Dalton Transactions最新文献

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The role of stereochemistry in the anticancer activity of Re(I) tricarbonyl complexes 立体化学在 Re(I) 三羰基复合物抗癌活性中的作用
IF 4 3区 化学
Dalton Transactions Pub Date : 2024-07-12 DOI: 10.1039/d4dt01643b
Atena B. Solea, Gozde Demirci, Freya Harvey, Aurelien Crochet, Fabio Zobi, Olimpia Mamula
{"title":"The role of stereochemistry in the anticancer activity of Re(I) tricarbonyl complexes","authors":"Atena B. Solea, Gozde Demirci, Freya Harvey, Aurelien Crochet, Fabio Zobi, Olimpia Mamula","doi":"10.1039/d4dt01643b","DOIUrl":"https://doi.org/10.1039/d4dt01643b","url":null,"abstract":"Cancer is the leading cause of death worldwide, accounting for about one among six deaths, so the quest for new and improved therapies is of crucial importance. The discovery of cisplatin as an anticancer agent has paved the way for the development of other metal-based therapeutic agents and Re(I)-based candidates have been recently found to show promising results. It is known as well that chirality plays a central role in the interactions of metal-based drugs with intrinsically chiral biomolecules such as membrane transport proteins or DNA. To further exploit this property, we have developed a series of diastereomeric dinuclear Re(I) complexes with chiral ligands containing pinene-bipyridine units. These complexes offer unique insights into the relation between stereochemistry and biological activity. Single-crystal X-ray diffraction studies, spectroscopic analysis including UV-Vis and circular dichroism (CD), confirmed the chiral structures of these complexes. Biological activity assessments were carried out against various cancer cell lines, with a particular focus on breast and colon cancer. The diastereomers exhibited distinct anticancer activities, with some displaying promising results. Notably, one diastereomer showed exceptional cytotoxicity against HCT116 and MCF-7 cancer cells. This research underscores the significance of chirality in the design of novel anticancer agents, providing insights into the potential of dinuclear Re(I) complexes as effective candidates for cancer treatment.","PeriodicalId":71,"journal":{"name":"Dalton Transactions","volume":null,"pages":null},"PeriodicalIF":4.0,"publicationDate":"2024-07-12","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"141597286","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":3,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Synthesis and characterisation of copper(I) complexes with relevance to intramolecular Ullmann O,S-arylation. 与分子内乌尔曼 O,S-芳香化相关的铜(I)配合物的合成与表征。
IF 3.5 3区 化学
Dalton Transactions Pub Date : 2024-07-12 DOI: 10.1039/d4dt01418a
Xiaodong Jin, Bao-Nguyen T Nguyen, Robert P Davies
{"title":"Synthesis and characterisation of copper(I) complexes with relevance to intramolecular Ullmann <i>O</i>,<i>S</i>-arylation.","authors":"Xiaodong Jin, Bao-Nguyen T Nguyen, Robert P Davies","doi":"10.1039/d4dt01418a","DOIUrl":"https://doi.org/10.1039/d4dt01418a","url":null,"abstract":"<p><p>Copper-catalysed intramolecular Ullman arylation has been frequently used to synthesise benzoxazoles and benzothiazoles. Despite widespread use, investigations into the mechanism and speciation of copper-containing complexes relevant to the catalytic pathway have remained relatively limited. Accordingly, this study aims to elucidate the structural details of potential copper(I) intermediates through the analysis of their solid-state structures using X-ray crystallography, while also investigating the reactivities of these complexes. Five novel copper complexes are reported which are formed prior to the aryl halide activation step and feature distinct aggregation modes based on either Cu<sub>4</sub>N<sub>4</sub>O<sub>4</sub>C<sub>4</sub> or Cu<sub>4</sub>N<sub>4</sub>S<sub>4</sub>C<sub>4</sub> clusters.</p>","PeriodicalId":71,"journal":{"name":"Dalton Transactions","volume":null,"pages":null},"PeriodicalIF":3.5,"publicationDate":"2024-07-12","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"141588951","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":3,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Solvent-controlled solid-state phase transitions of heterospin Cu(II) complex with imidazolyl-substituted nitronyl nitroxide 咪唑基取代硝基亚硝基异质磷铜(II)配合物的溶剂控制固态相变
