ACS Applied Materials & Interfaces最新文献

{"title":"Enantioselective Recognition Driven Photocatalytic Degradation of d-Tryptophan Enantiomers Based on l-Cysteine-Modified β-Cyclodextrin","authors":"Hongfang Zhao, Jianrong Wang, Hongxia Li, Xiaohui Niu, Hui Xu, Kunjie Wang","doi":"10.1021/acsami.4c21850","DOIUrl":"https://doi.org/10.1021/acsami.4c21850","url":null,"abstract":"The enantioselective recognition and separation of racemic tryptophan are of significant importance in the fields of medicine, pharmaceutics, and biochemistry. However, conventional methods are costly, energy intensive, and environmentally unfriendly. In this case, <span>l</span>-Cys with amino (−NH₂) and sulfhydryl (−SH) groups was chosen to modify β-CD with a chiral cavity to achieve self-assembly via hydrogen bonding, which not only serves as an electrochemical chiral sensor with enhanced chiral sites at the sensing interface but also achieves a higher enantioselectivity for <span>d</span>-tryptophan enantiomers through hydrogen bonding between the host and guest. Moreover, the <span>d</span>-tryptophan enantiomers were subsequently degraded under catalytic conditions simulating visible light, which was a new approach to introduce chiral properties in photocatalysis without organic synthesis. The use of inclusion-complex formation with β-CD combined with simple electrochemical technology and photocatalytic degradation techniques to efficiently and rapidly identify and degrade harmful <span>d</span>-type amino acid enantiomers offers new avenues, which would have great potential in future studies.","PeriodicalId":5,"journal":{"name":"ACS Applied Materials & Interfaces","volume":"53 1","pages":""},"PeriodicalIF":9.5,"publicationDate":"2025-02-26","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"143495907","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":2,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

{"title":"Radiation-Hardened Position-Sensitive Photodetector Based on Undoped 4H-SiC","authors":"Miaomiao Yang, Haoran Mu, Yanxia Cui, Jiangwei Cui, Yuying Xi, Shaoding Liu, Ye Yuan, Yun Li, Yu Wang, Youchen Chen, Guohui Li, Shenghuang Lin","doi":"10.1021/acsami.4c21547","DOIUrl":"https://doi.org/10.1021/acsami.4c21547","url":null,"abstract":"Position-sensitive photodetectors (PSDs) have been widely used for seamless, high-resolution light tracking, but applications such as aerospace and prolonged field operations require stable performance in extreme environments. Conventional PSDs, typically based on the lateral photovoltaic effect of silicon or other semiconductor junctions, are prone to radiation damage and material degradation, limiting their reliability under harsh conditions. Silicon carbide (SiC), with its wide bandgap, high mobility, low defect density, and strong resistance to radiation damage, offers a promising alternative for developing robust detectors. In this work, we present a PSD based on undoped 4H-SiC, designed with a simple vertical structure that eliminates the need for complex multi-interface architectures. The device demonstrates excellent performance, including a light on–off ratio exceeding 10³ under sub-milliwatt illumination, spatial resolution of ∼0.1 μm, and fast response times of ∼10 μs (rise) and ∼6.3 μs (fall). It also exhibits remarkable stability under γ-ray irradiation (300 krad) with minimal photocurrent variation, making it suitable for accurate position tracking in radiation-prone environments. This work highlights the potential of 4H-SiC-based PSDs for advanced sensing applications that demand both high performance and resilience in extreme environments.","PeriodicalId":5,"journal":{"name":"ACS Applied Materials & Interfaces","volume":"40 1","pages":""},"PeriodicalIF":9.5,"publicationDate":"2025-02-26","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"143495911","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":2,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

