Nano EnergyPub Date : 2025-05-31DOI: 10.1016/j.nanoen.2025.111200
Chengbin Fei, Xinwen Zhang, Meng Zhou, He Wang
{"title":"Manipulating Phase Distribution and Transformation Kinetics by Substrate Clamping for DMAxCs1-xPbI3 Perovskite Solar Cells","authors":"Chengbin Fei, Xinwen Zhang, Meng Zhou, He Wang","doi":"10.1016/j.nanoen.2025.111200","DOIUrl":"https://doi.org/10.1016/j.nanoen.2025.111200","url":null,"abstract":"The black-phase CsPbI<sub>3</sub>, a Br-free wide-bandgap perovskite with promising light and thermal stability, tends to transition to a non-perovskite yellow phase at room temperature, posing a significant challenge for its application in solar cell devices. To tackle this issue, dimethylammonium iodide (DMAI) is frequently included to form black phase DMA<sub>x</sub>Cs<sub>1-x</sub>PbI<sub>3</sub> to accommodate the tolerance factor, however, its phase behavior and effect on device stability are still not well understood. In this work, we employed transient reflection spectroscopy with front and back laser excitation to investigate the phase transformation kinetics and the vertical phase distribution of DMA<sub>x</sub>Cs<sub>1-x</sub>PbI<sub>3</sub> films during thermal annealing. Our results indicate that these properties are influenced by the choice of substrate. During prolonged annealing, DMAI partially evaporates, causing lattice reorganization and leading to surface degradation. For substrates with a strong clamping effect, the surface DMA<sub>x</sub>Cs<sub>1-x</sub>PbI<sub>3</sub> transitions to a black phase CsPbI<sub>3</sub>, whereas for those with a weak clamping effect, it degrades directly to the yellow phase. Importantly, films of DMA<sub>x</sub>Cs<sub>1-x</sub>PbI<sub>3</sub> exhibit improved stability when annealed close to the boundary where the black CsPbI<sub>3</sub> phase emerges at the surface, particularly when supported by an organic substrate that has a suitable thermal expansion coefficient and strong coordination with perovskite.","PeriodicalId":394,"journal":{"name":"Nano Energy","volume":"50 1","pages":""},"PeriodicalIF":17.6,"publicationDate":"2025-05-31","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"144184011","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":1,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Nano EnergyPub Date : 2025-05-31DOI: 10.1016/j.nanoen.2025.111202
Bo Huang, Jiayi Pan, Linfeng Lan, Jiale Huang, Yutian Liu, Churou Wang, Yang Lu, Junbiao Peng, Yong Cao
{"title":"Emotion-modulated visual perception in ultra-low-energy flexible neuromorphic synaptic transistors enabled by directionally polarized lactam-based polymer electrets","authors":"Bo Huang, Jiayi Pan, Linfeng Lan, Jiale Huang, Yutian Liu, Churou Wang, Yang Lu, Junbiao Peng, Yong Cao","doi":"10.1016/j.nanoen.2025.111202","DOIUrl":"https://doi.org/10.1016/j.nanoen.2025.111202","url":null,"abstract":"Electret materials are receiving intensive scrutiny in the field of neuromorphic electronics owing to their remarkable capability to retain charges. This work presents a flexible neuromorphic synaptic transistor (NST) with multimodal neuromorphic computation and multiwavelength light response using a strong-polarity lactam-based polymer electret. The NSTs exhibited excellent multimodal (electrical and optical) performance (even bent at a curvature of 5<!-- --> <!-- -->mm), including ultra-low energy consumption (4.8 aJ for single optical event), broadband response (395-620<!-- --> <!-- -->nm), short/long-term plasticity (STP/LTP), pair-pulse facilitation (PPF, as high as 241%), spike voltage/frequency/duration/number-dependent plasticity (SVDP/SFDP/SDDP/SNDP), good learning-forgetting-relearning feature, and high recognition accuracy of 89.7% by handwritten digital datasets. Interestingly, the electrical stimulation is able to affect the optical excitatory post-synaptic current (EPSC), which is attributed to the PVP directional polarization effect. This makes the gate voltage of the NSTs can function as an external parameter like human emotion that influences visual perception and thereby reflecting visual adaptive characteristics. Our work suggests a promising strategy toward developing wearable brain-inspired artificial neuromorphic systems with high-efficiency computing in memory (CiM) ability.","PeriodicalId":394,"journal":{"name":"Nano Energy","volume":"50 1","pages":""},"PeriodicalIF":17.6,"publicationDate":"2025-05-31","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"144188992","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":1,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Nano EnergyPub Date : 2025-05-30DOI: 10.1016/j.nanoen.2025.111197
