Progress in Materials Science最新文献

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Bridging biodegradable metals and biodegradable polymers: A comprehensive review of biodegradable metal–organic frameworks for biomedical application 桥接生物可降解金属和生物可降解聚合物:生物医学应用的生物可降解金属-有机框架的综合综述
IF 33.6 1区 材料科学
Progress in Materials Science Pub Date : 2025-06-15 DOI: 10.1016/j.pmatsci.2025.101526
Ting Zhang , Yameng Yu , Yupu Lu , Hao Tang , Kai Chen , Jiahui Shi , Zeqi Ren , Shuilin Wu , Dandan Xia , Yufeng Zheng
{"title":"Bridging biodegradable metals and biodegradable polymers: A comprehensive review of biodegradable metal–organic frameworks for biomedical application","authors":"Ting Zhang ,&nbsp;Yameng Yu ,&nbsp;Yupu Lu ,&nbsp;Hao Tang ,&nbsp;Kai Chen ,&nbsp;Jiahui Shi ,&nbsp;Zeqi Ren ,&nbsp;Shuilin Wu ,&nbsp;Dandan Xia ,&nbsp;Yufeng Zheng","doi":"10.1016/j.pmatsci.2025.101526","DOIUrl":"10.1016/j.pmatsci.2025.101526","url":null,"abstract":"<div><div>Metal-organic frameworks (MOFs) represent a category of intricate coordination polymers that are formed by the deliberate assembly of metal ions/clusters with organic ligands via coordination bonds. Their hybrid inorganic–organic composition and programmable structural adaptability endow them with multifunctionality. This integration enables degradation-controlled release of bioactive components, positioning MOFs as a uniquely versatile platform for biomedical applications. This review systematically outlines the structural taxonomy of MOFs and underscores their transformative potential in pharmaceutical delivery, therapeutic interventions, and biomedical imaging applications. The degradation behavior of MOFs is systematically summarized, as it governs the controlled release of guest molecules and metal ions, critically influencing their biosafety and therapeutic efficacy. Therefore, we further summarize the impacts of MOF degradation products in both <em>in vitro</em> and <em>in vivo</em> environments. Finally, we outline the challenges in translating laboratory findings into clinical products, and propose future research directions, so that to guide the rational design and construction of MOF-based biomedical platforms.</div></div>","PeriodicalId":411,"journal":{"name":"Progress in Materials Science","volume":"155 ","pages":"Article 101526"},"PeriodicalIF":33.6,"publicationDate":"2025-06-15","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"144290013","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":1,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Recent progress on segregated polymer composites for functional applications 功能型分离聚合物复合材料研究进展
IF 33.6 1区 材料科学
Progress in Materials Science Pub Date : 2025-06-14 DOI: 10.1016/j.pmatsci.2025.101524
Yue-Yi Wang , Jie Li , Li-Chuan Jia , Jun Lei , Ding-Xiang Yan , Zhong-Ming Li
{"title":"Recent progress on segregated polymer composites for functional applications","authors":"Yue-Yi Wang ,&nbsp;Jie Li ,&nbsp;Li-Chuan Jia ,&nbsp;Jun Lei ,&nbsp;Ding-Xiang Yan ,&nbsp;Zhong-Ming Li","doi":"10.1016/j.pmatsci.2025.101524","DOIUrl":"10.1016/j.pmatsci.2025.101524","url":null,"abstract":"<div><div>Polymer composites embedded with functional particles (e.g., conductive, thermally conductive, or magnetic fillers) integrate the processability of polymers with the tailored functionalities of these additives. However, conventional composites often necessitate excessively high loadings to establish percolation networks, leading to challenges such as increased costs, diminished mechanical performance, and compromised processability. Segregated structures-where particles are selectively localized at polymer domain interfaces-significantly enhance filler utilization efficiency, outperforming traditional composites with uniformly dispersed particles. Since our group’s seminal 2014 review on electrically conductive segregated polymer composites, extensive advancements have been achieved across diverse applications, including electromagnetic interference shielding, thermal management, and gas barriers. Innovative processing strategies have also been tailored to accommodate various polymer matrices. Despite these breakthroughs, critical gaps persist in understanding the mechanistic interplay and scalable fabrication of multifunctional segregated systems. This review systematically synthesizes the progress in segregated polymer composites over the past decade, emphasizing novel fabrication techniques, matrix-dependent design principles, and emerging functional applications. We critically analyze persistent challenges-such as interfacial control, and scalability-alongside recent solutions and evolving research trends. By elucidating structure–property correlations and offering actionable design guidelines, this work aims to drive the broader adoption of segregated structures and accelerate the development of next-generation high-performance functional materials.