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Polyanionic Hydrogel Electrolytes to Regulate Ion Transport Behavior in Long Cycle Life Zinc-ion Batteries 聚阴离子水凝胶电解质调节长循环寿命锌离子电池中的离子传输行为
IF 17.6 1区 材料科学
Nano Energy Pub Date : 2025-06-27 DOI: 10.1016/j.nanoen.2025.111284
Yufan Lei, Fangfei Liu, Lizhi Chen, Minghui Xu, Yubo Hu, Tursun Abdiryim, Feng Xu, Jiangan You, Yun Tan, Zhouliang Tan, Xiong Liu
{"title":"Polyanionic Hydrogel Electrolytes to Regulate Ion Transport Behavior in Long Cycle Life Zinc-ion Batteries","authors":"Yufan Lei, Fangfei Liu, Lizhi Chen, Minghui Xu, Yubo Hu, Tursun Abdiryim, Feng Xu, Jiangan You, Yun Tan, Zhouliang Tan, Xiong Liu","doi":"10.1016/j.nanoen.2025.111284","DOIUrl":"https://doi.org/10.1016/j.nanoen.2025.111284","url":null,"abstract":"The practical implementation of aqueous zinc-ion batteries (ZIBs) is distinctly hindered by the intrinsic challenges concerned with Zn anodes, primarily manifested through two key issues: (1) the occurrence of irreversible side reactions at the electrode-electrolyte interface and (2) the formation and growth of dendritic structures during electrochemical cycles. Herein, a sulfonate-based polyanionic hydrogel electrolyte with good adhesion and mechanical properties is designed for building dendrite-free and long cycle life ZIBs. The introduction of anion moieties induces the partial substitution of coordinated water molecules in Zn (H<ce:inf loc=\"post\">2</ce:inf>O)<ce:inf loc=\"post\">6</ce:inf><ce:sup loc=\"post\">2+</ce:sup>, promoting the reorganization of the solvation environment around Zn<ce:sup loc=\"post\">2+</ce:sup> and facilitating the ion transport kinetics and Zn<ce:sup loc=\"post\">2+</ce:sup> diffusion. The anionic macromolecular structure effectively regulates the potential distribution at the electrode-electrolyte interface, minimizing parasitic reactions and alleviating dendrite growth. The Zn symmetric cells employing the polyanionic hydrogel electrolyte exhibit the long-term electrochemical stability, maintaining the stable zinc plating/stripping cycles over 3300<ce:hsp sp=\"0.25\"></ce:hsp>h at 1<ce:hsp sp=\"0.25\"></ce:hsp>mA<ce:hsp sp=\"0.25\"></ce:hsp>cm<ce:sup loc=\"post\">-2</ce:sup> and 1100<ce:hsp sp=\"0.25\"></ce:hsp>h at 5<ce:hsp sp=\"0.25\"></ce:hsp>mA<ce:hsp sp=\"0.25\"></ce:hsp>cm<ce:sup loc=\"post\">-2</ce:sup>. When configured as full cells with Zn//NVO/MWCNTs cathodes, the system delivers superior specific capacity and remarkable cycling performance. This work provides new insights for developing the advanced hydrogel-based electrolyte systems to address the Zn anode instability and safety issues in aqueous ZIBs.","PeriodicalId":394,"journal":{"name":"Nano Energy","volume":"46 1","pages":"111284"},"PeriodicalIF":17.6,"publicationDate":"2025-06-27","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"144515741","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":1,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Trace Crystal Water Reinforces Mn−N Bonds to Achieve Structurally Stable Sodium Manganese Hexacyanoferrates for Sodium-Ion Batteries 微量结晶水增强Mn - N键,以实现钠离子电池结构稳定的六氰高铁锰酸钠
IF 17.6 1区 材料科学
Nano Energy Pub Date : 2025-06-27 DOI: 10.1016/j.nanoen.2025.111285
Wenbo Wang, Xinxin Zhu, Tengteng Qin, Zhen Pei, Zhou Xu, Juncheng Bi, Jingran Yin, Tiantian Li, Xingzhong Guo, Jun Lu
