{"title":"Correction: The effect of anhydride categories on the properties of UV-curable epoxy acrylic resin","authors":"Rouyan Li, Ting Peng, Yanan Zhu, Jinqing Qu","doi":"10.1007/s11998-025-01112-9","DOIUrl":"10.1007/s11998-025-01112-9","url":null,"abstract":"","PeriodicalId":619,"journal":{"name":"Journal of Coatings Technology and Research","volume":"22 3","pages":"1219 - 1219"},"PeriodicalIF":2.3,"publicationDate":"2025-04-07","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"143896770","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Artem A. Golubev, Ksenia S. Baranova, Alexander A. Galkin, Mikhail A. Soldatov, Anna A. Shcherbina
{"title":"Preparation and characterization of UV-curable water-based alkyd-siloxane composition","authors":"Artem A. Golubev, Ksenia S. Baranova, Alexander A. Galkin, Mikhail A. Soldatov, Anna A. Shcherbina","doi":"10.1007/s11998-024-01058-4","DOIUrl":"10.1007/s11998-024-01058-4","url":null,"abstract":"<div><p>A UV-curable alkyd-siloxane composition on a water basis was obtained, as an alternative to a similar composition based on an organic solvent. The emulsion was prepared using commercially available surfactants and free of volatile organic substances (VOCs). The most applicable technology for the production of alkyd-siloxane emulsions is direct emulsification at a temperature of 60°C, and using dynamic light scattering, the hydrodynamic radius of the particles was determined to be 132 ± 38 nm. The resulting emulsion has an aggregative and sedimentation stability during storage up to 3 months; however, the temperature difference causes the destruction of the colloidal system. The curing reaction occurs within 10 min to form a coating containing 95% gel fraction. Emulsion-based coatings have better properties relative to alkyd coatings but are not significantly inferior to coatings from an organo-soluble UV-curable composition. Coatings based on UV-cured materials have shown low chemical resistance, which limits their use in conditions where contact with aggressive liquids occurs. The presence of surfactants in the coating reduces the water contact angle by 4° and increases water absorption by 1.5% relative to coatings based on organo-soluble alkyd-siloxane composition. Sorption studies have shown that the diffusion coefficients of water into the coating from the emulsion and the organo-soluble system have the same values and amount to 8.35·10<sup>−9</sup> cm<sup>2</sup>/s. The difference in the glass transition temperature of coatings obtained from an emulsion (21.0°C) and a solution (24.2°C), as well as a decrease in heat resistance, indicates a lower degree of crosslinking due to the presence of surfactants in the system. Elemental and morphological analysis showed that there is no phase decay during the process of coating formation, and all elements are evenly distributed over the surface. A comparative analysis of the results of the study with the literature data showed that the obtained emulsion is not inferior in properties to other UV-curable water-based materials.</p></div>","PeriodicalId":619,"journal":{"name":"Journal of Coatings Technology and Research","volume":"22 3","pages":"1185 - 1205"},"PeriodicalIF":2.3,"publicationDate":"2025-03-26","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"143896699","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Gunvant K. Badgujar, Nilesh P. Badgujar, Karuppiah Nagaraj, Raja Kaliyaperumal, Lakshmanan Archana Devi, Thangavel Manimegalai
{"title":"Nanocontainer-based self-healing coatings: advancements, applications, and future directions in anticorrosion technology: a short review","authors":"Gunvant K. Badgujar, Nilesh P. Badgujar, Karuppiah Nagaraj, Raja Kaliyaperumal, Lakshmanan Archana Devi, Thangavel Manimegalai","doi":"10.1007/s11998-024-01052-w","DOIUrl":"10.1007/s11998-024-01052-w","url":null,"abstract":"<div><p>Metal corrosion presents a major challenge that demands urgent solutions. The scientific community is increasingly focusing on self-healing coatings based on nanocontainers due to their adaptability and long-term corrosion inhibition properties. These coatings control the release of active agents, such as corrosion inhibitors, from micro-/nanocontainers. They can respond to