Journal of Chemical & Engineering Data最新文献

How Deep is Your DES? A Numerical Framework for Ideal Eutectic Prediction in Multicomponent Mixtures 你的DES有多深？多组分混合物中理想共晶预测的数值框架

IF 2.4 3区工程技术

Journal of Chemical & Engineering Data Pub Date : 2026-10-08 Epub Date: 2026-09-03 DOI: 10.1021/acs.jced.6c00332

Gabriela A. Nogueira, Leandro dos Santos Silva, Mario H. Gonzalez, Milton A. Faria Neto, Thiago A. L. Burgo

{"title":"How Deep is Your DES? A Numerical Framework for Ideal Eutectic Prediction in Multicomponent Mixtures","authors":"Gabriela A. Nogueira, Leandro dos Santos Silva, Mario H. Gonzalez, Milton A. Faria Neto, Thiago A. L. Burgo","doi":"10.1021/acs.jced.6c00332","DOIUrl":"https://doi.org/10.1021/acs.jced.6c00332","url":null,"abstract":"Here, we presenta simple and computationally efficient procedureto determine the eutectic temperatures of ideal binary, ternary, andhigher-order mixtures, providing a quantitative reference for evaluatingdeep eutectic solvent (DES) behavior. In the DES literature, ternarysystems are often simplified as pseudo-binaries by fixing the molarratio of two components and varying only the third along a fixed-compositionline (isopleth). Although this reduces the experimental effort, itrestricts liquidus mapping to a single compositionalpathway and may fail to identify the global ideal eutectic. In contrast,our implementation solves the classical ideal liquidus equations for all components, assuming Raoult-law ideality and pure,mutually immiscible solid phases. Using pure-component melting temperaturesand molar fusion enthalpies, the method enables multidimensional liquidus-surface mapping. The root-finding implementationwas verified against analytical symmetric-mixture solutions, independent80-digit calculations, a MATLAB implementation, permutation tests,3,521 stress-test systems, and published benchmarks. All stress-testsystems converged, and published ideal eutectic temperatures werereproduced within 0.7 K. Application to literature-reported binaryand ternary mixtures further showed that comparison with the globalideal eutectic combines an apparent local thermal deviation with anonnegative ideal-composition penalty. The framework therefore providesa transparent and extensible ideal-equilibrium baseline for multicomponenteutectic screening.","PeriodicalId":42,"journal":{"name":"Journal of Chemical & Engineering Data","volume":"71 10","pages":"4156–4167"},"PeriodicalIF":2.4,"publicationDate":"2026-10-08","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"149124645","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":3,"RegionCategory":"工程技术","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

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Experimental Investigation of Isobaric Specific Heat Capacity for Methyl Decanoate and Ethyl Decanoate at Temperatures from 313 to 453 K and Pressures up to 10 MPa 温度为313 ~ 453k，压力为10mpa时癸酸甲酯和癸酸乙酯等压比热容的实验研究

IF 2.4 3区工程技术

Journal of Chemical & Engineering Data Pub Date : 2026-10-08 Epub Date: 2026-09-10 DOI: 10.1021/acs.jced.6c00346

Shaohua Lv, Haojie Song, Bo Wang, Yun Hao, Yali Su, Linghong Tang

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Solid–Liquid Equilibria of the Quaternary System Li+, K+, Ca2+ // Cl––H2O at 323.2 and 348.2 K: Li/K Crystallization from Calcium-Rich Deep Brine Li+, K+， Ca2+ // Cl—H2O在323.2和348.2 K下的固液平衡：富钙深盐水中Li/K结晶

IF 2.4 3区工程技术

Journal of Chemical & Engineering Data Pub Date : 2026-10-08 Epub Date: 2026-09-25 DOI: 10.1021/acs.jced.6c00357

