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Columnar structure solid-liquid nanogenerator based on triboiontronics 基于摩擦电子的柱状结构固液纳米发电机
IF 17.1 1区 材料科学
Nano Energy Pub Date : 2026-04-01 Epub Date: 2026-02-07 DOI: 10.1016/j.nanoen.2026.111783
Yan Xia , Cuiying Ye , Rongbing Han , Qiqi Ming , Pengfei Chen , Xu Zhang , Tao Jiang
{"title":"Columnar structure solid-liquid nanogenerator based on triboiontronics","authors":"Yan Xia ,&nbsp;Cuiying Ye ,&nbsp;Rongbing Han ,&nbsp;Qiqi Ming ,&nbsp;Pengfei Chen ,&nbsp;Xu Zhang ,&nbsp;Tao Jiang","doi":"10.1016/j.nanoen.2026.111783","DOIUrl":"10.1016/j.nanoen.2026.111783","url":null,"abstract":"<div><div>Triboiontronics has been proposed in recent years, which realizes the synergistic coupling of ion-electron by adjusting electrical double layer (EDL), and plays significant roles in biological signal transmission, human-machine interaction, energy harvesting, etc. In this work, by changing dielectric substrate and liquids to regulate EDL, we studied the effects of dielectric substrate and liquid on the electron and ion motion behavior, and proposed a columnar structure solid-liquid triboiontronic nanogenerator (TING). By detailly analyzing the effect of dielectric substrate and ion concentration on the output performance of TING, we found that the polyvinyl chloride/platinum (PVC/Pt) surface has the optimal output performance with ion solution. Using the active copper film to replace the bottom solid surface of PVC/Pt, the metal-based TING (M-TING) generated the highest transferred charge density of 2348.05 mC m<sup>−2</sup>. Finally, the columnar structure direct-current TING (CD-TING) was developed to harvest environment mechanical energy, and exhibited an excellent output of 22.20 mC min<sup>−1</sup> using 1 mol L<sup>−1</sup> NaCl solution and rapid charging capability. This work deepens the understanding of triboiontronics and provides practical and efficient strategy for harvesting environmental distributed mechanical energy.</div></div>","PeriodicalId":394,"journal":{"name":"Nano Energy","volume":"150 ","pages":"Article 111783"},"PeriodicalIF":17.1,"publicationDate":"2026-04-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"146135242","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":1,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Evaporative hydrogels for high-performance ambient body heat harvesting via thermoelectric 蒸发水凝胶,用于通过热电收集高性能环境体热
IF 17.1 1区 材料科学
Nano Energy Pub Date : 2026-04-01 Epub Date: 2026-02-05 DOI: 10.1016/j.nanoen.2026.111780
Zichen Gong , Jinfeng Dong , Soe Ko Ko Aung , Thang Bach Phan , Qi Qian , Tosawat Seetawan , Surasak Ruamruk , Yujie Ke , Bhuvanesh Srinivasan , Zhaogang Dong , Sai Kishore Ravi , Ady Suwardi , Jing Cao
{"title":"Evaporative hydrogels for high-performance ambient body heat harvesting via thermoelectric","authors":"Zichen Gong ,&nbsp;Jinfeng Dong ,&nbsp;Soe Ko Ko Aung ,&nbsp;Thang Bach Phan ,&nbsp;Qi Qian ,&nbsp;Tosawat Seetawan ,&nbsp;Surasak Ruamruk ,&nbsp;Yujie Ke ,&nbsp;Bhuvanesh Srinivasan ,&nbsp;Zhaogang Dong ,&nbsp;Sai Kishore Ravi ,&nbsp;Ady Suwardi ,&nbsp;Jing Cao","doi":"10.1016/j.nanoen.2026.111780","DOIUrl":"10.1016/j.nanoen.2026.111780","url":null,"abstract":"<div><div>The increasing demand in power of modern environmental and health sensors have spurred the development of ambient energy harvesting to reduce reliance in battery. Thermoelectric generators (TEGs) are a promising technology, which convert waste or body heat into electricity. However, their power output is severely limited by the thermal impedance mismatch, particularly between the human skin and TEG interface. This work introduces a novel approach to overcome this limitation by integrating a hydrogel into the TEG system. It has been revealed that the enthalpy from the hydrogel's water evaporation effectively achieves thermal impedance matching while simultaneously maximizing the heat flux. Furthermore, by