Matter最新文献 - Book学术

Electrical control of a metal-mediated DNA memory 金属介导的DNA记忆的电子控制

IF 18.9 1区材料科学

Matter Pub Date : 2025-10-06 DOI: 10.1016/j.matt.2025.102470

Bo Liu, Brandon Lu, Arpan De, Kyoungdu Kim, Lara Perren, Karol Woloszyn, Galina Petrova, Ruihao Li, Chu-fan Yang, Chengde Mao, Antia S. Botana, Yoel P. Ohayon, James W. Canary, Ruojie Sha, M.P. Anantram, Simon Vecchioni, Joshua Hihath

引用次数: 0

Rapid scalable plasma processing of thin-film Li–La–Zr–O solid-state electrolytes 薄膜Li-La-Zr-O固态电解质的快速可扩展等离子体处理

IF 18.9 1区材料科学

Matter Pub Date : 2025-10-04 DOI: 10.1016/j.matt.2025.102468

Gabriel Badillo Crane, Thomas W. Colburn, Sarah E. Holmes, Justus Just, Yi Cui, Reinhold H. Dauskardt

引用次数: 0

Precise heterodimerization of acceptors for high-efficiency binary organic solar cells 高效二元有机太阳能电池受体的精确异二聚化

IF 18.9 1区材料科学

Matter Pub Date : 2025-10-03 DOI: 10.1016/j.matt.2025.102465

Guangkuo Dai, Jiali Song, Jiawei Deng, Haisheng Ma, Ziwei Zhang, Yi Chan, Cen Zhang, Xunchang Wang, Jiaying Wu, Renqiang Yang, Xiaobo Sun, Yanming Sun

{"title":"Precise heterodimerization of acceptors for high-efficiency binary organic solar cells","authors":"Guangkuo Dai, Jiali Song, Jiawei Deng, Haisheng Ma, Ziwei Zhang, Yi Chan, Cen Zhang, Xunchang Wang, Jiaying Wu, Renqiang Yang, Xiaobo Sun, Yanming Sun","doi":"10.1016/j.matt.2025.102465","DOIUrl":"https://doi.org/10.1016/j.matt.2025.102465","url":null,"abstract":"Although dimeric acceptors have demonstrated promising efficacy for improving operational stability of organic solar cells (OSCs), the power conversion efficiencies (PCEs) of corresponding binary devices remain constrained due to their weak intermolecular interactions and undesirable molecular packing. Here, we integrate a dimerization with asymmetric terminal strategy to design a heterodimer acceptor, NVB. Breaking molecular symmetry enhances dipole interactions and optimizes molecular packing, leading to superior charge transport and suppressed recombination. As a result, the PM6:NVB-based device achieves a record-high efficiency of 19.90% (certified as 19.35%), representing the highest value reported for all dimer-based binary devices thus far. Remarkably, the NVB-based device exhibits enhanced stability with a <em>T</em><sub>80</sub> (lifetime for maintaining 80% of its initial efficiency) over 1,500 h, attributed to elevated glass transition temperature (<em>T</em><sub>g</sub>). Overall, this work establishes an “asymmetric dimerization” paradigm that concurrently improves efficiency and stability through molecular engineering, providing a practical pathway toward high-performance OSCs.","PeriodicalId":388,"journal":{"name":"Matter","volume":"1 1","pages":""},"PeriodicalIF":18.9,"publicationDate":"2025-10-03","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"145209745","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":1,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

引用次数: 0

MOF-based magnetically manipulated microwheel-robots for triglyceride degradation 基于mof的甘油三酯降解磁操纵微轮机器人

IF 17.5 1区材料科学

Matter Pub Date : 2025-10-01 DOI: 10.1016/j.matt.2025.102198

Zixian Liang , Jiahao Zhang , Qinyi Cao , Wanyuan Li , Yuting Dai , Yining Zhao , Leyan Ou , Dapeng Lei , Kunfeng Liu , Zonghua Luo , Ze Xiong , Guihua Jiang , Yin Ning , Jizhuang Wang , Jinyao Tang , Dan Li