{"title":"Trace Crystal Water Reinforces Mn−N Bonds to Achieve Structurally Stable Sodium Manganese Hexacyanoferrates for Sodium-Ion Batteries","authors":"Wenbo Wang, Xinxin Zhu, Tengteng Qin, Zhen Pei, Zhou Xu, Juncheng Bi, Jingran Yin, Tiantian Li, Xingzhong Guo, Jun Lu","doi":"10.1016/j.nanoen.2025.111285","DOIUrl":"https://doi.org/10.1016/j.nanoen.2025.111285","url":null,"abstract":"Sodium manganese hexacyanoferrates (MnHCF) featuring high specific capacity and low cost are highly promising cathode materials for sodium-ion batteries (SIBs). However, the structural instability of MnHCF severely limits its practical application in SIBs, while the controversial role of trace crystal water in stabilizing its framework further complicates performance optimization. In this work, the effects of varying crystal water content on the structure and electrochemical performance of MnHCF materials were systematically investigated. The results indicated that rhombohedral MnHCF with trace crystal water (R-MnHCF-W) exhibits superior structural stability compared to monoclinic MnHCF (M-MnHCF) with abundant crystal water and anhydrous MnHCF (R-MnHCF-0). The trace crystal water compensates for structural vacancies and strengthens Mn−N bonds, effectively mitigating Mn<ce:sup loc=\"post\">3+</ce:sup> dissolution. Specifically, the R-MnHCF-W cathode exhibits excellent electrochemical performances with a remarkable reversible capacity of 157.0 mAh g<ce:sup loc=\"post\">-1</ce:sup> and maintains 79.6% capacity retention after 100 cycles at 0.2<ce:hsp sp=\"0.25\"></ce:hsp>C. Notably, R-MnHCF-W would transform into M-MnHCF when exposed to moist air, and they can be reversibly restored to R-MnHCF through heat treatment, almost retaining the pristine electrochemical performance. This study elucidates the stabilizing role of trace crystal water and provides a strategic pathway for optimizing MnHCF cathodes.","PeriodicalId":394,"journal":{"name":"Nano Energy","volume":"657 1","pages":"111285"},"PeriodicalIF":17.6,"publicationDate":"2025-06-27","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"144515740","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":1,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Fully self-powered pipeline leakage detection and localization enabled by triboelectric nanogenerator 摩擦电纳米发电机实现全自供电管道泄漏检测和定位
IF 16.8 1区 材料科学
Nano Energy Pub Date : 2025-06-26 DOI: 10.1016/j.nanoen.2025.111280
Yuntao Cheng , Kaixian Li , Siqi Gong , Xue Wang , Meng Li , Kuan Sun , Chenguo Hu , Xindan Hui , Hengyu Guo
{"title":"Fully self-powered pipeline leakage detection and localization enabled by triboelectric nanogenerator","authors":"Yuntao Cheng ,&nbsp;Kaixian Li ,&nbsp;Siqi Gong ,&nbsp;Xue Wang ,&nbsp;Meng Li ,&nbsp;Kuan Sun ,&nbsp;Chenguo Hu ,&nbsp;Xindan Hui ,&nbsp;Hengyu Guo","doi":"10.1016/j.nanoen.2025.111280","DOIUrl":"10.1016/j.nanoen.2025.111280","url":null,"abstract":"<div><div>An accurate and reliable leakage detection and localization system is essential for reducing resource waste and potentially hazardous incidents caused by leaks in industrial transportation pipelines. However, existing technologies often entail high implementation costs and reliance on external power sources, limiting their widespread industrial adoption. Here, we propose a cost-efficient, battery-free pipeline leakage detection device comprising a vibration-driven triboelectric nanogenerator (VD-TENG), an energy storage/release management circuit (EMC), and a wireless transmission module. The VD-TENG effectively harvests micro-vibrations from pipeline leaks into electricity, converting them into periodic pulse signals on the user interface via the EMC and wireless module, with the signal frequency determined by the vibration amplitude. The system accumulates a minimum electrical energy of 4.5 mJ to emit a pulse signal and demonstrates excellent stability. Ultimately, multiple integrated devices are uniformly deployed across the pipeline surface, forming a comprehensive sensing network. By leveraging the vibration attenuation characteristics along the pipeline, the leakage location can be accurately identified through analyzing the signal frequency relation among the devices. This work offers an alternative solution to the challenges in industrial pipeline leakage detection and location.</div></div>","PeriodicalId":394,"journal":{"name":"Nano Energy","volume":"142 ","pages":"Article 111280"},"PeriodicalIF":16.8,"publicationDate":"2025-06-26","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"144488748","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":1,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Engineering durable nitrate-enriched solvation sheaths in carbonate electrolytes through functional separator design for high-voltage lithium metal batteries 通过高压锂金属电池功能分离器设计碳酸盐电解质中持久的硝酸盐富集溶剂化护套
