SmallPub Date : 2025-04-01DOI: 10.1002/smll.202407007
Kyoungtae Kim, Taeho Moon, Jinhyun Kim
{"title":"Wide Bandgap Perovskites: A Comprehensive Review of Recent Developments and Innovations","authors":"Kyoungtae Kim, Taeho Moon, Jinhyun Kim","doi":"10.1002/smll.202407007","DOIUrl":"https://doi.org/10.1002/smll.202407007","url":null,"abstract":"Recent advances in wide-bandgap (WBG) perovskite solar cells (PSCs) demonstrate a burgeoning potential to significantly enhance photovoltaic efficiencies beyond the Shockley–Queisser limit for single-junction cells. This review explores the multifaceted improvements in WBG PSCs, focusing on novel compositions, halide substitution strategies, and innovative device architectures. The substitution of iodine with bromine and organic ions such as FA and MA with Cs in the perovskite lattice is emphasized for its effectiveness in achieving higher open-circuit voltages and reduced thermalization losses. Furthermore, the integration of advanced charge transport layers and interface engineering techniques is discussed as critical to minimizing open-circuit voltage (<i>V<sub>OC</sub></i>) deficits and improving the photo-stability of these cells. The utilization of WBG PSCs in diverse applications such as semitransparent devices, indoor photovoltaics, and multijunction tandem devices is also explored, addressing both their current limitations and potential solutions. The review culminates in a comprehensive assessment of the current challenges impeding the industrial scale-up of WBG PSC technology and offers a perspective on future research directions aimed at realizing highly efficient and stable WBG PSCs for commercial photovoltaic applications.","PeriodicalId":228,"journal":{"name":"Small","volume":"72 1","pages":""},"PeriodicalIF":13.3,"publicationDate":"2025-04-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"143745669","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":2,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
SmallPub Date : 2025-04-01DOI: 10.1002/smll.202411870
Mila N. Krstajić Pajić, Ana S. Dobrota, Anca Mazare, Slađana Đurđić, Xin Zhou, Nikita Denisov, Natalia V. Skorodumova, Dragan Manojlović, Rastko Vasilić, Igor A. Pašti, Patrik Schmuki, Uroš Lačnjevac
{"title":"Polydisperse Pt Deposits Over TiO2-Nanotube-Array-Supported Ru Nanoparticles: Harnessing the Interfacial Synergy for Efficient Hydrogen Evolution Electrocatalysis","authors":"Mila N. Krstajić Pajić, Ana S. Dobrota, Anca Mazare, Slađana Đurđić, Xin Zhou, Nikita Denisov, Natalia V. Skorodumova, Dragan Manojlović, Rastko Vasilić, Igor A. Pašti, Patrik Schmuki, Uroš Lačnjevac","doi":"10.1002/smll.202411870","DOIUrl":"https://doi.org/10.1002/smll.202411870","url":null,"abstract":"Developing cost-effective precious metal electrocatalysts for the hydrogen evolution reaction (HER) is key to realizing the economic viability of acidic water electrolysis. Herein, galvanic displacement is employed for in situ formation of bimetallic Pt/Ru deposits on H-intercalated TiO<sub>2</sub> nanotube arrays. It is found that a two-step procedure yields polydisperse deposits with a dominant fraction of Ru nanoparticles coated with atomic and subnanometric Pt islands. These Pt|Ru nanointerfaces induce charge transfer from Pt to Ru, which modulates the electronic structure of Pt sites for accelerated HER kinetics. By varying the platinization time in the second step, a balance between the exposure of catalytically active Pt|Ru nanointerfaces and the total number of Pt surface sites is achieved. The optimized composite, termed Ru-30min@Pt-30min, requires an overpotential of 58 mV to deliver a current density of 100 mA cm<sup>−2</sup> in 1.0 <span>m</span> HClO<sub>4</sub> and maintains performance stability and structure integrity under prolonged operation. Moreover, it presents a 3.5-fold increase in precious metal mass activity over Pt/C at <i>η</i> = 80 mV. Theoretical calculations reveal that the electronic interactions generated by Pt-modification of Ru and hydrogenated TiO<sub>2</sub> surfaces provide multiple active sites with improved H<sub>ads</sub> energetics compared to pure Pt and Ru.","PeriodicalId":228,"journal":{"name":"Small","volume":"103 1","pages":""},"PeriodicalIF":13.3,"publicationDate":"2025-04-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"143745672","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":2,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
