Matter最新文献 - Book学术

Unlocking a self-driving research workflow for perovskite photovoltaics 解锁钙钛矿光伏电池的自动驾驶研究工作流程

IF 17.3 1区材料科学

Matter Pub Date : 2025-06-04 DOI: 10.1016/j.matt.2025.102097

Lifang Xie , Yalan Zhang , Noah Peterkes , Xiaofen Li , Yike Guo , Yuanyuan Zhou

{"title":"Unlocking a self-driving research workflow for perovskite photovoltaics","authors":"Lifang Xie , Yalan Zhang , Noah Peterkes , Xiaofen Li , Yike Guo , Yuanyuan Zhou","doi":"10.1016/j.matt.2025.102097","DOIUrl":"10.1016/j.matt.2025.102097","url":null,"abstract":"<div><div>Perovskite solar cells (PSCs) have attained high power-conversion efficiencies in recent years. However, as the core materials of PSCs, metal halide perovskites (MHPs) still require the field to overcome the relatively low stability and processing reproducibility. In this context, artificial intelligence (AI) has been examined as a transformative tool for chemical-space exploration and experiment automation. This review presents a self-driving research workflow for MHP studies. We integrate computation and automatic experiments to realize this workflow, achieving a closed-cycle design from automated platform data outputs to theoretical models. In computational design, generative AI and discriminative AI are used to explore the vast MHP chemical space. In automatic experiments, recent innovations in hardware and the integration of experimental data streams are discussed. Global optimization incorporates experimental data into the overall workflow to achieve self-iteration. This proposed virtual workflow aims to provide a robust framework for self-driven research to accelerate the development of MHPs and PSCs.</div></div>","PeriodicalId":388,"journal":{"name":"Matter","volume":"8 6","pages":"Article 102097"},"PeriodicalIF":17.3,"publicationDate":"2025-06-04","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"144205366","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":1,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

引用次数: 0

Biomimetic, hierarchical-programmed gel coating for adaptive and sustainable thermal modulation 用于自适应和可持续热调节的仿生、分层编程凝胶涂层

IF 17.3 1区材料科学

Matter Pub Date : 2025-06-04 DOI: 10.1016/j.matt.2025.102057

Zhi-Guang Guo , Peng-Qi Xiong , Hai-Feng Nan , Ding-Xiang Yan , Gan-Ji Zhong , Jun Lei , Zhong-Ming Li

{"title":"Biomimetic, hierarchical-programmed gel coating for adaptive and sustainable thermal modulation","authors":"Zhi-Guang Guo , Peng-Qi Xiong , Hai-Feng Nan , Ding-Xiang Yan , Gan-Ji Zhong , Jun Lei , Zhong-Ming Li","doi":"10.1016/j.matt.2025.102057","DOIUrl":"10.1016/j.matt.2025.102057","url":null,"abstract":"<div><div>Radiative cooling coating (RCC) provides a sustainable pathway for thermal management. However, the spectrally engineered RCC’s thermal regulation behavior relies heavily on clear weather, limiting the development of its adaptive thermal management performance and high cooling power. Inspired by the skin’s thermo-regulation, we report a bionic skin meta-gel coating (BSMC) with an adaptive spectrum and moisture modulation capability through hierarchical structure design and localized molecular confinement engineering. Autonomous thermal regulation and high cooling power are attained for the BSMC. Compared to conventional RCC, the BSMC achieves superior cooling performance (a reduction of 4°C) at high temperatures. Conversely, the BSMC can heat a space via photo-thermal effect at low temperatures. Moreover, the BSMC addresses heat accumulation in thermal camouflage nets. According to calculations, the BSMC improves cooling power by 233 W/m<sup>2</sup> and significantly decreases global CO<sub>2</sub> emissions by 1.9 billion tons/year. The BSMC solves the bottleneck of RCCs and promotes global low-carbon development.</div></div>","PeriodicalId":388,"journal":{"name":"Matter","volume":"8 6","pages":"Article 102057"},"PeriodicalIF":17.3,"publicationDate":"2025-06-04","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"143678119","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":1,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