factors like crack formation, pH changes, and temperature variations, often reducing crack propagation rates. This paper provides a comprehensive analysis of the nanocontainers and corrosion inhibitors used in self-healing anticorrosion coatings, covering the types, applications, and synthesis methods of these materials. Additionally, recent advances in producing nanocontainer-based self-healing coatings across various industries are discussed. The report concludes with a summary of key findings and a forecast for the future development of sustainable, efficient, cost-effective, and multifunctional self-healing coatings based on nanotechnology. Further research is recommended to enhance coating formulations with sustainable and advanced approaches.</p></div>","PeriodicalId":619,"journal":{"name":"Journal of Coatings Technology and Research","volume":"22 3","pages":"859 - 876"},"PeriodicalIF":2.3,"publicationDate":"2025-03-19","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"143896800","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Yunwei Huang, Qiumin Chen, Wanzhi Wu, Hongzhen Peng, Qian Ji, Yanling Li, Jiangfei Cao, Feihua Ye, Chunsheng Li, Pingke Ai
{"title":"Investigation on the preparation of a highly water-resistant emulsion coating for paper-based packaging materials","authors":"Yunwei Huang, Qiumin Chen, Wanzhi Wu, Hongzhen Peng, Qian Ji, Yanling Li, Jiangfei Cao, Feihua Ye, Chunsheng Li, Pingke Ai","doi":"10.1007/s11998-024-01040-0","DOIUrl":"10.1007/s11998-024-01040-0","url":null,"abstract":"<div><p>To enhance the water resistance of paper-based packaging materials, an emulsion coating with high water resistance properties has been developed for application to these materials. This coating was synthesized using isooctyl acrylate, lauryl methacrylate, styrene, and methacrylic acid as reactive monomers, organosilicone KH151 as a coupling agent, heptadecanol polyoxyethylene ether monophosphate as the emulsifier, and glycerol triglycidyl ether as a post-crosslinking agent. Through a seed emulsion polymerization process, a water-based organosilicone-modified styrene-acrylic emulsion was expertly crafted. After being spread onto a substrate paper and subsequently dried, the highly water-resistant emulsion coating was obtained. The results showed a remarkable decrease in water absorption from 89.23 to 3.15 g/m<sup>2</sup> at a coating weight of 3.01 gsm on the substrate paper, and no water seepage was observed on the reverse side of the paper for 20 min, demonstrating the highly water-resistant properties of the coating. Moreover, this coating also possesses the advantages of antiadhesion and endurance at temperatures below 360.3 °C. The coating emulsion has no acute toxicity risks at the tested concentration of 100 mg/L, suggesting its safety for application in paper-based packaging materials.</p></div>","PeriodicalId":619,"journal":{"name":"Journal of Coatings Technology and Research","volume":"22 3","pages":"1159 - 1169"},"PeriodicalIF":2.3,"publicationDate":"2025-03-04","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"143896701","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
{"title":"Visualizing latex film formation using freeze-drying and scanning electron microscopy","authors":"Annie Moorhead, Lorraine F. Francis","doi":"10.1007/s11998-024-01044-w","DOIUrl":"10.1007/s11998-024-01044-w","url":null,"abstract":"<div><p>Aqueous latex coatings transform from a suspension of discrete particles to a continuous polymer film during drying. Characterizing these microstructural changes is challenging given the transient nature of drying and the presence of water within samples. The present work proposes a freeze-drying preparation method that captures intermediate microstructural states during latex film formation so that they can be characterized by scanning electron microscopy (SEM) at room temperature. To develop this method, aqueous coatings prepared from diluted styrene acrylic latex (Primal DC-420, DOW Chemical) were deposited onto silicon substrates and dried just above the latex minimum film formation temperature (MFFT) of ~ 30°C. Coatings were then flash-frozen at various time points during drying, and then the ice within the frozen coating was sublimed under