{"title":"MOF-based magnetically manipulated microwheel-robots for triglyceride degradation","authors":"Zixian Liang , Jiahao Zhang , Qinyi Cao , Wanyuan Li , Yuting Dai , Yining Zhao , Leyan Ou , Dapeng Lei , Kunfeng Liu , Zonghua Luo , Ze Xiong , Guihua Jiang , Yin Ning , Jizhuang Wang , Jinyao Tang , Dan Li","doi":"10.1016/j.matt.2025.102198","DOIUrl":"10.1016/j.matt.2025.102198","url":null,"abstract":"<div><div><span><span>Micro/nanorobots (MNRs) have demonstrated immense potential in the biomedical field<span>, particularly magnetic-controlled MNRs, due to their non-invasive operation, high controllability, and excellent penetration abilities. Metal-organic frameworks (MOFs) are ideal for micro-robot design due to their high payload capacity and responsiveness. But creating customizable MOF-based micro-robots presents challenges. This study presents a novel method combining micro/nanofabrication and biphasic interfacial crystallization to construct customizable MOF-based magnetically manipulated microwheel-robots (MMWRs). By incorporating magnetic </span></span>nanoparticles </span><em>in situ</em><span><span>, these MMWRs exhibit excellent magnetic responsiveness, performing various motions—such as standing, lying, rotating, tumbling, and rolling—under adjustable magnetic fields, enabling precise control and complex task execution. Furthermore, lipase-loaded MMWRs efficiently degrade tributyrin, with motion-induced diffusion and a pH-responsive feedback mechanism enhancing </span>lipase<span><span><span> release and degradation efficiency. Positron emission </span>tomography with </span>computed tomography imaging confirmed the potential of MMWRs in a simulated pipeline scenario. The customizable MOF-based micro-robots pave the way for advancements in environmental degradation and disease treatment.</span></span></div></div>","PeriodicalId":388,"journal":{"name":"Matter","volume":"8 10","pages":"Article 102198"},"PeriodicalIF":17.5,"publicationDate":"2025-10-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"144237897","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":1,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

引用次数: 0

Micropillar-enabled tough adhesion and enhanced sensing 微柱支持牢固的附着力和增强的传感

IF 17.5 1区材料科学

Matter Pub Date : 2025-10-01 DOI: 10.1016/j.matt.2025.102221

Xi Xia , Xingxing Chen , Junli Shi , Zhibin Li , Bingfa Jiang , Kaixi Huang , Mengxue Guo , Zeyun Yang , Zelong Liao , Chaoyang Song , Chuan Fei Guo

{"title":"Micropillar-enabled tough adhesion and enhanced sensing","authors":"Xi Xia , Xingxing Chen , Junli Shi , Zhibin Li , Bingfa Jiang , Kaixi Huang , Mengxue Guo , Zeyun Yang , Zelong Liao , Chaoyang Song , Chuan Fei Guo","doi":"10.1016/j.matt.2025.102221","DOIUrl":"10.1016/j.matt.2025.102221","url":null,"abstract":"<div><div><span><span>Skin-like sensors are key for humanoid robots<span> and wearables. Achieving both robust interfaces and promoted sensing performances in soft sensors may enable their applications in extreme mechanical conditions of high shear. However, strong interfacial adhesion in multilayer sensors often compromise sensing properties. Here, we design hyperbranched </span></span>polyurethane<span><span> micropillars with (diameter < length of flaw sensitivity) that serve dual roles as an adhesion layer for exceptional </span>mechanical stability<span>, and adaptive spacer for enhanced sensing properties. We show a strong size effect of the structure to toughen the interface, with ultrahigh interfacial toughness up to 5,095 J m</span></span></span><sup>−2</sup><span> at a 50-μm pillar diameter. Simultaneously, the micropillars enhance sensitivity and limit of detection by decreasing the stiffness via elastic buckling and enable a rapid response to the acoustic range by reducing energy loss during loading and unloading. The sensors are ideal for the manipulation of heavy objects in humanoid robots and other applications.</span></div></div>","PeriodicalId":388,"journal":{"name":"Matter","volume":"8 10","pages":"Article 102221"},"PeriodicalIF":17.5,"publicationDate":"2025-10-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"144329194","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":1,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

引用次数: 0

Materials-empowered smart versatile building envelopes toward a sustainable energy-water-environment nexus 材料驱动的智能多功能建筑围护结构，实现可持续的能源-水-环境关系

IF 17.5 1区材料科学

Matter Pub Date : 2025-10-01 DOI: 10.1016/j.matt.2025.102293

Haosheng Lin , Zengguang Sui , Fuxiang Li , Wei Wu

引用次数: 0

Multiresonance-donor-multiresonance emitter for efficient narrowband blue OLEDs 高效窄带蓝色oled的多共振-给体-多共振发射极

