Journal of Coatings Technology and Research最新文献

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Preparation and application of benzotriazole-loaded CaSiO3 in epoxy coatings with corrosion resistance 苯并三唑负载CaSiO3在耐腐蚀环氧涂料中的制备及应用
IF 3.4 4区 材料科学
Journal of Coatings Technology and Research Pub Date : 2026-06-08 DOI: 10.1007/s11998-025-01275-5
Phi Hung Dao, Thuy Chinh Nguyen, Dinh Hieu Vu, Anh Hiep Nguyen, Dang Hoang Nguyen, Hoang Thai
{"title":"Preparation and application of benzotriazole-loaded CaSiO3 in epoxy coatings with corrosion resistance","authors":"Phi Hung Dao,&nbsp;Thuy Chinh Nguyen,&nbsp;Dinh Hieu Vu,&nbsp;Anh Hiep Nguyen,&nbsp;Dang Hoang Nguyen,&nbsp;Hoang Thai","doi":"10.1007/s11998-025-01275-5","DOIUrl":"10.1007/s11998-025-01275-5","url":null,"abstract":"<div><p>This study presents a epoxy coating system using CaSiO<sub>3</sub> particles loaded with benzotriazole (BTA) as a corrosion inhibitor. BTA adsorption onto porous CaSiO<sub>3</sub> was confirmed by FTIR and XRD, indicating physical interaction without structural disruption. SEM revealed improved surface morphology and filler dispersion. BTA release from CaSiO<sub>3</sub>-BTA was pH-responsive, accelerating in acidic and alkaline media, and followed Korsmeyer–Peppas and Higuchi kinetic models. Mechanical testing showed that incorporating CaSiO<sub>3</sub> and CaSiO<sub>3</sub>-BTA enhanced hardness and abrasion resistance without affecting adhesion. Electrochemical impedance spectroscopy indicated that epoxy/CaSiO<sub>3</sub>-BTA coatings offered improved long-term corrosion protection in NaCl solution, owing to triggered BTA release and the formation of a protective film. These results demonstrate the potential of CaSiO<sub>3</sub>-BTA as a multifunctional additive that reinforces mechanical strength and enables self-healing corrosion resistance in epoxy coatings.</p></div>","PeriodicalId":619,"journal":{"name":"Journal of Coatings Technology and Research","volume":"23 5","pages":"2557 - 2571"},"PeriodicalIF":3.4,"publicationDate":"2026-06-08","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"148837548","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Adhesion mechanisms of waterborne epoxy coatings to steel substrates: A molecular-level investigation 水性环氧涂料与钢基体的粘附机理:分子水平的研究
IF 3.4 4区 材料科学
Journal of Coatings Technology and Research Pub Date : 2026-06-08 DOI: 10.1007/s11998-026-01293-x
Ali Moshkriz, Stefan Urth Nielsen, Søren Kiil
{"title":"Adhesion mechanisms of waterborne epoxy coatings to steel substrates: A molecular-level investigation","authors":"Ali Moshkriz,&nbsp;Stefan Urth Nielsen,&nbsp;Søren Kiil","doi":"10.1007/s11998-026-01293-x","DOIUrl":"10.1007/s11998-026-01293-x","url":null,"abstract":"<div><p>For optimization of adhesion strength and long-term performance, an understanding of the interfacial chemistry between waterborne epoxy coatings and steel substrates is crucial. While it is generally accepted that physical interactions, such as Van der Waals forces, contribute to adhesion, direct evidence for covalent Fe–O–C bonds in epoxy–steel systems have not been reported. In this study, a multi-technique approach was used to investigate molecular interactions at the coating–steel interface. Depth-resolved X-ray photoelectron spectroscopy (XPS) with line-scan analysis revealed a transition from organic oxygen groups (–C–O, –C = O) at the air–coating surface to inorganic signals of the steel substrate (Fe–O–C bond) at the buried interphase. Complementary attenuated total reflectance–Fourier transform infrared spectroscopy (ATR-FTIR) showed accumulation of unreacted epoxide groups, reduced β-hydroxyl formation, and suppressed epoxy–amine curing, together revealing an interphase with a significant degree of covalent Fe–O–C bonds. The results highlight the importance of interfacial chemistry in waterborne epoxy coatings and provide mechanistic insight for optimization of coating formulations and surface preparation strategies to enhance adhesion performance.</p></div>","PeriodicalId":619,"journal":{"name":"Journal of Coatings Technology and Research","volume":"23 5","pages":"2301 - 2318"},"PeriodicalIF":3.4,"publicationDate":"2026-06-08","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://link.springer.com/content/pdf/10.1007/s11998-026-01293-x.pdf","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"148837549","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"OA","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Acrylated tannic acid as bio-based adhesion promoter for EB-curable coatings 丙烯酸单宁酸作为eb固化涂料的生物基附着力促进剂