Liang Chen, Providence Buregeya Ingabire, Jian Sun, Jie Xiong, Can Cui, Pingfan Du
{"title":"Multifunctional Polymer-Regulation of SnO2 Nanocrystals and Perovskite Buried Interface Passivation by Plant-derived Fucoidan-Ammonium for Air-Stable Photovoltaic Fabrics","authors":"Liang Chen, Providence Buregeya Ingabire, Jian Sun, Jie Xiong, Can Cui, Pingfan Du","doi":"10.1016/j.nanoen.2025.111197","DOIUrl":"https://doi.org/10.1016/j.nanoen.2025.111197","url":null,"abstract":"Flexible perovskite solar cells (f-PSCs) have attracted significant interest in wearable self-powered clothing. However, the lack of skin-friendliness of the polymer substrate and the fragility of the ITO conductive layer hinders their practical application. Therefore, this study developed a silver nanowire-based fabric electrode to address these challenges. Subsequently, the ammonium salt of fucoidan was employed for the multifunctional regulation of SnO<sub>2</sub> nanocrystals, inhibiting agglomeration and improving the quality of the formed films. Consequently, the interface wettability and strain release showed significant improvement, and the vertical growth of the perovskite nanocrystals was enhanced. Subsequently, infrared radiation annealing was performed to form a highly crystalline perovskite layer on the fabric electrode. The optimized photovoltaic fabric fabricated under ambient conditions achieved a PCE of 13.05%, which is particularly impressive for the fabric-based f-PSCs. Therefore, this study provides an innovative approach for the preparation of self-powered smart clothing.","PeriodicalId":394,"journal":{"name":"Nano Energy","volume":"4 1","pages":"111197"},"PeriodicalIF":17.6,"publicationDate":"2025-05-30","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"144184018","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":1,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Nano EnergyPub Date : 2025-05-30DOI: 10.1016/j.nanoen.2025.111198
Xin Qin, Xianqiang Xie, Laju Bu, Yafei Wang, Yong Cui, Jianhui Hou, Yang Liu, Yinhua Zhou, Beibei Shi, Hang Yin, Wei Ma, Han Yan
{"title":"Developing Absorption-Matched and Encapsulation-Free Underwater Organic Photovoltaics with the Acceptor-Poor Active Layer","authors":"Xin Qin, Xianqiang Xie, Laju Bu, Yafei Wang, Yong Cui, Jianhui Hou, Yang Liu, Yinhua Zhou, Beibei Shi, Hang Yin, Wei Ma, Han Yan","doi":"10.1016/j.nanoen.2025.111198","DOIUrl":"https://doi.org/10.1016/j.nanoen.2025.111198","url":null,"abstract":"The underwater photovoltaic technique requires easily-tuned absorption range of photoactive layer and good water-resistant property. Organic solar cells (OSCs) based on the acceptor-poor active layer well satisfy the two demands. Unfortunately, the reduced acceptor content inevitably suppresses the photovoltaic performance by cutting off the electron transporting pathway. To alleviate the performance decay at this situation, a three-aspect strategy is proposed. First, polymer acceptors are used instead of small molecule acceptors to provide continuous channels for electron transport. Second, more extended chain conformation is introduced. Third, enhance acceptor crystallinity with proper domain purity to decrease the charge recombination. Obeying these rules, the steep power conversion efficiency (PCE) decay appears at a smaller donor:acceptor (D:A) ratio. Comparing at the same ratio of 1:0.4, the optimized all-polymer OSC has a PCE of 15.13% which largely outperforms that of 11.23% in the polymer-small molecule counterpart. Taking advantage of the water-resistant device structure, the all-polymer OSC displays PCEs of 13.41% and 17.78% under actual/simulated solar irradiation at 1<!