Carbon Letters最新文献

Toward high energy and durable anodes: critical review on Li4Ti5O12–MXene composites 迈向高能耐用阳极：Li4Ti5O12-MXene复合材料综述

IF 5.5 3区材料科学

Carbon Letters Pub Date : 2025-03-18 DOI: 10.1007/s42823-025-00888-5

Fereshteh Abbasi, Farshad Boorboor Ajdari, Mohammadreza Mansournia, Parnaz Asghari, Ali Molaei Aghdam

{"title":"Toward high energy and durable anodes: critical review on Li4Ti5O12–MXene composites","authors":"Fereshteh Abbasi, Farshad Boorboor Ajdari, Mohammadreza Mansournia, Parnaz Asghari, Ali Molaei Aghdam","doi":"10.1007/s42823-025-00888-5","DOIUrl":"10.1007/s42823-025-00888-5","url":null,"abstract":"<div><p>LTO is a commercial anode material that contributes to delivered energy and cycle stability. With affordability and high energy density, graphite faces limited cycle time and inferior stability. Here, we discussed the LTO challenges and compared the Ti-based anode from the original structure to the LTO-MXene composites, which are promising alternative anodes. Spinel lithium titanate (LTO) possesses high working voltage, stability, safety, and negligible volume change, while it suffers from low electronic conductivity that limits rate performance at large current densities. 2D Mxenes have recently drawn attention to various applications due to high conductivity, large surface area, flexibility, and polar surface benefits. We critically reviewed the synthesis approaches, morphology views, and electrochemical behavior of LTO-MXene as new anode materials in lithium-ion batteries (LIBs). There are few reports on LTO-MXene anodes in LIBs. They provide a synergistic action of LTO and MXene, enhancing the accessibility of electrolytes and reducing the distance, benefiting fast diffusion. This review paper sheds light on how the synthesis approaches can directly affect LIB configurations' durability and energy density and lead researchers to develop features of LTO anodes with promising engagement.</p><h3>Graphical abstract</h3>\u0000<div><figure><div><div><picture><source><img></source></picture></div></div></figure></div></div>","PeriodicalId":506,"journal":{"name":"Carbon Letters","volume":"35 2","pages":"515 - 537"},"PeriodicalIF":5.5,"publicationDate":"2025-03-18","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"143740900","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":3,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

引用次数: 0

Agriculture biomass-derived carbon materials for their application in sustainable energy storage 农业生物质衍生碳材料在可持续能源储存中的应用

IF 5.5 3区材料科学

Carbon Letters Pub Date : 2025-03-04 DOI: 10.1007/s42823-025-00884-9

Phibarisha Sohtun, Deepjyoti Deb, Neelam Bora, Rupam Goswami, Pradyumna Kumar Choudhury, Rajender Boddula, Prakash Kumar Sarangi, Rupam Kataki, Tonni Agustiono Kurniawan

{"title":"Agriculture biomass-derived carbon materials for their application in sustainable energy storage","authors":"Phibarisha Sohtun, Deepjyoti Deb, Neelam Bora, Rupam Goswami, Pradyumna Kumar Choudhury, Rajender Boddula, Prakash Kumar Sarangi, Rupam Kataki, Tonni Agustiono Kurniawan","doi":"10.1007/s42823-025-00884-9","DOIUrl":"10.1007/s42823-025-00884-9","url":null,"abstract":"<div><p>Industrialization and increasing consumerism have driven up energy demand and fossil fuel consumption, significantly contributing to global climate change and environmental pollution. While renewable energy sources are sustainable, their intermittent nature necessitates the development of efficient energy storage devices to ensure uninterrupted power supply and optimal energy utilization. Electrochemical energy storage devices are promising for sustainable energy. Traditionally, carbon electrode materials for these devices come from non-renewable sources. However, using biomass and biomass–coal blends can help substitute fossil fuels, reducing environmental impact. Recent advancements in carbon materials have achieved specific surface areas of over 2500 m<sup>2</sup>/g, resulting in supercapacitor capacitances of 250–350 F/g and cycling stability exceeding 10,000 cycles with < 5% capacity loss. In lithium-ion batteries, biomass-based anodes deliver 400–600 mA h/g, outperforming graphite. Doped carbon materials enhance charge-transfer efficiency by 20–30%, while CO₂ emissions from production are reduced by 40–60%. With 50–70% lower costs than fossil-based alternatives, biomass-derived carbons present a viable pathway for scalable, eco-friendly energy storage solutions, accelerating the transition toward sustainable energy systems. Overall, this work highlights the influence of carbon materials on the electrochemical properties and hydrogen storage capacity of biomass-based carbon materials. This also underscores their potential application in energy storage.</p></div>","PeriodicalId":506,"journal":{"name":"Carbon Letters","volume":"35 2","pages":"481 - 513"},"PeriodicalIF":5.5,"publicationDate":"2025-03-04","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"143740645","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":3,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

