ACS Macro LettersPub Date : 2024-12-09DOI: 10.1021/acsmacrolett.4c00775
Caitlin S. Sample, Brenden D. Hoehn, Marc A. Hillmyer
{"title":"Correction to “Cross-Linked Polyolefins through Tandem ROMP/Hydrogenation”","authors":"Caitlin S. Sample, Brenden D. Hoehn, Marc A. Hillmyer","doi":"10.1021/acsmacrolett.4c00775","DOIUrl":"https://doi.org/10.1021/acsmacrolett.4c00775","url":null,"abstract":"In our original publication, we made an error in Figure 4 and the corresponding caption. The legend labels in Figure 4b are inverted, with the gray curves incorrectly labeled as “C90D10” and the black curves as “C10D90”. The caption has an additional typographical error. These errors do not affect the results or conclusions of the article, as the values in Figure 4a and the associated discussion reference the accurate data. The corrected versions of Figure 4 and the caption are presented here. Figure 4. (a) Mechanical properties of samples before and after hydrogenation. Values are average ± standard deviation for 5 (C90D10, C10D90, H–C10D90) or 3 (H–C90D10) replicates. (b) Representative tensile curves for C90D10, H–C90D10, C10D90, and H–C10D90. *Samples pulled out from grips. This article has not yet been cited by other publications.","PeriodicalId":18,"journal":{"name":"ACS Macro Letters","volume":"56 1","pages":""},"PeriodicalIF":5.8,"publicationDate":"2024-12-09","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"142797620","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
ACS Macro LettersPub Date : 2024-12-07DOI: 10.1021/acsmacrolett.4c00665
Chihui Zheng, Gadi Slor, Youwei Ma, Francesco Stellacci
{"title":"Direct Monomer Recovery from Ring-Closing Depolymerization of Thermosets","authors":"Chihui Zheng, Gadi Slor, Youwei Ma, Francesco Stellacci","doi":"10.1021/acsmacrolett.4c00665","DOIUrl":"https://doi.org/10.1021/acsmacrolett.4c00665","url":null,"abstract":"Recovering monomers from the depolymerization of thermosets presents a significant challenge, which becomes even more daunting if one sets the goal of doing it directly, i.e., without complex chemical separation steps. To this end, we have synthesized a new type of polycarbonate thermoset by first copolymerizing alkyl cyclic carbonates (<b>ACC</b>s) with small amounts of allyloxy cyclic carbonates (<b>AoCC</b>s), followed by cross-linking the resulting allyloxy polycarbonate with excess tetrathiol compounds under UV irradiation. These cross-linked polycarbonates demonstrate enhanced thermal and mechanical properties compared to their linear analogues, while maintaining the linear polymers’ capacity for ring-closing depolymerization. The depolymerization process enables the direct recovery of <b>ACC</b> and its dimer, bypassing complex chemical separation steps that are commonly employed in the recycling of conventional chemically recyclable thermosets. The yields range from 74.7% to 91.7% depending on the ratios of <b>AoCC</b> to <b>ACC</b> in the thermosets. Furthermore, the recovered compounds can be repolymerized with <b>AoCC</b>s leading to polycarbonate of the same quality to the initially synthesized one.","PeriodicalId":18,"journal":{"name":"ACS Macro Letters","volume":"220 1","pages":""},"PeriodicalIF":5.8,"publicationDate":"2024-12-07","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"142788623","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
ACS Macro LettersPub Date : 2024-12-05DOI: 10.1021/acsmacrolett.4c00651
Yuta Miyamori, Youngwon Kong, Yuta Nabae, Kan Hatakeyama-Sato, Teruaki Hayakawa
{"title":"Highly Ordered Bimodal Mesoporous Carbon from ABC Triblock Terpolymers with Phenolic Resol","authors":"Yuta Miyamori, Youngwon Kong, Yuta Nabae, Kan Hatakeyama-Sato, Teruaki Hayakawa","doi":"10.1021/acsmacrolett.4c00651","DOIUrl":"https://doi.org/10.1021/acsmacrolett.4c00651","url":null,"abstract":"Mesoporous carbons (MPCs) with a bimodal distribution of pore diameters are more advantageous than their monomodal counterparts for applications in adsorption, catalysis, and drug delivery systems; however, reports on their fabrication remain limited. In this study, we successfully fabricated bimodal MPCs using a soft template method with poly(2,2,2-trifluoroethyl methacrylate) (PTFEMA)-<i>b</i>-poly(4-vinylpyridine) (P4VP)-<i>b</i>-polystyrene (PS) and resol. The blend samples formed microphase-separated structures comprising PTFEMA spheres, PS cylinders, and matrix domains composed of P4VP and resol, leading to the separation of the PTFEMA and PS domains. The P4VP and resol matrix domains were carbonized at a high temperature of 900 °C, whereas the PTFEMA and PS domains were thermally decomposed. This process resulted in bimodal MPCs with both spherical and cylindrical mesopores. The pore diameters calculated using scanning electron microscopy were approximately 10 and 30 nm, while nitrogen adsorption measurements indicated a large specific surface area with a bimodal pore distribution.","PeriodicalId":18,"journal":{"name":"ACS Macro Letters","volume":"79 1","pages":""},"PeriodicalIF":5.8,"publicationDate":"2024-12-05","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"142782866","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
