{"title":"Tailored architectures in desalination membranes with MXene: Is this the way forward?","authors":"Sutar Rani Ananda , T.M. Subrahmanya , Shambhulinga Aralekallu , Wei-Song Hung , Mahaveer D. Kurkuri","doi":"10.1016/j.pmatsci.2025.101537","DOIUrl":null,"url":null,"abstract":"<div><div>Just with one decade of history (The discovery of Ti<sub>3</sub>C<sub>2</sub> − 2011), studies on two-dimensional (2D) transition metal carbides, carbonatites, and nitrides (comprehensively stated as MXenes) vastly expanded from fundamental to applications level. The engineered MXenes are good competitors to 2D materials like graphene, metal–organic frameworks, etc., with widespread applications such as gas sensors, water purification, EMI shielding, energy storage, and catalysts etc. Owing to the 2D layered structure, the intercalation of cations, comprising multivalent ones and polar organic molecules, allows the control of interlayer distance and enables MXenes to be used in water purification and desalination. Besides, MXenes have a high aspect ratio due to the sheet structure, which provides nanochannels as diffusion paths for these applications. In this review, we explored the MXenes as membrane materials for pressure-driven membrane-based water desalination technology and the various physico-chemical modifications of MXene’s structure to enhance desalination performance. We also highlight membrane-desalination metrics, fabrication strategies of membranes, trade-off analysis, and the mechanisms behind enhanced performances due to modifications, which provide essential insights about these materials. Ultimately, we summarize the present challenges and provide the future outlook as the foundation for early researchers.</div></div>","PeriodicalId":411,"journal":{"name":"Progress in Materials Science","volume":"155 ","pages":"Article 101537"},"PeriodicalIF":33.6000,"publicationDate":"2025-07-16","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"0","resultStr":null,"platform":"Semanticscholar","paperid":null,"PeriodicalName":"Progress in Materials Science","FirstCategoryId":"88","ListUrlMain":"https://www.sciencedirect.com/science/article/pii/S007964252500115X","RegionNum":1,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"Q1","JCRName":"MATERIALS SCIENCE, MULTIDISCIPLINARY","Score":null,"Total":0}
引用次数: 0
Abstract
Just with one decade of history (The discovery of Ti3C2 − 2011), studies on two-dimensional (2D) transition metal carbides, carbonatites, and nitrides (comprehensively stated as MXenes) vastly expanded from fundamental to applications level. The engineered MXenes are good competitors to 2D materials like graphene, metal–organic frameworks, etc., with widespread applications such as gas sensors, water purification, EMI shielding, energy storage, and catalysts etc. Owing to the 2D layered structure, the intercalation of cations, comprising multivalent ones and polar organic molecules, allows the control of interlayer distance and enables MXenes to be used in water purification and desalination. Besides, MXenes have a high aspect ratio due to the sheet structure, which provides nanochannels as diffusion paths for these applications. In this review, we explored the MXenes as membrane materials for pressure-driven membrane-based water desalination technology and the various physico-chemical modifications of MXene’s structure to enhance desalination performance. We also highlight membrane-desalination metrics, fabrication strategies of membranes, trade-off analysis, and the mechanisms behind enhanced performances due to modifications, which provide essential insights about these materials. Ultimately, we summarize the present challenges and provide the future outlook as the foundation for early researchers.
期刊介绍:
Progress in Materials Science is a journal that publishes authoritative and critical reviews of recent advances in the science of materials. The focus of the journal is on the fundamental aspects of materials science, particularly those concerning microstructure and nanostructure and their relationship to properties. Emphasis is also placed on the thermodynamics, kinetics, mechanisms, and modeling of processes within materials, as well as the understanding of material properties in engineering and other applications.
The journal welcomes reviews from authors who are active leaders in the field of materials science and have a strong scientific track record. Materials of interest include metallic, ceramic, polymeric, biological, medical, and composite materials in all forms.
Manuscripts submitted to Progress in Materials Science are generally longer than those found in other research journals. While the focus is on invited reviews, interested authors may submit a proposal for consideration. Non-invited manuscripts are required to be preceded by the submission of a proposal. Authors publishing in Progress in Materials Science have the option to publish their research via subscription or open access. Open access publication requires the author or research funder to meet a publication fee (APC).
Abstracting and indexing services for Progress in Materials Science include Current Contents, Science Citation Index Expanded, Materials Science Citation Index, Chemical Abstracts, Engineering Index, INSPEC, and Scopus.