引用次数: 0

Recent research trends in the rational designing of single atom catalysts for electrochemical CO2 reduction reaction to CO—a mini review 综述了电化学CO2还原反应中单原子催化剂合理设计的研究进展

IF 5.5 3区材料科学

Carbon Letters Pub Date : 2025-03-01 DOI: 10.1007/s42823-025-00874-x

Jinuk Choi, Seoyeon Yoo, Gnanaprakasam Janani, Subramani Surendran, Sathyanarayanan Shanmugapriya, Heechae Choi, Gibum Kwon, Kyoungsuk Jin, Uk Sim

引用次数: 0

Hydrothermal synthesis and structural design of zero- to three-dimensional biomass-derived carbon nanomaterials 零至三维生物质衍生碳纳米材料的水热合成与结构设计

IF 5.5 3区材料科学

Carbon Letters Pub Date : 2025-02-24 DOI: 10.1007/s42823-025-00872-z

Guo Cheng, Hui-jia Li, Jing-hua Fang, Xue-qing Wang, Jia-qi Li, Jun-feng Chang, Na Teng, Ji-tong Wang

{"title":"Hydrothermal synthesis and structural design of zero- to three-dimensional biomass-derived carbon nanomaterials","authors":"Guo Cheng, Hui-jia Li, Jing-hua Fang, Xue-qing Wang, Jia-qi Li, Jun-feng Chang, Na Teng, Ji-tong Wang","doi":"10.1007/s42823-025-00872-z","DOIUrl":"10.1007/s42823-025-00872-z","url":null,"abstract":"<div><p>The synthesis of functional carbon materials with controllable morphology and structure using a simple, effective, and green process starting from biomass has been an attractive and challenging topic in recent years. After decades of technological development, high value-added biomass-derived carbon nanomaterials with different morphologies and structures prepared by low-temperature hydrothermal carbonization (HTC) have been gradually developed into a huge system covering different series in different dimensions, and are widely used in the fields of adsorption, electrochemical energy storage, and catalysis. However, due to a vague understanding of the fundamental structure–performance correlation and the absence of customized material design strategies, the diverse needs in practical applications cannot be well met. Herein, we reviewed the mechanism, modifications, and applications of the low-temperature HTC method for biomass. The synthesis mechanisms, structural designs strategies, and related applications of biomass-derived hydrochar are highlighted and summarized in different dimensions, including six major categories: zero-dimensional spherical structure, one-dimensional fibrous and tubular structure, two-dimensional lamellar structure, three-dimensional hierarchical porous structure, and special-shaped asymmetric structure. Then a sustainability assessment is conducted on the hydrothermal carbonization process. Finally, the controllable preparation of biomass-derived hydrochar is summarized and prospected for the application requirements in different fields.</p></div>","PeriodicalId":506,"journal":{"name":"Carbon Letters","volume":"35 2","pages":"441 - 467"},"PeriodicalIF":5.5,"publicationDate":"2025-02-24","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"143740581","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":3,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

引用次数: 0

Optimizing microalgal biomass conversion into carbon materials and their application in water treatment: a machine learning approach 优化微藻生物质转化为碳材料及其在水处理中的应用：机器学习方法

IF 5.5 3区材料科学

Carbon Letters Pub Date : 2025-02-23 DOI: 10.1007/s42823-024-00837-8

Arwa Al-Huqail, Khidhair Jasim Mohammed, Meldi Suhatril, Hamad Almujibah, Sana Toghroli, Sultan Saleh Alnahdi, Joffin Jose Ponnore

{"title":"Optimizing microalgal biomass conversion into carbon materials and their application in water treatment: a machine learning approach","authors":"Arwa Al-Huqail, Khidhair Jasim Mohammed, Meldi Suhatril, Hamad Almujibah, Sana Toghroli, Sultan Saleh Alnahdi, Joffin Jose Ponnore","doi":"10.1007/s42823-024-00837-8","DOIUrl":"10.1007/s42823-024-00837-8","url":null,"abstract":"<div><p>Microalgae, such as <i>Chlorella vulgaris</i> and <i>Scenedesmus obliquus</i>, are highly efficient at capturing carbon dioxide through photosynthesis, converting it into valuable biomass. This biomass can be further processed into carbon materials with applications in various fields, including water treatment. The reinforcement learning (RL) method was used to dynamically optimize environmental conditions for microalgae growth, improving the efficiency of biodiesel production. The contributions of this study include demonstrating the effectiveness of RL in optimizing biological systems, highlighting the potential of microalgae-derived materials in various industrial applications, and showcasing the integration of renewable energy technologies to enhance sustainability. The study demonstrated that <i>Chlorella vulgaris</i> and <i>Scenedesmus obliquus</i>, cultivated under controlled conditions, significantly improved absorption rates by 50% and 80%, respectively, showcasing their potential in residential heating systems. Post-cultivation, the extracted lipids were effectively utilized for biodiesel production. The RL models achieved high predictive accuracy, with <i>R</i><sup>2</sup> values of 0.98 for temperature and 0.95 for oxygen levels, confirming their effectiveness in system regulation. The development of activated carbon from microalgae biomass also highlighted its utility in removing heavy metals and dyes from water, proving its efficacy and stability, thus enhancing the sustainability of environmental management. This study underscores the successful integration of advanced machine learning with biological processes to optimize microalgae cultivation and develop practical byproducts for ecological applications.</p><h3>Graphical abstract</h3>\u0000<div><figure><div><div><picture><source><img></source></picture></div></div></figure></div></div>","PeriodicalId":506,"journal":{"name":"Carbon Letters","volume":"35 2","pages":"861 - 880"},"PeriodicalIF":5.5,"publicationDate":"2025-02-23","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"143740953","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":3,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

