Yin Wang, Zilong Cao, Tong Liu, Lin Wang, Zhongbao Fu, Yujuan Li, Jianhua Xu and Jiajun Fu
{"title":"High-modulus supramolecular glassy polymers: a review","authors":"Yin Wang, Zilong Cao, Tong Liu, Lin Wang, Zhongbao Fu, Yujuan Li, Jianhua Xu and Jiajun Fu","doi":"10.1039/D5QM00003C","DOIUrl":"https://doi.org/10.1039/D5QM00003C","url":null,"abstract":"<p >Supramolecular glassy polymers are innovative and versatile materials. Their tunable mechanical properties and sustainability have become the focus of current research. This review presents recent research on high-modulus and high-performance supramolecular glassy polymers, emphasizing the importance of using supramolecular bonding (non-covalent bonding) in design strategies to enhance material properties. In addition, the paper explores the cyclic utilization as well as self-healing capabilities of these polymers through non-covalent bonding and looks into the potential applications of supramolecular glassy polymers. Finally, the paper presents the current opportunities and major challenges in developing supramolecular glassy polymers, providing new ideas for high-performance materials.</p>","PeriodicalId":86,"journal":{"name":"Materials Chemistry Frontiers","volume":" 7","pages":" 1101-1117"},"PeriodicalIF":6.0,"publicationDate":"2025-02-27","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"143688101","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":2,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Bing Wang, Yao Liu, Hong Hao, YuZhen Zhao, ZeMin He, WenQi Song, EnZhou Liu, Zhuo Li and ZongCheng Miao
{"title":"Alteration of internal electron migration pathways in La-doped Ag3PO4 for improved photocatalytic stability†","authors":"Bing Wang, Yao Liu, Hong Hao, YuZhen Zhao, ZeMin He, WenQi Song, EnZhou Liu, Zhuo Li and ZongCheng Miao","doi":"10.1039/D5QM00039D","DOIUrl":"https://doi.org/10.1039/D5QM00039D","url":null,"abstract":"<p >Metal ion doping is an effective strategy to improve the charge carrier separation pathways in semiconductors. In this study, La<small><sup>3+</sup></small> ions were introduced into Ag<small><sub>3</sub></small>PO<small><sub>4</sub></small><em>via</em> an <em>in situ</em> co-precipitation method, forming p-type doped La<small><sub><em>x</em></sub></small>Ag<small><sub>3−<em>x</em></sub></small>PO<small><sub>4</sub></small> without altering the original cubic morphology of Ag<small><sub>3</sub></small>PO<small><sub>4</sub></small>. The introduction of La<small><sup>3+</sup></small> led to a reduction in the band gap, an expansion of the light absorption range, and an increase in electron localization. Density functional theory (DFT) calculations revealed that La doping introduces new states within the band gap, facilitating energy transitions and altering the electronic structure. Time-dependent DFT (TDDFT) calculations confirmed that the introduction of La<small><sup>3+</sup></small> enables photoexcited electrons to predominantly migrate from Ag 4d and O 2p orbitals to La 4d and P 2p orbitals. This key finding unveiled the anti-photocorrosion mechanism of La<small><sub><em>x</em></sub></small>Ag<small><sub>3−<em>x</em></sub></small>PO<small><sub>4</sub></small>. Free radical capture experiments and electron paramagnetic resonance (EPR) analysis demonstrated that La doping enhances the electron migration efficiency in La<small><sub><em>x</em></sub></small>Ag<small><sub>3−<em>x</em></sub></small>PO<small><sub>4</sub></small>, promoting the conversion of ˙O<small><sub>2</sub></small><small><sup>−</sup></small> to ˙OH radicals. This study not only provides an innovative approach for the application of La-doped Ag<small><sub>3</sub></small>PO<small><sub>4</sub></small> in environmental pollutant catalysis but also reveals a novel internal electron transfer pathway and the underlying mechanism for enhanced photocatalytic activity.</p>","PeriodicalId":86,"journal":{"name":"Materials Chemistry Frontiers","volume":" 7","pages":" 1189-1204"},"PeriodicalIF":6.0,"publicationDate":"2025-02-24","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"143688201","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":2,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
{"title":"Prolonged irradiation-induced delayed luminescence of PMMA-dispersed imide compounds containing ether- and thioether-bridged cores†","authors":"Marina Doi, Haonan Liu and Shinji Ando","doi":"10.1039/D4QM00871E","DOIUrl":"https://doi.org/10.1039/D4QM00871E","url":null,"abstract":"<p >Time variations in the photoluminescence (PL) properties of four types of imide compounds (ICs) with ether (OD-IC), thioether (SD-IC), dibenzofuran (BO-IC), and dibenzothiophene (BS-IC) cores dispersed in polymer films were investigated to elucidate the effects of the introduction of sulfur atoms and the structural rigidity of the ICs on their PL properties under continuous UV irradiation. These ICs exhibit photoactivated delayed phosphorescence (PH) from the excited triplet state (T<small><sub>1</sub></small>), which is called prolonged irradiation-induced delayed luminescence (PIDL), after a few minutes of induction time, during which only fluorescence is observed. This result is because oxygen quenching efficiency