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Fully Extended Conjugated Azo-Bridged Covalent Triazine Framework with Maximum Dual-Redox-Active Sites for Advanced Lithium Organic Batteries
IF 17.6 1区 材料科学
Nano Energy Pub Date : 2025-02-21 DOI: 10.1016/j.nanoen.2025.110808
Yanxin Yu, Qianqian Jin, Qiling Li, Huapeng Sun, Yanbiao Ren, Shubiao Xia, Shi Wang, Zhong Jin
{"title":"Fully Extended Conjugated Azo-Bridged Covalent Triazine Framework with Maximum Dual-Redox-Active Sites for Advanced Lithium Organic Batteries","authors":"Yanxin Yu, Qianqian Jin, Qiling Li, Huapeng Sun, Yanbiao Ren, Shubiao Xia, Shi Wang, Zhong Jin","doi":"10.1016/j.nanoen.2025.110808","DOIUrl":"https://doi.org/10.1016/j.nanoen.2025.110808","url":null,"abstract":"Lithium organic batteries based on organic electrode materials (OEMs) have opened up a new way to develop high-performance and environmentally friendly energy storage devices. However, OEMs reported thus far are still severely limited by poor electrical conductivity and unsatisfactory capacity. Herein, we creatively propose to directly conjugate the active motifs with functional linkers in OEMs for simultaneously increasing conductivity and capacity. As the first attempt, an exclusive azo-bridged covalent triazine frameworks (Azo-CTF) where triazine motifs are directly linked with azo groups, is cleverly designed and constructed. By virtue of the thoroughly electron conjugation throughout azo bridges and triazine π units, Azo-CTF with the lowest energy bandgap (2.62<!-- --> <!-- -->eV) exhibits excellent essential charge conductivity. More excitingly, Azo-CTF achieves maximum redox-active sites integration (with the mass ratio reached to 70%) to date. Therefore, Azo-CTF anode shows an almost record performance with a high reversible capacity (2332.8 mAh g<sup>-1</sup> at 0.1<!-- --> <!-- -->A<!-- --> <!-- -->g<sup>-1</sup>) and inspiring rate characteristics (1034.4 mAh g<sup>-1</sup> undergoing 500 cycles at 2<!-- --> <!-- -->A<!-- --> <!-- -->g<sup>-1</sup>, 690.2 mAh g<sup>-1</sup> undergoing 1000 cycles at 5<!-- --> <!-- -->A<!-- --> <!-- -->g<sup>-1</sup>). Our work provides a new strategy for synchronously improving the conductivity and capacity of OEMs, which would greatly promote the development of lithium organic batteries.","PeriodicalId":394,"journal":{"name":"Nano Energy","volume":"27 1","pages":""},"PeriodicalIF":17.6,"publicationDate":"2025-02-21","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"143471022","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":1,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Dual Nano/Micro Tip-Array based LiquidSolid Interface for Ultrahigh Sensitive Triboelectric Pressure Sensors
IF 17.6 1区 材料科学
Nano Energy Pub Date : 2025-02-21 DOI: 10.1016/j.nanoen.2025.110810
Huabo Zhang, Lingjie Xie, Yina Liu, Ziang Chen, Zhenqiu Gao, Yuhan Peng, Changpeng Qiao, Shengqi Gao, Ziming Fu, Peng Jiang, Ruizhi Yang, Xuhui Sun, Zhen Wen
{"title":"Dual Nano/Micro Tip-Array based LiquidSolid Interface for Ultrahigh Sensitive Triboelectric Pressure Sensors","authors":"Huabo Zhang, Lingjie Xie, Yina Liu, Ziang Chen, Zhenqiu Gao, Yuhan Peng, Changpeng Qiao, Shengqi Gao, Ziming Fu, Peng Jiang, Ruizhi Yang, Xuhui Sun, Zhen Wen","doi":"10.1016/j.nanoen.2025.110810","DOIUrl":"https://doi.org/10.1016/j.nanoen.2025.110810","url":null,"abstract":"Specific liquid<img alt=\"single bond\" src=\"https://sdfestaticassets-us-east-1.sciencedirectassets.com/shared-assets/55/entities/sbnd.gif\" style=\"vertical-align:middle\"/>solid contact electrification demonstrates a unique and promising generation of pressure sensors. However, improving sensitivity at the liquid<img alt=\"single bond\" src=\"https://sdfestaticassets-us-east-1.sciencedirectassets.com/shared-assets/55/entities/sbnd.gif\" style=\"vertical-align:middle\"/>solid interface remains a substantial challenge. In this work, we present a ferrofluid-based triboelectric pressure sensor (FTPS) based on a strain-concentrated dual tip-array design between the liquid and solid phases. A silicone rubber film with