IF 3.4 4区 材料科学
Journal of Coatings Technology and Research Pub Date : 2026-06-05 DOI: 10.1007/s11998-026-01306-9
Francesco Bisio, Katia Sparnacci, Gianni Mirone, Stefania Pasquin, Alessandro Nicorelli
{"title":"Acrylated tannic acid as bio-based adhesion promoter for EB-curable coatings","authors":"Francesco Bisio,&nbsp;Katia Sparnacci,&nbsp;Gianni Mirone,&nbsp;Stefania Pasquin,&nbsp;Alessandro Nicorelli","doi":"10.1007/s11998-026-01306-9","DOIUrl":"10.1007/s11998-026-01306-9","url":null,"abstract":"<div><p>Electron beam (EB) curing has emerged as a highly attractive technology for advanced coating systems due to its solvent-free nature, energy efficiency, and ability to initiate polymerization without photoinitiators. This feature minimizes extractable species, a critical advantage for environmental sustainability and food safety. This study investigates partially acrylated tannic acid derivatives (TA–GMx) as bio-based adhesion promoters for EB-curable acrylic coatings in metal packaging applications. Tannic acid was functionalized with glycidyl methacrylate to tailor its polarity and introduce polymerizable groups capable of directly participating in EB-induced crosslinking. The resulting TA–GMx additives, synthesized with varying degrees of acrylation x, were incorporated into an industrial, partially bio-based formulation at different loadings (1.0 and 3.0 wt%). Their influence on network formation and interfacial performance was systematically evaluated. Mechanical and electrochemical tests on various metal substrates demonstrated that the incorporation of TA–GMx additives significantly improved adhesion, flexibility under deformation, and resistance to corrosion-induced delamination. Optimal performance was achieved at 1.0 wt% additive concentrations, where a balance between crosslink density and interfacial interactions was established. These findings highlight the synergy between EB technology and bio-based adhesion promoters as an effective strategy for developing high-performance, sustainable coatings for food metal packaging</p></div>","PeriodicalId":619,"journal":{"name":"Journal of Coatings Technology and Research","volume":"23 5","pages":"2329 - 2339"},"PeriodicalIF":3.4,"publicationDate":"2026-06-05","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://link.springer.com/content/pdf/10.1007/s11998-026-01306-9.pdf","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"148837618","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"OA","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Preparation of anticounterfeit films based on two-dimensional photonic crystals 基于二维光子晶体的防伪薄膜的制备
IF 3.4 4区 材料科学
Journal of Coatings Technology and Research Pub Date : 2026-06-05 DOI: 10.1007/s11998-026-01291-z
Qiang Zhao, Tongtong Cao, Yun Zhang, Xiaoyu Bai, Ming Li, Yuhua Cao
{"title":"Preparation of anticounterfeit films based on two-dimensional photonic crystals","authors":"Qiang Zhao,&nbsp;Tongtong Cao,&nbsp;Yun Zhang,&nbsp;Xiaoyu Bai,&nbsp;Ming Li,&nbsp;Yuhua Cao","doi":"10.1007/s11998-026-01291-z","DOIUrl":"10.1007/s11998-026-01291-z","url":null,"abstract":"<div><p>In this paper, the two-dimensional photonic crystals (2D PCs) composite films were prepared using poly (styrene/2-hydroxyethyl methacrylate) (PSH) microspheres by soap-free emulsion polymerization as 2D PCs’ building blocks and poly (2-hydroxyethyl methacrylate) (PHEMA) as the coating to obtain 2D PCs’ anticounterfeit films. PSH particles and PCs’ films were characterized by scanning electron microscopy, X-ray photoelectron spectroscopy, and micro-fiber optic spectrometer. The effects of the key parameters on the formation of 2D PCs’ films and 2D anticounterfeit PCs’ films were investigated. The results showed that the amount of St could be used to regulate the particle size of PSH microspheres, thereby adjusting the structural color of PCs. As the volume ratio of water to ethanol in the range of 10:1–1:3, corresponding to the surface tension of the mixed solvents between 48.3 and 25.1 mN/m, 2D PSH PCs’ films with angular dependence could be formed on the surface by gas-liquid interfacial self-assembly. 