引用次数: 0

Prussene: Transforming ancient pigments into magnetic nanoalloyed 2D layers 普鲁士：将古代颜料转化为磁性纳米合金二维层

IF 17.3 1区材料科学

Matter Pub Date : 2025-06-04 DOI: 10.1016/j.matt.2025.102090

Shizhuo Zhang , Feng Liu , Senlin Rao , Gary J. Cheng

{"title":"Prussene: Transforming ancient pigments into magnetic nanoalloyed 2D layers","authors":"Shizhuo Zhang , Feng Liu , Senlin Rao , Gary J. Cheng","doi":"10.1016/j.matt.2025.102090","DOIUrl":"10.1016/j.matt.2025.102090","url":null,"abstract":"<div><div>This study redefines Prussian blue analogs (PBAs), transforming them into Prussene—a two-dimensional (2D) layered nanomaterial—via laser-shock-induced 2D phase transition synthesis (LSPT<sup>2D</sup>). This scalable nanomanufacturing technique harnesses high-temperature/pressure plasmas to drive phase transitions, converting PBA nanocubes into N-doped carbon nanosheets embedded with ultrafine magnetic nanoalloys. Unlike conventional exfoliation method, LSPT<sup>2D</sup> enables chemical phase engineering, preserving structural integrity while imparting exceptional properties. Prussene exhibits a high saturation magnetization (108.3 emu/g) and enhanced conductivity due to its conductive carbon matrix. Demonstrating transformative electromagnetic wave absorption, it achieves a reflection loss of −51.7 dB and a 5.87 GHz effective bandwidth across GHz–THz frequencies, surpassing state-of-the-art absorbers. These attributes position Prussene as a breakthrough for stealth technologies and ultrahigh-frequency communications. This work establishes a scalable paradigm for synthesizing chemically modified 2D materials, unlocking applications in catalysis, energy storage, and multifunctional nanoelectronics. Prussene’s innovation lies in its synthesis-process-property triad, heralding a new era in high-performance nanomaterials.</div></div>","PeriodicalId":388,"journal":{"name":"Matter","volume":"8 6","pages":"Article 102090"},"PeriodicalIF":17.3,"publicationDate":"2025-06-04","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"143736912","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":1,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

引用次数: 0

I’m busy: The search for peer reviewers 我很忙：寻找同行审稿人

IF 17.3 1区材料科学

Matter Pub Date : 2025-06-04 DOI: 10.1016/j.matt.2025.102161

Steve Cranford

引用次数: 0

Engineering emissive excited states in organic electroluminescent materials 有机电致发光材料的工程发射激发态

IF 17.3 1区材料科学

Matter Pub Date : 2025-06-04 DOI: 10.1016/j.matt.2025.102142

Peng Tao (陶鵬) , Jibiao Jin (靳繼彪) , Xiaokang Zheng (鄭小康) , Yong-Jin Pu (夫勇進) , Wai-Yeung Wong (黃維揚)

{"title":"Engineering emissive excited states in organic electroluminescent materials","authors":"Peng Tao (陶鵬) , Jibiao Jin (靳繼彪) , Xiaokang Zheng (鄭小康) , Yong-Jin Pu (夫勇進) , Wai-Yeung Wong (黃維揚)","doi":"10.1016/j.matt.2025.102142","DOIUrl":"10.1016/j.matt.2025.102142","url":null,"abstract":"<div><div>The progress of full-color displays and solid-state lighting technology is greatly promoted by the rapid development of cutting-edge research on the design of organic luminescent materials and device architecture. The nature of the excited state plays a central role in governing the photophysical properties of the emitters, which then determine the performance of the organic electroluminescence. This review presents the engineering of emissive excited states in organic luminescent materials toward highly efficient electroluminescence. The fundamentals of electroluminescence and a discussion of excited-state engineering of organic electroluminescent materials are presented. From the perspective of spin multiplicity of the excited state, representative breakthroughs in molecular design strategies for triplet excited-state-utilizable emitters and doublet excited-state-based ones, as well as their application in high-performance electroluminescence, are discussed. Finally, we provide perspectives to emphasize the current challenges and potential opportunities for further development of high-performance electroluminescent materials.</div></div>","PeriodicalId":388,"journal":{"name":"Matter","volume":"8 6","pages":"Article 102142"},"PeriodicalIF":17.3,"publicationDate":"2025-06-04","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"144205386","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":1,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