{"title":"Goodbye 2024, Hello to an Exciting 2025!","authors":"Xing Yi Ling","doi":"10.1021/acsami.5c01680","DOIUrl":"https://doi.org/10.1021/acsami.5c01680","url":null,"abstract":"Time truly flies when you are enjoying the journey, and it is hard to believe it has already been a year since I became Editor-in-Chief of &lt;i&gt;ACS Applied Materials &amp; Interfaces&lt;/i&gt; portfolio of journals. Reflecting on the past year, I feel deeply grateful for the growth we have shared and the achievements we have accomplished together. I am pleased to report that our submissions continued to increase in 2024. We are grateful for the ongoing support from authors, reviewers, and our dedicated journal development team. This year also marked the beginning of our Early Career Board Members program, and the overwhelming response is a testament to our community’s enthusiasm and engagement. Our 2024 ACS outreach activities (Figure 1), primarily in China, the United States, and South Korea, allowed me to meet many authors and reviewers and gain a deeper appreciation for their excellent work. I applaud each of you for your invaluable contributions to the field. Figure 1. (Top) Group photo and (bottom left) panel discussion at ACS On Campus at Sichuan University, October 2024. The panel discussion featured Erika Zhang (ACS Managing Editor), Yiying Wu (Deputy Editor of &lt;i&gt;ACS Applied Energy Materials&lt;/i&gt;), and Jiagang Wu (Associate Editor of &lt;i&gt;ACS Applied Materials &amp; Interfaces&lt;/i&gt;) on stage together, sharing insights. (Bottom right) A wonderful gathering to enjoy an authentic Korean meal after an afternoon of meetings at Ewha Womans University in November 2024 with our editors from Korean institutions, including Profs. Hyun-Jae Kim, Joohoo Moon, So-Jung Park, Sang Hoon Joo, Jang-Kun Song, Hyo Jae Yoon, Suyeon Cho, and Juyoung Yoon. . Year 2024 concluded with successful in-person Associate Editor meetings, such as &lt;i&gt;ACS Applied Materials &amp; Interfaces&lt;/i&gt; and &lt;i&gt;ACS Applied Polymer Materials&lt;/i&gt; at the ACS Spring Meeting 2024, &lt;i&gt;ACS Applied Optical Materials&lt;/i&gt; and &lt;i&gt;ACS Applied Electronic Materials&lt;/i&gt; at MRS, Seattle, &lt;i&gt;ACS Applied Bio Materials&lt;/i&gt; at CCS Chemistry in Guangzhou, and &lt;i&gt;ACS Applied Nano Materials&lt;/i&gt; and &lt;i&gt;ACS Applied Engineering Materials&lt;/i&gt; at the ACS Fall 2024 meeting. It is always challenging to bring our team together in one place, so thank you to everyone who made the effort to attend. At &lt;i&gt;ACS Applied Materials &amp; Interfaces&lt;/i&gt;, in 2024, we welcomed new Executive Editor Huaping Xu (Tsinghua University, China) and new Associate Editors Hao Ming Chen (National Taiwan University, Taiwan), Chong Liu (University of California Los Angeles, United States), Biswarup Pathak (Indian Institute of Technology Indore, India), Su Ying Quek (National University of Singapore, Singapore), Simone Raugei (Pacific Northwest National Laboratory, United States), Jianfang Wang (The Chinese University of Hong Kong, China), Yan Yu (University of Science and Technology of China, China), and Sara Thoi (Johns Hopkins University, United States). We also congratulate Prof. Fengwei Huo (Nanjing Tech University, China) on his promotion to Ex","PeriodicalId":5,"journal":{"name":"ACS Applied Materials & Interfaces","volume":"90 1","pages":""},"PeriodicalIF":9.5,"publicationDate":"2025-02-26","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"143496082","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":2,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

