Inorganic Chemistry最新文献

Assessing the Reactivity of Cobalt(II) Amide Co(TMP)2 toward Unsaturated Organic Molecules 评估钴（II）酰胺Co(TMP)2对不饱和有机分子的反应性

IF 4.6 2区化学

Inorganic Chemistry Pub Date : 2026-11-10 DOI: 10.1021/acs.inorgchem.6c04847

Na Jin,Eva Hevia

引用次数: 0

Probing the Structures, Electronic Properties, and Bonding Patterns of RbOn–/0 and CsOn–/0 (n = 4–7) by Photoelectron Spectroscopy and Theoretical Calculations 用光电子能谱和理论计算探测RbOn - /0和CsOn - /0 （n = 4-7）的结构、电子性质和成键模式

IF 4.6 2区化学

Inorganic Chemistry Pub Date : 2026-11-10 DOI: 10.1021/acs.inorgchem.6c04335

Bai-Bai Wan,Bin Yang,Ke-Wei Ding,Xi-Ling Xu,Hong-Guang Xu,Wei-Jun Zheng

{"title":"Probing the Structures, Electronic Properties, and Bonding Patterns of RbOn–/0 and CsOn–/0 (n = 4–7) by Photoelectron Spectroscopy and Theoretical Calculations","authors":"Bai-Bai Wan,Bin Yang,Ke-Wei Ding,Xi-Ling Xu,Hong-Guang Xu,Wei-Jun Zheng","doi":"10.1021/acs.inorgchem.6c04335","DOIUrl":"https://doi.org/10.1021/acs.inorgchem.6c04335","url":null,"abstract":"This study combines anion photoelectron spectroscopy with density functional theory calculations to explore the geometric structures, electronic structures, and bonding properties of RbOn–/0 and CsOn–/0 (n = 4–7). The measured spectra exhibit a clear size-dependent evolution: as the number of oxygen atoms increases, all features shift progressively toward higher binding energies. Theoretical analysis reveals that RbOn– and CsOn– have similar structures. They can be described as polyoxide units electrostatically stabilized by alkali metal cations, with structural motifs that follow systematic trends: [O2]−–M+–[O2]− (n = 4), [O3]−–M+–[O2]− (n = 5), [O2]−–M+–[O2]2– (n = 6), and [O3]−–M+–[O2]2– (n = 7). These results confirm that electrostatic interactions dominate the bonding between alkali metal cations and oxygen-rich units, and the polarization effects become more pronounced with the increase of cluster size. The neutral RbOn and CsOn clusters undergo pronounced structural reorganization compared with their corresponding anionic structures yet largely retain the same basic framework as their anionic counterparts.","PeriodicalId":40,"journal":{"name":"Inorganic Chemistry","volume":"19 1","pages":""},"PeriodicalIF":4.6,"publicationDate":"2026-11-10","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"149374732","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":2,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

引用次数: 0

In Situ Cyanide-to-Bipyridine Coordination-Sphere Reconstruction of [Fe(CN)6]3– into Surface-Confined Fe(bpy)32+ on Nafion/Carbon Soot for Selective Electrocatalytic Nitrite Oxidation and Sensing [Fe(CN)6]3 -在Nafion/Carbon Soot上还原成表面受限Fe(bpy)32+的原位氰化物-联吡啶配位球重建及其选择性电催化亚硝酸盐氧化和传感