IF 4 3区 化学
Dalton Transactions Pub Date : 2024-07-12 DOI: 10.1039/d4dt01861c
Kristina A. Smirnova, Irina V. Golomolzina, Galina Romanenko, Sergey V. Fokin, Svyatoslav E. Tolstikov, Gleb Letyagin, Platon A. Chernavin, Artem Bogomyakov
{"title":"Solvent-controlled solid-state phase transitions of heterospin Cu(II) complex with imidazolyl-substituted nitronyl nitroxide","authors":"Kristina A. Smirnova, Irina V. Golomolzina, Galina Romanenko, Sergey V. Fokin, Svyatoslav E. Tolstikov, Gleb Letyagin, Platon A. Chernavin, Artem Bogomyakov","doi":"10.1039/d4dt01861c","DOIUrl":"https://doi.org/10.1039/d4dt01861c","url":null,"abstract":"Spontaneous solvent-controlled solid-state transformations were observed for a series of polymeric chain solvates [Cu(hfac)<small><sub>2</sub></small>L<small><sup>Pr</sup></small>]·0.5Solv (Solv = (CH<small><sub>3</sub></small>)<small><sub>2</sub></small>CO, THF, CH<small><sub>2</sub></small>Cl<small><sub>2</sub></small>, CH<small><sub>2</sub></small>Br<small><sub>2</sub></small>, CHCl<small><sub>3</sub></small>) with 2-(1-propyl-1H-imidazol-5-yl)-4,4,5,5-tetramethyl-4,5-dihydro-1H-imidazole-3-oxide-1-oxyl (L<small><sup>Pr</sup></small>) at ambient conditions. The conversion of powdered polymeric chain [Cu(hfac)<small><sub>2</sub></small>L<small><sup>Pr</sup></small>]·0.5THF and [Cu(hfac)<small><sub>2</sub></small>L<small><sup>Pr</sup></small>]·0.5(CH<small><sub>3</sub></small>)<small><sub>2</sub></small>CO complexes, accompanied by the loss of solvent molecules, occurs completely into binuclear [Cu(hfac)<small><sub>2</sub></small>L<small><sup>Pr</sup></small>]<small><sub>2</sub></small> within a day. On the other hand, in the case of [Cu(hfac)<small><sub>2</sub></small>L<small><sup>Pr</sup></small>]·0.5Solv (Solv = CH<small><sub>2</sub></small>Cl<small><sub>2</sub></small>, CH<small><sub>2</sub></small>Br<small><sub>2</sub></small>, CHCl<small><sub>3</sub></small>), the partial transformation into desolvated 1D polymer [Cu(hfac)<small><sub>2</sub></small>L<small><sup>Pr</sup></small>] or its mixture with [Cu(hfac)<small><sub>2</sub></small>L<small><sup>Pr</sup></small>]<small><sub>2</sub></small> takes much longer time. The magnetic behavior of the isostructural solvates is highly sensitive to the included solvent molecules. The complexes with THF, CH<small><sub>2</sub></small>Cl<small><sub>2</sub></small>, CH<small><sub>2</sub></small>Br<small><sub>2</sub></small>, and CHCl<small><sub>3</sub></small> undergo a transition to a magnetically ordered state below 4 K, a phenomenon reported for the first time for the polymeric chain Cu(II) complexes with a “head-to-tail” motif. [Cu(hfac)<small><sub>2</sub></small>L<small><sup>Pr</sup></small>]·0.5THF and [Cu(hfac)<small><sub>2</sub></small>L<small><sup>Pr</sup></small>]·0.5(CH<small><sub>3</sub></small>)<small><sub>2</sub></small>CO undergo a spin transition at 190 K, which is induced by the transformation of the Cu atom environment. In the case of the THF solvate, the increase in the distances between the Cu and oxygen atoms leads to enhanced ferromagnetic exchange interactions, while in the acetone solvate, the nitroxide coordination type changes from axial to equatorial at certain coordination sites, resulting in the emergence of strong antiferromagnetic exchange.","PeriodicalId":71,"journal":{"name":"Dalton Transactions","volume":null,"pages":null},"PeriodicalIF":4.0,"publicationDate":"2024-07-12","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"141597288","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":3,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Cyclometalated iridium(III) tetrazine complexes for mitochondria-targeted two-photon photodynamic therapy 用于线粒体靶向双光子光动力疗法的环甲基化铱(III)四嗪配合物
IF 4 3区 化学
Dalton Transactions Pub Date : 2024-07-12 DOI: 10.1039/d4dt01665c
Zanru Tan, Mingwei Lin, Jiangping Liu, Huihui Wu, Hui Chao