{"title":"Fe3O4-Based Nanospheres with High Photothermal Conversion Efficiency for Dual-Effect and Mild Biofilm Eradication against Periodontitis","authors":"Yuyao Li, Pei Wang, Yifan Liu, Xuefei Wu, Guangning Long, Yi Chen, Jiyan Wang, Fei Tong, Xiaolei Wang","doi":"10.1021/acsami.4c17966","DOIUrl":"https://doi.org/10.1021/acsami.4c17966","url":null,"abstract":"Periodontitis, a chronic inflammatory oral disease resulting from plaque biofilms, affects about 743 million individuals worldwide. However, the efficacy of current treatments is hampered by challenges in delivering antibiotics to recalcitrant oral biofilms and bacterial resistance, thereby impeding successful treatment of infectious diseases. To address the issues, an antibacterial photothermal material was designed, comprising a spherical structure of zinc oxide (ZnO) wrapped with triiron tetraoxide (Fe₃O₄). The outer layer of the material adsorbed epsilon-polylysine (EPL) by electrostatic action, ultimately leading to the fabrication of Fe₃O₄/ZnO/EPL nanoparticles (FZE NPs). The Fe₃O₄ core endowed the nanoparticles with efficient photothermal properties, facilitating the dispersion of dense biofilms, which dramatically promoted the adsorption and penetration of ZnO and EPL into the biofilms to effectively kill bacteria in biofilms <i>in vitro</i> with enhanced sterilization ability. Additionally, upon dissolution in aqueous media, EPL acts as a positively charged antimicrobial peptide that adsorbs onto the surface of negatively charged bacterial membranes, thereby effectively modulating inflammatory responses. In order to ascertain the efficacy of FZE NPs, an investigation was conducted into their antimicrobial effects against the periodontitis-associated pathogen <i>Porphyromonas gingivalis</i> (<i>P. gingivalis</i>) <i>in vitro</i>. Furthermore, the antiperiodontitis potential of FZE NPs was evaluated in Sprague–Dawley (SD) rats of ligamentous periodontitis. In addition, toxicity evaluations indicated that the material had an acceptable biosafety profile <i>in vitro</i> and <i>in vivo</i>. In summary, the nanospheres (FZE NPs) represent a promising therapeutic strategy for the treatment of periodontitis.","PeriodicalId":5,"journal":{"name":"ACS Applied Materials & Interfaces","volume":"15 1","pages":""},"PeriodicalIF":9.5,"publicationDate":"2025-02-26","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"143495906","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":2,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

{"title":"Simultaneous Visualization of Dynamical and Static Tactile Perception Using Piezoelectric-Ultrasonic Bimodal Electronic Skin Based on In Situ Polarized PVDF–TrFE/2DBP Composites and the TFT Array","authors":"Fuyang Wang, Pengfei Yang, Wei Liu, Zhiqiang Li, Zhao Wang, Yong Xiang, Qian Zhang, Xiaoran Hu","doi":"10.1021/acsami.4c21925","DOIUrl":"https://doi.org/10.1021/acsami.4c21925","url":null,"abstract":"The key to realizing completed bionic tactile perception of human skin using electronic skin relies on simultaneously distinguishing dynamic and static stimuli and restoring their characteristic information, which is realized by integration of several individual sensors but remains certain limitations including large physical size and high energy consumption. In this study, a piezoelectric-ultrasonic bimodal electronic skin (PUVE) based on <i>in situ</i> polarized PVDF–TrFE/2DBP composites and a thin-film transistor (TFT) array is fabricated. The incorporation of 2DBP into the PVDF–TrFE film and the <i>in situ</i> polarization approach provide excellent piezoelectric and ultrasonic performances of PVDF–TrFE/2DBP composites. PUVE has an ultrahigh sensitivity of 3.2 mV kPa^–1 over a wide pressure (0–310 kPa) range, with excellent spatial resolution (50 μm) and response time (40 ms). Meanwhile, the PUVE demonstrated outstanding repeatability and bending stability in 1500 cycles of cyclic pressure and 4000 cycles of 180° bending. The integrated piezoelectric and ultrasonic functions of PUVE can respond individually to dynamic and static tactile stimuli to ensure perceiving and decoupling of the dynamical and static mechanical signals with one single sensor. The PVDF–TrFE/2DBP composites is further integrated with the TFT array, realizing visualization function of contacting objects and restoring their characteristic information including the texture and location. Thus, the PUVE is expected to have a wide range of applications in intelligent robots and human prostheses.","PeriodicalId":5,"journal":{"name":"ACS Applied Materials & Interfaces","volume":"10 1","pages":""},"PeriodicalIF":9.5,"publicationDate":"2025-02-26","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"143495908","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":2,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