a conical micro/nanostructure array and a ferrofluid with incisive spike microstructures tuned by a solid baseplate are employed as triboelectric pairs. The array-shaped microstructures of the solid- and liquid-sensing layers exhibit an opposing arrangement, manifesting a dual tip-array structure. The strain concentration effect arises from the coupling of high hydrophobicity caused by solid tip microstructures and high sharpness of liquid tip microstructures. In a load-bearing structure, there is a significant increase in strain when a sudden change in shape occurs. The sensitivity of the FTPS is positively correlated with the vertical deformation at the interface per unit pressure. Thus, an unprecedentedly high sensitivity of 38.84 kPa<sup>−1</sup> and an inconceivably low detection limit of 0.76<!-- --> <!-- -->Pa are attained. Finally, wind speed and direction detection with high sensitivity and stability based on the FTPS is demonstrated, indicating extensive practical applications for environmental monitoring and meteorological forecasting.","PeriodicalId":394,"journal":{"name":"Nano Energy","volume":"52 1","pages":""},"PeriodicalIF":17.6,"publicationDate":"2025-02-21","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"143471065","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":1,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Optimizing Reaction Pathways through Inner Surface Ion Confinement for High Energy Efficiency Neutral Zinc-Air Batteries
IF 17.6 1区 材料科学
Nano Energy Pub Date : 2025-02-20 DOI: 10.1016/j.nanoen.2025.110806
Sha Luo, Haotian Chen, Jiaqi Wang, Yu Feng, Bao Zhang, Wei Sun
{"title":"Optimizing Reaction Pathways through Inner Surface Ion Confinement for High Energy Efficiency Neutral Zinc-Air Batteries","authors":"Sha Luo, Haotian Chen, Jiaqi Wang, Yu Feng, Bao Zhang, Wei Sun","doi":"10.1016/j.nanoen.2025.110806","DOIUrl":"https://doi.org/10.1016/j.nanoen.2025.110806","url":null,"abstract":"Near-neutral rechargeable zinc-air batteries (ZABs) offer high energy density, safety, and economic benefits but suffer from higher polarization due to low-conductivity discharge products. Herein, we demonstrate an inner surface ion confinement effect within hydrophilic porous carbon to accelerate cathodic reaction kinetics of neutral ZABs. Operando electrochemical pH and in-situ XRD measurements reveal that microporous structure can temporarily store intermediate OH<sup>-</sup>, shifting the reaction pathway to a more efficient electrolyte mechanism, similar to high-performance aprotic Li-O<sub>2</sub> batteries. This reduces basic zinc salt precipitation and ORR/OER overpotential, boosting energy efficiency from 46.0% to 74.5% at 0.1<!-- --> <!-- -->mA<!-- --> <!-- -->cm<sup>-2</sup> and 2 mAh cm<sup>-2</sup>. The resulting 10 Ah pouch cell and flexible belt-shaped cell offer scalable solutions for neutral zinc-air batteries across various applications, opening new avenues for high-performance metal-air batteries.","PeriodicalId":394,"journal":{"name":"Nano Energy","volume":"154 1","pages":""},"PeriodicalIF":17.6,"publicationDate":"2025-02-20","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"143452132","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":1,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Constructing Synthetic Organosulfur Additive for High Voltage Lithium-ion Batteries
IF 17.6 1区 材料科学
Nano Energy Pub Date : 2025-02-20 DOI: 10.1016/j.nanoen.2025.110807
Chi-Cheung Su, Meinan He, Michael A. Dato, Ziqi Liu, Hasnain Hafiz, Jeffrey Lopez, Khalil Amine