optimizing the TEG's fill-factor, we increased the power density by nearly two orders of magnitude compared to conventional TEG systems. As a proof of concept, our device combined body heat with hydrogel evaporation using an optimized fill-factor of 0.48 (using 52 % less material). This setup achieved a power density of 150 μWcm⁻², which was sufficient to power four wireless sensors. This work demonstrates a counter-intuitive synergistic benefit, that is achieving superior thermal matching while significantly reducing thermoelectric material usage. Our findings redefine optimization approach for TEGs and offer a viable pathway toward realizing off-grid, self-powered sensors.</div></div>","PeriodicalId":394,"journal":{"name":"Nano Energy","volume":"150 ","pages":"Article 111780"},"PeriodicalIF":17.1,"publicationDate":"2026-04-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"146135247","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":1,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Flexible sensor arrays with high-resolution and high-density 高分辨率、高密度柔性传感器阵列
IF 17.1 1区 材料科学
Nano Energy Pub Date : 2026-04-01 Epub Date: 2026-01-31 DOI: 10.1016/j.nanoen.2026.111748
Jinrong Huang , Jiahui Liu , Guoyi Zhang , Lanyu Nie , Yao Xiong , Yutian Zhu , Zhong Lin Wang , Qijun Sun
{"title":"Flexible sensor arrays with high-resolution and high-density","authors":"Jinrong Huang ,&nbsp;Jiahui Liu ,&nbsp;Guoyi Zhang ,&nbsp;Lanyu Nie ,&nbsp;Yao Xiong ,&nbsp;Yutian Zhu ,&nbsp;Zhong Lin Wang ,&nbsp;Qijun Sun","doi":"10.1016/j.nanoen.2026.111748","DOIUrl":"10.1016/j.nanoen.2026.111748","url":null,"abstract":"<div><div>Flexible sensor arrays, as core components for high-precision perception and distributed signal acquisition, are rapidly evolving toward higher resolution and greater integration. High-resolution arrays enable fine-grained spatial mapping, while densely integrated layouts enhance overall sensing coverage and functionality. However, these advances also introduce challenges such as complex interconnect routing, increased signal crosstalk, and attenuation of signal fidelity. This review summarizes the recent five-year progress in the design of high-resolution, highly integrated flexible sensor arrays, emphasizing structural strategies to improve spatial resolution, microstructure-engineered sensing mechanisms, and scalable interconnection architectures. It further discusses multi-level approaches to maintain signal integrity through synergistic optimization of materials, circuit design, and algorithms. Representative studies demonstrate how high-density arrays enable skin-like tactile feedback, multimodal perception, and biomedical monitoring. Finally, this review outlines emerging directions in scalable array manufacturing, intelligent signal decoupling, and AI-driven tactile systems. Overall, it provides a comprehensive overview of the latest technological trends and offers systematic insights into the convergence of flexible electronics and embodied intelligence.</div></div>","PeriodicalId":394,"journal":{"name":"Nano Energy","volume":"150 ","pages":"Article 111748"},"PeriodicalIF":17.1,"publicationDate":"2026-04-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"146095936","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":1,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
High-loading dual-atom iron catalysts via host-guest nested architecture 基于主-客嵌套结构的高负载双原子铁催化剂
IF 17.1 1区 材料科学
Nano Energy Pub Date : 2026-04-01 Epub Date: 2026-01-27 DOI: 10.1016/j.nanoen.2026.111755
Xingru Yan , Zhiyuan Yang , Jingchi Gao , Qi Yu , Jingxiang Yang , Ruiqiao Wu , Changshui Huang