ACS Macro LettersPub Date : 2024-11-27DOI: 10.1021/acsmacrolett.4c00687
Zhezhe Li, Yue Zhang, Suzhen Wang, Yihan Wu, Hailong Che
{"title":"Rational Design of Self-Reporting Polymersomes for the Controlled Release of Sulfur Dioxide","authors":"Zhezhe Li, Yue Zhang, Suzhen Wang, Yihan Wu, Hailong Che","doi":"10.1021/acsmacrolett.4c00687","DOIUrl":"https://doi.org/10.1021/acsmacrolett.4c00687","url":null,"abstract":"As a new member of the gaseous regulators, sulfur dioxide (SO<sub>2</sub>) plays a crucial role in many biological activities. Recent studies have shown that SO<sub>2</sub> is capable of inducing cancer cell apoptosis by regulating intracellular reactive oxygen species (ROS), allowing SO<sub>2</sub> to serve as an efficient therapeutic agent. Although various polymer-based platforms have presented great potential for the controlled release of SO<sub>2</sub>, most of the systems are incapable of monitoring the intracellular generation of SO<sub>2</sub>. In this work we present the rational design of SO<sub>2</sub>-releasing biodegradable polymersomes, accompanied by a self-reporting property. The polymersome consists of a hydrophilic block of poly(ethylene glycol) (PEG) and a hydrophobic segment of poly(trimethylene carbonate) (PTMC)-based SO<sub>2</sub> donors. The polymersomes not only exhibit good SO<sub>2</sub>-releasing performance upon treatment with glutathione (GSH), but can also regulate the fluorescence change of the system, offering a good platform for real-time monitoring of the intracellular production of SO<sub>2</sub>. Significantly, the <i>in vitro</i> and <i>in vivo</i> studies indicate the potential for exploitation of these polymersomes as antitumor agents. We expect that incorporating both the SO<sub>2</sub>-releasing capacity and self-reporting feature within a polymersome system will provide a unique opportunity for the development of intelligent gas nanovehicles.","PeriodicalId":18,"journal":{"name":"ACS Macro Letters","volume":"258 1","pages":""},"PeriodicalIF":5.8,"publicationDate":"2024-11-27","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"142718897","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
ACS Macro LettersPub Date : 2024-11-26DOI: 10.1021/acsmacrolett.4c00656
Ronan J. Flood, Aurélien Thureau, Peter B. Crowley
{"title":"A Macrocycle-Mediated Protein Cage","authors":"Ronan J. Flood, Aurélien Thureau, Peter B. Crowley","doi":"10.1021/acsmacrolett.4c00656","DOIUrl":"https://doi.org/10.1021/acsmacrolett.4c00656","url":null,"abstract":"Engineered protein cages are of great interest considering their diverse applications in delivery and catalysis. Here, we describe macrocycle-triggered icosahedral cage assembly of a designed β-propeller. Cage assembly was evidenced by small-angle X-ray scattering and X-ray crystallography.","PeriodicalId":18,"journal":{"name":"ACS Macro Letters","volume":"20 1","pages":""},"PeriodicalIF":5.8,"publicationDate":"2024-11-26","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"142718888","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
ACS Macro LettersPub Date : 2024-11-21DOI: 10.1021/acsmacrolett.4c00663
Jowon Shin, Heewoon Shin, Sang-Ho Lee, Jong Dae Jang, Hyeong Jun Kim
{"title":"Influence of Solvent Dielectric Constant on the Complex Coacervation Phase Behavior of Polymerized Ionic Liquids.","authors":"Jowon Shin, Heewoon Shin, Sang-Ho Lee, Jong Dae Jang, Hyeong Jun Kim","doi":"10.1021/acsmacrolett.4c00663","DOIUrl":"https://doi.org/10.1021/acsmacrolett.4c00663","url":null,"abstract":"<p><p>Complex coacervation is an associative phase separation process of oppositely charged polyelectrolyte solutions, resulting in a coacervate phase enriched with charged polymers and a polymer-lean phase. To date, studies on the phase behavior of complex coacervation have been largely restricted to aqueous systems with relatively high dielectric constants due to the limited solubility of most polyelectrolytes, hindering the exploration