{"title":"Constructing Synthetic Organosulfur Additive for High Voltage Lithium-ion Batteries","authors":"Chi-Cheung Su, Meinan He, Michael A. Dato, Ziqi Liu, Hasnain Hafiz, Jeffrey Lopez, Khalil Amine","doi":"10.1016/j.nanoen.2025.110807","DOIUrl":"https://doi.org/10.1016/j.nanoen.2025.110807","url":null,"abstract":"Despite its high anodic stability, common organosulfur solvents such as ethyl methyl sulfone and sulfolane typically exhibit poor solid-electrolyte interphase (SEI) formation capability. To address this, the fluorinated organic sulfate 4-(trifluoromethyl)-1,3,2-dioxathiolane 2,2-dioxide (TFDTD) was developed as an effective additive for tailoring organosulfur-based electrolytes in lithium-ion batteries. This development was guided by the functionality selection principle and careful evaluation of feasibility in organic synthesis. TFDTD can be readily synthesized through the reaction between trifluoropropylene glycol and sulfuryl chloride. The ring structure of the organic sulfate enables the formation of a stable SEI on the anode, while the fluorination of the sulfate not only enhances its chemical stability and oxidation potential, but also its effectiveness to protect the anode by increasing its reduction potential, rendering it preferentially reduced on the anode surface before the decomposition of other electrolyte components. Introducing TFDTD facilitates the generation of a robust solid-electrolyte interphase on the graphite anode, significantly enhancing cell performance. Moreover, coupling the use of TFDTD with vinylene carbonate provides further protection on the cathode surface, enabling exceptionally stable, high-voltage, long-term cycling of Gr||NMC full cells.","PeriodicalId":394,"journal":{"name":"Nano Energy","volume":"6 1","pages":""},"PeriodicalIF":17.6,"publicationDate":"2025-02-20","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"143462345","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":1,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Monolithic Low-tortuous Copper(I) Phosphide Nanorod Arrays for Exceptional Areal Performance in Electrochemical Chloride Ion Removal
IF 17.6 1区 材料科学
Nano Energy Pub Date : 2025-02-20 DOI: 10.1016/j.nanoen.2025.110792
Ziqing Zhou, Yifan Ren, Fei Yu, Jie Ma
{"title":"Monolithic Low-tortuous Copper(I) Phosphide Nanorod Arrays for Exceptional Areal Performance in Electrochemical Chloride Ion Removal","authors":"Ziqing Zhou, Yifan Ren, Fei Yu, Jie Ma","doi":"10.1016/j.nanoen.2025.110792","DOIUrl":"https://doi.org/10.1016/j.nanoen.2025.110792","url":null,"abstract":"Copper(I) phosphide (Cu<sub>3</sub>P) with high theoretical capacity and metalloid characteristics performs great potential as chloride ion (Cl<sup>−</sup>) storage electrodes in chloride-ion batteries and deionization. However, the unsatisfactory electrochemical performance of Cu<sub>3</sub>P due to the sluggish rate and poor stability severely limited the development of practical application in electrochemical Cl<sup>−</sup> removal. Herein, monolithic low-tortuous Cu<sub>3</sub>P nanorod arrays (mCu<sub>3</sub>P NA) have been fabricated through sacrificial template array engineering combined with the controlled phosphating strategy. Benefiting from the low-tortuous array structural advantages involving rapid charge transfer and plentiful active sites, the resultant mCu<sub>3</sub>P NA electrode exhibited excellent areal deionization capacity (2.21 mg-Cl<sup>−</sup> cm<sup>−2</sup> at 1.6<!-- --> <!-- -->V) and corresponding fabulous rate (0.074 mg-Cl<sup>−</sup> cm<sup>−2</sup> min<sup>−1</sup>), which was superior to previously reported electrodes in electrochemical deionization. Furthermore, the phosphating degree could adjust array architecture and component of Cu<sub>3</sub>P/Cu heterostructure, thus affecting areal deionization performance. In addition, the mechanism of Cl<sup>−</sup> capture by Cu<sub>3</sub>P was first elucidated, related to the redox of P<sup>3−</sup>/P<sup>0</sup> and the formation of CuCl. These findings unlock the potential and elucidate the mechanism of Cu<sub>3</sub>P for electrochemical Cl<sup>−</sup> removal, as well as provide a new idea for rational design of high-performance array electrodes for environmental applications.","PeriodicalId":394,"journal":{"name":"Nano Energy","volume":"34 1","pages":""},"PeriodicalIF":17.6,"publicationDate":"2025-02-20","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"143462348","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":1,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Self-powered real-time fall alarm microsystem based on reconfigurable paper-like piezoelectric nanogenerator