IF 4.6 2区化学

Inorganic Chemistry Pub Date : 2026-11-10 DOI: 10.1021/acs.inorgchem.6c03851

Jayaprakash Meena,M. Gabriela Almeida,Annamalai Senthil Kumar

{"title":"In Situ Cyanide-to-Bipyridine Coordination-Sphere Reconstruction of [Fe(CN)6]3– into Surface-Confined Fe(bpy)32+ on Nafion/Carbon Soot for Selective Electrocatalytic Nitrite Oxidation and Sensing","authors":"Jayaprakash Meena,M. Gabriela Almeida,Annamalai Senthil Kumar","doi":"10.1021/acs.inorgchem.6c03851","DOIUrl":"https://doi.org/10.1021/acs.inorgchem.6c03851","url":null,"abstract":"A simple electrochemical strategy is introduced for the in situ synthesis of a surface-confined tris(2,2′-bipyridine)iron(II), [Fe(bpy)3]2+, complex through coordination-sphere reconstruction (CSR) of hexacyanoferrate(III), [Fe(CN)6]3–. The process involves an electrochemically driven cyanide-to-bipyridine ligand exchange directly on a Nafion/carbon soot (Nf-CS)-modified electrode, thereby avoiding conventional multistep solution-phase synthesis. Cyclic voltammetry, Raman spectroscopy, Fourier transform infrared spectroscopy, UV–vis spectroscopy, high-resolution mass spectrometry, and electrochemical quartz crystal microbalance measurements collectively confirm the formation of surface-confined [Fe(bpy)3]2+ and provide evidence for transient Fe2+/Fe3+ intermediates during CSR. A selective Prussian Blue test further confirms CN– release, supporting the proposed ligand-exchange mechanism. The resulting GCE/Nf-CS@[Fe(bpy)3]2+ electrode exhibits remarkable electrocatalytic activity toward nitrite oxidation, with a sensitivity of 150 μA mM–1, approximately 10-fold higher than that of chemically synthesized [Fe(bpy)3]2+-based electrodes. The electrode also demonstrates a low overpotential, excellent operational stability, and negligible fouling. Coupling with batch injection analysis enables rapid, selective, and reproducible nitrite determination in serum, urine, saliva, spinach, and wastewater samples, with recoveries of 98–101%. This new approach provides a versatile platform for developing a variety of surface-confined molecular electrocatalysts and functional inorganic materials for real-time applications.","PeriodicalId":40,"journal":{"name":"Inorganic Chemistry","volume":"18 1","pages":""},"PeriodicalIF":4.6,"publicationDate":"2026-11-10","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"149374726","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":2,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

引用次数: 0

Organic Cation-Directed Tuning of Structure and Optical Band Gap of One-Dimensional Hybrid Sb(III) Iodides 一维杂化Sb（III）碘化物结构和光带隙的有机阳离子定向调谐

IF 4.6 2区化学

Inorganic Chemistry Pub Date : 2026-11-10 DOI: 10.1021/acs.inorgchem.6c04325

Aditi Saraswat,Arpitha Rajan,Pratap Vishnoi

{"title":"Organic Cation-Directed Tuning of Structure and Optical Band Gap of One-Dimensional Hybrid Sb(III) Iodides","authors":"Aditi Saraswat,Arpitha Rajan,Pratap Vishnoi","doi":"10.1021/acs.inorgchem.6c04325","DOIUrl":"https://doi.org/10.1021/acs.inorgchem.6c04325","url":null,"abstract":"Sb(III)-halide perovskite-related structures are environmentally benign alternatives to traditional lead-based perovskites. Here, we report three hybrid Sb(III) iodides: (H2BDA)SbI5, (H2PDA)SbI5, and (H2CDA)SbI5, where H2BDA, H2PDA, and H2CDA represent 1,4-butanediammonium, 1,5-pentanediammonium, and trans-1,4-cyclohexanediammonium cations, respectively. These compounds exhibit one-dimensional zigzag chains of [SbI6]3– octahedra separated by organic cations. Temperature-dependent X-ray diffraction and calorimetry reveal thermally reversible phase transitions for (H2BDA)SbI5 at 368 K upon heating and at 363 K upon cooling, while (H2PDA)SbI5 undergoes a transition at 428 K in the heating scan and at 424 K in the cooling scan. Specifically, (H2BDA)SbI5 undergoes a monoclinic (P21/n) to monoclinic (P21/m) phase change, while (H2PDA)SbI5 changes from orthorhombic (P212121) to orthorhombic (Pnma) at high temperatures. In contrast, (H2CDA)SbI5 does not show any detectable transition within the studied temperature range. The optical band gaps are in the 2.0–2.3 eV range, with (H2CDA)SbI5 exhibiting a significantly wider gap compared to the other two analogs, attributed to pronounced distortion of the Sb–I framework, particularly increased Sb–I–Sb tilting. Additionally, (H2BDA)SbI5 exhibits a broad, Stokes-shifted emission centered at 720 nm and extending to 1200 nm. The broad emission is attributable to self-trapped excitons, making this system a potential light-emitting material.","PeriodicalId":40,"journal":{"name":"Inorganic Chemistry","volume":"14 1","pages":""},"PeriodicalIF":4.6,"publicationDate":"2026-11-10","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"149374738","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":2,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

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Fluorination-Associated Symmetry Transformation and Band-Gap Widening in Antimony Tellurite-Based Birefringent Crystals 碲化锑双折射晶体的氟化相关对称变换和带隙加宽