2D PSH PCs’ films prepared at a volume ratio of 1:1 (surface tension of 28.8 mN/m) showed the strongest reflection intensity. PSH/PHEMA PCs’ composite films were successfully obtained through in-situ photopolymerization of HEMA. As the voids of 2D PCs were filled up with the monomer HEMA, the bright structural color of PCs disappeared. The composite films were colorless and transparent due to almost no refractive index difference between PSH and PHEMA. When the PSH/PHEMA PCs’ film absorbed water, the color appeared because the refractive index of water/PHEMA was lower than that of PSH. The adsorption of water further made PHEMA swollen, which enlarged the lattice spacing in 2D PCs and resulted in a red-shift of the reflected light. The patterned PSH/PHEMA PCs’ films exhibited a reversible switch between transparency and iridescent colors in dry and wet states, and would be applied in the field of anti-counterfeiting.</p></div>","PeriodicalId":619,"journal":{"name":"Journal of Coatings Technology and Research","volume":"23 5","pages":"2763 - 2774"},"PeriodicalIF":3.4,"publicationDate":"2026-06-05","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"148837619","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Hydroxyalkyl acrylate end-capping strategy for bio-based waterborne polyurethane acrylates: enhancing crosslinking density and UV-curable coating performance 生物基水性聚氨酯丙烯酸酯的丙烯酸羟烷基酯封端策略:提高交联密度和光固化涂层性能
IF 3.4 4区 材料科学
Journal of Coatings Technology and Research Pub Date : 2026-06-03 DOI: 10.1007/s11998-026-01289-7
Ren Liu, Zecheng Lin, Deqiang Xie, Yongbo Ding, Liang Shen
{"title":"Hydroxyalkyl acrylate end-capping strategy for bio-based waterborne polyurethane acrylates: enhancing crosslinking density and UV-curable coating performance","authors":"Ren Liu,&nbsp;Zecheng Lin,&nbsp;Deqiang Xie,&nbsp;Yongbo Ding,&nbsp;Liang Shen","doi":"10.1007/s11998-026-01289-7","DOIUrl":"10.1007/s11998-026-01289-7","url":null,"abstract":"<div><p>In this study, five bio-based waterborne polyurethane acrylates (WPUAs) were synthesized using coconut oil fatty acid-derived alkyd polyol as the raw material. These WPUAs were end-capped with hydroxyethyl acrylate (HEA), hydroxyethyl methacrylate (HEMA), pentaerythritol triacrylate (PETA), as well as mixtures of PETA combined with either HEA or HEMA. The effect of hydroxyalkyl acrylate on dispersion stability, UV-curing behavior, and final coating performance was systematically investigated. FTIR confirmed complete NCO consumption and the successful incorporation of acrylate groups. The choice of end-capper significantly influenced particle size, storage stability, and crosslinking density of WPUAs. HEA provided good flexibility, while HEMA increased hardness due to its higher glass transition temperature. Incorporation of multifunctional PETA markedly enhanced crosslinking density, tensile strength, and chemical resistance, but excessive PETA led to embrittlement and reduced toughness. Importantly, the WPUA prepared with HEMA/PETA at a 1:1 molar ratio exhibited the most well-balanced performance, combining long thermal storage stability (&gt;30d), high tensile strength (26.1 MPa), elevated Young’s modulus (379.3 MPa), increased pencil hardness (2H), excellent adhesion (5B), good flexibility (1 mm), and exceptional ethanol scrub resistance (1559 cycles). These findings demonstrate that hydroxyalkyl acrylate end-capping is a powerful strategy for tailoring the structure-property relationship of bio-based WPUAs, offering valuable guidance for the design of sustainable, high-performance UV-curable coatings.</p></div>","PeriodicalId":619,"journal":{"name":"Journal of Coatings Technology and Research","volume":"23 5","pages":"2741 - 2752"},"PeriodicalIF":3.4,"publicationDate":"2026-06-03","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"148837615","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Hierarchical hybrid nano-structured flame retardant HP@ZIF for improving fire resistance and smoke suppression of intumescent fire-retardant coatings 分级杂化纳米结构阻燃剂HP@ZIF用于提高膨胀型阻燃涂料的耐火性和抑烟性
