) remains challenging. The kinetics of Na<sup>+</sup> ions are primarily hindered by Na<sup>+</sup> desolvation sluggish, restricted ion transport within the solid electrolyte interphase (SEI), and slow solid-state diffusion in the anode. Moreover, several fundamental challenges, such as significant volume changes during sodiation/desodiation and interfacial chemistry-induced side reactions, are further exacerbated. This review provides a comprehensive analysis of the key factors limiting the fast-charging capability of SIB anodes and outlines targeted optimization strategies, including bulk structure engineering, synergistic electrolyte design, and the controlled formation of favorable SEI layers. Representative case studies are presented to illustrate both the challenges and recent advances. Finally, this review presents future perspectives and potential pathways to guide the rational design of advanced fast-charging anode materials for SIBs.</div></div>","PeriodicalId":411,"journal":{"name":"Progress in Materials Science","volume":"156 ","pages":"Article 101564"},"PeriodicalIF":40.0,"publicationDate":"2025-08-29","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"144919105","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":1,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
A comprehensive review on nature-inspired redox systems based on humic acids: Bridging microbial electron transfer and high-performance supercapacitors 基于腐植酸的自然激发氧化还原系统综述:桥接微生物电子转移和高性能超级电容器
IF 4 1区 材料科学
Progress in Materials Science Pub Date : 2025-08-24 DOI: 10.1016/j.pmatsci.2025.101563
Fangzhi Jiang , Ziyao Mu , Chenxu Zhang , Liang Deng , Xuecheng Zhang , Yaya Sun , He Liu , Xuedong Zhang , Salma Tabassum , Hongbo Liu
{"title":"A comprehensive review on nature-inspired redox systems based on humic acids: Bridging microbial electron transfer and high-performance supercapacitors","authors":"Fangzhi Jiang ,&nbsp;Ziyao Mu ,&nbsp;Chenxu Zhang ,&nbsp;Liang Deng ,&nbsp;Xuecheng Zhang ,&nbsp;Yaya Sun ,&nbsp;He Liu ,&nbsp;Xuedong Zhang ,&nbsp;Salma Tabassum ,&nbsp;Hongbo Liu","doi":"10.1016/j.pmatsci.2025.101563","DOIUrl":"10.1016/j.pmatsci.2025.101563","url":null,"abstract":"<div><div>Humic acids (HAs) have attracted increasing attentions owing to their vibrant bioelectrochemical activities. Although recent research on HAs demonstrated their ability to promote electron transfer via quinone and phenolic moieties, which allow them to perform various functions in metal immobilization, microbial energy metabolism, and pollutant degradation. The underlying redox mechanisms are still unclear and occasionally reported as contradictory. According to this study, electron shuttling and metal ion-mediated internal electron “bridges” are probably essential to the functional roles of HAs in microbial systems. As natural redox mediators and electron conductors, HAs facilitate microbial metabolism and enhance redox efficiency through direct and indirect pathways. Furthermore, in bioelectrochemical systems, HAs serve as effective electrode modifiers or electron transfer enhancers, improving charge storage and transport efficiency. However,<!--> <!-->numerous unresolved queries remain regarding their structure–function interactions, synergies with conductive materials, and microscale electron transport behavior. Existing research often overlooks the structural and performance instability of HAs under different environmental conditions, leading to reduced predictability of its application effectiveness. Future research should explore the mechanisms underlying HAs’ role in microbial community succession and the dynamic changes in electron transfer pathways to provide innovative strategies for sustainable development.</div></div>","PeriodicalId":411,"journal":{"name":"Progress in Materials Science","volume":"156 ","pages":"Article 101563"},"PeriodicalIF":40.0,"publicationDate":"2025-08-24","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"144932297","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":1,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Towards preferential lithium recovery from spent lithium-ion batteries: phase transition mechanisms, technical innovation and future perspectives 从废锂离子电池中优先回收锂:相变机制、技术创新和未来展望
IF 4 1区 材料科学
Progress in Materials Science Pub Date : 2025-08-22 DOI: 10.1016/j.pmatsci.2025.101557
Mengyu Lin , Yongqiang Chen , Chengyan Wang , Shengming Xu , Jialiang Zhang
{"title":"Towards preferential lithium recovery from spent lithium-ion batteries: phase transition mechanisms, technical innovation and future perspectives","authors":"Mengyu Lin ,&nbsp;Yongqiang Chen ,&nbsp;Chengyan Wang ,&nbsp;Shengming Xu ,&nbsp;Jialiang Zhang","doi":"10.1016/j.pmatsci.2025.101557","DOIUrl":"10.1016/j.pmatsci.2025.101557","url":null,"abstract":"<div><div>Lithium is an indispensable element for the sustainable development of the new energy industry. However, the strong market demand for LIBs has led to a shortage of lithium resources. Recycling lithium from spent LIBs is an effective approach to alleviate the lithium shortage. However, LIBs are all artificially synthesized complex materials, and phase transition is an indispensable pathway to extract lithium selectively and efficiently. The phase transition methods can be divided into two types: lithium selective leaching in the liquid phase and lithium preferential extraction in the solid phase. This review systematically summarizes the available methods for selective lithium recovery and analyzes the phase transition mechanism from a thermodynamic perspective. The environmental impact and economic benefits analysis were presented for selective lithium extraction methods in liquid phase systems. Innovatively, the “reactivity-selectivity principle” was first employed to evaluate the main solid phase transition methods, indicating the importance of phase transition control for higher lithium recovery efficiency and selectivity. Finally, the prospects of lithium recycling development were outlined from four dimensions of technological innovation, entire-process optimization, economical efficiency and environmental friendliness. This review aims to provide references and enlightenment for the efficient recycling of spent LIBs from the perspective of phase transition and assist in the healthy and long-term development of new energy industry.</div></div>","PeriodicalId":411,"journal":{"name":"Progress in Materials Science","volume":"156 ","pages":"Article 101557"},"PeriodicalIF":40.0,"publicationDate":"2025-08-22","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"144916650","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":1,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
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