IF 4.6 2区化学

Inorganic Chemistry Pub Date : 2026-11-10 DOI: 10.1021/acs.inorgchem.6c05198

Ziyi Wu,Xiaoke Liu,Binxiu Zhao,Xuehua Dong,Ling Huang,Liling Cao,Guohong Zou

{"title":"Fluorination-Associated Symmetry Transformation and Band-Gap Widening in Antimony Tellurite-Based Birefringent Crystals","authors":"Ziyi Wu,Xiaoke Liu,Binxiu Zhao,Xuehua Dong,Ling Huang,Liling Cao,Guohong Zou","doi":"10.1021/acs.inorgchem.6c05198","DOIUrl":"https://doi.org/10.1021/acs.inorgchem.6c05198","url":null,"abstract":"Balancing a wide optical band gap with large birefringence remains challenging for ultraviolet (UV) birefringent crystals. Herein, two antimony tellurite-based compounds, centrosymmetric (CS) Sb2O(TeO3)2 and noncentrosymmetric (NCS) SbTeO3F, were synthesized and compared to investigate fluorination-associated structural and optical regulation. Sb2O(TeO3)2 crystallizes in the CS space group P1̅ and features a layered framework of [SbO4], [SbO5], and [TeO3] units connected through Sb–O–Te linkages. In contrast, SbTeO3F adopts the NCS space group P212121, in which terminal Sb–F coordination accompanies changes in Sb coordination and Sb–Te–O framework connectivity. SbTeO3F exhibits improved UV transparency, shifting the absorption edge from 394 to 304 nm and increasing the experimental band gap from 3.15 to 4.08 eV. Both compounds retain large birefringence values of 0.29 and 0.30 at 546 nm, respectively. SbTeO3F also exhibits a measurable powder second-harmonic generation (SHG) response of approximately 0.6 times that of potassium dihydrogen phosphate (KDP, KH2PO4). First-principles calculations suggest that the band gap widening is related to modified band-edge electronic states, whereas large birefringence is associated with anisotropic lone-pair-active Sb3+ and Te4+ units. These findings highlight the potential of fluorination-associated structural regulation for improving UV transparency while preserving large birefringence in antimony tellurite-based crystals.","PeriodicalId":40,"journal":{"name":"Inorganic Chemistry","volume":"20 1","pages":""},"PeriodicalIF":4.6,"publicationDate":"2026-11-10","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"149374723","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":2,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

引用次数: 0

Programmable Synthesis of Monodisperse Multimetallic Alloy Nanoparticles 单分散多金属合金纳米颗粒的可编程合成

IF 4.6 2区化学

Inorganic Chemistry Pub Date : 2026-11-10 DOI: 10.1021/acs.inorgchem.6c03333

Gendi Zhang,Zedong Du,Yinhan Li,Yuzhu Zhao,Wenhua Li,Zhishan Bo

{"title":"Programmable Synthesis of Monodisperse Multimetallic Alloy Nanoparticles","authors":"Gendi Zhang,Zedong Du,Yinhan Li,Yuzhu Zhao,Wenhua Li,Zhishan Bo","doi":"10.1021/acs.inorgchem.6c03333","DOIUrl":"https://doi.org/10.1021/acs.inorgchem.6c03333","url":null,"abstract":"Multimetallic alloy nanoparticles (MMANPs) exhibit excellent properties, yet developing general colloidal routes toward monodisperse MMANPs is still challenging due to multidimensional synthetic complexity. Herein, we demonstrate a generalized Two-NP conversion strategy for the colloidal synthesis of a library of uniform MMANPs, in which parent precursor NPs with well-defined structures are clearly identified that can accommodate various metallic atoms throughout multistep transformation. This study defines two pivotal criteria for eligible parent precursors, verifying colloidal monometallic Pt, Au, and Pd NPs, as well as their bimetallic derivatives, as ideal candidates. The differential competency and rich diversity of parent precursors allow us to design a variety of rational synthetic routes, which enables that the versatile synthesis of MMANPs, including over 200 monodisperse Pt-based ternary-to-senary alloy nanocubes, to be theoretically achieved (the constituent metals studied include Pt, Au, Pd, Fe, Co, Ni, Rh, Ag, Cu, Mn, and Sn). Benefiting from the structural inheritance of parent precursor NPs, 64 representative monodisperse MMANPs with controllable constituent elements, morphology, and size are readily produced. We propose a mechanism-driven synthesis paradigm that replaces empirical screening with a reliable precursor-oriented synthetic methodology, enabling the programmable fabrication of diverse MMANPs.","PeriodicalId":40,"journal":{"name":"Inorganic Chemistry","volume":"10 1","pages":""},"PeriodicalIF":4.6,"publicationDate":"2026-11-10","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"149374728","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":2,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