引用次数: 0

Imaging of a multiferroic domain wall in a non-multiferroic environment 非多铁环境下多铁畴壁成像

IF 17.3 1区材料科学

Matter Pub Date : 2025-06-04 DOI: 10.1016/j.matt.2025.102051

Yannik Zemp , Ehsan Hassanpour , Yusuke Tokunaga , Yasujiro Taguchi , Yoshinori Tokura , Thomas Lottermoser , Mads C. Weber , Manfred Fiebig

{"title":"Imaging of a multiferroic domain wall in a non-multiferroic environment","authors":"Yannik Zemp , Ehsan Hassanpour , Yusuke Tokunaga , Yasujiro Taguchi , Yoshinori Tokura , Thomas Lottermoser , Mads C. Weber , Manfred Fiebig","doi":"10.1016/j.matt.2025.102051","DOIUrl":"10.1016/j.matt.2025.102051","url":null,"abstract":"<div><div>Compared with the surrounding bulk, the domain walls of materials exhibiting spontaneous long-range order exhibit significant changes in properties. The conducting domain walls in ferroelectrics are of great interest, for example, for their potential in rewriteable electric circuits. In contrast, it is rarely discussed that a ferroic material may also exhibit ferroic phases that are stable in the domain walls but not in the surrounding bulk material. Using Faraday rotation microscopy and second harmonic generation, we show that the domain walls in the antiferromagnetic and non-polar phase of <span><math><msub><mtext>Dy</mtext><mrow><mn>0</mn><mo>.</mo><mn>7</mn></mrow></msub><msub><mtext>Tb</mtext><mrow><mn>0</mn><mo>.</mo><mn>3</mn></mrow></msub><mtext>Fe</mtext><msub><mtext>O</mtext><mn>3</mn></msub></math></span> carry spontaneous magnetization and spontaneous polarization. By optical deconvolution, we find a stable width, magnetization, and polarization, supporting the wall-like nature. Magnetic domain formation within the walls is visualized, and magnetic and electric wall-domain switching is concluded from field-poling experiments. With our study, we thus provide visual evidence of the existence of multiferroic domain walls in a non-multiferroic environment.</div></div>","PeriodicalId":388,"journal":{"name":"Matter","volume":"8 6","pages":"Article 102051"},"PeriodicalIF":17.3,"publicationDate":"2025-06-04","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"143635769","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":1,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

引用次数: 0

Ion-migration-induced dual interface dipoles for high-performance perovskite solar cells 离子迁移诱导的高性能钙钛矿太阳能电池双界面偶极子

