Journal of Coatings Technology and Research最新文献

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A new approach to detect and grade the chipping defect of automotive coatings using a machine vision system 提出了一种利用机器视觉系统检测和评定汽车涂层剥落缺陷的新方法
IF 3.4 4区 材料科学
Journal of Coatings Technology and Research Pub Date : 2026-05-19 DOI: 10.1007/s11998-026-01294-w
Kazhal Afshargoli, Saeideh Gorji Kandi, Mohsen Mohseni, Hossein Yahyaei
{"title":"A new approach to detect and grade the chipping defect of automotive coatings using a machine vision system","authors":"Kazhal Afshargoli,&nbsp;Saeideh Gorji Kandi,&nbsp;Mohsen Mohseni,&nbsp;Hossein Yahyaei","doi":"10.1007/s11998-026-01294-w","DOIUrl":"10.1007/s11998-026-01294-w","url":null,"abstract":"<div><p>Chipping is a common surface defect in automotive coatings, caused by the high-velocity impact of tiny stones and gravels that leads to localized coating detachment and loss. Conventional methods for evaluating chipping resistance typically rely on visual inspection according to special standards, which is subjective and prone to inconsistency. This study aims to develop an automated machine vision and image processing method for the objective detection and grading this effect. Coated panels were prepared and tested in accordance with the PSA D241312-H (Peugeot) standard to report varying degrees of chipping. High-resolution images were acquired under uniform lighting. An image processing pipeline combining contrast enhancement, thresholding, and contour-based analysis was implemented to identify and classify damaged areas based on the chip size and chip distribution. The results demonstrated that the proposed system could accurately detect even subtle or complex defects that were often challenging for human observers, while providing consistent and reproducible grading. In contrast, visual evaluations by four experienced inspectors showed substantial variability, as reflected by large standard deviations across samples. Despite this disagreement, the system achieved a strong correlation with the inspectors’ mean ratings (R = 0.86), highlighting both its accuracy and its ability to provide a more stable reference. Moreover, the automated approach reduced inspection time by approximately a factor of seven compared to manual evaluation.</p></div>","PeriodicalId":619,"journal":{"name":"Journal of Coatings Technology and Research","volume":"23 5","pages":"2791 - 2803"},"PeriodicalIF":3.4,"publicationDate":"2026-05-19","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"148837485","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Recent advances in covalent organic frameworks (COFs) as smart nanocontainers for corrosion inhibitors in anticorrosive coatings: design strategies, responsive mechanisms, and long-term anticorrosion performance 共价有机框架(COFs)作为防腐蚀涂层中缓蚀剂的智能纳米容器的最新进展:设计策略、响应机制和长期防腐性能
IF 3.4 4区 材料科学
Journal of Coatings Technology and Research Pub Date : 2026-05-19 DOI: 10.1007/s11998-026-01279-9
Zi-Chen Wang, Feng-Jun Zhang
{"title":"Recent advances in covalent organic frameworks (COFs) as smart nanocontainers for corrosion inhibitors in anticorrosive coatings: design strategies, responsive mechanisms, and long-term anticorrosion performance","authors":"Zi-Chen Wang,&nbsp;Feng-Jun Zhang","doi":"10.1007/s11998-026-01279-9","DOIUrl":"10.1007/s11998-026-01279-9","url":null,"abstract":"<div><p>Metal corrosion has always been a challenging issue in marine, industrial, and atmospheric environments, leading to severe material degradation, economic losses, and safety hazards. Traditional protective coatings mainly rely on passive barrier effects, such as blocking the penetration of electrolytes and oxygen, but once micro-defects and cracks occur, their long-term protective effect will be limited. To overcome these drawbacks, active anticorrosion strategies using corrosion inhibitors have gained increasing attention. However, traditional corrosion inhibitor carriers (such as LDH, nanocapsules, graphene oxide, MXenes, and molybdenum disulfide) have problems, such as premature release of inhibitors, poor interfacial compatibility, or limited long-term stability. Covalent organic frameworks (COFs) are novel crystalline porous polymers featuring ordered channels, tunable functional groups, and excellent chemical stability, making them promising for intelligent nano-containers as