-- --> <!-- -->m and 20<!-- --> <!-- -->m underwater depths. In addition, 53.6% PCE retention is revealed after immersing the device in water for 96<!-- --> <!-- -->h without encapsulation.","PeriodicalId":394,"journal":{"name":"Nano Energy","volume":"30 1","pages":"111198"},"PeriodicalIF":17.6,"publicationDate":"2025-05-30","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"144184009","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":1,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Nano EnergyPub Date : 2025-05-30DOI: 10.1016/j.nanoen.2025.111199
Shingirirai Chakoma, Jerome Rajendran, Xiaochang Pei, Anita Ghandehari, Jorge Alfonso Tavares Negrete, Rahim Esfandyarpour
{"title":"Nanomaterials-based, Transducer-side Active-Electronic-free, Self-Powered, and Wireless Wearable E-Skin for Augmented Interactive Human-Robots","authors":"Shingirirai Chakoma, Jerome Rajendran, Xiaochang Pei, Anita Ghandehari, Jorge Alfonso Tavares Negrete, Rahim Esfandyarpour","doi":"10.1016/j.nanoen.2025.111199","DOIUrl":"https://doi.org/10.1016/j.nanoen.2025.111199","url":null,"abstract":"Wearable and flexible force sensors are vital for human-machine interfaces, robotics, and remote sensing applications, but most sensors rely on batteries, active electronics, are environmentally unstable, and have wireless transmission difficulties. To address these challenges, we introduce, for the first time, a fully passive, battery-free, self-powered, miniaturized force sensing system that transmits wirelessly at frequencies above 400<!-- --> <!-- -->MHz, without active electronics on the transducer side. Our MXene-based Triboelectric Nanogenerator Resonance Force-Sensing System (MXTENG-RFS) harnesses the sensed force to power itself, enabling long-term operation in remote environments. This system also employs resonant frequency shifts—immune to environmental factors, to effectively convey sensed information. Supported by an innovative frequency and amplitude boosting approach, the MXTENG-RFS achieves active-electronic-free wireless data transmission while maintaining minimal power consumption and electromagnetic emissions. The device is maintenance-free and stealth-compatible. Through precise nanomaterial engineering, we have achieved high power density, robust sensing performance, and long-term environmental stability. Furthermore, pioneering 3D-multi-nanomaterial printing protocols have been developed to enable scalability, large-scale production, rapid prototyping, low cost, design freedom, and high resolution for the MXTENG-RFS devices. As a proof of concept, we demonstrated a wearable e-skin for augmented interactive human–drone operation—providing battery-free, self-powered, and wireless drone control—ideal for reconnaissance and surveillance in remote environments. By enabling self-powered operation, electronic-free and direct, transmission, passive design, wireless functionality, robustness, a miniaturized form, low cost, and user-friendliness, we envision our MXTENG-RFS system as a maintenance-free sensing and communication solution ideally suited for resource-limited environments, space missions, and critical remote areas.","PeriodicalId":394,"journal":{"name":"Nano Energy","volume":"98 1","pages":""},"PeriodicalIF":17.6,"publicationDate":"2025-05-30","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"144177128","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":1,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