SmallPub Date : 2025-04-01DOI: 10.1002/smll.202501113
Xiaogeng Lin, Li Chen, Jiawang Zhuo, Rongxin Huang, Yiming Zeng, Yasan He
{"title":"Mechanistic Insights into the Formation of Nanofibrous Covalent Organic Frameworks (COFs) and their Promotion to the Catalysis of Hydrodechlorination","authors":"Xiaogeng Lin, Li Chen, Jiawang Zhuo, Rongxin Huang, Yiming Zeng, Yasan He","doi":"10.1002/smll.202501113","DOIUrl":"https://doi.org/10.1002/smll.202501113","url":null,"abstract":"The nanoscale morphologies of COFs deeply affect their performance in practical applications. However, it still lacks studies to well understand their formation mechanism for guiding and controlling the synthesis for desired nanomorphology. To achieve more mechanistic insights into the formation of nanofibrous COFs, herein a series of nanofibrous and non-fibrous COFs are synthesized and the intrinsic relationships among the morphology, chemical constituent, structure planarity, and the DFT calculated interlayer stacking energy are investigated comprehensively. The study reveals the planarity of building monomers is not decisive for forming the nanofibrous COFs. The presence of electron-withdrawing triazine group in amine monomers and the electron-donating ─OH group in aldehyde monomers are essential for suppressing the growth of COF crystallites in <i>x-y</i> plane and promoting the stacking in <i>z</i>-direction to form nanofibrous COFs. The COF morphology can be modulated by the functional groups in monomers by regulating the competition between lateral reaction activity and interlayer stacking energy. The prepared nanofibrous COFs exhibited two-fold increased catalytic activity and better stability than the non-fibrous counterpart in hydrodechlorination. The new insights and proposed mechanism here can help open up a domain for precise designing and modulating the COF nanomorphology from molecular level for specific application.","PeriodicalId":228,"journal":{"name":"Small","volume":"58 1","pages":""},"PeriodicalIF":13.3,"publicationDate":"2025-04-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"143745762","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":2,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
SmallPub Date : 2025-04-01DOI: 10.1002/smll.202502051
Qian Zhou, Shabab Hussain, Jisong Hu, Guanghao Zhang, Wenxing Zhang, Bin Zhang, Lei Wang
{"title":"Polybenzimidazole Composite Separators Engineered from MOFs-HNTs Composites Applicated in Lithium-Ion Batteries","authors":"Qian Zhou, Shabab Hussain, Jisong Hu, Guanghao Zhang, Wenxing Zhang, Bin Zhang, Lei Wang","doi":"10.1002/smll.202502051","DOIUrl":"https://doi.org/10.1002/smll.202502051","url":null,"abstract":"Incorporating inorganic nanostructured materials into polymeric separators for lithium-ion batteries (LIBs) enhances properties such as ionic conductivity, electrolyte wettability, and thermal resistance. However, poor interfacial compatibility between inorganic materials and the polymeric matrix remains a significant challenge. In this study, Zr-based UiO-66 metal-organic frameworks (MOFs) is employed as an interfacial binder between halloysite nanotubes (HNTs) and a poly-(arylene ether benzimidazole) (OPBI) matrix, preparing porous separators using the non-solvent phase separation (NIPS) method. The UiO-66 MOFs promote strong adhesion of HNTs to the OPBI chains, creating a more cohesive inorganic-organic system, as confirmed by molecular dynamics (MD) simulations of binding energy. The resulting OPBI@M-H10 composite separator exhibits high porosity (80%), an electrolyte absorption capacity of 377%, and an ionic conductivity of 1.59 mS·cm⁻¹. Furthermore, LiFePO<sub>4</sub> half-cells assembled with this composite separator show a discharge capacity of 161 mAh·g⁻¹ and a retention rate of 97.96% after 200 charge-discharge cycles. The separator also demonstrates excellent electrode stability in the plating/stripping test of Li symmetric cells, lasting up to 1600 hours and effectively inhibiting dendrite growth on the Li anode. This approach provides a promising solution for high-performance LIBs separators and paves the way for advancements in LIBs technology and energy storage applications.","PeriodicalId":228,"journal":{"name":"Small","volume":"134 1","pages":""},"PeriodicalIF":13.3,"publicationDate":"2025-04-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"143745473","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":2,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