of the effects of electrostatic interactions from differences in solvent permittivity. Herein, we prepare two symmetric but oppositely charged polymerized ionic liquids (PILs), consisting of poly[1-[2-acryloyloxyethyl]-3-butylimidazolium bis(trifluoromethane)sulfonimide] (PAT) and poly[1-ethyl-3-methylimidazolium 3-[[[(trifluoromethyl)sulfonyl]amino]sulfonyl]propyl acrylate] (PEA). Due to the delocalized ionic charges and their chemical structure similarity, both PAT and PEA are soluble in various organic solvents with a wide range of dielectric constants, ranging from 16.7 (hexafluoro-2-propanol (HFIP)) to 66.1 (propylene carbonate (PC)). Notably, no significant correlation is observed between the solvent dielectric constant and the phase diagram of the complex coacervation of PILs. Most organic solvents lead to similar phase diagrams and salt resistances regardless of their dielectric constants, except two protic solvents (HFIP and 2,2,2-trifluoroethanol (TFE)) showing significantly low salt resistances compared to the others. The low salt resistance in these protic solvents primarily arises from strong hydrogen bonding between PILs and solvents as evidenced by <sup>1</sup>H NMR and small-angle neutron scattering (SANS) experiments. Our finding suggests that for the coacervation of PILs, particularly those with delocalized and weak charge interactions, entropy from the counterion release and polymer-solvent interaction χ parameter play a more important role than the electrostatic interactions of charged molecules, rendered by the dielectric constant of the solvent medium.</p>","PeriodicalId":18,"journal":{"name":"ACS Macro Letters","volume":" ","pages":"1678-1685"},"PeriodicalIF":5.1,"publicationDate":"2024-11-21","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"142685397","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
ACS Macro LettersPub Date : 2024-11-21DOI: 10.1021/acsmacrolett.4c00709
Qinxin Sheng, Rui Tan, Xiaohua Zhang, Hang Shen, Zhengbiao Zhang
{"title":"Enhancing Mechanophore Activation through Polymer Crystallization","authors":"Qinxin Sheng, Rui Tan, Xiaohua Zhang, Hang Shen, Zhengbiao Zhang","doi":"10.1021/acsmacrolett.4c00709","DOIUrl":"https://doi.org/10.1021/acsmacrolett.4c00709","url":null,"abstract":"In the field of polymer mechanochemistry, the activation of mechanophores within linear polymers in the bulk state is often limited by low activation rates. Herein, we demonstrate that the crystallization of polymers can significantly enhance the activation of mechanophores. Employing rhodamine-containing poly(lactic acid) (PLA) and polycaprolactone (PCL) as representative examples, our study reveals that the micromechanical force generated by crystallization is more effective in activating mechanophores than the macroscopic mechanical force induced by compression and ultrasonication, which is particularly pronounced for polymers with low molecular weights. Furthermore, the activation of the mechanophore is found to be positively correlated with the degree of crystallinity and polymer molecular weight, whereas the chirality of polymers does not influence the activation. This study offers new insights into mechanochemical reactions induced by polymer crystallization and provides a novel approach to enhancing mechanochemical reactivity.","PeriodicalId":18,"journal":{"name":"ACS Macro Letters","volume":"253 1","pages":""},"PeriodicalIF":5.8,"publicationDate":"2024-11-21","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"142678678","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
ACS Macro LettersPub Date : 2024-11-19Epub Date: 2024-10-28DOI: 10.1021/acsmacrolett.4c00617
Nicola G Judge, Maddison I Segal, Robert O Silzer, Courtney S Dziewior, Yin Mei Chan, Sawyer J Grovogel, Matthew L Becker
{"title":"Semiaromatic Polyester-Ethers with Tunable Degradation Profiles.","authors":"Nicola G Judge, Maddison I Segal, Robert O Silzer, Courtney S Dziewior, Yin Mei Chan, Sawyer J Grovogel, Matthew L Becker","doi":"10.1021/acsmacrolett.4c00617","DOIUrl":"10.1021/acsmacrolett.4c00617","url":null,"abstract":"<p><p>Poly(ε-caprolactone) (PCL) is a widely utilized polymer within the biomedical field; however, one of its limitations is the multi-year long degradation profile. Herein, we report a semiaromatic polyester-ether (SAEE) PCL copolymer using a salicylic acid-based monomer which can disrupt the semicrystalline nature of the bulk material. The molar percentage of incorporation correlated to a linear decrease in melting and crystallization temperature, until a totally amorphous solid was seen at 37 mol %. Alongside this, mechanical analysis elucidated a softer, more extensible material with <i>E</i>' decreasing from 292 to 222 to 43.8 MPa for PCL to 10 to 22 mol % SAEE, respectively. Accelerated basic degradation studies (2 M NaOH) exhibited total mass loss after 16 weeks for 6 mol % compared to only 38% mass loss for PCL over the same period. Overall, by varying the SAEE mol %, we show the ability to finely tune the thermal, mechanical, and degradation profiles of PCL copolymers while maintaining an advantageous biological profile.