IF 17.6 1区 材料科学
Nano Energy Pub Date : 2025-02-20 DOI: 10.1016/j.nanoen.2025.110803
Yan-Yuan Ba, Yi-ming Chang, Fan-Yu Mu, Hai-Tao Deng, Xin-Ran Zhang, Song Shi, Xiao-Sheng Zhang
{"title":"Self-powered real-time fall alarm microsystem based on reconfigurable paper-like piezoelectric nanogenerator","authors":"Yan-Yuan Ba, Yi-ming Chang, Fan-Yu Mu, Hai-Tao Deng, Xin-Ran Zhang, Song Shi, Xiao-Sheng Zhang","doi":"10.1016/j.nanoen.2025.110803","DOIUrl":"https://doi.org/10.1016/j.nanoen.2025.110803","url":null,"abstract":"Piezoelectric nanogenerators (PENGs) have emerged as a promising technology for ambient energy harvesting, serving as robust power sources and enabling self-powered electronics. These devices hold great potential in the construction of intelligent medical monitoring systems owing to their unique ability to integrate self-powering capabilities with various functionalities. While numerous high-performance PENGs have been proposed and applied in the field of sensing, the focus has primarily been on device sensitivity and stability, neglecting another crucial characteristic: reconfigurability. Here, a reconfigurable paper-like PENG based on the material properties of the piezoelectric functional layer was developed. The polarization strategy of barium titanate (BTO) and cellulose nanofibril (CNF) piezoelectric film, the feasibility of reconfigurability and biodegradability of piezoelectric functional materials, and the effects of packaging on the electrical output of the device were comprehensively investigated through experimental measurements. Results revealed that 25<!-- --> <!-- -->wt% BTO content in the functional film yields the highest electrical output of the PENG, and this functional film maintains a stable output even after multiple reconfigurations. Furthermore, the BTO-CNF piezoelectric film provides PENGs with lower internal resistance, enabling compact integration with conventional circuits and showcasing great potential in the field of self-powered smart microsystems, particularly those requiring remarkable reconfigurable properties. Consequently, this study successfully demonstrated an intelligent monitoring microsystem for fall alarms, which is self-powered and flexible.","PeriodicalId":394,"journal":{"name":"Nano Energy","volume":"2 1","pages":""},"PeriodicalIF":17.6,"publicationDate":"2025-02-20","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"143462347","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":1,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Enhancing Cu(In, Ga)Se2 Solar Cell Efficiency with Vertically Channel-Stacked WSe2 Rear Passivation Layers
IF 17.6 1区 材料科学
Nano Energy Pub Date : 2025-02-20 DOI: 10.1016/j.nanoen.2025.110802
Jun-Nan Liu, Chia-Chen Chung, Lung-Hsin Tu, Tzu-Yi Yang, Yu-Ren Peng, Wei-Chih Lin, Chien-Yu Lai, Yi-Jen Yu, Tzu-Ying Lin, Yu-Lun Cheuh, Chih-Huang Lai
{"title":"Enhancing Cu(In, Ga)Se2 Solar Cell Efficiency with Vertically Channel-Stacked WSe2 Rear Passivation Layers","authors":"Jun-Nan Liu, Chia-Chen Chung, Lung-Hsin Tu, Tzu-Yi Yang, Yu-Ren Peng, Wei-Chih Lin, Chien-Yu Lai, Yi-Jen Yu, Tzu-Ying Lin, Yu-Lun Cheuh, Chih-Huang Lai","doi":"10.1016/j.nanoen.2025.110802","DOIUrl":"https://doi.org/10.1016/j.nanoen.2025.110802","url":null,"abstract":"The performance of Cu(In,Ga)Se<sub>2</sub> (CIGS) solar cells was significantly improved by introducing a layered WSe<sub>2</sub> thin film as a rear passivation layer in the back contact region. A vertically aligned stacking channel of the WSe<sub>2</sub> thin film was obtained by converting a WO<sub>x</sub> thin film using a plasma-assisted selenization process. With the insertion of the WSe<sub>2</sub> layer, we observed a notable accumulation of Ga at the rear side of the CIGS absorber layer, facilitated by the vertically channel-stacked WSe<sub>2</sub> thin film. Increased open-circuit voltage is attributed to the reconstruction of the band alignment due to the modified Ga concentration profile, effectively mitigating electron flowing toward