合成具有优异耐腐蚀耐磨性能的超强疏水性EP/F-CNTs/SiO2复合涂层

IF 2.8 4区 材料科学 Q2 CHEMISTRY, APPLIED
Jie Zhou, Jingying Su, Fenghua Su, Tianxin Zhao, Ji Li, Pengfei Yang, Qingyu Zhang
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引用次数: 0

摘要

目前,超疏水涂料在自清洁、减阻、防腐等方面有着广泛的应用。然而,它们较差的机械稳定性对涂层的使用寿命和有效性产生了重大影响。为了解决这一挑战,本研究引入了具有高强度和强附着力的环氧树脂(EP)作为树脂基体。该复合涂层通过简单的喷涂技术合成,采用改性碳纳米管(F-CNTs)和疏水性气相纳米二氧化硅(SiO2)作为填料。坚固的EP/F-CNTs/SiO2超疏水涂层表现出优异的抗摩擦能力和超粘接强度,这是由于EP中间层显著增强了涂层与不锈钢基体之间的粘接强度,粘接等级为1级。Tafel和EIS测试结果表明,该涂层的缓蚀效率高达99.75%。F-CNTs具有优异的电子转移能力,因此涂层具有优异的耐腐蚀性。此外,该涂层还能抵抗强酸和强碱的腐蚀。相信这种简单、低成本的方法为在各种金属材料上制造坚固、超防腐的超疏水表面提供了一种有效的策略和有前景的工业应用。
本文章由计算机程序翻译,如有差异,请以英文原文为准。
Synthesis of robust superhydrophobic EP/F-CNTs/SiO2 composite coating with excellent anti-corrosion and wear-resistant property

At present, superhydrophobic coatings have a wide range of applications in self-cleaning, drag reduction, and corrosion protection. However, their poor mechanical stability has a significant impact on the service life and effectiveness of the coatings. In addressing this challenge, this study introduced epoxy resin (EP) with high strength and strong adhesion as the resin matrix. The composite coating, synthesized through a straightforward spraying technique, incorporates modified carbon nanotubes (F-CNTs) and hydrophobic fumed nanosilica (SiO2) as fillers. The robust EP/F-CNTs/SiO2 superhydrophobic coating exhibited excellent anti-rubbing ability and superadhesion strength, which was attributed to the EP intermediate layer significantly enhancing the adhesion strength between the coating and the stainless steel substrate with a remarkable adhesion grade of one. Tafel and EIS test results revealed a corrosion inhibition efficiency of up to 99.75% for the coating. The exceptional corrosion resistance of the coating is attributed to the outstanding electron transfer capability of F-CNTs. In addition, the coating could resist corrosion from strong acids and bases. It is believed that the facile and low-cost method offers an effective strategy and promising industrial applications for fabricating robust and super anti-corrosion superhydrophobic surfaces on various metallic materials.

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来源期刊
Journal of Coatings Technology and Research
Journal of Coatings Technology and Research 工程技术-材料科学:膜
CiteScore
4.30
自引率
8.70%
发文量
130
审稿时长
2.5 months
期刊介绍: Journal of Coatings Technology and Research (JCTR) is a forum for the exchange of research, experience, knowledge and ideas among those with a professional interest in the science, technology and manufacture of functional, protective and decorative coatings including paints, inks and related coatings and their raw materials, and similar topics.
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