Haoran Qin, Xudong Yu, Tong Pan, Jiubo Liu, Siying Ren, Zongde Ma, Liping Wu

{"title":"Solid–Liquid Equilibria of the Quaternary System Li+, K+, Ca2+ // Cl––H2O at 323.2 and 348.2 K: Li/K Crystallization from Calcium-Rich Deep Brine","authors":"Haoran Qin, Xudong Yu, Tong Pan, Jiubo Liu, Siying Ren, Zongde Ma, Liping Wu","doi":"10.1021/acs.jced.6c00357","DOIUrl":"https://doi.org/10.1021/acs.jced.6c00357","url":null,"abstract":"In view of the high calcium characteristicsof deep brine and thetemperature change during its mining, transportation, and storageprocess, the solid–liquid phase equilibria of the quaternarysystem Li+, K+, Ca2+ // Cl––H2O at 323.2 and 348.2 K were studied by the isothermaldissolution equilibrium method, and the multitemperature phase diagramswere compared with the literature data at 273.2 and 298.2 K. The resultsshow that the crystal forms of lithium chloride and calcium chloridechange as follows: LiCl·2H2O (273.2 K) → LiCl·H2O (≥298.2 K); CaCl2·6H2O(273.2 K) → CaCl2·6H2O + CaCl2·4H2O (298.2 K) → CaCl2·2H2O (≥323.2 K); LiCl·CaCl2·5H2O (≤298.2 K) was formed at low temperature, and KCl·CaCl2 (≥323.2 K) was formed at high temperature. With theincrease of temperature, the crystalline phase region of KCl decreases,and the crystalline regions of LiCl·H2O and KCl·CaCl2 increase. The above phase diagram reveals the temperaturestep-by-step control separation route of “high temperaturepreferential precipitation of KCl·CaCl2, low temperatureextraction of potassium, high temperature extraction of lithium”,which provides a theoretical basis for the classification and utilizationof Li/K resources in high calcium deep brine.","PeriodicalId":42,"journal":{"name":"Journal of Chemical & Engineering Data","volume":"71 10","pages":"4407–4418"},"PeriodicalIF":2.4,"publicationDate":"2026-10-08","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"149124949","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":3,"RegionCategory":"工程技术","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

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Separation of Methanol and MTBE Azeotrope via Choline-Based Deep Eutectic Solvents: Liquid–Liquid Equilibrium and Molecular Mechanism 基于胆碱的深度共晶溶剂分离甲醇和MTBE共沸物：液-液平衡和分子机理

IF 2.4 3区工程技术

Journal of Chemical & Engineering Data Pub Date : 2026-10-08 Epub Date: 2026-09-22 DOI: 10.1021/acs.jced.6c00342

Hui Yang, Lingling Sun, Ying Qin, Tongshun Li, Hao Chen, Dongmei Xu, Jun Gao

{"title":"Separation of Methanol and MTBE Azeotrope via Choline-Based Deep Eutectic Solvents: Liquid–Liquid Equilibrium and Molecular Mechanism","authors":"Hui Yang, Lingling Sun, Ying Qin, Tongshun Li, Hao Chen, Dongmei Xu, Jun Gao","doi":"10.1021/acs.jced.6c00342","DOIUrl":"https://doi.org/10.1021/acs.jced.6c00342","url":null,"abstract":"Methyl tert-butyl ether (MTBE) is anexcellentadditive for gasoline. Because of the formation of an azeotropic mixtureby MTBE and methanol during its production, it is a challenge to separatethe azeotrope. To investigate the effect of hydrogen bond donor (HBD)functional groups on extraction performance, three choline chloride-baseddeep eutectic solvents (DESs) were prepared using ethylene glycol,ethanolamine and glycolic acid, which contain –OH, –NH2, and –COOH, respectively. For separating the azeotropicmixture MTBE and methanol by an extraction process, liquid–liquidequilibrium (LLE) data for the pseudoternary mixtures MTBE + methanol+ DESs were ascertained at 298.15 K. Distribution coefficient (D) and selectivity (S) were derived andcompared among the different systems. The optimal DES ChCl:MEA attaineda distribution coefficient of 8.85 and a selectivity of 436.21. TheNRTL model was employed to regress the LLE data. The reliability ofthe binary parameters of the thermodynamic model was validated throughGibbs energy topology analysis. In addition, quantum chemical calculationsand molecular dynamics simulations were applied to investigate theinteractions underlying the differences in extractant performance.This multiscale analysis revealed hydrogen bonding Cl···OHplays a crucial function, while van der Waals interactions serve asa secondary contributing factor.","PeriodicalId":42,"journal":{"name":"Journal of Chemical & Engineering Data","volume":"71 10","pages":"4325–4335"},"PeriodicalIF":2.4,"publicationDate":"2026-10-08","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"149130654","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":3,"RegionCategory":"工程技术","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

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Experimental Measurement and Modeling of Liquid–Liquid Equilibria for the Ternary System Water + Propan-1-ol + Ethyl Acetate 水+丙-1-醇+乙酸乙酯三元体系液-液平衡的实验测量与模拟

