ACS Applied Polymer Materials最新文献

{"title":"Template-Free Preparation of Highly Sensitive Flexible Pressure Sensors with Microtaper Structure by MXene Modification","authors":"Bokai Zhang,&nbsp;Renhan Li,&nbsp;Ying Wang,&nbsp;Chengbang Zhang,&nbsp;Lingjie Kong,&nbsp;Jian Zhang and Yafei Qin*,&nbsp;","doi":"10.1021/acsapm.5c02086","DOIUrl":"https://doi.org/10.1021/acsapm.5c02086","url":null,"abstract":"<p >In recent years, flexible pressure sensors have garnered significant attention for their potential applications in human-machine interfaces, medical monitoring, and electronic skin. However, the microstructure of the sensitive layer often relies on external templates, resulting in a complicated and costly preparation process. Additionally, the existing conductive networks are challenging to combine high sensitivity and a wide detection range due to uneven dispersion of fillers or weak interfacial bonding. In this paper, carboxylated carbon nanotubes (MWCNTs-COOH)/thermoplastic polyurethane (TPU) composite films with conical microstructure on the surface were directly prepared without an external template by optimizing the parameters of the electrostatic spinning process (RPS). The conductive network and its mechanical properties were enhanced by hydrogen bonding between MXene and TPU. This improved the sensitivity and increased the detection range simultaneously. Experimental findings demonstrate that the sensor demonstrates a sensitivity of up to 443.63 kPa^–1 within the range of 4 kPa, a detection limit as low as 2 Pa, respectively, and is capable of stable operation across a wide range of 266 kPa. Furthermore, the sensor demonstrates remarkable performance in scenarios such as human physiological signal monitoring and gesture recognition, thereby substantiating its practical value in the domains of medical health monitoring and human-computer interaction.</p>","PeriodicalId":7,"journal":{"name":"ACS Applied Polymer Materials","volume":"7 17","pages":"11618–11628"},"PeriodicalIF":4.7,"publicationDate":"2025-09-04","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"145036309","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":2,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

{"title":"Adsorption of Calcium Ion in Cooling Water Using Ion-Imprinted Adsorbents for Scale Inhibition","authors":"Ming Huang,&nbsp;Wenyu Qi,&nbsp;Bo Pang,&nbsp;Chengcheng Ding,&nbsp;Fanping Zhu,&nbsp;Chao Song* and Shu-Guang Wang*,&nbsp;","doi":"10.1021/acsapm.5c02104","DOIUrl":"https://doi.org/10.1021/acsapm.5c02104","url":null,"abstract":"<p >Calcium is the main ion that causes scaling in circulating cooling water, but current works mainly focus on developing scale inhibitors, lacking reports on the softening of hard water and efficient recovery of economic ions. In this study, calcium ion-imprinted polymers (Ca²⁺-IIP) were developed with the bulk polymerization method for the adsorption and recovery of calcium ions (Ca²⁺) from cooling water, aiming to mitigate scaling and achieve resource utilization. The Ca²⁺-IIP could effectively capture Ca²⁺ with a maximum adsorption capacity of 61.2 mg/g, and it only decreased by about 8% after six adsorption/desorption cycles. In addition, Ca²⁺-IIP could selectively adsorb Ca²⁺, with selectivity coefficients of up to 5.9, 2.8 and 3.7 for Na⁺, K⁺ and Mg²⁺, respectively. The adsorption mechanism was explored with Fourier transform infrared spectroscopy and X-ray photoelectron spectroscopy, and the carboxyl and hydroxyl groups were involved in the adsorption, where the O atoms provided lone pair electrons to interact with Ca²⁺. Moreover, Ca²⁺-IIP could obviously inhibit scaling in cooling water with different cycle times. This work develops a potentially effective adsorbent for Ca²⁺ recycling and scale inhibition in circulating cooling water.</p>","PeriodicalId":7,"journal":{"name":"ACS Applied Polymer Materials","volume":"7 17","pages":"11549–11557"},"PeriodicalIF":4.7,"publicationDate":"2025-09-03","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"145036598","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":2,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