IF 17.3 1区材料科学

Matter Pub Date : 2025-06-04 DOI: 10.1016/j.matt.2025.102085

Wenjuan Jiang , Cheng Peng , Haokun Jiang , Mingzhe Zhu , Zhongmin Zhou

{"title":"Ion-migration-induced dual interface dipoles for high-performance perovskite solar cells","authors":"Wenjuan Jiang , Cheng Peng , Haokun Jiang , Mingzhe Zhu , Zhongmin Zhou","doi":"10.1016/j.matt.2025.102085","DOIUrl":"10.1016/j.matt.2025.102085","url":null,"abstract":"<div><div>Low exciton binding energy and well-aligned energy levels are crucial for achieving efficient perovskite solar cells (PSCs). Here, we introduce pyridinium tetrafluoroborate (PyHBF<sub>4</sub>) into the perovskite layer to regulate the interfaces between the perovskite and the charge transport layers effectively. This results in dual interface dipoles due to the migration of BF<sub>4</sub><sup>−</sup>, which accelerates the separation of hole-electron pairs and the extraction of carriers. <em>Ab initio</em> and DFT calculations, combined with various experimental characterizations, reveal that the thermodynamically favored combination of PyH<sup>+</sup> and I<sup>−</sup> causes BF<sub>4</sub><sup>−</sup> to separate from the PyH<sup>+</sup> cation and migrate downward along the Pb-I framework within the perovskite layer. In addition, the formation of the secondary compound PyHI on the top surface enhances cation-π interaction with Spiro-OMeTAD and increases the hydrophobicity of the perovskite film. Consequently, the PyHBF<sub>4</sub>-treated PSCs achieve a champion efficiency of 24.93%, along with improved thermal, humidity, and operational stability.</div></div>","PeriodicalId":388,"journal":{"name":"Matter","volume":"8 6","pages":"Article 102085"},"PeriodicalIF":17.3,"publicationDate":"2025-06-04","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"143713628","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":1,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

引用次数: 0

Water-induced degradation mechanism of metal halide perovskite nanocrystals 金属卤化物钙钛矿纳米晶水致降解机理研究

IF 17.3 1区材料科学

Matter Pub Date : 2025-06-04 DOI: 10.1016/j.matt.2025.102083

Hyeonjong Ma , Eonhyoung Ahn , Daewon Lee , Hyeongseung Kim , Kyunghoon Lee , Hyo Cheol Lee , Soyeon Lee , Seunghyun Ji , Kiwook Kim , Hyungju Ahn , Haimei Zheng , Jiwoong Yang

{"title":"Water-induced degradation mechanism of metal halide perovskite nanocrystals","authors":"Hyeonjong Ma , Eonhyoung Ahn , Daewon Lee , Hyeongseung Kim , Kyunghoon Lee , Hyo Cheol Lee , Soyeon Lee , Seunghyun Ji , Kiwook Kim , Hyungju Ahn , Haimei Zheng , Jiwoong Yang","doi":"10.1016/j.matt.2025.102083","DOIUrl":"10.1016/j.matt.2025.102083","url":null,"abstract":"<div><div>Metal halide perovskites have emerged as promising materials for diverse optoelectronic devices due to their superior optical properties. However, their instability in moisture hinders practical use, highlighting the need for an atomic-scale understanding of their degradation mechanism. Here, we uncover water-induced degradation pathways of perovskite nanocrystals using <em>in situ</em> liquid-phase transmission electron microscopy, revealing a distinctive dissolution process driven by ion solvation. The dissolution rates vary according to crystallographic direction, influenced by the surface polarity of different crystal facets, leading to a shape transformation from nanocubes to nanospheres. These observations are further supported by <em>in situ</em> X-ray scattering analysis. Notably, surface passivation of perovskite nanocrystals with halide ion pair ligands provides effective edge passivation, alters the degradation trajectories by preserving their cubic shape during the initial stages, and significantly reduces the overall degradation rate. This study offers critical insights into the water-induced degradation mechanisms of perovskite nanocrystals, potentially guiding strategies to enhance their stability.</div></div>","PeriodicalId":388,"journal":{"name":"Matter","volume":"8 6","pages":"Article 102083"},"PeriodicalIF":17.3,"publicationDate":"2025-06-04","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"143713627","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":1,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

引用次数: 0

From lab to industry: High-safety separators for lithium-ion/-metal batteries 从实验室到工业：用于锂离子/金属电池的高安全性分离器

IF 17.3 1区材料科学

Matter Pub Date : 2025-06-04 DOI: 10.1016/j.matt.2025.102101

Jia Zhang , Zhongxiu Liu , Chenyang Dang , Xiaoqing Zhu , Tao Zhang , Jing Shen , Hao Yang , Yujie Zhang , Yunteng Cao , Chris Y. Yuan , C. Chase Cao , Guiyin Xu , Meifang Zhu