vacuum (<i>P</i> < 200 Pa). Specimens were stored and sputter coated with platinum at low temperature (<0°C) before SEM imaging. Surface and cross-sectional images showed multiple stages of film formation, enabled by a lateral drying front. Parallel cryogenic SEM studies verified that the freeze-drying method comparably captures microstructure after latex particles consolidate into a network. Studies with lower MFFT coatings, including those made from a different latex (Acronal S 790, BASF) or from Primal DC-420 with a coalescent (Texanol, Eastman Chemical), demonstrated the importance of storing and sputter coating specimens at temperatures less than the MFFT to maintain the microstructures for room temperature SEM imaging. Through the freeze-drying method, microstructures associated with all three stages of film formation (consolidation, compaction, and coalescence) were visualized, enabling the continued development and improvement of latex-containing coating formulations.</p></div>","PeriodicalId":619,"journal":{"name":"Journal of Coatings Technology and Research","volume":"22 3","pages":"1171 - 1184"},"PeriodicalIF":2.3,"publicationDate":"2025-03-04","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://link.springer.com/content/pdf/10.1007/s11998-024-01044-w.pdf","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"143896769","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"OA","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Jiaqing Zhang, Yi Guo, Lingxin He, Jie Huang, YuBiao Huang, Fengju Shang, Rui Liu, Xia Zhou
{"title":"Study on preparation and fire-resistant property of an organic silicone coating with compounding glass powder","authors":"Jiaqing Zhang, Yi Guo, Lingxin He, Jie Huang, YuBiao Huang, Fengju Shang, Rui Liu, Xia Zhou","doi":"10.1007/s11998-024-01035-x","DOIUrl":"10.1007/s11998-024-01035-x","url":null,"abstract":"<div><p>To improve the fire resistance performance of silicone resin, a silicone coating which can resist a flame temperature at 1200°C was designed and prepared by compounding glass powder, Mg(OH)<sub>2</sub>, talcum powder, kaoline, Al<sub>2</sub>O<sub>3</sub>, TiO<sub>2</sub>, and SiO<sub>2</sub> as functional fillers. After burning and oxidizing by acetylene flame at 1200°C for 90 min, there is no penetration and peeling of silicone coating. Moreover, the highest temperature on the back of the substrate is 263°C and the average temperature of it is 207°C, which are both lower than the softening temperature of steel. As analyzed, the functional fillers in silicone coating are evenly distributed. There are still high-temperature-resistant fillers including talcum powder, kaoline, SiO<sub>2</sub>, TiO<sub>2</sub>, and Al<sub>2</sub>O<sub>3</sub> in the char layer formed by the fire-resistant coating. After fire resistance test, the char layer of silicone coating does not possess a large area of voids, which indicates that the composite glass powder may melt and flow in time in the range of 400–500°C. The glass powder with low-melting point supplements the vacancies caused by pyrolysis of organic silicone resin film former. Furthermore, the existence of glass powder and Mg(OH)<sub>2</sub> composite improves the high-temperature adhesion of silicone coating, while talcum powder, kaoline, SiO<sub>2</sub>, TiO<sub>2</sub>, and Al<sub>2</sub>O<sub>3</sub> in the silicone coating have the function of reinforcement. The high-temperature resistance of talcum powder, kaoline, SiO<sub>2</sub>, TiO<sub>2</sub>, and Al<sub>2</sub>O<sub>3</sub> improves the fire resistance of the silicone coating as well.</p></div>","PeriodicalId":619,"journal":{"name":"Journal of Coatings Technology and Research","volume":"22 3","pages":"1087 - 1097"},"PeriodicalIF":2.3,"publicationDate":"2025-02-24","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"143896711","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