{"title":"Synergistic Enhancement of PTFE Tribological Performance via LDH-Induced Adsorption and PEEK Support Framework","authors":"Hankuo Wu,&nbsp;Jikai Xie,&nbsp;Cheng Zhang,&nbsp;Hong Yin,&nbsp;Zhu Luo,&nbsp;Min He,&nbsp;Zhi Hao*,&nbsp;Xiaolang Chen* and Haijiao Xie*,&nbsp;","doi":"10.1021/acsapm.5c01711","DOIUrl":"https://doi.org/10.1021/acsapm.5c01711","url":null,"abstract":"<p >This study addresses the critical limitations of polytetrafluoroethylene (PTFE), including low mechanical strength and high wear rate (10^–4 mm³/N·m), through a “rigid-flexible synergy” multiscale reinforcement strategy. Specifically, this study introduces a continuous spatial network particle structure coupled with layered lubrication, which incorporates polyetheretherketone (PEEK) and calcium–aluminum layered double hydroxide (LDH). LDH/PEEK/PTFE composites were fabricated via cold-press sintering, and their mechanical and tribological properties were systematically evaluated. The optimal performance was achieved at 20 wt % PEEK and 4 wt % LDH, where the compressive strength increased to 38.2 MPa (53% enhancement over pure PTFE), the friction coefficient decreased to 0.163 (10.4% reduction), and the wear rate reached 0.067 × 10^–13 m³/Nm (94.1% reduction). Multiscale characterization (SEM/EDS/FTIR/XRD/Raman) and density functional theory (DFT) calculations revealed the underlying synergistic mechanisms: (1) PEEK disperses loads by forming a continuous spatial network particle structure, inhibiting plastic deformation and crack propagation of the matrix (24% increase in Shore hardness); (2) LDH nanosheets generated shear-aligned lubricating films with enhanced transfer film stability via strong interfacial adsorption (−0.61 eV, DFT); (3) PEEK-LDH interactions promoted tribochemical reactions, yielding carboxylate metal chelates (FTIR peak at 1430 cm^–1) for optimized interfacial bonding. This work establishes the theoretical and technical foundations for advanced self-lubricating composites, demonstrating their potential in aerospace seals and heavy-duty bearings.</p>","PeriodicalId":7,"journal":{"name":"ACS Applied Polymer Materials","volume":"7 17","pages":"11202–11215"},"PeriodicalIF":4.7,"publicationDate":"2025-09-03","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"145036558","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":2,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

{"title":"Organic Superbase-Functionalized Fiber Catalyst for Green Catalysis of C–C Bond Formation and Downstream Tandem Reaction","authors":"Kun Yue,&nbsp;Lu Wang,&nbsp;Yu Ge,&nbsp;Yichen Zheng and Jian Xiao*,&nbsp;","doi":"10.1021/acsapm.5c02858","DOIUrl":"https://doi.org/10.1021/acsapm.5c02858","url":null,"abstract":"<p >A high-performance basic fiber catalyst (PAN_TBDF) was developed by loading 1,5,7-triazabicyclo[4.4.0]dec-5-ene (TBD) onto a polyacrylonitrile fiber. The functionalized fibers were thoroughly characterized using Fourier transform infrared spectroscopy, scanning electron microscopy, and X-ray photoelectron spectroscopy. The characterization results confirmed that the physical and chemical properties of the fibers aligned with the design objectives at each modification stage, verifying the successful incorporation of the desired functional groups. To evaluate the catalytic performance of the synthesized fibers, the Knoevenagel reaction was employed as a model reaction. The results revealed that PAN_TBDF efficiently catalyzed the Knoevenagel condensation between various aromatic aldehydes and cyano-containing compounds under mild conditions (50 °C, 3 mol % catalyst loading, deionized water as solvent) within 2 h. A total of 31 products were obtained, with isolated yields ranging from 59% to 98%. Additionally, PAN_TBDF demonstrated remarkable catalytic activity in the Knoevenagel–Michael multicomponent tandem reaction, producing 27 substrates with isolated yields between 53 and 94%. Remarkably, PAN_TBDF demonstrated exceptional recyclability by maintaining nearly consistent reaction times and yields across 12 consecutive cycles, underscoring its robust performance and practical applicability. Finally, a plausible mechanism for the heterogeneous catalytic process was proposed, providing insight into the reaction pathway.</p>","PeriodicalId":7,"journal":{"name":"ACS Applied Polymer Materials","volume":"7 17","pages":"12093–12104"},"PeriodicalIF":4.7,"publicationDate":"2025-09-03","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"145036681","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":2,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