back contact and recombination within the back contact region of the CIGS solar cell. Furthermore, a favorable conductivity along the channels of the vertically channel-stacked WSe<sub>2</sub> thin film and a steeper [Ga]/([Ga] + [In]) (GGI) gradient provide significant enhancements in short-circuit current density. The solar energy conversion efficiency of the CIGS solar cell, fabricated via a sequential process with elemental Se vapor, was boosted from 15.08% to 17.06%. The remarkable enhancement highlights the potential of employing two-dimensional materials as passivation layers in photovoltaic applications.","PeriodicalId":394,"journal":{"name":"Nano Energy","volume":"1 1","pages":""},"PeriodicalIF":17.6,"publicationDate":"2025-02-20","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"143452134","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":1,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Great Carbon Nano Materials based Composites for Electronic Skin: Intelligent Sensing, and Self-Powered Nano Generators
IF 17.6 1区 材料科学
Nano Energy Pub Date : 2025-02-20 DOI: 10.1016/j.nanoen.2025.110805
Vineet Kumar, Nargish Parvin, Sang Woo Joo, Tapas Kumar Mandal, Sang Shin Park
{"title":"Great Carbon Nano Materials based Composites for Electronic Skin: Intelligent Sensing, and Self-Powered Nano Generators","authors":"Vineet Kumar, Nargish Parvin, Sang Woo Joo, Tapas Kumar Mandal, Sang Shin Park","doi":"10.1016/j.nanoen.2025.110805","DOIUrl":"https://doi.org/10.1016/j.nanoen.2025.110805","url":null,"abstract":"Recent advancements (<strong>2019-2025</strong>) in carbon nanomaterials-based composites have been reported. These composites propelled the development of next-generation electronic skin (e-skin) with enhanced functionalities. These are multi-sensing, and self-powered nano generators. Such materials, featuring stretchable and conductive properties, allow for the creation of e-skin. This e-skin mimics human skin's mechanical flexibility while integrating advanced sensing capabilities for pressure, temperature, and tactile feedback. Self-healing elastomers, utilizing dynamic covalent bonds and supramolecular interactions, extend the durability and lifespan of e-skin by enabling autonomous damage repair. Meanwhile, innovations in thermoelectric, piezoelectric, and triboelectric elastomers provide mechanisms for harvesting mechanical and thermal energy, enabling self-powered e-skin devices. This review explores the latest developments in these materials and their applications in healthcare, wearable electronics, robotics, and prosthetics. Key challenges in material stability, manufacturing scalability, and multifunctional integration are also addressed, offering insights into future research directions that will further advance the field of elastomer-based e-skin.","PeriodicalId":394,"journal":{"name":"Nano Energy","volume":"20 1","pages":""},"PeriodicalIF":17.6,"publicationDate":"2025-02-20","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"143462346","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":1,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Magnet Gear-based Triboelectric Nanogenerator Harvesting Energy from Boiling Heat Transfer Environment
IF 17.6 1区 材料科学
Nano Energy Pub Date : 2025-02-20 DOI: 10.1016/j.nanoen.2025.110804
Wei Deng, Kejian Dong, Song Ni, Sihong He, Pengcheng Zhao, Tao Yu, Jiyun Zhao
{"title":"Magnet Gear-based Triboelectric Nanogenerator Harvesting Energy from Boiling Heat Transfer Environment","authors":"Wei Deng, Kejian Dong, Song Ni, Sihong He, Pengcheng Zhao, Tao Yu, Jiyun Zhao","doi":"10.1016/j.nanoen.2025.110804","DOIUrl":"https://doi.org/10.1016/j.nanoen.2025.110804","url":null,"abstract":"Boiling heat transfer has long been a promising thermal management technique across various industrial sectors. In the context of the energy crisis, recovering low-grade thermal energy from boiling environments is crucial for industrial advancement. Meanwhile, triboelectric nanogenerators (TENGs) are notable for low-grade energy harvesting due to their simple