</p>","PeriodicalId":18,"journal":{"name":"ACS Macro Letters","volume":" ","pages":"1531-1538"},"PeriodicalIF":5.1,"publicationDate":"2024-11-19","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"142520302","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
ACS Macro LettersPub Date : 2024-11-19Epub Date: 2024-11-01DOI: 10.1021/acsmacrolett.4c00573
Huanhuan Wu, Kaili Zhang, Hanyu Jiang, Ren'ai Li
{"title":"Eutectic Strategy for the Solvent-Free Synthesis of Hydrophobic Cellulosic Cross-Linked Networks with Broad Multifunctional Applications.","authors":"Huanhuan Wu, Kaili Zhang, Hanyu Jiang, Ren'ai Li","doi":"10.1021/acsmacrolett.4c00573","DOIUrl":"10.1021/acsmacrolett.4c00573","url":null,"abstract":"<p><p>Cellulose-based functional materials play a crucial role in sustainable social development. However, during the material synthesis process, there is typically significant reliance on various solvent systems for macroscopic- or molecular-scale functionalization modifications. In this study, an innovative hydrophobic eutectic solvent (HES) was developed using ethyl cellulose (EC) and thymol (Thy) without any external solvents. Utilizing this homogeneous system, it is convenient to chemically modify the components without any catalyst. Furthermore, a hydrophobic cellulosic cross-linked network (HCCN) can be successfully prepared through in situ photopolymerization. The HCCN film exhibits high transparency, excellent mechanical properties, chemical stability, and durability. The EC/Thy prepolymer system also demonstrates favorable processability for the preparation of various polymeric materials. Additionally, the applicability of other biomasses and derivatives based on the eutectic strategy has been verified. The methodology proposed in this study offers novel insights into the green and solvent-free preparation of biomass functional materials.</p>","PeriodicalId":18,"journal":{"name":"ACS Macro Letters","volume":" ","pages":"1558-1564"},"PeriodicalIF":5.1,"publicationDate":"2024-11-19","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"142556533","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
ACS Macro LettersPub Date : 2024-11-19DOI: 10.1021/acsmacrolett.4c00642
Evan K Stacy, Mac L McCormick, Kaden C Stevens, Penelope E Jankoski, Jeff Aguinaga, Derek L Patton, Brent S Sumerlin, Tristan D Clemons
{"title":"Aqueous Photoiniferter Polymerization of Acrylonitrile.","authors":"Evan K Stacy, Mac L McCormick, Kaden C Stevens, Penelope E Jankoski, Jeff Aguinaga, Derek L Patton, Brent S Sumerlin, Tristan D Clemons","doi":"10.1021/acsmacrolett.4c00642","DOIUrl":"10.1021/acsmacrolett.4c00642","url":null,"abstract":"<p><p>Polyacrylonitrile (PAN) is a key industrial polymer for the production of carbon fiber for high-strength, lightweight composite material applications, with an estimated 90% of the carbon fiber market relying on PAN-based polymers. Traditionally, PAN synthesis is achieved by conventional radical polymerization, resulting in broad molecular weight distributions and the use of toxic organic solvents or surfactants during the synthesis. Additionally, attempts to improve polymer and processing properties by controlled radical polymerization methods suffer from low monomer conversions and struggle to achieve molecular weights suitable for producing high-performance carbon fiber. In this study, we present an aqueous photoiniferter (aqPI) polymerization of acrylonitrile, achieving high monomer conversion and high PAN molecular weights with significantly faster kinetics and dispersity control when compared to traditional methods. This approach allows for the unprecedented control of polymer properties that are integral for downstream processing for enhanced carbon fiber production.</p>","PeriodicalId":18,"journal":{"name":"ACS Macro Letters","volume":" ","pages":"1662-1669"},"PeriodicalIF":5.1,"publicationDate":"2024-11-19","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"142666388","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}