IF 2.4 3区工程技术

Journal of Chemical & Engineering Data Pub Date : 2026-10-08 Epub Date: 2026-09-09 DOI: 10.1021/acs.jced.6c00298

John O. Bamikole, Caitlin Stapelberg, Caleb Narasigadu

{"title":"Experimental Measurement and Modeling of Liquid–Liquid Equilibria for the Ternary System Water + Propan-1-ol + Ethyl Acetate","authors":"John O. Bamikole, Caitlin Stapelberg, Caleb Narasigadu","doi":"10.1021/acs.jced.6c00298","DOIUrl":"https://doi.org/10.1021/acs.jced.6c00298","url":null,"abstract":"The world’sgrowing energy needs and the depletion of fossilfuels have driven demand for renewable alternatives, such as biofuels.Propan-1-ol is a valuable biofuel component; however, the presenceof water during its production remains a significant challenge. Aviable solution is liquid–liquid extraction to selectivelyrecover propan-1-ol from a water mixture. Ethyl acetate is considereda promising solvent due to its chemical stability, eco-friendly nature,moderate water immiscibility, and favorable density difference forphase separation in a water-propan-1-ol mixture. In this study, ternaryLLE measurements for water (1), propan-1-ol (2), and ethyl acetate(3) were conducted at 298.15, 313.15, and 328.15 K to evaluate ethylacetate as a solvent for extracting propan-1-ol. The selectivity andcapacity of the solvent were calculated. The experimental data weremodeled using the NRTL and UNIQUAC activity models, both of whichadequately describe the phase behavior, with NRTL slightly betterthan UNIQUAC. The group method of data handling (GMDH) neural networkwas also employed to complement the thermodynamic model, accuratelypredicting phase composition. The findings of this study show thatethyl acetate has excellent potential for selectively extracting propan-1-olfrom water, with the extraction efficiency increasing with temperature.","PeriodicalId":42,"journal":{"name":"Journal of Chemical & Engineering Data","volume":"71 10","pages":"4303–4314"},"PeriodicalIF":2.4,"publicationDate":"2026-10-08","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"149130639","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":3,"RegionCategory":"工程技术","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

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CO2 Capture Performance and Mechanism of an Amino-Functionalized Acetamide–1-Amino-2-propanol Deep Eutectic Solvent 氨基功能化乙酰酰胺- 1-氨基-2-丙醇深度共熔溶剂的CO2捕集性能及机理

IF 2.4 3区工程技术

Journal of Chemical & Engineering Data Pub Date : 2026-10-08 Epub Date: 2026-09-19 DOI: 10.1021/acs.jced.6c00229

He Dong, Yujie Ma, Xiaohong Xie

{"title":"CO2 Capture Performance and Mechanism of an Amino-Functionalized Acetamide–1-Amino-2-propanol Deep Eutectic Solvent","authors":"He Dong, Yujie Ma, Xiaohong Xie","doi":"10.1021/acs.jced.6c00229","DOIUrl":"https://doi.org/10.1021/acs.jced.6c00229","url":null,"abstract":"A low-cost, low-viscosity, easily synthesized, and environmentallyfriendly deep eutectic solvent (DES) was fabricated using acetamide(AA) and 1-amino-2-propanol (MIPA) as materials. Performance studiesdemonstrated that when the molar ratio of AA to MIPA was 1:5, thesystem exhibited a CO2 adsorption capacity of 0.2198 gCO2/gDES at 303.15 K, at which condition the viscosityand density were measured to be 19.05 mPa·s and 0.9650 g·cm–3. Furthermore, the desorption efficiency remainedat 94% after 5 adsorption–desorption cycles, indicating excellentcyclic stability. Through infrared spectroscopy, nuclear magneticresonance hydrogen spectrum, and quantum chemical calculations, itwas found that the DES was primarily stabilized by a hydrogen-bondednetwork between AA and MIPA molecules, with the amino groups in MIPAserving as the main active sites for the CO2 reaction.The absorption process exhibited a synergistic mechanism combiningchemical adsorption (formation of carbamate) and physical adsorption.This study provides theoretical and experimental foundations for thedevelopment of efficient and recyclable CO2 capture materials.","PeriodicalId":42,"journal":{"name":"Journal of Chemical & Engineering Data","volume":"71 10","pages":"4107–4117"},"PeriodicalIF":2.4,"publicationDate":"2026-10-08","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"149124748","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":3,"RegionCategory":"工程技术","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