{"title":"Goodbye 2024, Hello to an Exciting 2025!","authors":"Xing Yi Ling,&nbsp;","doi":"10.1021/acsami.5c0168010.1021/acsami.5c01680","DOIUrl":"https://doi.org/10.1021/acsami.5c01680https://doi.org/10.1021/acsami.5c01680","url":null,"abstract":"","PeriodicalId":5,"journal":{"name":"ACS Applied Materials & Interfaces","volume":"17 8","pages":"11373–11374 11373–11374"},"PeriodicalIF":8.3,"publicationDate":"2025-02-26","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"143486911","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":2,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

{"title":"Polylactic Acid (PLA)-Based Persistent Room-Temperature Phosphorescence Polymer Nanoparticles for Bioimaging","authors":"Kaimin Zhang, Danman Guo, Tianyi Tang, Xuankun Fang, Faxu Lin, Xiang Long, Fangfang Ke, Xiaoyu Ji, Nipeng Chen, Zhen Zhang, Huahua Huang, Zhenguo Chi, Zhiyong Yang","doi":"10.1021/acsami.5c00656","DOIUrl":"https://doi.org/10.1021/acsami.5c00656","url":null,"abstract":"Recent advancements have focused on developing nanoscale persistent room-temperature phosphorescence (pRTP) structures to expand their applicability in biomedical fields. Traditional fabrication methods typically produce surface-coated core–shell pRTP nanoparticles composed of nonbiocompatible pRTP emitters at very high concentrations in the core. To overcome this limitation, polymeric pRTP nanosystems have been presented in this study as a promising alternative by embedding RTP molecules within the biocompatible polymer matrix, thereby significantly reducing the required concentration of RTP molecules. These polymer nanoparticles were fabricated using a biocompatible poly(lactic acid) (PLA) matrix by an effective microemulsion-based method. They exhibited similar pRTP properties to the traditional nanoparticles, showing comparable long-lasting phosphorescence with a lifetime of 118 ms even when the phosphorescent molecule content is below 2%. Moreover, the pRTP polymer nanoparticles with excellent biocompatibility and stability demonstrate interesting reversible photoactivated pRTP properties. They have been successfully applied for <i>in vivo</i> imaging with a high signal-to-noise ratio (SBR) of 2061, maintaining strong and long-lived phosphorescent emissions even for 20 min. These results highlight a viable approach to advancing the pRTP technology for biological applications.","PeriodicalId":5,"journal":{"name":"ACS Applied Materials & Interfaces","volume":"1 1","pages":""},"PeriodicalIF":9.5,"publicationDate":"2025-02-26","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"143495909","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":2,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

{"title":"Advancing the Preparation Strategy of High-Performance Integrated Electrodes for eCO2RR via Sublimation","authors":"Hao Zeng, Xiangbin Zou, Liu Han, Muyao Gao, Zhaoyu Chen, Yang Liu, Ming Yang, Bing Li, Ming Liu","doi":"10.1021/acsami.4c21322","DOIUrl":"https://doi.org/10.1021/acsami.4c21322","url":null,"abstract":"The uniform dispersion and loading of phthalocyanine molecular catalysts on conductive carbon substrates are crucial for exposing their active sites. The significant amount of solvent needed to achieve appropriate dispersion of phthalocyanine leads to the risk of reaggregation during solvent evaporation. Hence, a solventless strategy is adopted by many to bypass the use of a solvent. In this study, we showcase the deposition of transition metal phthalocyanine (TMPc) molecules onto a self-supporting conductive carbon cloth electrode using an environmentally friendly sublimation technique for efficient electrocatalytic CO₂ reduction. We meticulously investigated the preparation conditions, including the heating temperature and TMPc type, to assess their impact on the CO₂ reduction activity. The as-prepared CC-CoPc-450 electrode demonstrated an outstanding comprehensive performance, showcasing a remarkable maximum CO Faradaic efficiency (FE_CO) of 97.1% at −0.86 V with a current density of 8.3 mA cm^–2. The electrode exhibited excellent stability during the 16 h long-term eCO₂RR process. Density functional theory (DFT) calculations demonstrated the role of <i>d</i>-orbitals in TM-N₄ and the synergy with π-conjugation electrons in facilitating the efficient electron transfer process in eCO₂RR. This study offers a fresh perspective on the eco-friendly dispersion of TMPcs on conductive substrates and provides insights into the design of π-species macrocyclic electrocatalyst electrodes.","PeriodicalId":5,"journal":{"name":"ACS Applied Materials & Interfaces","volume":"41 1","pages":""},"PeriodicalIF":9.5,"publicationDate":"2025-02-25","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"143486395","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":2,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