引用次数: 0

Fluorometric sensing probe using carbon quantum dots for selective detection of doxycycline antibiotic 碳量子点荧光传感探针选择性检测强力霉素类抗生素

IF 5.5 3区材料科学

Carbon Letters Pub Date : 2025-02-19 DOI: 10.1007/s42823-024-00839-6

Deepak Kumar, Subhash Chandra, Vivek Kumar, Pradeep Kumar Yadav, Syed Hadi Hasan

{"title":"Fluorometric sensing probe using carbon quantum dots for selective detection of doxycycline antibiotic","authors":"Deepak Kumar, Subhash Chandra, Vivek Kumar, Pradeep Kumar Yadav, Syed Hadi Hasan","doi":"10.1007/s42823-024-00839-6","DOIUrl":"10.1007/s42823-024-00839-6","url":null,"abstract":"<div><p>Due to the sturdy photoluminescence and absorption, CQDs emerged as a suitable candidate for optical sensing probe. The present study deals with the synthesis of blue-fluorescent Carbon Quantum Dot (TAA-CQD) using tannic acid and glycine as novel precursors. The TAA-CQD were synthesised hydrothermally with the high production yield and QY to be 86.12 and 21%, respectively, and an average particle size of 1.9 nm. The TAA-CQD aqueous solution displays excitation-dependent fluorescence emission in the excited range from 420 to 650 nm. The CIE co-ordinates in a highly blue region at (0.14, 0.19) confirmed the synthesised TAA-CQD were blue in fluorescent. Fluorescence of TAA-CQD was stable under all pH range, resisted the high ionic strengths condition and stable over 8 months. Furthermore, the fluorescent TAA-CQD was capable in detecting a tetracycline-classed antibiotic Doxycycline (DXY) along with remarkable selectivity and sensitivity. The measures limit of detection (LOD) was very low 2.42 mM in comparison to other methods. Moreover, the applicability of the proposed work has been fruitfully employed on the pharmaceutical waste. Thus, our designed TAA-CQD based fluorescence sensing system hold great promise for the advanced sensing materials in the detection of DXY and we believe that our approach will be promising and viable in a clinical applications.</p></div>","PeriodicalId":506,"journal":{"name":"Carbon Letters","volume":"35 2","pages":"895 - 905"},"PeriodicalIF":5.5,"publicationDate":"2025-02-19","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"143740903","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":3,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

引用次数: 0

Facile fabrication of CdS@GO binary nanocomposite coated GCE for separate and parallel electrochemical sensing of ascorbic acid, uric acid and nitrite 用于抗坏血酸、尿酸和亚硝酸盐分离和并行电化学传感的CdS@GO二元纳米复合涂层GCE的制备