IF 17.5 1区材料科学

Matter Pub Date : 2025-10-01 DOI: 10.1016/j.matt.2025.102188

Yi-Hui He , Jun-Yu Liu , Zhen Zhang , Guo-Wei Chen , Yan-Chun Wang , Guo Yuan , Feng-Ming Xie , Jian-Xin Tang , Yan-Qing Li

{"title":"Multiresonance-donor-multiresonance emitter for efficient narrowband blue OLEDs","authors":"Yi-Hui He , Jun-Yu Liu , Zhen Zhang , Guo-Wei Chen , Yan-Chun Wang , Guo Yuan , Feng-Ming Xie , Jian-Xin Tang , Yan-Qing Li","doi":"10.1016/j.matt.2025.102188","DOIUrl":"10.1016/j.matt.2025.102188","url":null,"abstract":"<div><div>Solution processing has emerged as an up-and-coming technique for the scalable manufacture of organic light-emitting diodes (OLEDs) owing to the material savings and compatibility with large-area manufacturing. Nonetheless, the development of solution-processable pure-blue emitters that exhibit optimal color purity and electroluminescent<span><span> efficiency presents a significant challenge in pursuing high-performance solution-processed devices. Here, we demonstrate a molecular configuration strategy to create solution-processable multiresonance thermally activated delayed fluorescence (MR-TADF) emitters. The methodology encompasses the construction of a “multiresonance-donor-multiresonance (MR-D-MR)” framework that features hybrid short/long-range charge transfer excitation characteristics. The proof-of-concept emitter demonstrates considerable </span>rigidity<span> and reduced vibronic progression, resulting in pure-blue narrowband emission at 474 nm. Furthermore, it possesses a large oscillator strength<span> and significant spin-orbit couplings, facilitating rapid exciton dynamics. These advantageous properties enable the emitter to achieve a record-high electroluminescent efficiency of 35.1% for sensitizer-free solution-processed OLEDs. The outstanding electroluminescent outcomes underscore the efficacy of our molecular construction strategy.</span></span></span></div></div>","PeriodicalId":388,"journal":{"name":"Matter","volume":"8 10","pages":"Article 102188"},"PeriodicalIF":17.5,"publicationDate":"2025-10-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"144145976","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":1,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

引用次数: 0

Approaching highly stable optoelectronic device operation at elevated temperature by locking backbone torsion of conjugated polymers 通过锁定共轭聚合物的主链扭转来实现高稳定的光电器件在高温下的工作

IF 17.5 1区材料科学

Matter Pub Date : 2025-10-01 DOI: 10.1016/j.matt.2025.102195

Zhiqiang Cao , Zhaofan Li , Angela Awada , Sara A. Tolba , Madison Mooney , Yangyang Wang , Yu-Cheng Chiu , Simon Rondeau-Gagné , Wenjie Xia , Xiaodan Gu

{"title":"Approaching highly stable optoelectronic device operation at elevated temperature by locking backbone torsion of conjugated polymers","authors":"Zhiqiang Cao , Zhaofan Li , Angela Awada , Sara A. Tolba , Madison Mooney , Yangyang Wang , Yu-Cheng Chiu , Simon Rondeau-Gagné , Wenjie Xia , Xiaodan Gu","doi":"10.1016/j.matt.2025.102195","DOIUrl":"10.1016/j.matt.2025.102195","url":null,"abstract":"<div><div>The ability of organic electronics to maintain stability at elevated temperatures is crucial for the longevity of optoelectronic devices. However, achieving stable optoelectronic properties for conjugated polymers remains fundamentally challenging. Here, we identify backbone twisting motion as the primary reason for the unstable optoelectronic properties of donor-acceptor (D-A) conjugated polymers, using diketopyrrolopyrrole (DPP)-based polymers as a model system. The backbone thiophene-ring twist transition is responsible for shifts in the band gap and alterations in charge transport properties. The twisting motion of the thiophene induces localization of the intrachain electrons, resulting in reduced charge carrier mobility and a significant blue shift in optical absorption. Additionally, we demonstrated that intramolecular hydrogen bonding interaction within DPP polymers can suppress undesired backbone twisting at elevated temperatures, thereby ensuring a more stable optoelectronic property. Our work offers fundamental insights into the decline in device stability at elevated temperatures and a strategy to enhance device stability.</div></div>","PeriodicalId":388,"journal":{"name":"Matter","volume":"8 10","pages":"Article 102195"},"PeriodicalIF":17.5,"publicationDate":"2025-10-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"144202361","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":1,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