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Determination of Solubility, Supersolubility, and Metastable Zone Width of Li2CO3 in the LiCl–CaCl2–NdCl3–PrCl3–FeCl3 Solution Environment from 293.15 to 363.15 K 293.15 ~ 363.15 K范围内Li2CO3在LiCl-CaCl2-NdCl3-PrCl3-FeCl3溶液环境中的溶解度、超溶解度和亚稳带宽度的测定

IF 2.4 3区工程技术

Journal of Chemical & Engineering Data Pub Date : 2026-10-08 Epub Date: 2026-07-11 DOI: 10.1021/acs.jced.6c00123

Wanhai Xiao, Junfeng Zhang, Zhi Wang, Yong Lin, Zhihan Zhang, Guobiao Li, Tao Qi, Pengxiang Zhao, Shanjun Liu, Dong Wang

{"title":"Determination of Solubility, Supersolubility, and Metastable Zone Width of Li2CO3 in the LiCl–CaCl2–NdCl3–PrCl3–FeCl3 Solution Environment from 293.15 to 363.15 K","authors":"Wanhai Xiao, Junfeng Zhang, Zhi Wang, Yong Lin, Zhihan Zhang, Guobiao Li, Tao Qi, Pengxiang Zhao, Shanjun Liu, Dong Wang","doi":"10.1021/acs.jced.6c00123","DOIUrl":"https://doi.org/10.1021/acs.jced.6c00123","url":null,"abstract":"Theturbidity technology was employed to determine the solubility,supersolubility, and metastable zone width of Li2CO3 in the mixed solution of the LiCl–CaCl2–NdCl3–PrCl3–FeCl3 environment over a temperature span from 293.15 to 363.15K. The experimental data show that the solubility, supersolubility,and metastable zone width of Li2CO3 in a LiClsolution are mainly affected by temperature and concentration of LiClsolution. In addition, increasing the concentration of the Na2CO3 solution significantly alters the supersolubilityand metastable zone width of Li2CO3. The additionof impurity ions (Ca2+, Nd3+, Pr3+, Fe3+) noticeably increases the solubility, supersolubility,and metastable zone width of Li2CO3. The effectmechanism of impurity ions on the solubility, supersolubility, andmetastable zone width of Li2CO3 in solutionis the salting out of LiCl and salting in of CaCl2, NdCl3, PrCl3, and FeCl3. Overall, this researchprovides fundamental data for the industrial-scale manufacture ofLi2CO3 via crystallization technology.","PeriodicalId":42,"journal":{"name":"Journal of Chemical & Engineering Data","volume":"71 10","pages":"4289–4302"},"PeriodicalIF":2.4,"publicationDate":"2026-10-08","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"149124783","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":3,"RegionCategory":"工程技术","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

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Solubility Measurement, Correlation, Hansen Solubility Parameters, and Solvent Effect of 4-Isopropylbenzoic Acid in Twelve Pure Solvents at Temperatures from 278.15 to 323.15 K 4-异丙基苯甲酸在12种纯溶剂中的溶解度测量、相关性、Hansen溶解度参数和溶剂效应

IF 2.4 3区工程技术

Journal of Chemical & Engineering Data Pub Date : 2026-10-08 Epub Date: 2026-09-12 DOI: 10.1021/acs.jced.6c00395

Yanmin Shen, Jigang Zhang, Wanying Wu, Xiaolu Wu, Xixian Niu, Beibei Luo, Yining Chen, Wenju Liu