</div></div>","PeriodicalId":411,"journal":{"name":"Progress in Materials Science","volume":"155 ","pages":"Article 101524"},"PeriodicalIF":33.6,"publicationDate":"2025-06-14","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"144288468","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":1,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Advances in morphological and interfacial tuning of metal oxides for electrochemical CO2 conversion 电化学CO2转化金属氧化物的形态和界面调整研究进展
IF 33.6 1区 材料科学
Progress in Materials Science Pub Date : 2025-06-12 DOI: 10.1016/j.pmatsci.2025.101522
Lu Liu , Younes Ahmadi , Young-Hoon Kim , Ki-Hyun Kim
{"title":"Advances in morphological and interfacial tuning of metal oxides for electrochemical CO2 conversion","authors":"Lu Liu ,&nbsp;Younes Ahmadi ,&nbsp;Young-Hoon Kim ,&nbsp;Ki-Hyun Kim","doi":"10.1016/j.pmatsci.2025.101522","DOIUrl":"10.1016/j.pmatsci.2025.101522","url":null,"abstract":"<div><div>The electrochemical CO<sub>2</sub> reduction reaction (CO<sub>2</sub>RR) has been recognized as a highly promising technological approach for realizing carbon capture and utilization. A plethora of metal-oxide (MO) nanostructures have been designed with the merits of unique crystal structures to achieve noticeable advances in the electrochemical CO<sub>2</sub>RR. However, more efforts are needed to properly elucidate the intricate relationships between their synthesis, structure, and activity. In this perspective, this review centers on: (i) the structural engineering of key factors (e.g., crystal facet, defect, interface, spin, and morphology), (ii) synthesis strategies governing the development of such structural features, (iii) structure–activity relationships, (iv) catalytic mechanisms of multiple proton/electron transfer steps in conversion of CO<sub>2</sub> (e.g., either into C<sub>1</sub> (e.g., CO, CH<sub>4</sub>, and CH<sub>3</sub>OH) or C<sub>2+</sub> products (e.g., C<sub>2</sub>H<sub>4</sub>, C<sub>2</sub>H<sub>6</sub>, C<sub>2</sub>H<sub>5</sub>OH, CH<sub>3</sub>COOH, and C<sub>3</sub>H<sub>7</sub>OH)), and (v) the performance metrics of diverse electrocatalysts (e.g., in terms of Faradaic efficiency, current density, and stability). The factors controlling the catalyst morphology and the adsorption/transfer behavior of the key intermediates are also discussed based on <em>in situ</em>/<em>ex-situ</em> techniques combined with density functional theory. Collectively, this review aims to provide critical insights that can guide the rational design of next-generation MO-based electrocatalysts for efficient and selective CO<sub>2</sub> electroreduction.</div></div>","PeriodicalId":411,"journal":{"name":"Progress in Materials Science","volume":"155 ","pages":"Article 101522"},"PeriodicalIF":33.6,"publicationDate":"2025-06-12","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"144279017","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":1,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Freeze-enabled synthesis of functional materials: fundamental, progress, and applications 冷冻合成功能材料:基础、进展和应用
IF 33.6 1区 材料科学
Progress in Materials Science Pub Date : 2025-06-11 DOI: 10.1016/j.pmatsci.2025.101523
Yunfeng Bai , Haifei Zhang
{"title":"Freeze-enabled synthesis of functional materials: fundamental, progress, and applications","authors":"Yunfeng Bai ,&nbsp;Haifei Zhang","doi":"10.1016/j.pmatsci.2025.101523","DOIUrl":"10.1016/j.pmatsci.2025.101523","url":null,"abstract":"<div><div>Ice-templating, or more broadly, freezing-enabled processing and synthesis, is a highly versatile approach to fabricating a wide range of porous, nanostructured, and functional materials. These materials have been extensively explored in the fields of engineering, energy storage, thermal management, wave shielding, biomedical applications, environmental remediation, and catalytical reactions, etc. The research in this topic has been continuously going strong and indeed has attracted intensive efforts from scientists across diverse research fields in recent years. In this review, we first describe key aspects and key parameters of freezing process and freeze-drying for the