gradually weakens as the ground-state oxygen decreases <em>via</em> energy transfer from the ICs in the T<small><sub>1</sub></small> state. As compared with the ICs containing ether linkages (OD-IC, BO-IC), the PHs of the ICs containing thioether linkages (SD-IC and BS-IC) were significantly enhanced by the heavy atom effect, and these showed bathochromic (red) shifts of the PL peaks owing to the extended π-conjugation. Furthermore, the ICs containing five-membered cores (BO-IC and BS-IC) demonstrated longer PIDL lifetimes and shorter induction times than those of the ICs containing flexible linkages (OD-IC and SD-IC), owing to their structural rigidity. In particular, BS-IC exhibited an excellent PIDL properties such as the largest intensity (<em>I</em> = 2480), a long lifetime (<em>τ</em><small><sub>PIDL</sub></small> = 410 ms), and a short induction time (<em>t</em><small><sub>ID</sub></small> = 1.55 min) owing to the rigid core containing a sulfur atom. Based on the results, this study provides a valuable strategy for developing novel PIDL materials.</p>","PeriodicalId":86,"journal":{"name":"Materials Chemistry Frontiers","volume":" 7","pages":" 1139-1148"},"PeriodicalIF":6.0,"publicationDate":"2025-02-18","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://pubs.rsc.org/en/content/articlepdf/2025/qm/d4qm00871e?page=search","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"143688104","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":2,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"OA","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Peipei Feng, Chaonan He, Guanrong Li, Jin Li, Chunhai Ke and Jingyun Ma
{"title":"Recent advances in tailored chitosan-based hydrogels for bone regeneration and repair","authors":"Peipei Feng, Chaonan He, Guanrong Li, Jin Li, Chunhai Ke and Jingyun Ma","doi":"10.1039/D4QM00944D","DOIUrl":"https://doi.org/10.1039/D4QM00944D","url":null,"abstract":"<p >The increasing prevalence of bone injuries and the current lack of effective repair solutions present a significant clinical challenge. Chitosan-based hydrogels have gained widespread use in bone regeneration and repair due to their favorable biocompatibility, biodegradability, and antimicrobial properties. Advances in preparation techniques have enabled the development of various tailored chitosan-based hydrogels, including nanogels, nanofibers, microspheres, and scaffolds, which are successfully applied in bone tissue regeneration. However, there is currently a lack of comprehensive reviews covering tailored chitosan hydrogels specifically for bone tissue repair. This paper addresses that gap by comprehensively summarizing the preparation processes of tailored chitosan-based hydrogels, along with their specific applications in bone regeneration. It aims to inspire innovative designs for improved chitosan-based hydrogels and foster expanded applications, ultimately leading to better therapeutic outcomes for patients with bone-related diseases.</p>","PeriodicalId":86,"journal":{"name":"Materials Chemistry Frontiers","volume":" 6","pages":" 910-934"},"PeriodicalIF":6.0,"publicationDate":"2025-02-17","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"143583291","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":2,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Cong Ma, Kai Bao, Junlei Qi, Wenbin Wang, Jingkun Wu, Ruijie Li, Yu Lin, Lingzhi Wang, Zhuangzhuang Yin, Zhixiang Tao, Chengxuan Ke, Zongxiao Wu, Yingxia Liu and Qiyuan He
{"title":"Emerging 15–16 group Xenes: structures, properties, preparation methods, and their catalytic applications","authors":"Cong Ma, Kai Bao, Junlei Qi, Wenbin Wang, Jingkun Wu, Ruijie Li, Yu Lin, Lingzhi Wang, Zhuangzhuang Yin, Zhixiang Tao, Chengxuan Ke, Zongxiao Wu, Yingxia Liu and Qiyuan He","doi":"10.1039/D4QM01089B","DOIUrl":"https://doi.org/10.1039/D4QM01089B","url":null,"abstract":"<p >Elemental two-dimensional (2D) materials, commonly referred to as Xenes, have attracted recent attention due to their many unique/remarkable chemical and physical properties. Xenes hold immense promise for multifarious applications across diverse domains, including optoelectronics, energy storage, energy conversion and biomedicine. Beyond graphene and phosphorene, a new cadre of Xenes has emerged, with particular attention directed toward antimonene, arsenene, tellurene and selenene. These nascent Xenes have garnered substantial interest due to their diverse allotropes, as well as their distinctive layer-dependent and modifiable properties, rendering them highly adaptable for engineering and catalytic applications. Herein, an overview is provided for the recent advancements in the structures, inherent properties and degradation behavior of Xenes, drawing upon both theoretical and experimental research. The synthesis methods of Xenes are summarized and primarily classified as bottom-up and top-down approaches. Furthermore, the catalytic potential of Xenes is elaborated, emphasizing both engineering strategies and theoretical understanding toward enhanced performance across a spectrum of catalytic reactions. Conclusively, a summary and perspectives on the future development of Xenes are given to boost their development.</p>","PeriodicalId":86,"journal":{"name":"Materials Chemistry Frontiers","volume":" 7","pages":" 1075-1100"},"PeriodicalIF":6.0,"publicationDate":"2025-02-16","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://pubs.rsc.org/en/content/articlepdf/2025/qm/d4qm01089b?page=search","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"143688100","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":2,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"OA","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