{"title":"Solubility Measurement, Correlation, Hansen Solubility Parameters, and Solvent Effect of 4-Isopropylbenzoic Acid in Twelve Pure Solvents at Temperatures from 278.15 to 323.15 K","authors":"Yanmin Shen, Jigang Zhang, Wanying Wu, Xiaolu Wu, Xixian Niu, Beibei Luo, Yining Chen, Wenju Liu","doi":"10.1021/acs.jced.6c00395","DOIUrl":"https://doi.org/10.1021/acs.jced.6c00395","url":null,"abstract":"In this study, the gravimetric method was applied tomeasure thesolubility of 4-isopropylbenzoic acid in 12 pure solvents (2-methoxyethanol,2-ethoxyethanol, 2-propoxyethanol, 2-butoxyethanol, methyl acetate,ethyl acetate, propyl acetate, isopropyl acetate, butyl acetate, isobutylacetate, acetonitrile, and N,N-dimethylformamide(DMF)) at the temperature range of 278.15–323.15 K under atmosphericpressure. The experimental results showed that the solubility of 4-isopropylbenzoicacid had a significant positive correlation with temperature, andthe mole fraction solubility (x) order of 4-isopropylbenzoicacid at the temperature of 298.15 K was: DMF (0.4498) > 2-propoxyethanol(0.2474) > 2-butoxyethanol (0.2382) ≈ 2-ethoxyethanol (0.2371)> 2-methoxyethanol (0.2242) > ethyl acetate (0.1801) > methylacetate(0.1461) > isobutyl acetate (0.1391) > propyl acetate (0.1231)≈butyl acetate (0.1202) > isopropyl acetate (0.1114) > acetonitrile(0.02216). The experimental solubility data correlated well with calculatedones from the modified Apelblat equation, the van’t Hoff equation,and the Yaws equation. Based on the principle of similar compatibility,the law of solubility and miscibility of 4-isopropylbenzoic acid inpure solvents were discussed through Hansen solubility parametersand solvent effects for predicting solubility behavior.","PeriodicalId":42,"journal":{"name":"Journal of Chemical & Engineering Data","volume":"71 10","pages":"4464–4473"},"PeriodicalIF":2.4,"publicationDate":"2026-10-08","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"149124864","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":3,"RegionCategory":"工程技术","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

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Solubility Measurement, Molecular Simulation, and Correlation of Glucono-δ-Lactone in Four Binary Solvents at 288.15–328.15 K 葡萄糖-δ-内酯在4种二元溶剂中288.15-328.15 K溶解度测定、分子模拟及相关性研究

IF 2.4 3区工程技术

Journal of Chemical & Engineering Data Pub Date : 2026-10-08 Epub Date: 2026-09-22 DOI: 10.1021/acs.jced.6c00367

Mei Ma, Yingchen Wang, Mingting Yuan, Yimin Jia, Yong Fu, Qiushuo Yu

{"title":"Solubility Measurement, Molecular Simulation, and Correlation of Glucono-δ-Lactone in Four Binary Solvents at 288.15–328.15 K","authors":"Mei Ma, Yingchen Wang, Mingting Yuan, Yimin Jia, Yong Fu, Qiushuo Yu","doi":"10.1021/acs.jced.6c00367","DOIUrl":"https://doi.org/10.1021/acs.jced.6c00367","url":null,"abstract":"The apparent mole fraction solubility of glucono-δ-lactone(GDL) was determined by a gravimetric method in four binary solventsystems: water + ethanol, water + i-propanol, water + n-propanol,and water + acetic acid. The experiments were carried out at atmosphericpressure over a temperature range from 288.15 K to 328.15 K. The resultsindicate that the solubility of GDL is positively correlated withtemperature and with the mole fraction of water in the binary solventsystems. In addition, the structural characteristics of GDL moleculesand intermolecular interactions were clarified by molecular electrostaticpotential surface (MEPS) analysis and Hirshfeld surface (HS) analysis.For correlating the solubility data, the modified Apelblat equation,the van’t Hoff equation, and the λh equation were compared.Based on an evaluation using relative deviation (RD), average relativedeviation (ARD), and root-mean-square deviation (RMSD), the modifiedApelblat equation was identified as the most suitable correlationmodel. Finally, this study provides a mechanistic explanation forthe creeping phenomenon observed during the experiments.","PeriodicalId":42,"journal":{"name":"Journal of Chemical & Engineering Data","volume":"71 10","pages":"4419–4437"},"PeriodicalIF":2.4,"publicationDate":"2026-10-08","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"149124968","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":3,"RegionCategory":"工程技术","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

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Diffusion Coefficients of Thiols in Hydrocarbon and Aqueous Alkaline Solutions 硫醇在烃类和碱性水溶液中的扩散系数

IF 2.4 3区工程技术

Journal of Chemical & Engineering Data Pub Date : 2026-10-08 Epub Date: 2026-09-23 DOI: 10.1021/acs.jced.6c00232

Nikolay Madaminov, Alexander Razinov, Alexander Klinov, Victor Arkhipov, Ivan Anashkin, Ruslan Arkhipov, Renat Akhmadullin

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