preparation of ice-templated materials. The understanding and control of freezing process is essential for many other processes, e.g., cryopreservation, freeze-desalination, although they are not covered in this review. This is followed by the production of biopharmaceuticals by freezing and freeze-drying. We then demonstrate how the freezing process can be applied to prepare a wide range of porous and nanostructured materials, organized by the materials morphologies. We further describe how freezing reaction and the synthesis of functional materials, particularly 2D materials, are enabled via freeze-concentration and catalytic property of ice surface. The applications of the ice-templated materials in diverse fields are then reviewed, with a focus on recent progress and how the ice-templated features and freeze-drying enhance the performance in these applications. This comprehensive review is completed with a conclusion and proposed challenges in moving this research field ahead.</div></div>","PeriodicalId":411,"journal":{"name":"Progress in Materials Science","volume":"155 ","pages":"Article 101523"},"PeriodicalIF":33.6,"publicationDate":"2025-06-11","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"144269209","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":1,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Advances in relaxation and memory effects of magnetic nanoparticles for biomedical applications 磁性纳米颗粒在生物医学应用中的放松和记忆效应研究进展
IF 33.6 1区 材料科学
Progress in Materials Science Pub Date : 2025-06-04 DOI: 10.1016/j.pmatsci.2025.101521
Pinki Singh , Nisha Shankhwar , Aditi Nachnani , Prashant Singh , Upendra Kumar , Satyendra Singh , Chandan Upadhyay
{"title":"Advances in relaxation and memory effects of magnetic nanoparticles for biomedical applications","authors":"Pinki Singh ,&nbsp;Nisha Shankhwar ,&nbsp;Aditi Nachnani ,&nbsp;Prashant Singh ,&nbsp;Upendra Kumar ,&nbsp;Satyendra Singh ,&nbsp;Chandan Upadhyay","doi":"10.1016/j.pmatsci.2025.101521","DOIUrl":"10.1016/j.pmatsci.2025.101521","url":null,"abstract":"<div><div>Functionalized magnetic nanoparticles are pivotal in magnetic resonance imaging, computed tomography, controlled drug delivery, and hyperthermia treatments due to their exceptional magnetic relaxation and functional properties. The magnetic core composition and structure significantly affects the complex magnetic properties of these nanoparticles necessitating a thorough examination of magnetism fundamentals related to these systems. One important aspect is the ability of magnetic nanoparticles to retain previous magnetic state configurations known as memory effect, primarily governed by domain structure and magnetic anisotropy. Despite its relevance to advanced applications, comprehensive studies on magnetic relaxation and memory effects remain limited. The present review aims to bridge this gap by investigating relaxation mechanisms, synthesis strategies, and applications, fostering further innovation. It investigates the memory effects and their dependence on particle composition and morphology along with key synthesis techniques for large-scale production in industrial adoption. Structured into focused sections on magnetic properties and their influence on biomedical and technological applications, this review provides essential insights into memory effects, magneto-relaxation mechanisms, influencing factors, and both experimental and theoretical methodologies. It also delves into computational modelling and AI-driven design, which are revolutionizing the prediction, discovery, and optimization of materials with tailored properties.</div></div>","PeriodicalId":411,"journal":{"name":"Progress in Materials Science","volume":"155 ","pages":"Article 101521"},"PeriodicalIF":33.6,"publicationDate":"2025-06-04","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"144219174","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":1,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Plasmonic metasurfaces: Light-matter interactions, fabrication, applications and future outlooks 等离子体超表面:光-物质相互作用、制造、应用和未来展望
IF 33.6 1区 材料科学
Progress in Materials Science Pub Date : 2025-05-29 DOI: 10.1016/j.pmatsci.2025.101508
Fan Yang , Wei Cao , Guangchao Zheng , Li Qiu , Zhihong Nie , Yue Li