{"title":"Cyclometalated iridium(III) tetrazine complexes for mitochondria-targeted two-photon photodynamic therapy","authors":"Zanru Tan, Mingwei Lin, Jiangping Liu, Huihui Wu, Hui Chao","doi":"10.1039/d4dt01665c","DOIUrl":"https://doi.org/10.1039/d4dt01665c","url":null,"abstract":"The fast-moving field of photodynamic therapy (PDT) has provided fresh opportunities to expand the potential of metallodrugs to combat cancers in a light-controlled manner. As such, in the present study, a series of cyclometalated Ir(III) complexes modified with tetrazine functional group (namely Ir-ppy-Tz, Ir-pbt-Tz, Ir-dfppy-Tz) are developed as potential two-photon photodynamic anticancer agents. These complexes target mitochondria but exhibit low toxicity towards HLF primary lung fibroblast normal cells in the dark. When receiving a low-dose one- or two-photon PDT, they become highly potent towards A549 lung cancer cells (IC50 values ranging from 24.0 nM to 96.0 nM) through the generation of reactive oxygen species (ROS) to induce mitochondrial damage and subsequent apoptosis. Our results indicated that the incorporation of tetrazine with cyclometalated Ir(III) matrices would increase the singlet oxygen (1O2) quantum yield (ΦΔ) and, meanwhile, enable a type I PDT mechanism. Ir-pbt-Tz, with an utmost two-photon absorption (TPA) cross-section (σ2 = 102 GM), shows great promise in serving as a two-photon PDT agent for phototherapy.","PeriodicalId":71,"journal":{"name":"Dalton Transactions","volume":null,"pages":null},"PeriodicalIF":4.0,"publicationDate":"2024-07-12","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"141597233","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":3,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Reduction of hexaazatrinaphthylenes by divalent lanthanocenes leads to ligand-based multiconfigurational properties 二价镧系元素还原六氮杂萘导致基于配体的多构型特性
IF 4 3区 化学
Dalton Transactions Pub Date : 2024-07-12 DOI: 10.1039/d4dt01835d
Siobhan Temple, Jinkui Tang, Graham J. Tizzard, Akseli Mansikkamäki, Richard Layfield
{"title":"Reduction of hexaazatrinaphthylenes by divalent lanthanocenes leads to ligand-based multiconfigurational properties","authors":"Siobhan Temple, Jinkui Tang, Graham J. Tizzard, Akseli Mansikkamäki, Richard Layfield","doi":"10.1039/d4dt01835d","DOIUrl":"https://doi.org/10.1039/d4dt01835d","url":null,"abstract":"Reduction of hexaazatrinaphthylene (HAN) and its hexamethyl derivative with [Cp*<small><sub>2</sub></small>Sm(THF)<small><sub>2</sub></small>] or [Cp*<small><sub>2</sub></small>Yb(OEt<small><sub>2</sub></small>)] produces [(Cp*<small><sub>2</sub></small>Ln)<small><sub>3</sub></small>(R<small><sub>6</sub></small>HAN)] (Ln = Sm, Yb; R = H, Me), where the heterocyclic ligand forms as a trianion. The magnetism and electronic structure of these compounds reflect unusual multiconfigurational character within the reduced ligand but not the lanthanide ions.","PeriodicalId":71,"journal":{"name":"Dalton Transactions","volume":null,"pages":null},"PeriodicalIF":4.0,"publicationDate":"2024-07-12","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"141597287","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":3,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Mechanochemical Synthesis of Iron Aluminyl Complexes 铁铝络合物的机械化学合成
IF 4 3区 化学
Dalton Transactions Pub Date : 2024-07-11 DOI: 10.1039/d4dt01774a
Fabian Kallmeier, Aidan Matthews, Gareth Roland Nelmes, Nina Ray Lawson, Jamie Hicks
{"title":"Mechanochemical Synthesis of Iron Aluminyl Complexes","authors":"Fabian Kallmeier, Aidan Matthews, Gareth Roland Nelmes, Nina Ray Lawson, Jamie Hicks","doi":"10.1039/d4dt01774a","DOIUrl":"https://doi.org/10.1039/d4dt01774a","url":null,"abstract":"A series of iron aluminyl complexes have been synthesised in good crystalline yields from reactions between bulky diamido aluminium iodide complexes and K[Fe(CO)2Cp] in the solid state. The series of metal-metal bonded complexes have been characterised by X-ray crystallography and were investigated using density functional theory to probe the effects of ligand substitution on the Al-Fe bond.","PeriodicalId":71,"journal":{"name":"Dalton Transactions","volume":null,"pages":null},"PeriodicalIF":4.0,"publicationDate":"2024-07-11","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"141597293","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":3,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Position of substituents directs the electron transfer properties of entatic state complexes: new insights from guanidine-quinoline copper complexes 取代基的位置引导内态复合物的电子转移特性:从胍-喹啉铜复合物中获得的新启示
IF 4 3区 化学
Dalton Transactions Pub Date : 2024-07-11 DOI: 10.1039/d4dt01539h