{"title":"Gate-Tunable Short-Wave Infrared Polycrystalline GeSn Phototransistors on Noncrystalline Substrates","authors":"Priyanka Petluru, Shang Liu, Luke McClintock, Tenzin Norden, Yicheng Wang, Aaron J. Muhowski, Julia Deitz, Timothy Ruggles, Ping Lu, Prashant Padmanabhan, Jifeng Liu, Tzu-Ming Lu","doi":"10.1021/acsami.4c20693","DOIUrl":"https://doi.org/10.1021/acsami.4c20693","url":null,"abstract":"GeSn is a group-IV alloy with immense potential to advance microelectronics technology due to its intrinsic compatibility with existing Si CMOS processes. With a sufficiently high Sn composition, GeSn is classified as a direct bandgap semiconductor. Polycrystalline GeSn holds several additional advantages, including its significantly lower synthesis cost compared to its epitaxial counterpart, as well as the versatility to grow these films on a variety of substrates. Here, we present a polycrystalline thin-film GeSn phototransistor on a fused silica substrate with a Sn composition of ∼10%, showing a photoresponse in the short-wave infrared wavelength range, critical for emerging sensing applications. This device shows a gate-tunable response, with responsivities approaching up to 1.7 mA/W with only a 30 nm-thick GeSn layer. Furthermore, phototransistors offer additional adaptability through gating, which allows for the reduction of dark current. This not only enhances the signal-to-noise ratio but also offers more flexible integration with various image sensor readout implementations using different substrates. The specific detectivity of this phototransistor is within an order of magnitude of those of previously reported GeSn photodetectors grown by molecular beam epitaxy and chemical vapor deposition, even though the absorber is 3 to 20× thinner while the electrode spacing for photocarrier transport is approximately 15× longer than the carrier diffusion length in this work, showing great potential benefits of extending similar device structures to epitaxial GeSn layers. As these GeSn phototransistors utilize a noncrystalline substrate, our work establishes a fundamentally more versatile path toward monolithically integrated GeSn-based photodetectors for next-generation multimodal sensors.","PeriodicalId":5,"journal":{"name":"ACS Applied Materials & Interfaces","volume":"18 1","pages":""},"PeriodicalIF":9.5,"publicationDate":"2025-02-25","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"143495735","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":2,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

{"title":"Fabrication of Large-Area, Crack-Free Inverse Opals on Microfluidic Chips via Wet Infiltration","authors":"Peng Dai, Cuimin Sun, Wenyun Su, Shengchang Tang, Xiangfu Wei, Yongchao Cai, Guangyong Huang, Zhaokun Xian, Wei Han, Ling Zhu, Hui You","doi":"10.1021/acsami.4c21524","DOIUrl":"https://doi.org/10.1021/acsami.4c21524","url":null,"abstract":"Inverse opals (IOs) exhibit attractive optical properties and high interconnected porosity; however, the large-area fabrication of continuously ordered IOs remains challenging. This study presents a method for preparing crack-free IO hydrogel films using a microfluidic chip. Through a “wet infiltration” technique, the drying process of the template is eliminated, thereby avoiding dense cracks that result from particle shrinkage. The fabricated IO films achieve long-range order with lateral dimensions of 1 × 1.2 cm² and thicknesses of 1 mm, with thickness precisely controlled using the dimensions of the microfluidic chamber. The absence of a covering layer exposes the highly porous photonic structures on the surface of the film. Additionally, this preparation method adopts varying ratios of hydrogel precursors, making it suitable for various applications. This study represents a simple, cost-effective, and scalable approach for generating thick IO films suitable for diverse applications.","PeriodicalId":5,"journal":{"name":"ACS Applied Materials & Interfaces","volume":"170 1","pages":""},"PeriodicalIF":9.5,"publicationDate":"2025-02-25","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"143495782","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":2,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}