引用次数: 0

Hydrometallogel-Templated, Plasmonic Au Nanoparticle Assemblies for NIR-Activated H2 Release from Ammonia-Borane 水金属模板，等离子体金纳米粒子组件用于nir活化的氨硼烷H2释放

IF 4.6 2区化学

Inorganic Chemistry Pub Date : 2026-11-10 DOI: 10.1021/acs.inorgchem.6c03968

Ainhoa Rodríguez-Gobernado,Daniel Blasco,Sonia Moreno,Hippolyte Amaveda,Mario Mora,M. Elena Olmos,José M. López-de-Luzuriaga,Miguel Monge,María Rodríguez-Castillo

{"title":"Hydrometallogel-Templated, Plasmonic Au Nanoparticle Assemblies for NIR-Activated H2 Release from Ammonia-Borane","authors":"Ainhoa Rodríguez-Gobernado,Daniel Blasco,Sonia Moreno,Hippolyte Amaveda,Mario Mora,M. Elena Olmos,José M. López-de-Luzuriaga,Miguel Monge,María Rodríguez-Castillo","doi":"10.1021/acs.inorgchem.6c03968","DOIUrl":"https://doi.org/10.1021/acs.inorgchem.6c03968","url":null,"abstract":"The addition of [Au(acac)(PMe3)] (acac = acetylacetonate) to orotic acid affords the mononuclear complex [Au(N-orotate)(PMe3)] (1) and the dinuclear species [{Au(PMe3)}2(μ-O,N-orotate)] (2), with the crystal structures of two polymorphs of complex 2 fully elucidated by X-ray diffraction studies. Remarkably, complex 1 undergoes ultrasound-induced supramolecular self-assembly in water to form a robust Au(I) hydrometallogel (1-hyd), whereas 2 lacks the capacity to gelate due to coordination-induced suppression of intermolecular hydrogen bonding. The hydrometallogel acts as both a soft template and an in situ gold precursor, enabling the formation of densely packed, belt-like assemblies of plasmonic Au nanoparticles (1-hyd-Au NPs) upon mild and short thermal treatment. These anisotropic nanoarrays display strong interparticle coupling, yielding a broad, red-shifted localized surface plasmon resonance (LSPR) absorption centered at ca. 650 nm with substantial NIR absorption. Under 808 nm excitation, the system exhibits efficient photothermal conversion accompanied by the generation of localized plasmonic hot spots. Exploiting this dual activation mode, 1-hyd-Au NPs photocatalyse the methanolysis of ammonia-borane, delivering significantly enhanced H2 release relative to purely thermal conditions. The results demonstrate that hydrometallogel-templated Au assemblies provide an effective and modular platform for NIR-driven plasmonic catalysis, integrating supramolecular templating with strong light-matter interactions to boost the dehydrogenation of chemical hydrogen carriers.","PeriodicalId":40,"journal":{"name":"Inorganic Chemistry","volume":"9 1","pages":""},"PeriodicalIF":4.6,"publicationDate":"2026-11-10","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"149374725","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":2,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

引用次数: 0

A Recyclable Ni(II) Metal–Organic Framework as a Catalyst for Imine Synthesis via Acceptorless Dehydrogenative Coupling and Oxidative Self-Condensation of Benzylamine 无受体脱氢偶联及苯胺氧化自缩合合成亚胺的可回收镍金属-有机骨架催化剂

IF 4.6 2区化学

Inorganic Chemistry Pub Date : 2026-11-10 DOI: 10.1021/acs.inorgchem.6c04153

Sk Sakir Hossain,Kalimuthu Abirami Sundari,Veerappan Karthik,Amarajothi Dhakshinamoorthy,Shyam Biswas