{"title":"Fur-inspired triboelectric tactile sensing array for intelligent human-machine interaction","authors":"Wenjun Wang, Jiaxuan Wu, Junfeng Zhong, Xiaobo Lin, Yating Xie, Haotian Chen, Bo Meng","doi":"10.1016/j.nanoen.2025.111187","DOIUrl":"https://doi.org/10.1016/j.nanoen.2025.111187","url":null,"abstract":"Tactile sensing plays a crucial role as an approach of human-machine interaction in the digital era. In this work, inspired by animal fur, we propose a triboelectric tactile sensing array in order to achieve sensitive awareness of gentle palm interactions. Which is of great significance for enhancing the functionality of companion and pet robots. The tactile sensor consists of a cluster of single-electrode structured triboelectric sensing units based on PTFE film coated conductive yarns. The dynamic signals of the tactile sensing array can accurately perceive 3D-depth interaction information of touch such as direction, speed and gesture. It allows for more comprehensive and accurate pattern recognition in human-machine interaction scenarios. Furthermore, a deep learning model is used to assist the recognition of complex signals from the tactile sensing array under various interactions. Among a dataset of 17 palmar interactions, a recognition accuracy up to 96.8% was achieved. As a demonstration, we finally construct an intelligent human-machine interface based on this tactile sensing array. It is integrated onto a shape-shifting robot working as a piece of fur of an intelligent pet robot. With the help of this fur, the robot can accurately recognize the interaction from the tester and act accordingly.","PeriodicalId":394,"journal":{"name":"Nano Energy","volume":"48 1","pages":""},"PeriodicalIF":17.6,"publicationDate":"2025-05-29","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"144164891","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":1,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Nano EnergyPub Date : 2025-05-29DOI: 10.1016/j.nanoen.2025.111193
Zhuo Li, Fuhan Cui, Mingyu Su, Junyi Li, Yiyang Mao, Yuao Wang, Zhendong Guo, Kai Zhu, Dianxue Cao
{"title":"Robust Inter-Molecular Coupling Effect Endowed Spatial Anchoring and Defect-Repaired layer for Dendrite-Free Zn Metal Anode","authors":"Zhuo Li, Fuhan Cui, Mingyu Su, Junyi Li, Yiyang Mao, Yuao Wang, Zhendong Guo, Kai Zhu, Dianxue Cao","doi":"10.1016/j.nanoen.2025.111193","DOIUrl":"https://doi.org/10.1016/j.nanoen.2025.111193","url":null,"abstract":"The active water-induced hydrogen evolution reaction (HER) and dendrite growth issues significantly impede the application of aqueous Zn metal batteries for grid-scale energy storage from renewable sources. Herein, we establish two types of robust inter-molecular coupling for solvent structure regulation and zinc ions transfer boosting. The coupling of γ-aminopropyltriethoxysilane and water (KH-H<sub>2</sub>O), achieving spatial anchoring for active water, decomposes the solvated structure and facilitates the nucleation. The coupling between zinc ions and nitrogen atoms constructs a highway for free zinc ions to hop, alleviating the concentration gradient. Interestingly, diminished nucleation barrier and fast zinc ions diffusion feature the zinc metal anode with self-repaired function, mitigating the effects of low current density field (LCF) and high current density field (HCF), and repairing the defects. The KH-modified Zn metal anode, with anchored active water, demonstrates an extended lifespan for symmetrical cells and stable performance in full capacitors.","PeriodicalId":394,"journal":{"name":"Nano Energy","volume":"16 1","pages":""},"PeriodicalIF":17.6,"publicationDate":"2025-05-29","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"144177131","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":1,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Nano EnergyPub Date : 2025-05-29DOI: 10.1016/j.nanoen.2025.111196
Yitong Wang, Yuanyuan Gao, Di Tan, Fungchi Nip, Hong Fu, Bingang Xu