{"title":"Quadruple H-Bond Cross-Linked Polyimide for High Temperature Resistance, Corrosion Protection, and Self-Healing Coatings","authors":"Jie Wang,&nbsp;Hongdi Zhou,&nbsp;Wei Yuan,&nbsp;Jun Tang,&nbsp;Hao Yu,&nbsp;Kexin Zhou,&nbsp;Nie Zhao,&nbsp;Biao Zhang*,&nbsp;Yue Zheng* and Fugang Qi*,&nbsp;","doi":"10.1021/acsapm.5c02512","DOIUrl":"https://doi.org/10.1021/acsapm.5c02512","url":null,"abstract":"<p >Integrating multiple functions effectively into a single material poses significant challenges. The analysis of the synergistic enhancement mechanisms of multifunctional organic coatings is also quite complex. This study proposes a molecular cross-linking structural strategy to prepare multifunctional composite coatings, achieved through the synergistic effect of a dynamic cross-linking network formed by the ‘rigid-flexible’ polyimide (PI) and urea-enhanced quadruple H-bond cross-linked of 2-ureido-4[1H]-pyrimidinone (Upy). Electrochemical impedance spectroscopy analysis indicates that the prepared Upy-PI composite coating exhibits an impedance modulus as high as 10¹² Ω·cm² after being immersed in a 3.5 wt % NaCl solution for 3 days, which is 5 orders of magnitude higher than the impedance modulus of pure PI coating at 10⁷ Ω·cm². After thermal aging at 200 °C for 480 h, the Upy-PI still retains long-term corrosion resistance. DTG analysis shows that Upy-PI (<i>T</i>_max = 528 °C) has an increase of 38 °C compared to pure PI (<i>T</i>_max = 490 °C). Upy-PI exhibits outstanding mechanical properties, with a tensile stress of 9.32 MPa, which is 72 times that of pure PI coating. Further microscopic characterization results indicate that Upy-PI possesses excellent self-healing capabilities compared to pure PI coating. This study also analyzes the potential mechanisms for the synergistic enhancement of multiple properties, which may provide references for subsequent research in related fields.</p>","PeriodicalId":7,"journal":{"name":"ACS Applied Polymer Materials","volume":"7 17","pages":"12053–12065"},"PeriodicalIF":4.7,"publicationDate":"2025-09-03","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"145036365","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":2,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

{"title":"Amide-Modified Polyethylenimine from Meldrum’s Acid/Aldehyde/Isocyanide/Amine Multicomponent Tandem Reaction for High-Efficiency Iodine Capture","authors":"Zhenzhen She,&nbsp;Jing Zhang,&nbsp;Baiyang Sun,&nbsp;Zhengfeng Xie and Wei Shi*,&nbsp;","doi":"10.1021/acsapm.5c02368","DOIUrl":"https://doi.org/10.1021/acsapm.5c02368","url":null,"abstract":"<p >Nuclear energy is an important form of energy supply, whereas its associated nuclear pollution issue is becoming more and more serious. The effective capture of radioactive iodines (¹²⁹I and ¹³¹I), which are typical nuclear fission products, is of great practical significance. In this work, an amide-modified, cross-linked polyethylenimine (PEI) derivative (MTB-PEI) containing N/O-heteroatoms was successfully synthesized by catalyst-free multicomponent tandem reaction (MCTR) using Meldrum’s acid, terephthalaldehyde, fluorene-based isocyanide (BIF), and PEI as substrates at room temperature. The chemical structure and fundamental properties of MTB-PEI were analyzed by FT-IR, XPS, scanning electron microscope, TGA characterization, etc. Based on the polyamine-type structural characteristic of MTB-PEI, its application for iodine capture was investigated followingly. Corresponding iodine adsorption performance was studied in different phases, and the results showed that the adsorption capacities were up to 6.09 g g^–1 (vapor phase), 2.04 g g^–1 (organic solution phase), 1.87 g g^–1 (single I₂ aqueous phase), and 2.74 g g^–1 (I₂/KI aqueous phase), respectively. Adsorption mechanism investigation revealed that diverse N/O-containing segments and aromatic rings in MTB-PEI’s structure contributed synergistically for capturing iodine.</p>","PeriodicalId":7,"journal":{"name":"ACS Applied Polymer Materials","volume":"7 17","pages":"11912–11924"},"PeriodicalIF":4.7,"publicationDate":"2025-09-03","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"145036596","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":2,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