{"title":"Greener route towards preparation of plant-based antifungal fatliquor for eco-conscious application during leather making","authors":"Sivaranjani Venugopal, Yasmin Khambhaty","doi":"10.1007/s11998-024-01036-w","DOIUrl":"10.1007/s11998-024-01036-w","url":null,"abstract":"<div><p>Fatliquors are essential wet chemicals in the leather-making process, enhancing softness, suppleness, and durability by preventing fibril aggregation and filling voids. However, some fatliquors can also promote fungal growth on finished leather products. This study explores the potential of fatliquor produced via a green route from <i>Azadirachta indica</i> (Neem) seed oil. Neem, a tropical and subtropical tree native to India and Southeast Asia, is renowned for its medicinal properties, earning the moniker “village pharmacy” due to its antiseptic, antimicrobial, anti-inflammatory, anti-ulcer, anti-malarial, and anticancer benefits. In this research, fatliquor was synthesized from Neem seed oil through sulphation and applied for fatliquoring of leather. This leather was compared with commercially fatliquored leather, showing enhanced lubricity and mechanical properties. Furthermore, the high unsaturation level and significant antifungal properties of the Neem-based fatliquor resulted in the development of a novel, eco-friendly fatliquor for leather application.</p><h3>Graphical abstract</h3><div><figure><div><div><picture><source><img></source></picture></div></div></figure></div></div>","PeriodicalId":619,"journal":{"name":"Journal of Coatings Technology and Research","volume":"22 3","pages":"1099 - 1112"},"PeriodicalIF":2.3,"publicationDate":"2025-02-21","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"143896712","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
{"title":"Evaluation of weatherability of latex paint films using synthetic aluminum silicate-modified titanium dioxide photocatalysts as a multifunctional filler","authors":"Fumihiko Ohashi, Atsushi Shibahara","doi":"10.1007/s11998-024-01043-x","DOIUrl":"10.1007/s11998-024-01043-x","url":null,"abstract":"<div><p>Nanocomposites of TiO<sub>2</sub> modified with semi-crystalline aluminum silicates (AS-T nanocomposites) with various chemical compositions were synthesized using a hydrothermal process and evaluated as fillers for aqueous latex paints. AS-T nanocomposite powders decomposed and mineralized gaseous acetaldehyde more efficiently than a commercial TiO<sub>2</sub>-based material. Coating films containing AS-T nanocomposites were prepared using a spray-coating method. The films exhibited high degradation behavior for methylene blue aqueous solution, and the degradation level of one of these films reached up to 80%. After 600 h of accelerated weathering tests, gloss of the reference films decreased to 40% and their surface condition deteriorated, while no change was confirmed in either gloss or the surface condition of AS-Ts-contained films. Furthermore, color difference after the same period showed a value of 8 Δ<i>E</i>* units (CIELAB) for the reference films due to discoloration but relatively favorable values ranging from 3.6 to 5.6 units for AS-Ts-contained films. These results indicate that AS-Ts-contained films possess superior weatherability compared to the reference films. For this film surface designing, appropriate ratios of the surface functional groups with different affinities and proportions of Si(Al)-OH and/or Si-OH-Al in a specific range of chemical compositions should be considered.</p></div>","PeriodicalId":619,"journal":{"name":"Journal of Coatings Technology and Research","volume":"22 3","pages":"1207 - 1218"},"PeriodicalIF":2.3,"publicationDate":"2025-02-21","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"143896700","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Gimhani C. Wikaramasinghe, Rangana M. Manamendra, K. R. Jaliya Manuda, Buddini Nissanka, Darshana L. Weerawarne, Dilushan R. Jayasundara
{"title":"Correction: Binder-free conductive graphite coatings on polyimide substrates for applications in flexible electronics","authors":"Gimhani C. Wikaramasinghe, Rangana M. Manamendra, K. R. Jaliya Manuda, Buddini Nissanka, Darshana L. Weerawarne, Dilushan R. Jayasundara","doi":"10.1007/s11998-025-01080-0","DOIUrl":"10.1007/s11998-025-01080-0","url":null,"abstract":"","PeriodicalId":619,"journal":{"name":"Journal of Coatings Technology and Research","volume":"22 2","pages":"857 - 857"},"PeriodicalIF":2.3,"publicationDate":"2025-02-20","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"143622252","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}