IF 16.8 1区 材料科学
Nano Energy Pub Date : 2025-06-26 DOI: 10.1016/j.nanoen.2025.111283
Can Liao , Tuning Zheng , Junfei Zhu , Xin Lin , Song Duan , Jianhua Xiao , Wei Wang , Yun Zheng , Wei Yan , Jiujun Zhang
{"title":"Engineering durable nitrate-enriched solvation sheaths in carbonate electrolytes through functional separator design for high-voltage lithium metal batteries","authors":"Can Liao ,&nbsp;Tuning Zheng ,&nbsp;Junfei Zhu ,&nbsp;Xin Lin ,&nbsp;Song Duan ,&nbsp;Jianhua Xiao ,&nbsp;Wei Wang ,&nbsp;Yun Zheng ,&nbsp;Wei Yan ,&nbsp;Jiujun Zhang","doi":"10.1016/j.nanoen.2025.111283","DOIUrl":"10.1016/j.nanoen.2025.111283","url":null,"abstract":"<div><div>Dendrite growth and high-voltage capacity fade conundrums persist as key barriers in lithium-metal batteries (LMBs). Although LiNO<sub>3</sub> effectively optimizes interfacial chemistry as an electrolyte additive, its application remains hampered by limited carbonate-electrolyte solubility and self-depleting behavior during extended cycling. This study presents an innovative interfacial engineering strategy through the strategic incorporation of LiNO<sub>3</sub>-impregnated hollow mesoporous silica composites (HMS@LiNO<sub>3</sub>) onto separator surfaces to achieve dual-interface modulation. Capitalizing on the strong adsorption capability of HMS within the high-dielectric ethylene carbonate, a nitrate-rich solvation structure is lastingly established at the anode interface. The configuration facilitates the formation of a Li<sub>3</sub>N-enriched solid electrolyte interphase with superior ionic conductivity, effectively enhancing lithium deposition kinetics while inhibiting dendritic growth. Concurrently, the cathode interface benefits from a controlled nitrate-lean solvation sheath that preferentially undergoes oxidative decomposition, generating a robust protective layer to mitigate electrolyte decomposition under 4.5 V operation. As a result, the lifetime in Li plating/stripping exceeds 1800 h and the average Coulombic efficiency is as high as 98.25 % over 350 cycles. The matched NCM811//Li full cell exhibits a high-capacity retention rate of 80.38 % after 500 cycles at a cut-off voltage of 4.5 V, providing valuable guidance into the development of long-life high-voltage LMBs.</div></div>","PeriodicalId":394,"journal":{"name":"Nano Energy","volume":"142 ","pages":"Article 111283"},"PeriodicalIF":16.8,"publicationDate":"2025-06-26","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"144488582","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":1,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
A miniaturized fully enclosed spherical triboelectric and electromagnetic hybrid generator for multidimensional low-frequency vibration energy harvesting 一种用于多维低频振动能量收集的小型化全封闭球形摩擦电电磁混合发电机
IF 16.8 1区 材料科学
Nano Energy Pub Date : 2025-06-26 DOI: 10.1016/j.nanoen.2025.111281
Mingkun Huang , Weiqiang Liao , Jiaqi Shi , Xiaoming Huang , Xiangming Gao , Zhao Ding , Shishang Guo