fabrication, adaptability to low mechanical frequencies, and lightweight nature. This study introduces a magnet gear-based TENG, designed to harness energy from boiling environments. The magnet gear facilitates remote force transmission from the rotor to the TENG module, effectively mitigating the adverse effects of high temperature and humidity. Rabbit fur is used to create a soft contact, enhancing coupling with the low-grade energy source, significantly reducing frictional resistance, and improving device durability. Tests demonstrate that the M-TENG does not impact the thermal management of boiling heat transfer, showing potential for integration with other thermal energy harvesting techniques. Its operational range spans the boiling curve from nucleation to critical heat flux, maintaining performance after 15,000 cycles. Furthermore, self-powered applications have been successfully demonstrated, such as powering small calculators, lighting at least 44 LEDs, and monitoring boiling heat flux, offering a viable strategy for industrial upgrading in boiling heat transfer scenarios.","PeriodicalId":394,"journal":{"name":"Nano Energy","volume":"130 1","pages":""},"PeriodicalIF":17.6,"publicationDate":"2025-02-20","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"143452133","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":1,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Enhancing organic solar cell efficiency with ester-based quinoxaline non-fullerene acceptors in ternary blends
IF 16.8 1区 材料科学
Nano Energy Pub Date : 2025-02-19 DOI: 10.1016/j.nanoen.2025.110801
Zhixin Liu , Chunguang Zhu , Jianpeng Xu , Yintai Xu , Jie Zeng , Jiangfeng Wang , Jiyao Zhang , Peide Zhu , Deng Wang , Xianyong Zhou , Yong Zhang , Xingzhu Wang , Lei Ying , Lei Yan , Baomin Xu
{"title":"Enhancing organic solar cell efficiency with ester-based quinoxaline non-fullerene acceptors in ternary blends","authors":"Zhixin Liu ,&nbsp;Chunguang Zhu ,&nbsp;Jianpeng Xu ,&nbsp;Yintai Xu ,&nbsp;Jie Zeng ,&nbsp;Jiangfeng Wang ,&nbsp;Jiyao Zhang ,&nbsp;Peide Zhu ,&nbsp;Deng Wang ,&nbsp;Xianyong Zhou ,&nbsp;Yong Zhang ,&nbsp;Xingzhu Wang ,&nbsp;Lei Ying ,&nbsp;Lei Yan ,&nbsp;Baomin Xu","doi":"10.1016/j.nanoen.2025.110801","DOIUrl":"10.1016/j.nanoen.2025.110801","url":null,"abstract":"<div><div>The ternary strategy has been recognized as an effective approach for boosting the power conversion efficiency (PCE) of organic solar cells (OSCs). For ternary devices, selecting an appropriate third component is critical to ensure that both the photocurrent and voltage outputs of OSCs are not compromised. In this study, we present the use of an ester-based quinoxaline core non-fullerene acceptor (QEIP-4Cl) for the fabrication of ternary devices, which demonstrate enhanced absorption spectra and beneficial cascading LUMO energy level arrangement when paired with the PM6:L8-BO blend. Compared to the binary system, the ternary blend system exhibits superior thin-film phase separation and better suppression of non-radiative recombination, resulting in a reduced energy loss (E<sub>loss</sub>) value. Moreover, by prolonging exciton lifetime, promoting charge carrier migration and suppressing charge recombination to facilitate improved <em>J</em><sub>SC</sub> in OSCs. With the combined enhancement of <em>V</em><sub>OC</sub> and <em>J</em><sub>SC</sub>, OSCs achieve an impressive efficiency of 19.27 %. This research demonstrates the effectiveness of the ternary strategy in enhancing the performance of OSCs. The careful selection of the third component contributes to improved absorption, energy level alignment, and overall efficiency, making it a notable advancement in organic solar cell technology.</div></div>","PeriodicalId":394,"journal":{"name":"Nano Energy","volume":"137 ","pages":"Article 110801"},"PeriodicalIF":16.8,"publicationDate":"2025-02-19","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"143452186","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":1,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
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