{"title":"Plasmonic metasurfaces: Light-matter interactions, fabrication, applications and future outlooks","authors":"Fan Yang ,&nbsp;Wei Cao ,&nbsp;Guangchao Zheng ,&nbsp;Li Qiu ,&nbsp;Zhihong Nie ,&nbsp;Yue Li","doi":"10.1016/j.pmatsci.2025.101508","DOIUrl":"10.1016/j.pmatsci.2025.101508","url":null,"abstract":"<div><div>Plasmonic metasurfaces (PMs) consist of thin, sub-wavelength layers formed by <em>meta</em>-atoms derived from metallic nanostructures, designed to manipulate the interaction between electromagnetic fields and matter. The collective features of PMs are determined by both the properties of the nanoparticles (NPs) and the symmetry, dimensions, order, and orientation of the underlying superstructure. These combined characteristics enable PMs to play a crucial role in applications such as sensing, energy harvesting, nanolasing, nonlinear optics and surface-enhanced spectroscopy. This review focuses on three main aspects of PMs: light-matter interactions, fabrication methods, and applications. The near-field and far-field optical properties of various plasmonic superstructures, from the simplest individual nanostructures to more complex one-dimensional (1D), two-dimensional (2D), and three-dimensional (3D) PM superstructures, are systematically analyzed. Following this, a summary of the techniques employed for the fabrication of these PMs is provided, covering top-down, bottom-up, and hybrid strategies. The diverse applications of PMs, including their weak and strong coupling with 2D materials, luminescent molecules, chiral molecules, quantum dots (QDs), upconversion materials, and more, are also discussed. The review concludes by highlighting the current challenges and future perspectives in PMs, along with insights into their potential advancements towards the next generation of nanophotonic platforms.</div></div>","PeriodicalId":411,"journal":{"name":"Progress in Materials Science","volume":"154 ","pages":"Article 101508"},"PeriodicalIF":33.6,"publicationDate":"2025-05-29","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"144194532","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":1,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Advances in high-temperature solid oxide electrolysis technology for clean hydrogen and chemical production: materials, cells, stacks, systems and economics 用于清洁氢和化工生产的高温固体氧化物电解技术进展:材料、电池、堆、系统和经济
IF 33.6 1区 材料科学
Progress in Materials Science Pub Date : 2025-05-29 DOI: 10.1016/j.pmatsci.2025.101520
Kyung Joong Yoon , Sanghoon Lee , Sun-Young Park , Nguyen Q. Minh
{"title":"Advances in high-temperature solid oxide electrolysis technology for clean hydrogen and chemical production: materials, cells, stacks, systems and economics","authors":"Kyung Joong Yoon ,&nbsp;Sanghoon Lee ,&nbsp;Sun-Young Park ,&nbsp;Nguyen Q. Minh","doi":"10.1016/j.pmatsci.2025.101520","DOIUrl":"10.1016/j.pmatsci.2025.101520","url":null,"abstract":"<div><div>Solid oxide electrolysis cells (SOECs) are solid-state electrochemical devices that convert electrical energy into chemical energy in the form of H<sub>2</sub>, CO, and O<sub>2</sub> at 500–1000 °C. In recent years, interest in SOECs has soared because they offer extremely efficient and versatile means of producing green hydrogen and chemicals. However, SOEC technology requires further advancements for its successful commercialization. This review aims to comprehensively analyze the entirety of SOEC technology, identifying critical challenges and guiding future research. It covers both technical and economic aspects of all functional units in SOECs, including cells, stacks, and systems, with a particular emphasis on the unique characteristics of high-temperature materials. It clarifies the nano-, micro-, and macroscale phenomena, offering insights into their distinct electrochemical properties and degradation behavior. This paper encompasses both oxygen ion- and proton-conducting SOECs, with a particular focus on materials-related challenges in newly developed protonic ceramics. As for economic perspectives, the viability of further cost reduction and market penetration are discussed based on techno-economic assessments and various applications. Future research directions are outlined by defining key drivers and important areas for improvement for the wide adoption of SOEC technology and its contribution to a more sustainable, efficient energy landscape.</div></div>","PeriodicalId":411,"journal":{"name":"Progress in Materials Science","volume":"154 ","pages":"Article 101520"},"PeriodicalIF":33.6,"publicationDate":"2025-05-29","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"144178268","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":1,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Critical current density in advanced superconductors 先进超导体中的临界电流密度