{"title":"Composite Hydrogel Based on Green Chlorella Polysaccharide–Selenium Nanoparticles for Simultaneous Wound Treatment and pH Monitoring","authors":"Jingjing Tian,&nbsp;Yuanke Zhang,&nbsp;Lvyao Yang,&nbsp;Lijuan Wang,&nbsp;Guixia Ling* and Peng Zhang*,&nbsp;","doi":"10.1021/acsapm.5c01561","DOIUrl":"https://doi.org/10.1021/acsapm.5c01561","url":null,"abstract":"<p >Once the skin was damaged, it lost the ability to prevent harmful bacteria from infiltrating into the tissues, leading to wound infection and even serious tissue damage. Although conventional therapies were effective in eradicating pathogenic bacteria, they could not promote the healing of damaged skin, which was easily affected by tissue adhesion and lacked the ability to maintain a moist wound environment. In this study, according to the principle of green chemistry, <i>Chlorella</i> extracellular polysaccharide–selenium nanoparticles (EPS-SeNPs) with high biological activity, high stability, and low toxicity were synthesized for the first time, which could be used to kill wound pathogens and relieve inflammation. EPS-SeNPs were combined with a wound dressing hydrogel, and the hydrogel was cross-linked by a Schiff base reaction between the biocompatible oxidized sodium alginate (OSA) and gelatin (Gel) to promote wound healing. At the same time, the pH fluctuation of the wound could be monitored by adding the acid–base indicator litmus to it by the solvent replacement method, thus indirectly predicting the healing process of the wound. The results of <i>in vitro</i> experiments showed that the composite hydrogel had strong antibacterial and anti-inflammatory abilities, which could inhibit the growth and reproduction of common pathogens. The experimental results showed that the antibacterial rate of the composite hydrogel could reach 99%, the ability to clear ABTS free radicals was 93.13%, and the ability to clear DPPH free radicals was 82.36%. In the <i>in vivo</i> experiment, SD rats were used to construct an infected wound model, and then wound healing experiments were conducted. The experimental results showed that the composite hydrogel could significantly accelerate the wound healing process, promote new epidermis formation and hair follicle growth, and reduce inflammatory response. This work may open up a way for the clinical management of infected wounds and the simultaneous monitoring of wound healing.</p>","PeriodicalId":7,"journal":{"name":"ACS Applied Polymer Materials","volume":"7 17","pages":"11091–11104"},"PeriodicalIF":4.7,"publicationDate":"2025-09-03","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"145036682","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":2,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

{"title":"Highly Efficient and Reusable Hydrogel-Based Packaging Material Enabled by Oriented Porous Structures and Hybrid Dual-Cross-Linking Networks","authors":"Yilin Yu,&nbsp;Jian Hu*,&nbsp;Wenbin Li,&nbsp;Hu Zhang and Zhengjin Wang*,&nbsp;","doi":"10.1021/acsapm.5c02421","DOIUrl":"https://doi.org/10.1021/acsapm.5c02421","url":null,"abstract":"<p >Multifunctional hydrogel-based packaging materials with high energy absorption efficiency and exceptional reusability are highly desired in various applications. However, these two requirements usually conflict. In this work, we design and fabricate a hydrogel-based packaging material with oriented porous structures and hybrid dual-cross-linking networks. This design achieves high stiffness and a wide compressive plateau stress, resulting in a hydrogel with exceptional energy absorption efficiency that surpasses that of most foam cushioning materials. The synergy of oriented pores and hybrid dual-cross-linking polymer networks endows the hydrogel with superior recovery properties in terms of strain and maximum stress under extreme compression, as well as excellent fatigue resistance under long-term cyclic loading. The hydrogel retains structural integrity and mechanical properties over a wide range of strain rates. In simulated transport tests, the hydrogel containing silver nanoparticles effectively extends the shelf life of strawberries by mitigating mechanical damage from occasional impacts and prolonged vibrations, maintaining stable humidity, and continuously releasing antibacterial additives. This work provides a highly efficient and reusable hydrogel-based packaging material for fragile and perishable items in harsh transport and storage environments.</p>","PeriodicalId":7,"journal":{"name":"ACS Applied Polymer Materials","volume":"7 17","pages":"11986–11997"},"PeriodicalIF":4.7,"publicationDate":"2025-09-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"145036360","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":2,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