{"title":"Conformational regulation to realize modifiable ESIPT (excited-state intramolecular proton transfer) through intermolecular interactions†","authors":"Shao-Zhe Yi, Bao-Ning Li, Wen He and Mei Pan","doi":"10.1039/D5QM00012B","DOIUrl":"https://doi.org/10.1039/D5QM00012B","url":null,"abstract":"<p >Regulating molecular conformation changes is crucial yet challenging for manipulating multiple-responsive emissions in excited-state intramolecular proton transfer (ESIPT) materials. In this work, we explored the specific emission regulation of a dual-ESIPT-active molecule, BDIBD (2,5-bis(4,5-diphenyl-1<em>H</em>-imidazol-2-yl)benzene-1,4-diol), by subtly controlling the ground and excited states through different crystallization conformations. Notably, the crystals obtained in dimethylformamide (BDIBD–DMF) and methanol (BDIBD–MeOH) exhibited a single emission band, corresponding to the green and red emission from the keto<small><sup>1st</sup></small> and keto<small><sup>2nd</sup></small> excited states, respectively, while the crystals obtained in acetone (BDIBD–ACE) displayed dual emissions from both states, resulting in an overall yellow color. A comprehensive theoretical study verified that the modified intermolecular interactions, due to different crystallization conformations, regulated emissions by affecting the energy barrier of dual-ESIPT processes. The above results provide a concrete understanding of the regulation of excited-state emissions through ground-state conformational changes in ESIPT processes, as well as unique insights into the design and application of novel ESIPT emission materials.</p>","PeriodicalId":86,"journal":{"name":"Materials Chemistry Frontiers","volume":" 7","pages":" 1181-1188"},"PeriodicalIF":6.0,"publicationDate":"2025-02-15","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://pubs.rsc.org/en/content/articlepdf/2025/qm/d5qm00012b?page=search","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"143688173","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":2,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"OA","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Yoshimichi Shimomura, Yuuto Iida, Eiji Tsurumaki and Gen-ichi Konishi
{"title":"Innovative molecular design of bridged biphenyls for calamitic nematic liquid crystals with extensive π-conjugated mesogens†","authors":"Yoshimichi Shimomura, Yuuto Iida, Eiji Tsurumaki and Gen-ichi Konishi","doi":"10.1039/D4QM01116C","DOIUrl":"https://doi.org/10.1039/D4QM01116C","url":null,"abstract":"<p >To develop advanced materials based on calamitic nematic liquid crystals, it is essential to design functional optoelectronic mesogens that can form nematic phases at low temperatures. This study proposes a new molecular design strategy for low-temperature nematic liquid crystals using large π-conjugated mesogens with optical/electrical functions. Bridged biphenyls were synthesized by bridging the two phenyl rings with propylene. This bridging structure reduced the molecular planarity and prevented the molecules from aligning neatly in one direction, resulting in lowering the temperature range of the nematic phases. Terphenyl and phenyltolane derivatives exhibited supercooled nematic phases at room temperature, while quarterphenyl and bis(phenylethynyl)-biphenyl derivates exhibited nematic phases below 100 °C. The proposed design is more effective for rigid mesogens compared to conventional calamitic nematic liquid crystal design.</p>","PeriodicalId":86,"journal":{"name":"Materials Chemistry Frontiers","volume":" 7","pages":" 1127-1138"},"PeriodicalIF":6.0,"publicationDate":"2025-02-14","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://pubs.rsc.org/en/content/articlepdf/2025/qm/d4qm01116c?page=search","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"143688103","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":2,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"OA","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