{"title":"From lab to industry: High-safety separators for lithium-ion/-metal batteries","authors":"Jia Zhang , Zhongxiu Liu , Chenyang Dang , Xiaoqing Zhu , Tao Zhang , Jing Shen , Hao Yang , Yujie Zhang , Yunteng Cao , Chris Y. Yuan , C. Chase Cao , Guiyin Xu , Meifang Zhu","doi":"10.1016/j.matt.2025.102101","DOIUrl":"10.1016/j.matt.2025.102101","url":null,"abstract":"<div><div>Rechargeable lithium-ion and lithium-metal batteries have achieved remarkable progress, yet frequent battery accidents demand urgent attention. The separator, which acts as both an electrical barrier and an ion transport medium between electrodes, fundamentally governs ionic kinetics, rate performance, and, most importantly, battery safety. Developing functional separators that ensure continuous and safe battery operation is therefore critical. This review systematically summarizes recent progress in high-safety separators for lithium-ion and lithium-metal batteries, spanning from laboratory research to industrial applications. Various safety concerns—chemical crosstalk and internal short circuits—are discussed in detail. Key performance requirements for high-safety separators, including mechanical strength, thermal conductivity, heat resistance, anti-dendrite properties, and crosstalk resistance, are highlighted. The industrial preparation processes and the associated challenges are also discussed, with an emphasis on the importance of close collaboration between academia and industry. Finally, we present the key challenges and future perspectives for the development of high-safety separators.</div></div>","PeriodicalId":388,"journal":{"name":"Matter","volume":"8 6","pages":"Article 102101"},"PeriodicalIF":17.3,"publicationDate":"2025-06-04","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"144205384","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":1,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

引用次数: 0

Personalized cervical plug combines mechanical and biological regulation for enhanced embryo implantation and live births 个性化宫颈塞结合了机械和生物调节，以增强胚胎植入和活产

IF 17.3 1区材料科学

Matter Pub Date : 2025-06-04 DOI: 10.1016/j.matt.2025.102043

Mei Chen , Mengyuan Dai , Gonghua Hong , Fangyuan Li , Yue Wu , Yiran Pu , Jialing Liu , Yaoyao Zhang , Wei Huang , Junling Guo

{"title":"Personalized cervical plug combines mechanical and biological regulation for enhanced embryo implantation and live births","authors":"Mei Chen , Mengyuan Dai , Gonghua Hong , Fangyuan Li , Yue Wu , Yiran Pu , Jialing Liu , Yaoyao Zhang , Wei Huang , Junling Guo","doi":"10.1016/j.matt.2025.102043","DOIUrl":"10.1016/j.matt.2025.102043","url":null,"abstract":"<div><div>Declining birth rates and widespread infertility highlight the urgency of addressing the global population crisis. Despite advancements in <em>in vitro</em> fertilization (IVF) embryo transfer, low implantation rates due to uterine peristalsis and insufficient embryo-endometrium interaction leads to low pregnancy rate and live births. We introduce a personalized, 3D-printed cervical plugging device (CervPlug), tailored to individual cervical dimensions. This non-invasive, patient-friendly intervention effectively improves embryo residence time in the uterus, enhancing embryo-endometrium contact and achieving efficient live births. Moreover, CervPlug also facilitates biological regulation by integrating a supramolecular phenolic nanocomplex composed of green tea polyphenol and Zn<sup>2+</sup> ions. This enables controlled release of progesterone, reduces cervical inflammation, and lowers intra-embryonic reactive oxygen species (ROS). <em>In vivo</em> experiments demonstrate that CervPlug significantly increases implantation rates from 45% to 65% and live births, with no significant adverse effects on the reproductive system. This biomaterial-driven strategy offers a safer, less intrusive alternative in reproductive medicine.</div></div>","PeriodicalId":388,"journal":{"name":"Matter","volume":"8 6","pages":"Article 102043"},"PeriodicalIF":17.3,"publicationDate":"2025-06-04","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"143640981","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":1,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

引用次数: 0