{"title":"High-loading dual-atom iron catalysts via host-guest nested architecture","authors":"Xingru Yan ,&nbsp;Zhiyuan Yang ,&nbsp;Jingchi Gao ,&nbsp;Qi Yu ,&nbsp;Jingxiang Yang ,&nbsp;Ruiqiao Wu ,&nbsp;Changshui Huang","doi":"10.1016/j.nanoen.2026.111755","DOIUrl":"10.1016/j.nanoen.2026.111755","url":null,"abstract":"<div><div>Dual-atom catalysts (DACs) have emerged as a frontier in electrocatalysis, offering unique active site geometries and exceptional performance across diverse electrochemical reactions. However, simultaneously achieving high metal loading while maintaining atomic precision in diatomic site synthesis remains a critical challenge. Here, we report a host-guest nested architecture strategy to synthesize high-loading dual-atom Fe catalysts with atomic precision. By leveraging graphdiyne (GDY)’s electron-rich sp-carbon bonding network and intrinsic triangular cavities as a host matrix, we covalently embed Fe<sub>2</sub>(CO)<sub>9</sub> guest molecules into its voids, enabling precise nesting of Fe<sub>2</sub> pairs at cavity centers. The resulting Fe<sub>2</sub>-N-GDY catalyst achieves an ultra high diatomic Fe loading of 16.2 wt%, while maintaining a well-defined 2.6 Å Fe-Fe spacing. This structure delivers exceptional oxygen reduction reaction (ORR) performance, with a half-wave potential of 0.92 V and limiting current density of 6.0 mA cm<sup>−2</sup>. In situ characterization reveal that due to the form of paired atoms, atomic Fe sites synergistically reduce the O-O bond cleavage energy barrier, accelerating the *OOH → *O + *OH conversion pathway and enhancing 4-electron selectivity. This work provides a route for designing high-loading DACs and elucidating their reaction mechanisms in electrochemical catalysis via targeted host-guest nested engineering, with insights into their structure performance relationships.</div></div>","PeriodicalId":394,"journal":{"name":"Nano Energy","volume":"150 ","pages":"Article 111755"},"PeriodicalIF":17.1,"publicationDate":"2026-04-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"146056530","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":1,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Controllable homogeneous oxygen crosslinking in pitch for high-performance sodium-ion batteries by sequential air-acid-air oxidation 采用序贯空气-酸-空气氧化法制备高性能钠离子电池沥青中可控均质氧交联
IF 17.1 1区 材料科学
Nano Energy Pub Date : 2026-04-01 Epub Date: 2026-01-23 DOI: 10.1016/j.nanoen.2026.111752
Yuhan Liu , Xueyan Kang , Qianxun Li , Wanran Lin , Ruohong Bian , Peiyuan Ye , Jiongjiong Li , Jiannan Pei , Feng Jiang , Hao Yang , Zhouguang Lu , Zhenghe Xu
{"title":"Controllable homogeneous oxygen crosslinking in pitch for high-performance sodium-ion batteries by sequential air-acid-air oxidation","authors":"Yuhan Liu ,&nbsp;Xueyan Kang ,&nbsp;Qianxun Li ,&nbsp;Wanran Lin ,&nbsp;Ruohong Bian ,&nbsp;Peiyuan Ye ,&nbsp;Jiongjiong Li ,&nbsp;Jiannan Pei ,&nbsp;Feng Jiang ,&nbsp;Hao Yang ,&nbsp;Zhouguang Lu ,&nbsp;Zhenghe Xu","doi":"10.1016/j.nanoen.2026.111752","DOIUrl":"10.1016/j.nanoen.2026.111752","url":null,"abstract":"<div><div>In contrast to the widely investigated biomass-derived systems, petroleum-pitch-based hard carbons face persistent challenges in balancing plateau capacity of closed pores and reversible storage efficiency of Na⁺. The difficulty originates from uncontrolled oxygen distribution and nonuniform crosslinking during preoxidation, which lead to undesired coking and limited pore confinement after carbonization. Herein, we introduce a sequential air-acid-air (AAA) pulsed strategy that programs oxygen flux to achieve homogeneous crosslinking in low-softening-point petroleum pitch before carbonization. Short liquid-oxidation pulses with intermediate drying suppress surface densification and guide the controlled uptake and staged removal of oxygenated groups. The resulting microstructure features confined voids and interlocking edge defects with tuned interlayer spacing, enabling fast Na<sup>+</sup> transport and plateau storage. Combining high capacity and durability, the optimized AAA-PHC-1400 achieves a Na<sup>+</sup> storage capacity of 392.9 mAh g<sup>−1</sup> with an 87.4 % initial Coulombic efficiency (ICE) and retains 89.0 % of