corrosion inhibitors. This review provides a comprehensive overview of the latest developments in anti-corrosion coatings utilizing COFs, mainly on different framework types - imine-linked, triazine-linked, and β-ketoenamine-linked frameworks. Among them, the β-ketoenamine covalent organic framework represented by TpPa-1 exhibits excellent structural stability and inhibitor loading capacity. We discuss the design strategies, release mechanisms, and the synergistic effect of COFs in combining passive barrier protection with active inhibitor release. Finally, we summarize the current challenges and future development prospects to stimulate the research and development of next-generation COF-based anti-corrosion coatings, making them more responsive and durable.</p><h3>Graphical abstract</h3><div><figure><div><div><picture><source><img></source></picture></div></div></figure></div></div>","PeriodicalId":619,"journal":{"name":"Journal of Coatings Technology and Research","volume":"23 4","pages":"1869 - 1896"},"PeriodicalIF":3.4,"publicationDate":"2026-05-19","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"148519449","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
A robust antisoiling coating based on dendritic-spherical silica nanocomposites synthesized via a PF-127-directed method 一种基于枝状球形二氧化硅纳米复合材料的防污涂层
IF 3.4 4区 材料科学
Journal of Coatings Technology and Research Pub Date : 2026-05-18 DOI: 10.1007/s11998-025-01276-4
Yadav Narendra Kumar Rajbahadur, Sushant Negi, Simanchal Kar
{"title":"A robust antisoiling coating based on dendritic-spherical silica nanocomposites synthesized via a PF-127-directed method","authors":"Yadav Narendra Kumar Rajbahadur,&nbsp;Sushant Negi,&nbsp;Simanchal Kar","doi":"10.1007/s11998-025-01276-4","DOIUrl":"10.1007/s11998-025-01276-4","url":null,"abstract":"<div><p>Super-hydrophilic coatings offer a highly effective strategy for self-cleaning, as they cause water to spread into a thin film that efficiently washes away surface contaminants. This study reports the development and assessment of a multifunctional super-hydrophilic, antireflective, and self-cleaning thin-film composite coating designed to maximize solar energy generation and mitigate the challenges associated with glass panels on high-rise buildings. The coating is based on a combination of dendritic silica nanoparticles (DSNs) and spherical silica nanoparticles (SSNs), with the DSNs synthesized using Pluronic F-127 as a structure-directing agent. Morphological analysis revealed a uniform, crack-free coating with well-distributed nanopores. The optimized coating exhibited a water contact angle as low as ~ 3° and a high optical transmittance of ~ 96%. In addition, the coating demonstrated good antifogging properties and facilitated the effective removal of surface contaminants. The film showed robust durability, maintaining a WCA of 24° and 92.1% transmittance after four abrasion cycles in sand impact test. Environmental durability was conducted through accelerated UV exposure for 16 days, as per IEC 61215 standards. The results revealed minimal degradation, with the WCA remaining below 10° and transmittance maintaining greater than 94%. The coating also possesses strong mechanical robustness with a pencil hardness of 6H. Crucially, application of the SSN/DSN coating increased solar cell efficiency by 2.53%, underscoring its significant potential for improving renewable energy systems.</p></div>","PeriodicalId":619,"journal":{"name":"Journal of Coatings Technology and Research","volume":"23 5","pages":"2573 - 2586"},"PeriodicalIF":3.4,"publicationDate":"2026-05-18","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"148837553","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
An insight into green corrosion inhibitors: solution towards sustainable corrosion control 绿色缓蚀剂的洞察:可持续腐蚀控制的解决方案
IF 3.4 4区 材料科学
Journal of Coatings Technology and Research Pub Date : 2026-05-18 DOI: 10.1007/s11998-025-01251-z
Deepanshu Patel, Kuravappullam Vedaiyan Radha