IF 3.4 4区 材料科学
Journal of Coatings Technology and Research Pub Date : 2026-06-03 DOI: 10.1007/s11998-026-01292-y
Qiuru Bao, Wen-Cong Xu, Yuyu Tian, Kai Zhang, Juying Wu
{"title":"Hierarchical hybrid nano-structured flame retardant HP@ZIF for improving fire resistance and smoke suppression of intumescent fire-retardant coatings","authors":"Qiuru Bao,&nbsp;Wen-Cong Xu,&nbsp;Yuyu Tian,&nbsp;Kai Zhang,&nbsp;Juying Wu","doi":"10.1007/s11998-026-01292-y","DOIUrl":"10.1007/s11998-026-01292-y","url":null,"abstract":"<div><p>In recent years, the development of intumescent fire-retardant coatings (IFRCs) has emerged as a critical strategy for enhancing fire safety in steel structures. However, traditional IFRCs exhibit limitations in meeting the demands of environmental protection, high-efficient fire resistance, and smoke suppression in construction applications. In this study, an organic-inorganic hybrid nanoflame retardant (HP@ZIF) was designed and synergistically applied with ammonium polyphosphate/triazine charring agent (APP/CFA) into an epoxy resin (EP) matrix, fabricating a high-performance IFRC. Back-surface temperature testing results suggested that HP@ZIF enhanced the thermal insulation of IFRC, which was also reflected in a significant increase in the char expansion ratio. The 20-min backside temperatures of the steel plate decreased from 576°C (uncoated steel) to 187°C (S3 coating), with the heat insulation efficiency of 67.5%, showing excellent fire retardant and thermal insulation performance of this EP coating. Additionally, total heat release (THR), total smoke release (TSR), and fire growth rate (FIGRA) of IFRC in the cone calorimeter test (CCT) were reduced by 70.1%, 72.0%, and 90.2%, respectively, demonstrating superior flame retardant and smoke suppression properties. Scanning electron microscopy (SEM) and Raman spectroscopy revealed that a dense, continuous char layer was formed after combustion, with enhanced mechanical integrity and thermal barrier functionality. More importantly, this EP coating maintained superior fire resistance after 7 d of water immersion. This study provides an economical and efficient solution for enhancing fire protection in modern buildings.</p></div>","PeriodicalId":619,"journal":{"name":"Journal of Coatings Technology and Research","volume":"23 5","pages":"2775 - 2789"},"PeriodicalIF":3.4,"publicationDate":"2026-06-03","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"148837614","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Review on engineering superhydrophobic surfaces: recent innovations and cross-sector applications 工程超疏水表面综述:最新的创新和跨部门应用
IF 3.4 4区 材料科学
Journal of Coatings Technology and Research Pub Date : 2026-05-27 DOI: 10.1007/s11998-025-01270-w
Vikrant Singh, Samandeep Kaur, N. Jeyaprakash, Karthik V. Shankar, Anuj Bansal, Anil Kumar Singla
{"title":"Review on engineering superhydrophobic surfaces: recent innovations and cross-sector applications","authors":"Vikrant Singh,&nbsp;Samandeep Kaur,&nbsp;N. Jeyaprakash,&nbsp;Karthik V. Shankar,&nbsp;Anuj Bansal,&nbsp;Anil Kumar Singla","doi":"10.1007/s11998-025-01270-w","DOIUrl":"10.1007/s11998-025-01270-w","url":null,"abstract":"<div><p>Superhydrophobic surfaces, inspired by naturally occurring systems such as lotus leaves and insect wings, have attracted significant attention due to their exceptional ability to repel water, resist contamination, and prevent icing. These surfaces derive their unique characteristics from hierarchical micro- and nanoscale textures combined with low-surface-energy chemistries. Advances in fabrication routes, characterization tools, and surface functionalization strategies have supported the transition of superhydrophobic coatings from laboratory prototypes to robust solutions for diverse engineering sectors. This review examines the fundamental wetting mechanisms governing superhydrophobicity and discusses emerging fabrication techniques and characterization approaches that enable precise control of surface properties. Major engineering