Joshua Heck, Anastasia Kucenko, Alexander Hoffmann, Sonja Herres-Pawlis
{"title":"Position of substituents directs the electron transfer properties of entatic state complexes: new insights from guanidine-quinoline copper complexes","authors":"Joshua Heck, Anastasia Kucenko, Alexander Hoffmann, Sonja Herres-Pawlis","doi":"10.1039/d4dt01539h","DOIUrl":"https://doi.org/10.1039/d4dt01539h","url":null,"abstract":"In a previous study, we showed that the properties and the ability as entatic state model of copper guanidine quinoline complexes are significantly influenced by a methyl or methyl ester substituent in the 2-position. To prove the importance of the 2-position of the substituent, two novel guanidine quinoline ligands with a methyl or methyl ester substituent in the 4-position and the corresponding copper complexes were synthesized and characterized in this study. The influence of the substituent position on the copper complexes was investigated with various experimental and theoretical methods. The molecular structures of the copper complexes were examined in the solid state by single-crystal X-ray diffraction (SCXRD) and by density functional theory (DFT) calculations indicating a strong dependency on the substituent position compared to the systems substituted in the 2-position from the previous study. Further, the significantly different influence on the donor properties in dependency on the substituent position was analyzed with natural bond orbital (NBO) calculations. By the determination of the redox potentials, the impact on the electrochemical stabilization was examined. With regard to further previously analyzed guanidine quinoline copper complexes, the electrochemical stabilization was correlated with the charge-transfer energies calculated by NBO analysis and ground state energies, revealing the substituent influence and enabling a comparatively easy and accurate possibility for the theoretical calculation of the relative redox potential. Finally, the electron transfer properties were quantified by determining the electron self-exchange rates via the Marcus theory and by theoretical calculation of the reorganization energies via Nelsen’s four-point method. The results gave important insights into the dependency between the ability of the copper complexes as entatic state model and the type and position of the substituent.","PeriodicalId":71,"journal":{"name":"Dalton Transactions","volume":null,"pages":null},"PeriodicalIF":4.0,"publicationDate":"2024-07-11","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"141597289","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":3,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Correction: Addressing the gaps in homeostatic mechanisms of copper and copper dithiocarbamate complexes in cancer therapy: a shift from classical platinum-drug mechanisms. 更正:解决铜和二硫代氨基甲酸铜复合物在癌症治疗中的平衡机制问题:经典铂类药物机制的转变。
IF 3.5 3区 化学
Dalton Transactions Pub Date : 2024-07-11 DOI: 10.1039/d3dt90193a
Lydia W Njenga, Simon N Mbugua, Ruth A Odhiambo, Martin O Onani
{"title":"Correction: Addressing the gaps in homeostatic mechanisms of copper and copper dithiocarbamate complexes in cancer therapy: a shift from classical platinum-drug mechanisms.","authors":"Lydia W Njenga, Simon N Mbugua, Ruth A Odhiambo, Martin O Onani","doi":"10.1039/d3dt90193a","DOIUrl":"https://doi.org/10.1039/d3dt90193a","url":null,"abstract":"<p><p>Correction for 'Addressing the gaps in homeostatic mechanisms of copper and copper dithiocarbamate complexes in cancer therapy: a shift from classical platinum-drug mechanisms' by Lydia W. Njenga <i>et al.</i>, <i>Dalton Trans.</i>, 2023, <b>52</b>, 5823-5847, https://doi.org/10.1039/D3DT00366C.</p>","PeriodicalId":71,"journal":{"name":"Dalton Transactions","volume":null,"pages":null},"PeriodicalIF":3.5,"publicationDate":"2024-07-11","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"141578319","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":3,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Co-doping regulation on Ni-based electrocatalyst to adjust the selectivity of oxygen reduction reaction for Zn-air battery and H2O2 production 在镍基电催化剂上进行共掺杂调节,以调整锌-空气电池和 H2O2 生产中氧还原反应的选择性
IF 4 3区 化学
Dalton Transactions Pub Date : 2024-07-11 DOI: 10.1039/d4dt01625d
SongHan Hu, Kai Wang, xinxin xu, Qiang Wang