{"title":"An insight into green corrosion inhibitors: solution towards sustainable corrosion control","authors":"Deepanshu Patel,&nbsp;Kuravappullam Vedaiyan Radha","doi":"10.1007/s11998-025-01251-z","DOIUrl":"10.1007/s11998-025-01251-z","url":null,"abstract":"<div><p>Corrosion is an inevitable physicochemical phenomenon that, although it cannot be eliminated, can be significantly retarded through appropriate mitigation strategies. From an industrial standpoint, corrosion represents a substantial economic burden, contributing no direct value to production while imposing additional maintenance, operational, and replacement costs. Conventional corrosion prevention and protection methods are often expensive and frequently associated with environmental hazards, necessitating the exploration of more sustainable alternatives. The ideal corrosion mitigation approach should be cost-effective, operationally simple, technically feasible, and, most importantly, environmentally benign. In this context, green corrosion inhibitors have emerged as a promising class of materials, generally offering an effective, low-cost, and eco-friendly solution with minimal environmental footprint. Their rising industrial relevance has spurred extensive research activity focused on their development, optimization, and application. Green corrosion inhibitors encompass a broad spectrum of substances, both traditional and recently developed. Conventional green inhibitors include plant extracts, essential oils, biomolecules, expired pharmaceuticals, rare-earth metal complexes, ionic liquids, and amino acids along with their derivatives. In contrast, modern innovations in this domain have led to the development of advanced green inhibitors such as volatile corrosion inhibitors, nanocomposite-based systems, metal–organic frameworks (MOFs), deep eutectic solvents (DESs) and MXene. These novel materials generally exhibit enhanced corrosion inhibition efficiency and align with principles of green chemistry and sustainable engineering. This chapter provides a comprehensive overview of various categories of green corrosion inhibitors, highlighting key examples and their mechanisms of action. Emphasis is placed on both well-established and emerging systems, underscoring their potential to revolutionize corrosion mitigation in an environmentally sustainable manner.</p></div>","PeriodicalId":619,"journal":{"name":"Journal of Coatings Technology and Research","volume":"23 4","pages":"1751 - 1792"},"PeriodicalIF":3.4,"publicationDate":"2026-05-18","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"148519501","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Synergistic effect of GO nanosheets and ZrO2 nanoparticles in epoxy coatings for improved electrochemical corrosion protection of stainless steel in saline solution 氧化石墨烯纳米片和ZrO2纳米颗粒在环氧涂层中的协同作用对不锈钢在盐水溶液中的电化学腐蚀防护效果的改善
IF 3.4 4区 材料科学
Journal of Coatings Technology and Research Pub Date : 2026-05-13 DOI: 10.1007/s11998-026-01278-w
Khalid Alshaybani, Khaled M. Chahrour, Hayrettin Ahlatçı, Ahmed Abdel Nazeer
{"title":"Synergistic effect of GO nanosheets and ZrO2 nanoparticles in epoxy coatings for improved electrochemical corrosion protection of stainless steel in saline solution","authors":"Khalid Alshaybani,&nbsp;Khaled M. Chahrour,&nbsp;Hayrettin Ahlatçı,&nbsp;Ahmed Abdel Nazeer","doi":"10.1007/s11998-026-01278-w","DOIUrl":"10.1007/s11998-026-01278-w","url":null,"abstract":"<div><p>This study investigates the synergistic effect of incorporating graphene oxide (GO) nanosheets and ZrO<sub>2</sub> nanoparticles into an epoxy coating to enhance corrosion protection and extend the service life of stainless steel in saline environments. The micromorphological, structural, thermal, hydrophobic, and mechanical properties of epoxy, ZrO<sub>2</sub>/epoxy, and GO/ZrO<sub>2</sub>/epoxy coatings were systematically investigated using FESEM, FTIR, XRD, thermogravimetric analysis, water contact angle measurements, and microhardness testing. Corrosion resistance was evaluated using potentiodynamic polarization (PDP) and electrochemical impedance spectroscopy (EIS). Compared with pure epoxy and ZrO<sub>2</sub>/epoxy coatings, the GO/ZrO<sub>2</sub>/epoxy nanocomposite exhibited superior corrosion protection, achieving a corrosion current density of 16.8 nA/cm<sup>2</sup>, a corrosion rate of 0.001 mpy, and a charge transfer resistance of 923000 Ω. The enhanced performance is attributed to the dual barrier effect of GO nanosheets, which provide impermeability and mechanical reinforcement, combined with reduced coating porosity and blocked corrosive pathways induced by ZrO<sub>2</sub> nanoparticles. Long-term corrosion behavior was evaluated after 72 h of immersion in saline solution. The hybrid coating maintained a low corrosion current density of 24.7 nA/cm<sup>2</sup>, corrosion rate of 0.0013 mpy, and charge transfer resistance of 913200 Ω, demonstrating excellent durability and confirming the long-term protective capability of the GO/ZrO<sub>2</sub>/epoxy nanocomposite coating system.