applications are presented, including anti-icing and drag-reduction coatings in aerospace, corrosion-resistant and fouling-resistant surfaces in marine environments, and self-cleaning, antimicrobial, and low-adhesion coatings in biomedical devices, food processing equipment, and architectural materials. In addition to these widely explored domains, the review also outlines other relevant surface-related applications that broaden the technological scope of superhydrophobic coatings across industrial and functional systems. The potential of superhydrophobic materials in smart textiles, microfluidics, and environmental remediation is also highlighted. Key challenges, such as long-term mechanical durability, large-area scalability, and environmental sustainability, are discussed along with emerging trends including fluorine-free coatings, bio-inspired architectures, and multifunctional hybrid materials. Overall, this review provides a consolidated perspective and forward-looking framework for guiding the development of next-generation superhydrophobic materials and coatings.</p><h3>Graphical abstract</h3>\u0000<div><figure><div><div><picture><source><img></source></picture></div></div></figure></div></div>","PeriodicalId":619,"journal":{"name":"Journal of Coatings Technology and Research","volume":"23 4","pages":"1805 - 1832"},"PeriodicalIF":3.4,"publicationDate":"2026-05-27","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"148519502","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Synergistic optimization of waterborne epoxy coatings via rheology and curing tuning with graphene oxide modification 用氧化石墨烯改性对水性环氧涂料进行流变和固化调节的协同优化
IF 3.4 4区 材料科学
Journal of Coatings Technology and Research Pub Date : 2026-05-26 DOI: 10.1007/s11998-026-01282-0
Meng Wang, Yue Wu, Guo-jun Ji
{"title":"Synergistic optimization of waterborne epoxy coatings via rheology and curing tuning with graphene oxide modification","authors":"Meng Wang,&nbsp;Yue Wu,&nbsp;Guo-jun Ji","doi":"10.1007/s11998-026-01282-0","DOIUrl":"10.1007/s11998-026-01282-0","url":null,"abstract":"<div><p>Graphene oxide (GO)-modified waterborne epoxy resin (WEP) coatings have gained significant attention as a promising candidate for marine anti-corrosion applications, owing to their exceptional corrosion resistance, tunable rheological behavior, and environmental benefits. However, during preparation, GO/WEP coatings often develop defects such as micropores and cracks due to improper GO loading and curing-induced stress concentration, which considerably compromise their protective performance and limit their large-scale implementation. In this study, a \"rheology-curing synergistic regulation\" strategy is proposed, focusing on the optimization of GO content and curing procedures. Using steady-state rheological measurements and electrochemical corrosion assessments, the optimal GO formulation was identified. Subsequently, differential scanning calorimetry (DSC) and dynamic rheological analysis were employed to design a stepwise curing protocol that effectively mitigates interfacial stress concentration, enabling the controlled fabrication of high-performance anti-corrosion coatings. The optimized coating demonstrated an order-of-magnitude increase in impedance modulus and a corrosion current density (<i>I</i><sub>corr</sub>) as low as 9.68 × 10<sup>−10</sup> A/cm<sup>2</sup>. This work provides valuable insights into the coordinated regulation of processing and performance.</p></div>","PeriodicalId":619,"journal":{"name":"Journal of Coatings Technology and Research","volume":"23 5","pages":"2653 - 2663"},"PeriodicalIF":3.4,"publicationDate":"2026-05-26","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"148838105","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Effect of acetone as a cosolvent on the properties of waterborne silicone antifouling coating 丙酮作为助溶剂对水性有机硅防污涂料性能的影响
IF 3.4 4区 材料科学
Journal of Coatings Technology and Research Pub Date : 2026-05-26 DOI: 10.1007/s11998-026-01277-x
Yanguo Zhang, Zhanping Zhang, Ziyang Liu, Yuhong Qi