{"title":"Co-doping regulation on Ni-based electrocatalyst to adjust the selectivity of oxygen reduction reaction for Zn-air battery and H2O2 production","authors":"SongHan Hu, Kai Wang, xinxin xu, Qiang Wang","doi":"10.1039/d4dt01625d","DOIUrl":"https://doi.org/10.1039/d4dt01625d","url":null,"abstract":"Although Ni-based materials are widely used as electrocatalysts, it remains necessary to further explore their selectivity towards four- or two-electron oxygen reduction reaction (ORR). Herein, it is proposed to synthesize NiO@NCNTs (NCNTs = N-doped carbon nanotubes) with a metal-organic framework (MOF), [Ni(BZIDA)(H2O)]n (NiMOF, BZIDA = benzimidazole-5,6-dicarboxylic acid) as precursor after the calcination with dicyandiamide (DCDA). Regarding NiO@NCNTs, small NiO particles are distributed in the NCNTs derived from DCDA homogeneously. NiO@NCNTs is a typical two-electron electrocatalyst. The H2O2 production rate of NiO@NCNTs reaches 0.5 mol•g-1•h-1 at 0.46 V (vs. RHE). After doping of Co2+ in NiMOF, Co/NiO@NCNTs is synthesized using a similar method, with four-electron character shown in ORR. Zn-air battery is assembled by applying Co/NiO@NCNTs as cathode material. When discharge occurs at 5 and 10 mA•cm-2, its specific capacitance reaches 779.3 and 832.2 mAh•g-1 with an energy density of 928.6 and 948.5 Wh•kg-1, respectively. Theoretical calculation suggests a variation in ORR selectivity between NiO@NCNTs and Co/NiO@NCNTs, which results from their different interactions with OOH*. This study demonstrates the effect of structure on ORR selectivity for Ni-based electrocatalysts.","PeriodicalId":71,"journal":{"name":"Dalton Transactions","volume":null,"pages":null},"PeriodicalIF":4.0,"publicationDate":"2024-07-11","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"141597292","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":3,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Recent Advances and Perspectives for Intercalation Layered Compounds Part 1: Design and applications in the field of energy 互锁层状化合物的最新进展与前景 第 1 部分:能源领域的设计与应用
IF 4 3区 化学
Dalton Transactions Pub Date : 2024-07-11 DOI: 10.1039/d4dt00755g
Chiara Bisio, Jocelyne Brendle, Sébastien Cahen, Yongjun Feng, Seong-Ju Hwang, Klara Melanova, Morena Nocchetti, Dermot O'Hare, Pierre Rabu, Fabrice Leroux
{"title":"Recent Advances and Perspectives for Intercalation Layered Compounds Part 1: Design and applications in the field of energy","authors":"Chiara Bisio, Jocelyne Brendle, Sébastien Cahen, Yongjun Feng, Seong-Ju Hwang, Klara Melanova, Morena Nocchetti, Dermot O'Hare, Pierre Rabu, Fabrice Leroux","doi":"10.1039/d4dt00755g","DOIUrl":"https://doi.org/10.1039/d4dt00755g","url":null,"abstract":"After a general overview of the overworld financial support for chemistry devoted to materials science and more specifically to intercalation layered compounds (ILCs), the strategies to synthesize such host structure and subsequent guest-host hybrid assembly are exemplified on the basis of some families of materials including pillared clays (PILC), porous clay heterostructure (PCH), Zirconium phosphate (ZrP), layered double hydroxide (LDH), graphite intercalation compounds (GIC), graphene-based, MXenes… Additionally a non-exhaustive survey on their possible application in the field of energy through electrochemical storage mostly as electrode materials but also as electrolyte additives is presented including lithium technologies based on lithium ion batterie (LIB) and also «beyond LiBs» with a focus on the possible alternatives such XIB (X = Na (NIB), K (KIB), Al (AIB), Zn (ZIB), Cl (CIB), reversible Mg batteries (RMB), Dual-ion batteries (DIB), Zn-air, Zn-sulphur… and supercapacitors as well as their relevance in other fields regarding (opto)electronics. This selective panorama should help to better understand the reason why ILCs are expected to meet the challenge of tomorrow as electrode materials.","PeriodicalId":71,"journal":{"name":"Dalton Transactions","volume":null,"pages":null},"PeriodicalIF":4.0,"publicationDate":"2024-07-11","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"141597291","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":3,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
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