</p></div>","PeriodicalId":619,"journal":{"name":"Journal of Coatings Technology and Research","volume":"23 5","pages":"2599 - 2615"},"PeriodicalIF":3.4,"publicationDate":"2026-05-13","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://link.springer.com/content/pdf/10.1007/s11998-026-01278-w.pdf","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"148837825","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"OA","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Optimal formulation and plasma-assisted deposition of a fluorine-free coating for highly durable superhydrophobic paper 高耐用超疏水纸无氟涂层的最佳配方和等离子辅助沉积
IF 3.4 4区 材料科学
Journal of Coatings Technology and Research Pub Date : 2026-05-13 DOI: 10.1007/s11998-025-01274-6
Paveena Laokul, Punakit Tipparak, Porntipa Phuengyen, Nattakan Kanjana, Kattiya Srakaew, Artit Chingsungnoen, Phitsanu Poolcharuansin
{"title":"Optimal formulation and plasma-assisted deposition of a fluorine-free coating for highly durable superhydrophobic paper","authors":"Paveena Laokul,&nbsp;Punakit Tipparak,&nbsp;Porntipa Phuengyen,&nbsp;Nattakan Kanjana,&nbsp;Kattiya Srakaew,&nbsp;Artit Chingsungnoen,&nbsp;Phitsanu Poolcharuansin","doi":"10.1007/s11998-025-01274-6","DOIUrl":"10.1007/s11998-025-01274-6","url":null,"abstract":"<div><p>The development of paper materials with advanced functionalities offers new opportunities for applications beyond traditional uses. In this study, a fluorine-free and environmentally friendly superhydrophobic coating was fabricated via a simple spray coating method. VTMS-modified SiO<sub>2</sub> nanoparticles (VTMS/SiO<sub>2</sub>) were applied to atmospheric plasma-treated paper using polydimethylsiloxane (PDMS) and KH550 as crosslinking and coupling agents, respectively. The chemical functionalities of the surface and the morphology of the coated samples were characterized by FTIR and SEM. Among the different formulations, the optimum condition, i.e., 15 s plasma treatment followed by coating with 7.5VTMS/SiO<sub>2</sub>/0.75KH550, resulted in excellent superhydrophobicity with a water contact angle (WCA) of 160.4 ± 0.5° and a sliding angle (WSA) of 4.5 ± 1.1°. In addition, the coating exhibited excellent mechanical resistance and retained its properties after 20 Taber abrasion cycles. Chemical stability under acidic and alkaline conditions was also maintained. Compared to coatings without plasma treatment, the plasma-enhanced surface exhibited significantly improved adhesion and robustness. These results illustrate a scalable, fluorine-free strategy for producing durable, multifunctional paper surfaces suitable for advanced packaging and protective applications.</p></div>","PeriodicalId":619,"journal":{"name":"Journal of Coatings Technology and Research","volume":"23 5","pages":"2545 - 2555"},"PeriodicalIF":3.4,"publicationDate":"2026-05-13","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"148837480","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Polymer particles as dispersants for inorganic pigments in waterborne paint formulations 水性涂料配方中无机颜料的聚合物分散剂
IF 3.4 4区 材料科学
Journal of Coatings Technology and Research Pub Date : 2026-05-13 DOI: 10.1007/s11998-025-01261-x
Sara Beldarrain, Vincent Vreeken, Jose Ramon Leiza, Edurne González
{"title":"Polymer particles as dispersants for inorganic pigments in waterborne paint formulations","authors":"Sara Beldarrain,&nbsp;Vincent Vreeken,&nbsp;Jose Ramon Leiza,&nbsp;Edurne González","doi":"10.1007/s11998-025-01261-x","DOIUrl":"10.1007/s11998-025-01261-x","url":null,"abstract":"<div><p>The effective dispersion of titanium dioxide (TiO<sub>2</sub>) in waterborne coatings is essential for optimizing optical properties such as opacity. Traditional dispersing agents often fail to fully stabilize inorganic pigment particles and may increase the water sensitivity of the final film due to their hydrophilic nature. This study explores the use of functionalized polymer particles as an alternative to conventional dispersants. Polymer particles of varying size and functionalities were evaluated to assess their influence on TiO<sub>2</sub> disaggregation and dispersion. This effect was directly analyzed in a conventional waterborne coating formulation. The polymer particles used as dispersants also form the polymer matrix during film formation. Results indicate that a functionalization of the particles is needed to enhance pigment dispersion when no conventional pigment dispersant is used. Interestingly, the obtained optical performance of the coating depends on the binder composition. Regardless of the functionality of the polymer particles used, the resulting films exhibited reduced water sensitivity.