{"title":"Effect of acetone as a cosolvent on the properties of waterborne silicone antifouling coating","authors":"Yanguo Zhang,&nbsp;Zhanping Zhang,&nbsp;Ziyang Liu,&nbsp;Yuhong Qi","doi":"10.1007/s11998-026-01277-x","DOIUrl":"10.1007/s11998-026-01277-x","url":null,"abstract":"<div><p>Waterborne silicone coatings were prepared in this paper by mechanically blending different mass ratios of emulsions to acetone, using <i>γ</i>-methacryloxypropyltrimethoxysilane and dibutyltin dilaurate as the curing agent and catalyst, respectively. The properties of the coatings were examined by laser confocal microscopy, contact angle and surface energy test, tensile test, crosslinking density test, marine bacterial attachment test, and <i>Navicula Tenera</i> attachment test to explore the impact of acetone as a cosolvent on the properties of waterborne silicone antifouling coatings. The results show that the surface of the coating with acetone added formed a special microstructure, which increased the surface roughness and improved the antifouling performance of the coating. Specifically, the surface roughness of the coating increases and the surface energy decreases from 20.48 to 9.98 mJ/m<sup>2</sup> as the acetone content decreases. The bacterial adhesion gradually decreases, and the removal rates of bacteria and <i>Navicula Tenera</i> increase by 52.11 and 46.72%, respectively. In addition, acetone reduces the crosslinking density of the coating, improving its mechanical properties. The addition of small amounts of acetone to silicone emulsions is beneficial for improving the mechanical properties, antifouling, and self-cleaning abilities of waterborne silicone coatings.</p></div>","PeriodicalId":619,"journal":{"name":"Journal of Coatings Technology and Research","volume":"23 5","pages":"2587 - 2598"},"PeriodicalIF":3.4,"publicationDate":"2026-05-26","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"148838104","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Interpenetrating polymer networks (IPNs)-based hybrid organic–inorganic flame-retardant wood coating 互穿聚合物网络(IPNs)基杂化有机-无机阻燃木器涂料
IF 3.4 4区 材料科学
Journal of Coatings Technology and Research Pub Date : 2026-05-22 DOI: 10.1007/s11998-025-01272-8
Malav R. Sanghvi, Karan Chugh, S. T. Mhaske
{"title":"Interpenetrating polymer networks (IPNs)-based hybrid organic–inorganic flame-retardant wood coating","authors":"Malav R. Sanghvi,&nbsp;Karan Chugh,&nbsp;S. T. Mhaske","doi":"10.1007/s11998-025-01272-8","DOIUrl":"10.1007/s11998-025-01272-8","url":null,"abstract":"<div><p>Wood, a widely used substrate, is inherently flammable, necessitating flame-retardant (FR) coatings for safety. Traditionally, these coatings are synthesized by additive or reactive routes. In the current work, a novel approach of using interpenetrating polymer networks (IPNs) was pursued. The hybrid organic–inorganic IPN combines the film-forming properties of polyvinyl alcohol (PVA) with the thermal stability and flame retardancy of inorganic constituents (silicon, nitrogen and boron) polymerized by the solgel technique. PVA was crosslinked by glutaraldehyde in presence of sol to form the IPN causing the FR units to get intertwined in the binder preventing their leaching, a drawback associated with additive type FR coatings. The coatings were characterized using FTIR, NMR, TGA, DSC, and SEM, and their flame-retardant properties evaluated through UL-94 and limiting oxygen index (LOI) tests. Results demonstrated significant improvements in flame retardancy, with LOI values exceeding 30% and char yields up to 30%. The presence of boric acid also imparted antimicrobial property. Additionally, the coatings exhibited significant adhesion, hardness and resistance to solvents and stains. This study presents an alternative to the conventional halogenated or phosphorus-based FR compounds, which pose environmental and health risks, with potential applications in construction, furniture, and other industries requiring fire-safe materials.</p></div>","PeriodicalId":619,"journal":{"name":"Journal of Coatings Technology and Research","volume":"23 5","pages":"2507 - 2534"},"PeriodicalIF":3.4,"publicationDate":"2026-05-22","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"148837768","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
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