SmallPub Date : 2025-04-01DOI: 10.1002/smll.202412177
Qing Zhang, Di Qin, Chengyang Liu, Zeqiang Chen, Xuelin Gong, Shuang Wang, Ruipeng Gao, Sun Yu, Jiaojiao Qi, Yusheng Niu, Shichao Xing, Shichao Bi, Bo Tang
{"title":"Injectable Hydrogel Loaded with Plasma-Rich Platelets Repairing Endometrial Injury and Remodeling Reproductive Function by Regulating PI3K/AKT Pathway","authors":"Qing Zhang, Di Qin, Chengyang Liu, Zeqiang Chen, Xuelin Gong, Shuang Wang, Ruipeng Gao, Sun Yu, Jiaojiao Qi, Yusheng Niu, Shichao Xing, Shichao Bi, Bo Tang","doi":"10.1002/smll.202412177","DOIUrl":"https://doi.org/10.1002/smll.202412177","url":null,"abstract":"Infertility resulting from uterine damage has emerged as a significant challenge confronting the development of modern society. Existing therapeutic approaches frequently encounter limitations due to the intricate physical and physiological environment of uterus. Platelet-rich plasma (PRP), a concentrate of platelets enriched with various growth factors, has been used in uterine injury repair. However, the rapid release of activating factors from PRP limits its timeliness in therapeutic applications. This work involves the synthesis of a biodegradable hydrogel based on natural polysaccharides through dynamic Schiff base. The hydrogel demonstrates tissue adhesion, self-healing, and injectability. Furthermore, its internal porous architecture facilitates the loading and sustained release of PRP. In vitro experiments, the hydrogel loaded with RPR (HOHP) exhibits a significant enhancement in cell proliferation and migration and promotes vascular regeneration by upregulating the expression of VEGFA and further activating the intracellular phosphatidylinositol kinase (PI3K)/protein kinase B (AKT) pathway. In vivo experiments on uterine endometrial injury model, HOHP restores endometrial thickness and gland number, reduces collagen deposition, promotes angiogenesis to repair uterine damage and restore fertility, which provides reinforced endorsement for the clinical management of uterine injury and enhances fertility.","PeriodicalId":228,"journal":{"name":"Small","volume":"1 1","pages":""},"PeriodicalIF":13.3,"publicationDate":"2025-04-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"143745679","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":2,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
{"title":"High Thermoelectric Figure of Merit (zT) in β-Ag2Se via Aliovalent Doping","authors":"Aradhana Acharya, Suneetha Nagaraja, Nahid Hassan, Kartick Tarafder, Nirmalya Ballav","doi":"10.1002/smll.202411498","DOIUrl":"https://doi.org/10.1002/smll.202411498","url":null,"abstract":"High-performance thermoelectric materials are essential for efficient low-temperature (300–400 K) heat energy harvesting, with <i>n</i>-type Ag<sub>2</sub>Se being a promising candidate. To further enhance the thermoelectric figure of merit (zT) of Ag<sub>2</sub>Se, aliovalent doping has emerged as a key strategy. However, achieving wet-chemical aliovalent doping of Ag<sub>2</sub>Se at ambient temperature has proven challenging. In this work, a high <i>zT</i><sub>max</sub> of 1.57 at 398 K is reported for an optimally Cd(II)-doped Ag<sub>2</sub>Se sample, specifically in the structurally phase-pure Ag<sub>1.98</sub>Cd<sub>0.02</sub>Se, which is successfully synthesized via an aqueous-based method at room-temperature (300 K). The Ag<sub>1.98</sub>Cd<sub>0.02</sub>Se sample also exhibits an impressive average <i>zT</i><sub>avg</sub> of 1.12 over the temperature range of 315–400 K. Density functional theory (DFT) calculations for both the pristine and doped samples reveal significant changes in the electronic band structures, including notable modulations in the density of states near the Fermi energy, particularly for the Ag-3<i>d</i> states. The remarkable thermoelectric performance of Ag<sub>1.98</sub>Cd<sub>0.02</sub>Se is attributed to an optimization of charge carrier induced by the Cd(II)-doping.","PeriodicalId":228,"journal":{"name":"Small","volume":"32 1","pages":""},"PeriodicalIF":13.3,"publicationDate":"2025-04-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"143745668","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":2,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