</p></div>","PeriodicalId":619,"journal":{"name":"Journal of Coatings Technology and Research","volume":"23 5","pages":"2385 - 2393"},"PeriodicalIF":3.4,"publicationDate":"2026-05-13","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://link.springer.com/content/pdf/10.1007/s11998-025-01261-x.pdf","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"148837826","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"OA","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Multifunctional integration of renewable raw material-based waterborne polyurethanes: Schiff base dynamic bond-mediated self-healing and UV resistance enhancement mechanisms 基于可再生原料的水性聚氨酯的多功能集成:希夫碱动态键介导的自愈和抗紫外线增强机制
IF 3.4 4区 材料科学
Journal of Coatings Technology and Research Pub Date : 2026-05-12 DOI: 10.1007/s11998-026-01302-z
Ziqing Jiang, Pingbo Zhang, Mingming Fan, Pingping Jiang, Shijun Chen
{"title":"Multifunctional integration of renewable raw material-based waterborne polyurethanes: Schiff base dynamic bond-mediated self-healing and UV resistance enhancement mechanisms","authors":"Ziqing Jiang,&nbsp;Pingbo Zhang,&nbsp;Mingming Fan,&nbsp;Pingping Jiang,&nbsp;Shijun Chen","doi":"10.1007/s11998-026-01302-z","DOIUrl":"10.1007/s11998-026-01302-z","url":null,"abstract":"<div><p>Biomass-derived vanillin and ethylenediamine were used as raw materials to synthesize Schiff base chain extenders, which were then incorporated into waterborne polyurethane (WPU) systems to fabricate a series of multifunctional composite films (VWPUs) with tunable Schiff base contents. Research results indicate that all VWPU films exhibit excellent mechanical properties, self-healing capabilities, significant UV resistance, and moderate thermal stability. Among them, the VWPU-2 film demonstrated the best repair effect. Benefiting from the dynamic reversible nature of the Schiff base bond (C=N), the material achieved noticeable healing of surface scratches after 2 h of static storage at 60 °C. After 6 h of repair, the mechanical property self-healing efficiency reached 93.5%. Furthermore, the aromatic ring and phenolic hydroxyl structure in vanillin molecules enhance the polyurethane film's absorption capacity in the 280–400 nm wavelength range, resulting in reduced UV transmittance. This study provides a novel and sustainable design approach for constructing multifunctional water-based polyurethanes with both self-healing and UV resistance, where Schiff base dynamic bonds and vanillin-derived functional groups synergistically realize self-healing and UV resistance, opening new avenues for the development of high-performance, eco-friendly polymer materials.</p><h3>Graphical Abstract</h3>\u0000<div><figure><div><div><picture><source><img></source></picture></div></div></figure></div></div>","PeriodicalId":619,"journal":{"name":"Journal of Coatings Technology and Research","volume":"23 4","pages":"2283 - 2297"},"PeriodicalIF":3.4,"publicationDate":"2026-05-12","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"148519477","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Development of POA/formaldehyde/SiO2 and POA/cinnamaldehyde/SiO2 composite-based epoxy anticorrosion coatings POA/甲醛/SiO2和POA/肉桂醛/SiO2复合基环氧防腐涂料的研制
IF 3.4 4区 材料科学
Journal of Coatings Technology and Research Pub Date : 2026-05-11 DOI: 10.1007/s11998-025-01254-w
Aakanksha Mukesh Mhatre, Aarti P. More