IF 33.6 1区 材料科学
Progress in Materials Science Pub Date : 2025-05-26 DOI: 10.1016/j.pmatsci.2025.101492
H.S. Ruiz , J. Hänisch , M. Polichetti , A. Galluzzi , L. Gozzelino , D. Torsello , S. Milošević-Govedarović , J. Grbović-Novaković , O.V. Dobrovolskiy , W. Lang , G. Grimaldi , A. Crisan , P. Badica , A.M. Ionescu , P. Cayado , R. Willa , B. Barbiellini , S. Eley , A. Badía–Majós
{"title":"Critical current density in advanced superconductors","authors":"H.S. Ruiz ,&nbsp;J. Hänisch ,&nbsp;M. Polichetti ,&nbsp;A. Galluzzi ,&nbsp;L. Gozzelino ,&nbsp;D. Torsello ,&nbsp;S. Milošević-Govedarović ,&nbsp;J. Grbović-Novaković ,&nbsp;O.V. Dobrovolskiy ,&nbsp;W. Lang ,&nbsp;G. Grimaldi ,&nbsp;A. Crisan ,&nbsp;P. Badica ,&nbsp;A.M. Ionescu ,&nbsp;P. Cayado ,&nbsp;R. Willa ,&nbsp;B. Barbiellini ,&nbsp;S. Eley ,&nbsp;A. Badía–Majós","doi":"10.1016/j.pmatsci.2025.101492","DOIUrl":"10.1016/j.pmatsci.2025.101492","url":null,"abstract":"<div><div>This review paper delves into the concept of critical current density <span><math><mrow><mo>(</mo><msub><mrow><mi>J</mi></mrow><mrow><mi>c</mi></mrow></msub><mo>)</mo></mrow></math></span> in high-temperature superconductors (HTS) across macroscopic, mesoscopic, and microscopic perspectives. Through this exploration, a comprehensive range of connections is unveiled aiming to foster advancements in the physics, materials science, and the engineering of applied superconductors. Beginning with the macroscopic interpretation of <span><math><msub><mrow><mi>J</mi></mrow><mrow><mi>c</mi></mrow></msub></math></span> as a central material law, the review traces its development from C.P. Bean’s foundational work to modern extensions. Mesoscopic challenges in understanding vortex dynamics and their coherence with thermodynamic anisotropy regimes are addressed, underscoring the importance of understanding the limitations and corrections implicit in the macroscopic measurement of <span><math><msub><mrow><mi>J</mi></mrow><mrow><mi>c</mi></mrow></msub></math></span>, linked with mesoscopic phenomena such as irradiation effects, defect manipulation, and vortex interactions. The transition to supercritical current densities is also discussed, detailing the superconductor behavior beyond critical thresholds with a focus on flux-flow instability regimes relevant to fault current limiters and fusion energy magnets. Enhancing <span><math><msub><mrow><mi>J</mi></mrow><mrow><mi>c</mi></mrow></msub></math></span> through tailored material microstructures, engineered pinning centers, grain boundary manipulation, and controlled doping is explored, along with radiation techniques and their impact on large-scale energy systems. Emphasizing the critical role of <span><math><msub><mrow><mi>J</mi></mrow><mrow><mi>c</mi></mrow></msub></math></span>, this review focuses on its physical optimization and engineering manipulation, highlighting its significance across diverse sectors.</div></div>","PeriodicalId":411,"journal":{"name":"Progress in Materials Science","volume":"155 ","pages":"Article 101492"},"PeriodicalIF":33.6,"publicationDate":"2025-05-26","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"144145465","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":1,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Mechanical behavior of microstructurally stable nanocrystalline alloys: Processing, properties, performance, and prospects 微观结构稳定的纳米晶合金的力学行为:加工、性质、性能和前景
IF 33.6 1区 材料科学
Progress in Materials Science Pub Date : 2025-05-25 DOI: 10.1016/j.pmatsci.2025.101519
K.A. Darling , Y. Mishin , N.N. Thadhani , Q. Wei , K. Solanki
{"title":"Mechanical behavior of microstructurally stable nanocrystalline alloys: Processing, properties, performance, and prospects","authors":"K.A. Darling ,&nbsp;Y. Mishin ,&nbsp;N.N. Thadhani ,&nbsp;Q. Wei ,&nbsp;K. Solanki","doi":"10.1016/j.pmatsci.2025.101519","DOIUrl":"10.1016/j.pmatsci.2025.101519","url":null,"abstract":"<div><div>This review presents a comprehensive overview of the scientific revolution enabled by recent emergence of structurally stabilized NC materials. It captures major breakthroughs in achieving nanoscale stability through thermodynamic and kinetic pathways, and critically examines the fundamental mechanisms underpinning the stabilization, including GB segregation, solute drag, Zener pinning, and nanocluster formation. It describes how stabilization of NC materials can enable unprecedented access to their intrinsic mechanical and physical behaviors, revealing phenomena previously