{"title":"A miniaturized fully enclosed spherical triboelectric and electromagnetic hybrid generator for multidimensional low-frequency vibration energy harvesting","authors":"Mingkun Huang ,&nbsp;Weiqiang Liao ,&nbsp;Jiaqi Shi ,&nbsp;Xiaoming Huang ,&nbsp;Xiangming Gao ,&nbsp;Zhao Ding ,&nbsp;Shishang Guo","doi":"10.1016/j.nanoen.2025.111281","DOIUrl":"10.1016/j.nanoen.2025.111281","url":null,"abstract":"<div><div>This paper presents a miniaturized fully enclosed spherical triboelectric and electromagnetic hybrid Generator (MFES-TEHG) that introduces a novel working mechanism for harvesting multidimensional low-frequency (≤5 Hz) vibration energy. Compared to previous designs, it is extremely easy to trigger, and any small vibration can be picked up. The device effectively collects vibration energy from various environmental sources, including low-frequency vibrations from mechanical equipment, human biomechanical energy, and wave energy. The fully enclosed spherical design allows the generator to operate stably under vibrations from different directions and effectively handle irregular and complex vibration sources in extreme and harsh environments. Additionally, the nanofibers produced through electrospinning technology enhance the triboelectric performance of the materials. To demonstrate the capability of MFES-TEHG in environmental vibration energy harvesting, a 120 mAh lithium battery was successfully charged to 3.2 V within 36 min, providing stable power to support various mechanical sensors for real-time monitoring of equipment operating conditions. It also collects multidirectional vibration energy during human movement, sustainably driving wearable bioelectronic devices for monitoring multiple physiological parameters. Furthermore, it successfully harvested wave energy to autonomously power smart monitoring systems for water environment parameters. The design of MFES-TEHG is expected to provide more efficient and stable power support for low-power electronic devices, driving the continuous development of fields such as structural health monitoring, smart health monitoring, and water environment monitoring.</div></div>","PeriodicalId":394,"journal":{"name":"Nano Energy","volume":"142 ","pages":"Article 111281"},"PeriodicalIF":16.8,"publicationDate":"2025-06-26","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"144488752","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":1,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Visible droplet luminescence in daylight 日光中可见的微滴发光
IF 17.6 1区 材料科学
Nano Energy Pub Date : 2025-06-26 DOI: 10.1016/j.nanoen.2025.111282
Shicai Zhu, Xuefeng Xu, Liran Ma, Yu Tian
{"title":"Visible droplet luminescence in daylight","authors":"Shicai Zhu, Xuefeng Xu, Liran Ma, Yu Tian","doi":"10.1016/j.nanoen.2025.111282","DOIUrl":"https://doi.org/10.1016/j.nanoen.2025.111282","url":null,"abstract":"Droplet luminescence (DL), which is based on the coupling of contact electrification and electroluminescence, has great potential in various fields owing to its unique motion-driven optical response. However, the current DL method is limited by its weak intensity, complex structure, and laborious techniques. In this study, intense DL, visible even in daylight, was realized using a facile method. An exact multi-physics simulation confirmed that DL could be directly excited by the interfacial electric field in liquid-solid contact without any pretreatment. A relevant strategy of semi-embedding luminescent particles in ultra-thin polymer film was proposed to ensure sufficient liquid-solid contact to transfer the interfacial charge and maximize the direct excitation of luminescent particles by the interfacial electric field. This bright DL demonstrates considerable potential for practical applications in sensors, display, and information storage. More importantly, this DL throws a light onto the liquid-solid interface for visualizing the dynamic process of charge transfer throughout the liquid-solid contact, which may provide insights for the exploration of interfacial charge transfer.","PeriodicalId":394,"journal":{"name":"Nano Energy","volume":"106 1","pages":""},"PeriodicalIF":17.6,"publicationDate":"2025-06-26","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"144515743","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":1,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Li6Zn0.5Co0.5O4 with high oxygen oxidation reaction activity as a cathode pre-lithiation material for lithium-ion batteries 具有高氧氧化反应活性的Li6Zn0.5Co0.5O4作为锂离子电池正极预锂化材料