{"title":"Development of POA/formaldehyde/SiO2 and POA/cinnamaldehyde/SiO2 composite-based epoxy anticorrosion coatings","authors":"Aakanksha Mukesh Mhatre,&nbsp;Aarti P. More","doi":"10.1007/s11998-025-01254-w","DOIUrl":"10.1007/s11998-025-01254-w","url":null,"abstract":"<div><p>Corrosion protection of metal surfaces demands durable, efficient, and environmentally friendly solutions. This study presents the synthesis and evaluation of a novel conductive polymer composite, poly(o-anisidine)/cinnamaldehyde/silicon dioxide (POA/CIN/SiO<sub>2</sub>), in comparison to its formaldehyde-based counterpart (POA/FA/SiO<sub>2</sub>). The composite was synthesized via an in situ schiff base reaction and characterized using FTIR, SEM, EDX, and XRD. Mechanical properties, including hardness, scratch and impact resistance, along with chemical stability, hydrophobicity, and corrosion resistance, were assessed. The POA/CIN/SiO<sub>2</sub> (5 wt%) formulation demonstrated the best overall performance, achieving high pencil hardness (6H), excellent scratch (2.8 kg) and impact resistance (74.8 kg-cm), superior chemical resistance in acid, alkali, and solvents, and the highest contact angle (74.64°), indicating hydrophobicity. Salt spray tests showed minimal corrosion, while electrochemical impedance spectroscopy (EIS) and potentiodynamic polarization revealed significantly improved barrier properties and reduced corrosion rates. The synergistic effect of POA’s redox activity, CIN’s eco-friendly inhibition via imine crosslinking, and SiO<sub>2</sub>’s barrier reinforcement makes this composite a promising candidate for sustainable and high-performance corrosion protection.</p><h3>Graphical abstract</h3>\u0000<div><figure><div><div><picture><source><img></source></picture></div></div></figure></div></div>","PeriodicalId":619,"journal":{"name":"Journal of Coatings Technology and Research","volume":"23 4","pages":"2199 - 2218"},"PeriodicalIF":3.4,"publicationDate":"2026-05-11","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"148519470","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
MXene-polymer nanocomposites: a novel frontier in advanced corrosion-resistant coatings mxene -聚合物纳米复合材料:先进耐腐蚀涂层的新前沿
IF 3.4 4区 材料科学
Journal of Coatings Technology and Research Pub Date : 2026-05-08 DOI: 10.1007/s11998-025-01271-9
R. Priyadharshini, S. P. Vinodhini, JR Xavier
{"title":"MXene-polymer nanocomposites: a novel frontier in advanced corrosion-resistant coatings","authors":"R. Priyadharshini,&nbsp;S. P. Vinodhini,&nbsp;JR Xavier","doi":"10.1007/s11998-025-01271-9","DOIUrl":"10.1007/s11998-025-01271-9","url":null,"abstract":"<div><p>MXene–polymer nanocomposites have emerged as a promising new frontier in advanced corrosion-resistant coatings, driven by the unique properties of MXenes—two-dimensional transition-metal carbides and nitrides with high conductivity, hydrophilicity, and tunable surface terminations. These characteristics promote robust interfacial interactions with polymer matrices, aiding in uniform dispersion and augmenting mechanical reinforcement. Recent progress in MXene synthesis, including HF-based, molten-salt, electrochemical, and fluoride-free methods, has expanded material accessibility and improved structural stability. When incorporated into polymer coatings, MXenes create compact, tortuous pathways that impede the ingress of corrosive species, while polymers contribute flexibility, adhesion, and film-forming capability. This synergy results in improved barrier performance, mechanical robustness, and resistance to wear, fatigue, and thermal degradation. Electrochemical impedance spectroscopy (EIS), polarization testing, and salt-spray evaluations consistently show that these materials are better at preventing corrosion than traditional graphene- and CNT-based nanocomposites. Beyond corrosion resistance, MXene–polymer systems offer multifunctional advantages, including electrical conductivity, EMI shielding, flame retardancy, and antibacterial activity. However, challenges remain related to oxidation susceptibility, interfacial compatibility, environmental concerns, and scalable production. Ongoing developments in surface modification, hybrid architectures, and intelligent self-healing designs are expected to overcome these limitations, positioning MXene–polymer nanocomposites as strong candidates for next-generation high-performance protective coatings.</p></div>","PeriodicalId":619,"journal":{"name":"Journal of Coatings Technology and Research","volume":"23 4","pages":"1833 - 1868"},"PeriodicalIF":3.4,"publicationDate":"2026-05-08","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"148519499","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
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