inaccessible due to the microstructural evolution during testing. Examples include superlative strength-ductility synergy, infinite fatigue endurance limits, creep resistance rivaling single crystals, radiation damage tolerance, and evidence of defect-mediated self-healing. The review also explores how stabilized NC materials challenge long-held assumptions about the mechanisms of deformation, recrystallization, and phase transformations. It further examines how stabilized NC alloys have revolutionized our theoretical understanding of these mechanisms and created new avenues for their fabrication as well as industrial applications. While significant challenges remain with scalable fabrication processes and standardization, we outline new design principles, manufacturing pathways, and strategic directions for future exploration and application frontiers that are poised to overcome long-standing limitations making structurally stabilized NC materials as a transformative class of structural materials for extreme environments and advanced technologies.</div></div>","PeriodicalId":411,"journal":{"name":"Progress in Materials Science","volume":"155 ","pages":"Article 101519"},"PeriodicalIF":33.6,"publicationDate":"2025-05-25","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"144137192","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":1,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Additively manufactured function-tailored bone implants made of graphene-containing biodegradable metal matrix composites 增材制造的功能定制骨植入物由含石墨烯的可生物降解金属基复合材料制成
IF 33.6 1区 材料科学
Progress in Materials Science Pub Date : 2025-05-24 DOI: 10.1016/j.pmatsci.2025.101517
Keyu Chen, Jiahui Dong, Niko Eka Putra, Lidy Elena Fratila-Apachitei, Jie Zhou, Amir A. Zadpoor
{"title":"Additively manufactured function-tailored bone implants made of graphene-containing biodegradable metal matrix composites","authors":"Keyu Chen,&nbsp;Jiahui Dong,&nbsp;Niko Eka Putra,&nbsp;Lidy Elena Fratila-Apachitei,&nbsp;Jie Zhou,&nbsp;Amir A. Zadpoor","doi":"10.1016/j.pmatsci.2025.101517","DOIUrl":"10.1016/j.pmatsci.2025.101517","url":null,"abstract":"<div><div>While conventionally manufactured metallic biomaterials can hardly meet all the requirements for bone implants including complex geometry, exact dimensions, adequate biodegradability, bone-matching mechanical properties, and biological function, two additional tools have recently appeared in the arsenal of biomaterials scientists which promise to deliver the desired combination of properties. First, the unique mechanical, electrical, and biological properties of graphene (Gr) and its derivatives (GDs), <em>e.g.</em>, a Young’s modulus up to 1 TPa, can be utilized to create metal matrix composites in which GDs of varied contents (typically not more than 2 wt%), sizes (lateral sizes from a few nanometers to several micrometers), surface areas (up to the theoretical value of 2630 m<sup>2</sup>/g), and layer numbers (typically up to 10) are embedded in the biodegradable metal matrix, thereby endowing the composite implants with extraordinary properties. Second, the distinct advantages of additive manufacturing (AM) make it possible for GD-containing composite materials to precisely mimic the complex shapes and structures of bones at multiple length scales. Here, a comprehensive review of the recent advances in the development of GD-containing biodegradable metal matrix composites (GBMMCs), ranging from composite fabrication, including composite powder preparation, and AM processes, to the evaluation of AM composites in terms of their mechanical and biological properties, is presented. Furthermore, the constraints in processing composite powders, the advantages and disadvantages of applicable AM techniques, and the mechanisms of mechanical reinforcement, biodegradation modulation, osteogenesis improvement, and cytotoxicity/antibacterial balance are critically analyzed. Thereafter, the foreseeable challenges faced in the development of the next-generation of bone implants based on GBMMCs are presented and some future directions of research are identified.</div></div>","PeriodicalId":411,"journal":{"name":"Progress in Materials Science","volume":"155 ","pages":"Article 101517"},"PeriodicalIF":33.6,"publicationDate":"2025-05-24","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"144130613","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":1,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
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