SmallPub Date : 2025-04-01DOI: 10.1002/smll.202410793
Shintaro Aoyagi, Etsuro Iwama, Keisuke Matsumura, Kazuaki Kisu, Keita Okazaki, Yoshihiko Egawa, McMahon Thomas Homer Reid, Wako Naoi, Patrick Rozier, Patrice Simon, Katsuhiko Naoi
{"title":"Ultra-Densified TiO₂(B) Anode With Fluid-Like Compressibility: Enhancing Volumetric Capacity for High-Performance Supercapacitors","authors":"Shintaro Aoyagi, Etsuro Iwama, Keisuke Matsumura, Kazuaki Kisu, Keita Okazaki, Yoshihiko Egawa, McMahon Thomas Homer Reid, Wako Naoi, Patrick Rozier, Patrice Simon, Katsuhiko Naoi","doi":"10.1002/smll.202410793","DOIUrl":"https://doi.org/10.1002/smll.202410793","url":null,"abstract":"This study develops a highly densified bronze-type TiO₂ (TiO<sub>2</sub>(B)) anode to enhance the volumetric energy and power density of supercapacitors. By integrating ultracentrifugation with strategic carbon reduction via annealing, a TiO₂(B) anode with fluid-like lubrication, high compressibility, and improved electrode density is synthesized. The annealing process facilitated a hierarchical nanoporous TiO₂(B) network while preventing agglomeration, achieving an electrode density of 2.24 g cm⁻<sup>3</sup>, surpassing conventional values. The densified electrode exhibited an exceptional volumetric capacity of 400 mAh cm⁻<sup>3</sup>, maintaining high-rate performance at 120C. This approach effectively links mechanical and physicochemical properties to electrochemical performance, offering a scalable strategy for optimizing TiO₂(B) anodes. The findings highlight the potential of highly densified TiO₂(B) for hybrid supercapacitors, particularly in applications requiring maximum energy and power density within compact volumes. These advancements hold promise for electric mobility, portable electronics, and renewable energy storage, where efficiency and performance are critical. By demonstrating a method for achieving high-density energy storage, this study provides a framework for next-generation supercapacitor materials. Addressing the growing demands of modern technologies, this research advances high-performance, space-efficient energy storage solutions crucial for future energy applications","PeriodicalId":228,"journal":{"name":"Small","volume":"183 1","pages":""},"PeriodicalIF":13.3,"publicationDate":"2025-04-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"143745676","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":2,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
{"title":"Concentration Dependent Modulation in Optoelectronic Traits of Self-Collated CsPbBr3 Perovskites","authors":"Leepsa Mishra, Aradhana Panigrahi, Priyanka Dubey, Soumi Dutta, Himanshu Kumar, Manas Kumar Sarangi","doi":"10.1002/smll.202412614","DOIUrl":"https://doi.org/10.1002/smll.202412614","url":null,"abstract":"Self-collation of perovskite nanocrystals into superstructures of larger length scales has been growing in research interest due to their dramatically enhanced performance in various nano-devices, modulating their optical and electrical traits. Herein, the unique concentration-dependent self-assembly of phenethylamine (PEA)-capped CsPbBr<sub>3</sub> (PCPB) perovskites spanning a size range of nano to micron level without structural phase alteration is infered. By optimizing various synthetic parameters like PEA amount, and solvents, the self-coalescence in PCPB crystal growth is controlled. Furthermore, the highest-concentrated PCPB (C5) has improved the charge transfer (CT) efficiency to 1,4-Napthoquinone (NPQ), corroborated with stronger binding between C5 and NPQ, compared to the lowest-concentrated PCPB (C1). Incorporating NPQ into such concentration-dependent PCPB enhances their local conductance unveiling the CT-induced current rise, while the detrimental insulating property of PEA molecules reduces the conductance in C5 compared to C1. These outcomes offer a foundation for tailoring the properties of self-assembled perovskites for optoelectronic devices and energy conversion technologies.","PeriodicalId":228,"journal":{"name":"Small","volume":"74 1","pages":""},"PeriodicalIF":13.3,"publicationDate":"2025-04-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"143745764","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":2,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