{"title":"One-Step Preparation of Hierarchical Structured Nanofibers Using Coaxial Electrospinning for Lithium-Ion Batteries","authors":"Jingjie Xie,&nbsp;Jie Wang and Lan Xu*,&nbsp;","doi":"10.1021/acsapm.5c02539","DOIUrl":"https://doi.org/10.1021/acsapm.5c02539","url":null,"abstract":"<p >Nanofibers with unique structures and functions can be prepared in one step by using coaxial electrospinning technology. In recent years, with in-depth research on polymer properties and spinning parameters, it has been possible to flexibly synthesize nanofibers with diverse internal structures, including core–shell, hollow, and porous structures, by adjusting the shape and structure of spinnerets. These special structures of nanofibers significantly enhance their performances and practical values, especially in lithium-ion batteries (LIBs), where they are used to solve problems such as the low capacity and volume expansion of electrode materials as well as the safety of separator materials. This article describes the advantages of coaxial electrospinning technology in the one-step preparation of nanofibers with various structures, summarizes the application of this technology in electrode materials, separators, and electrolytes for LIBs, highlights the promotion of the LIB performance by nanofibers with unique structures (such as core–shell, hollow, porous, and multilayer), identifies possibilities for achieving nanostructures through coaxial electrospinning, and looks forward to its future research directions and application prospects in LIBs.</p>","PeriodicalId":7,"journal":{"name":"ACS Applied Polymer Materials","volume":"7 17","pages":"10965–10980"},"PeriodicalIF":4.7,"publicationDate":"2025-09-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"145036361","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":2,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

{"title":"Ultrahigh Linear Temperature Sensors Based on Poly(3,4-Ethylenedioxythiophene):Poly(Styrenesulfonate) with Negative Temperature Compensation for Wireless Temperature Monitoring","authors":"Chenguang Kong,&nbsp;Hangzhou Wang,&nbsp;Jun Shi*,&nbsp;Youcheng Huang,&nbsp;Shumin Jiang,&nbsp;Kun Wu and Yi Fu,&nbsp;","doi":"10.1021/acsapm.5c01913","DOIUrl":"https://doi.org/10.1021/acsapm.5c01913","url":null,"abstract":"<p >With further exploration in wearable electronic devices, thermally responsive nanocomposites with high sensitivity, fast response, and good linearity characteristics are urgently needed. In this study, a flexible thermoresistive temperature sensor with high sensitivity and linearity was fabricated by integrating poly(3,4-ethylenedioxythiophene):poly(styrenesulfonate) (PEDOT:PSS), multiwall carbon nanotubes (MWCNTs), and waterborne polyurethane (WPU). Notably, doping PEDOT:PSS with a negative temperature coefficient as the temperature compensation effectively addressed the nonlinear problem of responsive resistance from the material level, realizing the extraordinary linearity and high sensitivity of the PEDOT:PSS/MWCNT@WPU (PMW) temperature sensors. The prepared sensors exhibit high sensitivity (−2.0%·°C^–1), linearity (<i>R</i>² = 0.994), accuracy (0.1 °C), and response (0.63 s/°C) within the range of 30–60 °C. Based on this, the fabricated temperature sensor can combine with the Arduino electronic components to achieve the wireless real-time monitoring of skin temperature, ambient temperature, and respiratory rate, highlighting its great potential in electronic skins, intelligent robotic platforms, environmental surveillance, and other fields.</p>","PeriodicalId":7,"journal":{"name":"ACS Applied Polymer Materials","volume":"7 17","pages":"11394–11403"},"PeriodicalIF":4.7,"publicationDate":"2025-09-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"145036335","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":2,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}