its original capacity after 2900 cycles, while Na<sub>3</sub>V<sub>2</sub>(PO<sub>4</sub>)<sub>2</sub>F<sub>3</sub> (NVPF)|AAA-PHC-1400 full cells maintain 86.6 % of its original capacity after 100 cycles. By varying the liquid oxidant chemistry and concentration, terminal pre-oxidation temperature and carbonization temperature, we mapped out a practical process window of linking sequence parameters with pore architecture and electrochemical metrics. Mechanistic evidence from <em>in-situ</em> Raman tracking of band shifts during sodiation, together with EPR and XPS signatures of paramagnetic species at low potentials, corroborates a plateau storage pathway arising from confined pores and tuned interlayer spacing. This work elevates pitch pre-oxidation from empirical practice to a sequence-encoded design principle, providing a scalable route of manufacturing high-performance hard carbon anode materials.</div></div>","PeriodicalId":394,"journal":{"name":"Nano Energy","volume":"150 ","pages":"Article 111752"},"PeriodicalIF":17.1,"publicationDate":"2026-04-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"146047867","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":1,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
High-performance self-polarized PVDF film based on one-dimensional core-shell nanofiller and direct ink writing 3D printing 基于一维核壳纳米填料和直接墨水书写3D打印的高性能自极化PVDF薄膜
IF 17.1 1区 材料科学
Nano Energy Pub Date : 2026-04-01 Epub Date: 2026-02-01 DOI: 10.1016/j.nanoen.2026.111771
Huimin Qi , Siyao Qin , Zhipeng Zhang , Zifei Meng , Long Zheng , Xucong Wang , Xiangcheng Chu , Fang Wang , Li Zheng , Xiangyu Chen
{"title":"High-performance self-polarized PVDF film based on one-dimensional core-shell nanofiller and direct ink writing 3D printing","authors":"Huimin Qi ,&nbsp;Siyao Qin ,&nbsp;Zhipeng Zhang ,&nbsp;Zifei Meng ,&nbsp;Long Zheng ,&nbsp;Xucong Wang ,&nbsp;Xiangcheng Chu ,&nbsp;Fang Wang ,&nbsp;Li Zheng ,&nbsp;Xiangyu Chen","doi":"10.1016/j.nanoen.2026.111771","DOIUrl":"10.1016/j.nanoen.2026.111771","url":null,"abstract":"<div><div>The self-polarization approach for fabricating poly(vinylidene fluoride) (PVDF)-based piezoelectric materials can avoid drawbacks of post-poling treatment, such as high energy consumption, electrical breakdown, and depolarization. In this work, a core–shell nanofiller with abundant surface hydroxyl groups is prepared as the dopant for sufficiently inducing local self-polarization for the 3D printed PVDF film. Hydrogen bonding between these groups and PVDF molecular chains promotes β-phase crystallization and enables local polarization anchoring. Furthermore, the shear field at the nozzle tip of 3D printer can be utilized for orienting the nanorod-induced self-polarization. Simultaneously, the induced shear and tensile stresses facilitate PVDF molecular chain extension and β-phase crystallization, achieving macroscopic self-polarization in the out-of-plane direction. Benefiting from this synergistic strategy, the composite film exhibits excellent long-term polarization stability and a high piezoelectric coefficient of 117.3 pC/N, which exceeds all the previously reported self-polarization PVDF films. This study offers an effective strategy for developing high-performance piezoelectric composites without polarization treatment. Owing to its high piezoelectric output performance, this PVDF film can be used for mechanical energy harvesting and motion signal sensing in various conditions.</div></div>","PeriodicalId":394,"journal":{"name":"Nano Energy","volume":"150 ","pages":"Article 111771"},"PeriodicalIF":17.1,"publicationDate":"2026-04-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"146110644","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":1,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Optimizing CuSCN/photoactive interface towards efficient semitransparent organic solar cell with 55 % average visible transmittance 优化CuSCN/光活性界面,实现平均可见光透过率为55%的高效半透明有机太阳能电池