SmallPub Date : 2025-04-01DOI: 10.1002/smll.202501464
Mizna Naseem, Muhammad Tahir, Jun Dai, Longbing Qu, Fazal Ul Nisa, Waheed Ahmad, Iqra Shahbaz, Zeyu Ma, Arif Ullah Khan, Liang He
{"title":"Tuning the Catalytic Activity of MoS2−x−NbSx Heterostructure Nanosheets for Bifunctional Acidic Water Splitting","authors":"Mizna Naseem, Muhammad Tahir, Jun Dai, Longbing Qu, Fazal Ul Nisa, Waheed Ahmad, Iqra Shahbaz, Zeyu Ma, Arif Ullah Khan, Liang He","doi":"10.1002/smll.202501464","DOIUrl":"https://doi.org/10.1002/smll.202501464","url":null,"abstract":"Developing durable electrocatalysts with high activity for the oxygen evolution reaction (OER) and hydrogen evolution reaction (HER) in acidic media is critically important for clean power production. In this study, MoS<sub>2−<i>x</i></sub>−NbS<sub><i>x</i></sub> heterostructure nanosheets are synthesized from a solid-state reaction method followed by liquid phase exfoliation, and their catalytic performance is optimized. The MoS<sub>2−<i>x</i></sub>−NbS<sub><i>x</i></sub> heterostructure nanosheets with optimal precursors ratio exhibit promising attributes for applications in the HER and OER compared to pristine MoS<sub>2</sub> and Nb under the same conditions. The MoS<sub>2−<i>x</i></sub>−NbS<sub><i>x</i></sub> heterostructure nanosheets catalyst on glassy carbon electrodes shows the minimum overpotential of 159 mV for HER and 295 mV for OER at a current density of 10 mA cm<sup>−2</sup> in 0.5 m H<sub>2</sub>SO<sub>4</sub>. This research offers valuable insights into the fabrication of heterostructure nanosheets and evaluates their potential as effective electrocatalysts for water splitting compared with pristine 2D materials in an acid environment.","PeriodicalId":228,"journal":{"name":"Small","volume":"2 1","pages":""},"PeriodicalIF":13.3,"publicationDate":"2025-04-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"143745464","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":2,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
{"title":"Integrated Network Cathodes by In Situ Phase Transition Break Diffusion Limitation for Zinc Ion Battery","authors":"Tianning Pian, Nengze Wang, Xiaohe Ren, Shengbo Yang, Mengxuan Sun, Ziwei Gan, Jianing Lv, Chunyang Jia","doi":"10.1002/smll.202411860","DOIUrl":"https://doi.org/10.1002/smll.202411860","url":null,"abstract":"The cathode materials set the limitation of aqueous zinc ion batteries (AZIBs) in capacity and restrict their development. Vanadium-based materials show unsatisfactory conductivity and strong interactions with Zn<sup>2+</sup> as well as a narrow voltage window. Herein, an integrated network structure is obtained by modulating the voltage window to phase transition from VO<sub>2</sub> to H<sub>X</sub>V<sub>2</sub>O<sub>5</sub>. This has multiple advantages: low crystallinity and abundant active sites; good electrolyte wetting; and two-electron transfer for high specific capacity. The AZIBs exhibit impressive rate performance (545 mAh g<sup>−1</sup> at 0.1 A g<sup>−1</sup> and 185 mAh g<sup>−1</sup> at 20 A g<sup>−1</sup>) and cycling performance (179 mAh g<sup>−1</sup> after 15 000 cycles at 20 A g<sup>−1</sup>), stable operation even at −20 °C (391 mAh g<sup>−1</sup> at 1 A g<sup>−1</sup>, 97 mAh g<sup>−1</sup> at 10 A g<sup>−1</sup>). AZIBs have high power density and high energy density based on the mass of cathode material (405 Wh kg<sup>−1</sup> at 74 W kg<sup>−1</sup> and 102 Wh kg<sup>−1</sup> at 11 127 W kg<sup>−1</sup>). The pouch-type cell can run for over 500 h, has a maximum energy density of 45.5 Wh kg<sup>−1</sup>. The phase transition mechanism and energy storage mechanism are identified, which is conducive to promoting the development of cathodes for AZIBs.","PeriodicalId":228,"journal":{"name":"Small","volume":"1 1","pages":""},"PeriodicalIF":13.3,"publicationDate":"2025-04-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"143745470","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":2,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}