IF 5.5 3区材料科学

Carbon Letters Pub Date : 2025-01-23 DOI: 10.1007/s42823-024-00838-7

A. Dhamodharan, E. Murugan, Huan Pang, K. Perumal, K. Jhansirani, Yajun Gao

{"title":"Facile fabrication of CdS@GO binary nanocomposite coated GCE for separate and parallel electrochemical sensing of ascorbic acid, uric acid and nitrite","authors":"A. Dhamodharan, E. Murugan, Huan Pang, K. Perumal, K. Jhansirani, Yajun Gao","doi":"10.1007/s42823-024-00838-7","DOIUrl":"10.1007/s42823-024-00838-7","url":null,"abstract":"<div><p>The accurate detection of vital biomarkers such as Ascorbic Acid (AA), Uric Acid (UA) and Nitrite (NO<sub>2</sub><sup>−</sup>) is crucial for human health surveillance. However, existing methods often struggle with concurrent detection and quantification of multiple species, highlighting the need for a more effective solution. To address this challenge, this study aimed to develop a multifunctional electrochemical sensor capable of parallel detection of AA, UA and NO<sub>2</sub><sup>−</sup> using a synergistic combination of Graphene Oxide (GO) and Cadmium Sulfide (CdS) materials. Notably, the fabricated CdS@GO/Glassy Carbon Electrode (GCE) exhibited exceptional electrochemical activity, as evidenced by Differential Pulse Voltammetry (DPV) analysis. The sensor demonstrated remarkable sensitivity (8.13, 10.12, and 9.05 μA·μM<sup>−1</sup>·cm<sup>−2</sup>) and ultra-low detection limits (0.034, 0.062, and 0.084 µM) for AA, UA and NO<sub>2</sub><sup>−</sup>, respectively. Furthermore, it successfully identified single molecules of each analyte in aqueous and biologic fluid samples, with recovery values comparable to those obtained using High-Performance Liquid Chromatography (HPLC) standard addition methods. The significance of this study lies in developing a novel CdS@GO/GCE sensor that enables concurrent detection and quantification of multiple vital biomarkers, offering a promising tool for human health monitoring and diagnosis.</p></div>","PeriodicalId":506,"journal":{"name":"Carbon Letters","volume":"35 2","pages":"881 - 893"},"PeriodicalIF":5.5,"publicationDate":"2025-01-23","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"143740954","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":3,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

引用次数: 0

Advancements in carbon microsphere-based nanocomposites: synthesis, properties and multifaceted applications: a comprehensive review 碳微球基纳米复合材料的合成、性能和多方面应用研究进展

IF 5.5 3区材料科学

Carbon Letters Pub Date : 2025-01-20 DOI: 10.1007/s42823-024-00851-w

A. Vindhyasarumi, Appukuttan Saritha, A. S. Sethulekshmi, Kuruvilla Joseph

引用次数: 0

Advance in the modification of g-C3N4-based composite for photocatalytic H2 production g- c3n4基复合材料光催化制氢改性研究进展

IF 5.5 3区材料科学

Carbon Letters Pub Date : 2025-01-20 DOI: 10.1007/s42823-024-00853-8

Jizhou Jiang, Lianglang Yu, Jiahe Peng, Weiping Gong, Wei Sun

{"title":"Advance in the modification of g-C3N4-based composite for photocatalytic H2 production","authors":"Jizhou Jiang, Lianglang Yu, Jiahe Peng, Weiping Gong, Wei Sun","doi":"10.1007/s42823-024-00853-8","DOIUrl":"10.1007/s42823-024-00853-8","url":null,"abstract":"<div><p>The development of hydrogen energy is crucial for achieving global dual-carbon strategic goals, namely \"carbon peak\" and \"carbon neutrality.\" Photocatalytic water splitting, powered by solar energy, presents a promising approach to hydrogen production. Advancing this technology requires the development of photocatalysts that are cost-effective, highly active, and stable. As a non-metallic semiconductor, g-C<sub>3</sub>N<sub>4</sub> stands out for its potential in sustainable energy and environmental remediation technologies, garnering considerable interest for its efficiency in harnessing light-driven reactions. Although g-C<sub>3</sub>N<sub>4</sub> exhibits promising characteristics, its practical application is significantly hindered by the rapid recombination of photogenerated charge carriers and its limited light absorption range. This review highlights various strategies employed to improve the photocatalytic hydrogen production efficiency of g-C<sub>3</sub>N<sub>4</sub>, including heteroatom doping, microstructure control, co-catalyst modification, defect engineering, and heterojunction construction. These strategies enhance active site density, light absorption capacity, and photogenerated charge separation in g-C<sub>3</sub>N<sub>4</sub>, thereby boosting electron migration rates and improving photocatalytic hydrogen production. Additionally, we explore the potential of integrating cutting-edge AI technology with advanced instrumentation for the prediction, design, preparation, and in-situ characterization of g-C<sub>3</sub>N<sub>4</sub>-based photocatalytic systems. This review aims to offer key insights into the design, development, and practical application of innovative, high-performance carbon-based catalysts.</p></div>","PeriodicalId":506,"journal":{"name":"Carbon Letters","volume":"35 2","pages":"417 - 440"},"PeriodicalIF":5.5,"publicationDate":"2025-01-20","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"143740910","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":3,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

引用次数: 0

Effect of multiple stretching on microstructure and mechanical properties of PAN-based carbon fibers 多次拉伸对pan基碳纤维微观结构和力学性能的影响

IF 5.5 3区材料科学

Carbon Letters Pub Date : 2025-01-19 DOI: 10.1007/s42823-024-00840-z

Shuang Li, Di Cui, Yu Wang, Aijun Gao, Yuanjian Tong

引用次数: 0