IF 17.1 1区 材料科学
Nano Energy Pub Date : 2026-04-01 Epub Date: 2026-02-05 DOI: 10.1016/j.nanoen.2026.111776
Xin Tan , Fei Xue , Xin Qin, Wei Ma, Han Yan
{"title":"Optimizing CuSCN/photoactive interface towards efficient semitransparent organic solar cell with 55 % average visible transmittance","authors":"Xin Tan ,&nbsp;Fei Xue ,&nbsp;Xin Qin,&nbsp;Wei Ma,&nbsp;Han Yan","doi":"10.1016/j.nanoen.2026.111776","DOIUrl":"10.1016/j.nanoen.2026.111776","url":null,"abstract":"<div><div>Developing highly-transparent organic solar cell (OSC) with an average visible transmittance (AVT) over 55 % and a reasonable light utilization efficiency (LUE) over 2.50 % is vital to enlarge its application scenarios for commercialization. Reducing electron-donor (D) content in photoactive layer represents a primary strategy for achieving this goal. However, the intrinsic transparent photoactive layer typically incurs exciton utilization penalty which requires the CuSCN in replacement of PEDOT:PSS to form an additional exciton splitting interface. Herein, we study the CuSCN-based OSC in the <span>D</span>-poor region for potential over 60 % AVT. Though CuSCN produces higher short-circuit current density (<em>J</em><sub><em>SC</em></sub>) than PEDOT:PSS as hole-transporting layer (HTL), the lower fill factor (FF) and its light-healing behavior suppress the power conversion efficiency (PCE) value. Detailed recombination analysis and Cu valence state comparison confirm the hole-trap at CuSCN/photoactive interface as the determinant reason for FF loss and its light-healing behavior. Targeted p-type doping close to the interface increases the FF in CuSCN-based PM6:L8-BO (0.10:1) OSC from 56.0 % to 62.1 % and mitigates the light-healing phenomenon as well as stability problem by hole-trap passivation. Taking advantage of the improved CuSCN device, a semitransparent OSC (ST-OSC) with an AVT exceeding 55 % and an appealing LUE of 2.66 % is fabricated.</div></div>","PeriodicalId":394,"journal":{"name":"Nano Energy","volume":"150 ","pages":"Article 111776"},"PeriodicalIF":17.1,"publicationDate":"2026-04-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"146135248","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":1,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Titanium tuned alluaudite sulfate cathodes assisted metastable FeNaO10 framework for wide-temperature range sodium storage 钛调谐铝矾土硫酸盐阴极辅助亚稳FeNaO10框架用于宽温度范围钠储存
IF 17.1 1区 材料科学
Nano Energy Pub Date : 2026-04-01 Epub Date: 2026-01-27 DOI: 10.1016/j.nanoen.2026.111765
Wenyuan Li , Lei Sun , Weishun Jian , Jingyao Zeng , Jinqiang Gao , Li Yang , Wentao Deng , Guoqiang Zou , Hongshuai Hou , Xiaobo Ji
{"title":"Titanium tuned alluaudite sulfate cathodes assisted metastable FeNaO10 framework for wide-temperature range sodium storage","authors":"Wenyuan Li ,&nbsp;Lei Sun ,&nbsp;Weishun Jian ,&nbsp;Jingyao Zeng ,&nbsp;Jinqiang Gao ,&nbsp;Li Yang ,&nbsp;Wentao Deng ,&nbsp;Guoqiang Zou ,&nbsp;Hongshuai Hou ,&nbsp;Xiaobo Ji","doi":"10.1016/j.nanoen.2026.111765","DOIUrl":"10.1016/j.nanoen.2026.111765","url":null,"abstract":"<div><div>Alluaudite-type Na<sub>2.6</sub>Fe<sub>1.7</sub>(SO<sub>4</sub>)<sub>3</sub> is a promising high-voltage cathode material for sodium-ion batteries (SIBs), whose practical application is severely hindered by intrinsic structural instability. To overcome this limitation, high-charge-density Ti<sup>4 +</sup> was incorporated into the Fe site to stabilize the lattice framework by modulating local electron distribution and mitigating Na<sup>+</sup> enrichment. Cationic rearrangement is effectively suppressed, primarily attributed to the Ti-induced regulation of the local Na<sup>+</sup> distribution, as revealed by CV. Furthermore, b-axis lattice distortion is remarkedly alleviated owing to the strong covalent nature of Ti-O bonds, which enhances structural stability accompanied with the introduction of the metastable FeNaO<sub>10</sub> framework, as confirmed by in-situ XRD measurements. Consequently, a high specific capacity of 71.68 mAh g<sup>−1</sup> was observed at 20 C, with 75.22 % capacity retention after 6000 cycles, and 49.19 mAh g<sup>−1</sup> was retained at −20 °C under 2 C conditions. Overall, this strategy effectively enables structural stabilization and demonstrates a widely applicable and generalizable approach for advancing high-performance SIBs.