{"title":"Recent advances in nanozyme-based materials for environmental pollutant detection and remediation","authors":"Bei Li, Ping Li and Ruijiao Dong","doi":"10.1039/D4QM01009D","DOIUrl":"https://doi.org/10.1039/D4QM01009D","url":null,"abstract":"<p >Natural enzymes inevitably suffer from inherent limitations, including low stability, high cost, sensitive catalytic activity toward environmental stimuli, and difficulties in recycling and reusing. To address these limitations, a number of enzyme mimics, particularly nanozymes, have been widely explored as superior candidates to mimic natural enzymes because of their low cost, high stability, flexibility and controllable catalytic activity. Because of their outstanding physicochemical properties, nanozymes demonstrate widespread applications in disease diagnosis and treatment, antibacterial agents, chemical sensing, and environmental pollutant monitoring and remediation. This review summarizes recent progress in the design and fabrication of nanozyme-based materials and their catalytic mechanisms and application in environmental pollutant detection and remediation. The present challenges and future perspectives are discussed for the development of multifunctional nanozyme material systems with high-efficiency, high-selectivity, and good stability. Further expansion of their real-world applicability in environmental fields would greatly inspire more novel research directions in this emerging area.</p>","PeriodicalId":86,"journal":{"name":"Materials Chemistry Frontiers","volume":" 6","pages":" 935-952"},"PeriodicalIF":6.0,"publicationDate":"2025-02-13","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"143583294","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":2,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Zhifang Wang, Yingying Zhang, Di Xue, Yandong Wang, Zi Wang, Lifeng Chi and Lizhen Huang
{"title":"Promoting phototransistor performance by utilizing solution epitaxy templated organic semiconductor films†","authors":"Zhifang Wang, Yingying Zhang, Di Xue, Yandong Wang, Zi Wang, Lifeng Chi and Lizhen Huang","doi":"10.1039/D4QM00896K","DOIUrl":"https://doi.org/10.1039/D4QM00896K","url":null,"abstract":"<p >The quality of organic semiconductor films plays a crucial role in carrier transport and the overall performance of organic phototransistors (OPTs). Various approaches have been explored to enhance the morphology of organic films, and one effective method involves using crystalline templates with large domain sizes to promote the growth of the upper active films. However, strategies for obtaining continuous and uniform template layers over large areas are still in high demand. Herein, we employ a “solution epitaxy” method to fabricate a uniform C<small><sub>32</sub></small>H<small><sub>66</sub></small> crystalline film as the template layer, facilitating the growth of the organic semiconductor 2,8-difluoro-5,11-bis(triethylsilylethynyl)anthradithiophene (diF-TES-ADT) over a large area. Our results demonstrate that the morphology of the epitaxial films strongly depends on the morphology and thickness of the template layer. By optimizing the template layer, we successfully obtain terraced-like organic semiconductor films with excellent crystallinity with large domain sizes. These epitaxially grown films are then employed as carrier transport channels in OPTs, leading to the development of high-performance devices with a sensitivity of 3.74 × 10<small><sup>6</sup></small> and a responsivity of 6.2 × 10<small><sup>3</sup></small> A W<small><sup>−1</sup></small>. Furthermore, the obtained phototransistors show promising potential for emulating synaptic behavior with their dependence on illumination power intensity and UV light addition time. This finding provides a feasible strategy for obtaining high-quality organic films with efficient charge transport and high photoresponse properties.</p>","PeriodicalId":86,"journal":{"name":"Materials Chemistry Frontiers","volume":" 7","pages":" 1174-1180"},"PeriodicalIF":6.0,"publicationDate":"2025-02-13","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"143688107","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":2,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
{"title":"Piezoelectric polymers and their applications in antimicrobial fields","authors":"Xiuqing Wang, Shujun Zhang, Yushan Hu, Wen Zhou and Xiaojing Huang","doi":"10.1039/D4QM00930D","DOIUrl":"https://doi.org/10.1039/D4QM00930D","url":null,"abstract":"<p >Bacterial resistance poses a significant threat to human beings, highlighting the crucial need to explore new antimicrobial strategies. Piezoelectric polymers, as innovative macromolecules, can exhibit antimicrobial effects through the generation of electric fields when triggered by mechanical energy. Recent research studies have highlighted piezoelectric polymers as promising antimicrobial strategies due to their unique piezoelectric characteristics, lower susceptibility to bacterial resistance, and superior biocompatibility. These polymers exert antimicrobial effects in response to external mechanical stimuli, offering the advantages of precise treatment and remote control, showing application potential in various areas, such as healthcare, textile manufacturing, food packaging, and environmental protection. This review summarizes the antimicrobial effects, mechanisms, biocompatibility, and applications of piezoelectric polymers in the antimicrobial fields, aiming to provide a theoretical basis and practical guidance for their further in-depth explorations and innovative applications.</p>","PeriodicalId":86,"journal":{"name":"Materials Chemistry Frontiers","volume":" 5","pages":" 754-771"},"PeriodicalIF":6.0,"publicationDate":"2025-02-10","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"143480862","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":2,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}