{"title":"Stretchable 3D Kirigami-structured Textiles for High-performance Wearable Energy Harvesting and Self-powered Sensing","authors":"Yitong Wang, Yuanyuan Gao, Di Tan, Fungchi Nip, Hong Fu, Bingang Xu","doi":"10.1016/j.nanoen.2025.111196","DOIUrl":"https://doi.org/10.1016/j.nanoen.2025.111196","url":null,"abstract":"Bio-mechanical energy from human motion is considered as one of the most ubiquitous, free, and sustainable resources, which has led to the development of wearable energy harvesting devices such as triboelectric nanogenerators (TENGs). However, generating excellent energy outputs while achieving high wearing comfort for wearable TENGs has long been a major challenge. In this study, we introduce a novel stretchable kirigami-structured textile-based triboelectric nanogenerator (SKS-TENG) that adopts a simple and economical kirigami approach. Owing to its special kirigami structure, the contact-separation efficiency of the surface is significantly improved, which can generate more charging output. The SKS-TENG has a unique repetitively stretchable structure and achieves amazing electrical performance with a power density of 3,380<!-- --> <!-- -->mW<!-- --> <!-- -->m<sup>−2</sup>, which are several times higher than most existing textile-based TENGs. Even after twenty cycles of washing, it can still maintain stable electrical performance and has an impressive durability that can withstand more than 10,000 cycles. In addition, SKS-TENG is also assembled with clothing, which can power small electronic devices and light up 1,636 LEDs on clothing. The excellent power generation performance of SKS-TENG demonstrates its great potential for future development in human motion energy harvesting, wearable electronic devices and smart textile applications.","PeriodicalId":394,"journal":{"name":"Nano Energy","volume":"71 1","pages":""},"PeriodicalIF":17.6,"publicationDate":"2025-05-29","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"144177125","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":1,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Nano EnergyPub Date : 2025-05-28DOI: 10.1016/j.nanoen.2025.111189
Cheng Chi , Xingyu Zhang , Chen Shen , Qi Hu , Ze Liu , Jiahao Hu , Zhi Li , Yang Li , Xiaoli Yu , Hao Xiao , Zhaoquan Zhao , Yuan Yao , Xing Liang , Hongwei Wu , Xiaoze Du
{"title":"Bioinspired double-layer thermogalvanic cells with engineered ionic gradients for high-efficiency waste heat recovery","authors":"Cheng Chi , Xingyu Zhang , Chen Shen , Qi Hu , Ze Liu , Jiahao Hu , Zhi Li , Yang Li , Xiaoli Yu , Hao Xiao , Zhaoquan Zhao , Yuan Yao , Xing Liang , Hongwei Wu , Xiaoze Du","doi":"10.1016/j.nanoen.2025.111189","DOIUrl":"10.1016/j.nanoen.2025.111189","url":null,"abstract":"<div><div>Thermogalvanic cells (TGCs) have emerged as a promising technology for harvesting low-grade thermal energy, but their widespread application has been hindered by limited conversion efficiencies. A critical factor in enhancing TGC performance lies in establishing substantial ion concentration gradients, which remains challenging due to the inherent tendency of ion pairing. Here, we present a double-layer thermogalvanic cell (DTGC) architecture that spatially segregates redox pairs into two distinct gel layers, enabling unprecedented control over ion concentration gradients. This innovative design yields a single p-type gelatin-K<sub>4</sub>[Fe(CN)<sub>6</sub>]/K<sub>3</sub>[Fe(CN)<sub>6</sub>] DTGC unit with remarkable performance metrics of an open-circuit voltage of 220 mV, a power density of 1.73 mW m<sup>−2</sup> K<sup>−2</sup>, and a relative Carnot efficiency (<em>η</em><sub>r</sub>) of 1.34 % at ΔT = 10 K, representing a tenfold improvement over conventional TGCs. Scaling up this technology, we demonstrate a modular thermoelectric generator comprising a 4 × 12 array of alternating p-type and n-type DTGCs, capable of delivering an output voltage exceeding 11.3 V at ΔT = 20 K, sufficient to directly power commercial LED lights and electronic displays. This work establishes a new paradigm for efficient low-grade thermal energy conversion, offering a scalable and practical solution for waste heat recovery applications.</div></div>","PeriodicalId":394,"journal":{"name":"Nano Energy","volume":"142 ","pages":"Article 111189"},"PeriodicalIF":16.8,"publicationDate":"2025-05-28","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"144153975","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":1,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}