{"title":"A Recyclable Ni(II) Metal–Organic Framework as a Catalyst for Imine Synthesis via Acceptorless Dehydrogenative Coupling and Oxidative Self-Condensation of Benzylamine","authors":"Sk Sakir Hossain,Kalimuthu Abirami Sundari,Veerappan Karthik,Amarajothi Dhakshinamoorthy,Shyam Biswas","doi":"10.1021/acs.inorgchem.6c04153","DOIUrl":"https://doi.org/10.1021/acs.inorgchem.6c04153","url":null,"abstract":"A new Ni(II) metal–organic framework (MOF), IITG-12 (IITG: Indian Institute of Technology Guwahati), was solvothermally synthesized in mixed solvents (acetonitrile and water). The as-synthesized MOF was thermally activated, followed by solvent exchange with methanol to obtain the activated MOF, namely IITG-12a. The catalytic potential of IITG-12a was explored for imine synthesis via two distinct pathways, which included oxidative coupling of benzyl alcohol and aniline derivatives through acceptorless dehydrogenation and oxidative self-condensation of benzylamine. For oxidative coupling reaction, optimal conditions are 3 mol % IITG-12a loading, KOtBu as base, toluene as solvent, 115 °C, and 8 h, with 83% isolated yield. For oxidative self-condensation of benzylamine, the optimized conditions were established as 100 °C, 24 h, under an O2 atmosphere under a solvent-free medium, delivering a yield of 96%. Both catalytic systems demonstrated a broad substrate scope with diverse functional group tolerance. The catalyst, IITG-12a, exhibited remarkable recyclability over four consecutive cycles. The stability of the catalyst after the catalytic reactions was examined via different characterization techniques. The mechanistic pathways for both transformations were studied through control experiments and reported literature analysis. This work represents the introduction of a new MOF single crystal and its catalytic applications for sustainable imines syntheses via two distinct pathways.","PeriodicalId":40,"journal":{"name":"Inorganic Chemistry","volume":"24 1","pages":""},"PeriodicalIF":4.6,"publicationDate":"2026-11-10","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"149374727","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":2,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

引用次数: 0

Comparative Study of Dihydrogen, Tetrel, and Metal Bonds in Complexes of C3H4 Isomers with MH and MH2 (M = Li, Na, Be, and Mg) C3H4同分异构体与MH、MH2 （M = Li、Na、Be、Mg）配合物中二氢键、四氢键、金属键的比较研究

IF 4.6 2区化学

Inorganic Chemistry Pub Date : 2026-11-10 DOI: 10.1021/acs.inorgchem.6c04095

Mohammadmehdi Moradkhani

{"title":"Comparative Study of Dihydrogen, Tetrel, and Metal Bonds in Complexes of C3H4 Isomers with MH and MH2 (M = Li, Na, Be, and Mg)","authors":"Mohammadmehdi Moradkhani","doi":"10.1021/acs.inorgchem.6c04095","DOIUrl":"https://doi.org/10.1021/acs.inorgchem.6c04095","url":null,"abstract":"In this manuscript, the interactions of metal hydrides, MH and MH2 (M = Li, Na, Be, and Mg), with the C3H4 isomers cyclopropane (CP) and propyne (P) were investigated using quantum chemical calculations at the MP2/aug-cc-pVTZ level of theory. The molecular electrostatic potential (MEP) results showed that each isomer exhibits distinct behavior and participates in different types of interactions with specific characteristics. The interaction patterns differ markedly between the MH and MH2 hydrides. For the MH monomers, Structure A is stabilized by a tetrel bond (TB), while Structure C is characterized by the simultaneous presence of dihydrogen bond and metal bond interactions (DHB–MB). In contrast, the corresponding MH2 monomers form TB complexes in Structure A but are stabilized exclusively by metal bond (MB) interactions in Structure C. By comparison, cyclopropane participates only in DHB complexes, giving rise to Structure B.The interaction energy (ΔECPint) and thermodynamic calculations highlighted that the stability of the complexes follows the order C > B > A. They also indicated that complex formation is governed by an exothermic process. Moreover, ΔG was negative only for Structure C, indicating that the formation of these complexes is thermodynamically favorable under the specified gas-phase conditions at 298 K and 1 atm","PeriodicalId":40,"journal":{"name":"Inorganic Chemistry","volume":"9 1","pages":""},"PeriodicalIF":4.6,"publicationDate":"2026-11-10","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"149374724","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":2,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

引用次数: 0

Electrochemical Acetonitrile Release from Dinitrogen-Derived Rhenium Imido Complexes through Proton-Coupled Electron Transfer 二氮衍生亚胺铼配合物通过质子耦合电子转移释放乙腈的电化学研究

IF 4.6 2区化学

Inorganic Chemistry Pub Date : 2026-11-10 DOI: 10.1021/acs.inorgchem.6c04283

Ciara I. Kiene,Richt S. van Alten,Markus Finger,Josh Abbenseth,Christian Würtele,Inke Siewert,Sven Schneider

引用次数: 0