引用次数: 0

High-entropy alloys extra-stabilized by carbon dots as highly efficient catalysts for dehydrogenation/hydrogenation reactions 碳点超稳定的高熵合金作为脱氢/加氢反应的高效催化剂

IF 17.5 1区材料科学

Matter Pub Date : 2025-10-01 DOI: 10.1016/j.matt.2025.102199

Feifei Mei , Jun Yao , Chenyang Shen , Bingqing Ge , Mingyang Deng , Fengfeng Li , Xuefeng Guo , Weiping Ding

{"title":"High-entropy alloys extra-stabilized by carbon dots as highly efficient catalysts for dehydrogenation/hydrogenation reactions","authors":"Feifei Mei , Jun Yao , Chenyang Shen , Bingqing Ge , Mingyang Deng , Fengfeng Li , Xuefeng Guo , Weiping Ding","doi":"10.1016/j.matt.2025.102199","DOIUrl":"10.1016/j.matt.2025.102199","url":null,"abstract":"<div><div><span><span>We report here the high-entropy alloy (HEA) FeCoNiCuZn extra-stabilized by carbon dots<span><span><span> (CDs) formed at temperatures as low as 400°C, featuring high surface area and tuned electronic states and atomic arrangement. </span>Density functional theory reveals that CDs lower the nucleation energy via interactions of interfacial matching and enhance the control on </span>crystallinity<span> by adsorption energy. The FeCoNiCuZn-CD HEA thus obtained shows excellent catalytic performance in reactions of methylcyclohexane/toluene dehydrogenation/hydrogenation and </span></span></span>furfural hydrogenation to </span>furfuryl alcohol<span>, achieving unitary selectivity and exceptional stability. Results of characterizations and theoretical calculations fully demonstrate the extra-stabilization of CDs on the FeCoNiCuZn HEA and the modulation of CDs as electron sink on the FeCoNiCuZn HEA to promote its catalytic activity. This strategy provides an approach for the efficient synthesis of HEAs as well as highlights the dual roles of CDs for catalyst modification, paving the way for the design of more multifunctional catalytic materials.</span></div></div>","PeriodicalId":388,"journal":{"name":"Matter","volume":"8 10","pages":"Article 102199"},"PeriodicalIF":17.5,"publicationDate":"2025-10-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"144237925","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":1,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

引用次数: 0

Regenerable triboelectric artificial hyperaccumulator for sustainable heavy- metals detection and remediation 可持续重金属检测与修复的可再生摩擦电人工超蓄能器

IF 17.5 1区材料科学

Matter Pub Date : 2025-10-01 DOI: 10.1016/j.matt.2025.102219

Geng-Sheng Lin , Lan Gan , Ji Gao , Yong Ding , Zhong Lin Wang , Yongsheng Chen , Haiyang Zou , Zhaohui Tong

{"title":"Regenerable triboelectric artificial hyperaccumulator for sustainable heavy- metals detection and remediation","authors":"Geng-Sheng Lin , Lan Gan , Ji Gao , Yong Ding , Zhong Lin Wang , Yongsheng Chen , Haiyang Zou , Zhaohui Tong","doi":"10.1016/j.matt.2025.102219","DOIUrl":"10.1016/j.matt.2025.102219","url":null,"abstract":"<div><div><span><span><span><span>The remediation of heavy metals in wastewater remains a critical challenge due to their toxicity, diverse chemical forms, and </span>nanoscale<span> size. Conventional identification and removal methods are often complex and costly, lacking a unified, efficient solution. Inspired by hyperaccumulators—plants that capture, respond to, and detoxify heavy metals—we developed a regenerable artificial hyperaccumulator system. This system integrates a cellulose-based adsorptive membrane into a triboelectric membrane sensor (TEMS) for simultaneous adsorption and detection. The membrane effectively captures multiple heavy metal ions, while the TEMS device exhibits a 74.2% enhancement in the triboelectric effect, achieving highly </span></span>sensitive detection<span> (1 nM–1 mM) and accurate feed concentration predictions (5.14% error). Notably, the system maintains 100% reusability over six regeneration cycles. This work presents a cost-effective, multifunctional platform, advancing sustainable solutions for </span></span>water purification and </span>energy harvesting.</div></div>","PeriodicalId":388,"journal":{"name":"Matter","volume":"8 10","pages":"Article 102219"},"PeriodicalIF":17.5,"publicationDate":"2025-10-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"144319848","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":1,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

引用次数: 0