</div></div>","PeriodicalId":394,"journal":{"name":"Nano Energy","volume":"150 ","pages":"Article 111765"},"PeriodicalIF":17.1,"publicationDate":"2026-04-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"146071679","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":1,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
S/Cl Co-doped biomass-derived carbon electrocatalysts: Low ΔE of 0.58 V for ORR/OER and application in high-performance zinc-air batteries S/Cl共掺杂生物质碳电催化剂:ORR/OER低ΔE 0.58 V及其在高性能锌-空气电池中的应用
IF 17.1 1区 材料科学
Nano Energy Pub Date : 2026-04-01 Epub Date: 2026-02-09 DOI: 10.1016/j.nanoen.2026.111791
Chenfeng Lin , Xin Cao , Linlin Wang , Mingli Cai , Rui Ma , Jinfu Ma
{"title":"S/Cl Co-doped biomass-derived carbon electrocatalysts: Low ΔE of 0.58 V for ORR/OER and application in high-performance zinc-air batteries","authors":"Chenfeng Lin ,&nbsp;Xin Cao ,&nbsp;Linlin Wang ,&nbsp;Mingli Cai ,&nbsp;Rui Ma ,&nbsp;Jinfu Ma","doi":"10.1016/j.nanoen.2026.111791","DOIUrl":"10.1016/j.nanoen.2026.111791","url":null,"abstract":"<div><div>Development of efficient bifunctional electrocatalysts for oxygen reduction and oxygen evolution reactions is critical for advancing zinc-air batteries. This study introduces an innovative synthesis strategy to fabricate sulfur- and chlorine-codoped metal-free carbon catalysts, designated CTS/Cl/S, derived from chitosan biomass through single-step pyrolysis-activation. The catalyst features a three-dimensional mesoporous architecture with dual heteroatom doping. Synergistic codoping optimizes the carbon matrix electronic structure, while hierarchical mesopores enhance mass transfer and active site accessibility. Significantly, CTS/Cl/S demonstrates an ultralow Δ<em>E</em> value of 0.58 V, outperforming most documented nonprecious metal catalysts. In liquid zinc-air battery configurations, it delivers 180 mW cm⁻² peak power density, 815 mAh <span><math><msubsup><mrow><mi>g</mi></mrow><mrow><mi>Zn</mi></mrow><mrow><mo>−</mo><mn>1</mn></mrow></msubsup></math></span> specific capacity, and exceptional cycling stability exceeding 2000 h at 1 mA cm⁻² current density. Flexible battery variants also achieve 155 mW cm⁻² power density, 759 mAh <span><math><msubsup><mrow><mi>g</mi></mrow><mrow><mi>Zn</mi></mrow><mrow><mo>−</mo><mn>1</mn></mrow></msubsup></math></span> capacity, and over 200-hour durability. Coupling in-situ spectroscopic analyses with Density Functional Theory calculations, we elucidate the underlying reaction mechanism. Spectroscopic evidence explicitly captures key *OOH intermediate adsorption and desorption, thereby enhancing intrinsic catalytic activity for both oxygen reactions. This work establishes a scalable methodology for designing high-performance metal-free electrocatalysts for next-generation energy conversion devices.</div></div>","PeriodicalId":394,"journal":{"name":"Nano Energy","volume":"150 ","pages":"Article 111791"},"PeriodicalIF":17.1,"publicationDate":"2026-04-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"146146625","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":1,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Spatially confined triboelectric acupuncture drives biometric reprogramming in cutaneous wounds 空间受限摩擦电针刺驱动皮肤伤口的生物特征重编程
IF 17.1 1区 材料科学
Nano Energy Pub Date : 2026-04-01 Epub Date: 2026-02-09 DOI: 10.1016/j.nanoen.2026.111789
Saira Iqbal , Renjie Tan , Chenjie Xu, Jinlian Hu
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