IF 16.8 1区 材料科学
Nano Energy Pub Date : 2025-06-25 DOI: 10.1016/j.nanoen.2025.111278
Naifeng Wen , Jie Li , Xianggang Gao , Bin Zhu , Chaohong Guan , Zhian Zhang
{"title":"Li6Zn0.5Co0.5O4 with high oxygen oxidation reaction activity as a cathode pre-lithiation material for lithium-ion batteries","authors":"Naifeng Wen ,&nbsp;Jie Li ,&nbsp;Xianggang Gao ,&nbsp;Bin Zhu ,&nbsp;Chaohong Guan ,&nbsp;Zhian Zhang","doi":"10.1016/j.nanoen.2025.111278","DOIUrl":"10.1016/j.nanoen.2025.111278","url":null,"abstract":"<div><div>Antifluorite hyper-lithiated metal oxides have the ability to release numerous lithium ions to compensate for active lithium loss (ALL) through a potential oxygen oxidation reaction (OOR). Nevertheless, developing antifluorite hyper-lithiated metal oxides with high specific capacity and significant OOR is a challenge. Here we construct a novel antifluorite dual metal oxide pre-lithiation material (Li<sub>6</sub>Zn<sub>0.5</sub>Co<sub>0.5</sub>O<sub>4</sub>) with a high charge specific capacity of 802.7 mAh g<sup>−1</sup> below 4.5 V. The weakened chemical bond and energy band rearrangement through Co<sup>2+</sup> substitution in the Li<sub>6</sub>ZnO<sub>4</sub> framework stimulate the OOR activity. However, it suffers from the inevitable structural degradation upon storage in air, which needs to be addressed. Finally, by coupling the pre-lithiation layer, the NCM811||Si/C full cell achieves higher reversible capacity and better cycle life. This study provides a promising strategy to design hyper-lithiated metal oxides with irreversible OOR by simply introducing transition metal ions capable of weakening the chemical bond and elevating the Fermi energy level into the antifluorite framework.</div></div>","PeriodicalId":394,"journal":{"name":"Nano Energy","volume":"142 ","pages":"Article 111278"},"PeriodicalIF":16.8,"publicationDate":"2025-06-25","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"144479617","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":1,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Empowering perovskite modules for solar and indoor lighting applications by 1,8-diiodooctane/phenethylammonium iodide 2D perovskite passivation strategy 通过1,8-二碘辛烷/苯乙基碘化铵2D钙钛矿钝化策略,为太阳能和室内照明应用赋予钙钛矿模块
IF 16.8 1区 材料科学
Nano Energy Pub Date : 2025-06-25 DOI: 10.1016/j.nanoen.2025.111279
Francineide Lopes de Araujo , Maurizio Stefanelli , Antonio Agresti , Sara Pescetelli , Alessia Di Vito , Matthias Auf Der Maur , Luigi Vesce , Ana Flavia Nogueira , Aldo Di Carlo
{"title":"Empowering perovskite modules for solar and indoor lighting applications by 1,8-diiodooctane/phenethylammonium iodide 2D perovskite passivation strategy","authors":"Francineide Lopes de Araujo ,&nbsp;Maurizio Stefanelli ,&nbsp;Antonio Agresti ,&nbsp;Sara Pescetelli ,&nbsp;Alessia Di Vito ,&nbsp;Matthias Auf Der Maur ,&nbsp;Luigi Vesce ,&nbsp;Ana Flavia Nogueira ,&nbsp;Aldo Di Carlo","doi":"10.1016/j.nanoen.2025.111279","DOIUrl":"10.1016/j.nanoen.2025.111279","url":null,"abstract":"<div><div>To accelerate commercialization of perovskite technology and its use in multiple application fields, several device processing strategies have been developed. These efforts primarily target scaling-up device fabrication for mass production and enhancing performance for different light sources (sun or indoor light). This work presents a novel 3D/2D perovskite heterostructure by depositing a mixed layer of phenethylammonium iodide (PEAI) and 1,8-diiodooctane (DIO) directly atop the 3D perovskite absorber without a further annealing step. The addition of DIO enables the formation of pure 2D PEA₂PbI₄ 4 (n = 1) at room temperature, leading to defect passivation of 3D perovskite surface, improvement in the crystallinity of 2D perovskite, and optimizing the dipole moment at perovskite/hole transport interface. Large-area PSC modules treated with PEAI:DIO achieve remarkable power conversion efficiencies of 17.7 % (32 cm²) and 15.6 % (121 cm²) under 1Sun irradiation. When exposed to indoor illumination with various LED intensities (200, 500 and 1000 lux) the PEAI:DIO engineered module demonstrated efficiency approaching 34 %, among the highest reported so far for large area modules employing perovskite with bandgap below 1.7 eV. Long-term stability tests following the ISOS-D-1 protocol reveal a threefold increase in T<sub>80</sub> lifetime compared to untreated devices.</div></div>","PeriodicalId":394,"journal":{"name":"Nano Energy","volume":"142 ","pages":"Article 111279"},"PeriodicalIF":16.8,"publicationDate":"2025-06-25","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"144488847","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":1,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Advancing perovskite light-emitting diodes: Multifunctional role of polymer, organic, and inorganic ligands in stability and efficiency enhancement 改进钙钛矿发光二极管:聚合物、有机和无机配体在稳定性和效率提高中的多功能作用
IF 16.8 1区 材料科学
Nano Energy Pub Date : 2025-06-25 DOI: 10.1016/j.nanoen.2025.111272
Muhammad Imran Saleem , Attia Batool , Jaehyun Hur
{"title":"Advancing perovskite light-emitting diodes: Multifunctional role of polymer, organic, and inorganic ligands in stability and efficiency enhancement","authors":"Muhammad Imran Saleem ,&nbsp;Attia Batool ,&nbsp;Jaehyun Hur","doi":"10.1016/j.nanoen.2025.111272","DOIUrl":"10.1016/j.nanoen.2025.111272","url":null,"abstract":"<div><div>Metal halide perovskites have revolutionized semiconductor optoelectronics and are emerging as exceptional candidates for high-performance perovskite light-emitting diodes (PeLEDs) owing to their outstanding properties including high color purity, narrow emission width (15–20 nm), tunable photoluminescence, and cost-effective solution processability. Despite these advantages, the widespread adoption of PeLEDs remains hindered by critical challenges, particularly their limited operational stability. In this review, we provide a comprehensive analysis of the recent advancements in stabilizing perovskite LEDs, focusing on the role of polymeric additives and inorganic and organic ligands in enhancing their operational half-lifetime (<em>T</em><sub><em>50</em></sub>). These strategies have been demonstrated to influence the device performance, including the suppression of ion migration, reduction of interfacial hydrophilicity, minimization of nonradiative exciton recombination, and balancing of carrier injection, thereby facilitating improved carrier dynamics and enhancing both efficiency and stability. This review highlights the critical roles of polymeric additives, as well as inorganic and organic ligands, in addressing the key limitations of perovskite emitters and offers new perspectives for their integration into commercially viable optoelectronic applications.</div></div>","PeriodicalId":394,"journal":{"name":"Nano Energy","volume":"142 ","pages":"Article 111272"},"PeriodicalIF":16.8,"publicationDate":"2025-06-25","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"144488846","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":1,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Synaptic metaplasticity and associative learning in low-power neuromorphic computing using W-diffused BaTiO₃ memristors 基于w扩散BaTiO₃记忆电阻器的低功耗神经形态计算中的突触元可塑性和联想学习
IF 16.8 1区 材料科学
Nano Energy Pub Date : 2025-06-24 DOI: 10.1016/j.nanoen.2025.111276
Muhammad Ismail , Hyesung Na , Maria Rasheed , Chandreswar Mahata , Yoon Kim , Sungjun Kim
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