SmallPub Date : 2025-07-04DOI: 10.1002/smll.202505552
Yufeng Su, Baolin Zhang, Shengguang Qi, Tongmei Ma, Boyong Wu, Yankui Mo, Mianrui Li, Siyuan Peng, Li Du
{"title":"Ordering the Coordination Environment of Solvated Ionic Liquid Gel Electrolytes: Pathway to High-Efficiency 4.5 V Lithium Metal Batteries.","authors":"Yufeng Su, Baolin Zhang, Shengguang Qi, Tongmei Ma, Boyong Wu, Yankui Mo, Mianrui Li, Siyuan Peng, Li Du","doi":"10.1002/smll.202505552","DOIUrl":"https://doi.org/10.1002/smll.202505552","url":null,"abstract":"<p><p>Solvated ionic liquids (SILs) are promising candidates for lithium metal battery (LMB) electrolytes owing to their facile synthesis and high safety. However, the high-voltage stability and ionic conductivity of ether-based SILs are compromised by their chaotic coordination structure, characterized by bulky solvation shells and poor oxidation stability. Here, optimizing electrolyte performance is proposed by incorporating weakly coordinating fluoroethylene carbonate (FEC) and a hydrogen-bond (H-bond)-rich polymer into SILs. FEC occupies the second solvation shell, suppressing large-volume solvation structures and improving ion transfer kinetics, while H-bonds anchor TFSI<sup>-</sup>, reducing its competitive coordination and suppressing its diffusion. This dual approach inhibits the formation of chaotic structures, leading to the development of a SIL-FEC (SILF) based H-bond gel electrolyte (SFHE) for LMBs, which exhibits high Li<sup>+</sup> conductivity and superior oxidative stability. The resulting electrolyte exhibits a high Li<sup>+</sup> transference number of 0.65. Furthermore, Li/SFHE/LiNi<sub>0.6</sub>Co<sub>0.2</sub>Mn<sub>0.2</sub>O<sub>2</sub> (NCM622) battery can operate stably at a high cut-off voltage of 4.5 V, achieving an impressive capacity retention of ≈80% after 400 cycles at 1C. Additionally, the Li/SFHE/LiFePO<sub>4</sub> (LFP) retains 81.8% capacity after 450 cycles at a high rate of 3C at 60 °C. This work provides a strategy for achieving high-voltage LMBs by ordering electrolyte micro-solvation structures.</p>","PeriodicalId":228,"journal":{"name":"Small","volume":" ","pages":"e2505552"},"PeriodicalIF":13.0,"publicationDate":"2025-07-04","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"144558575","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":2,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
SmallPub Date : 2025-07-04DOI: 10.1002/smll.202506968
Cheng Lu, Zhilong Wang, Jinjin Li, Liangming Wei
{"title":"Steric Hindrance Effects of Linear/Branched Saccharides at Ceramic-Modified Zinc Anodes Enable Ultrastable Aqueous Al-Zn Hybrid Ion Batteries.","authors":"Cheng Lu, Zhilong Wang, Jinjin Li, Liangming Wei","doi":"10.1002/smll.202506968","DOIUrl":"https://doi.org/10.1002/smll.202506968","url":null,"abstract":"<p><p>Aluminum-based electrolytes and zinc anodes respectively provide aqueous Al-Zn hybrid-ion batteries with high theoretical capacity and reversible plating/stripping behavior. However, parasitic reactions at the zinc anode/aluminum-based electrolyte interface - including dendrite growth, hydrogen evolution, and corrosion passivation - significantly limit cycle life and accelerate capacity degradation. Herein, a comparative investigation of the synergistic effects between glucose (a linear monosaccharide) and sucrose (a branched disaccharide) electrolyte additives with the ZnCr₂O₄ interface of PVDF@ZnCr₂O₄@Zn anodes is conducted, specifically examining spontaneous adsorption, steric hindrance, and conductivity enhancement effects on battery performance. The study reveals that glucose, due to its intrinsic properties and lower steric hindrance, exhibits stronger synergistic effects with the ZnCr₂O₄ interface than sucrose, leading to more effective suppression of parasitic reactions and capacity fade. The glucose/sucrose-modified electrolyte enables the battery to achieve exceptional cycling stability (19,000 and 8,000 cycles) while maintaining high specific discharge capacities (267 and 215 mAh g⁻¹). The synergistic effects between these electrolyte additives and the engineered anode interface present promising strategies and theoretical foundations for developing next-generation high-performance batteries.</p>","PeriodicalId":228,"journal":{"name":"Small","volume":" ","pages":"e2506968"},"PeriodicalIF":13.0,"publicationDate":"2025-07-04","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"144558579","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":2,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
SmallPub Date : 2025-07-04DOI: 10.1002/smll.202570201
Seokhyeon Baek, Wonsik Kim, Won-June Lee, Jun-Gyu Choi, Sungjun Park
{"title":"Selectively Self-Aligned Sol-Gel Copper Oxide for Large-Area Multi-Valued Logic Devices (Small 26/2025)","authors":"Seokhyeon Baek, Wonsik Kim, Won-June Lee, Jun-Gyu Choi, Sungjun Park","doi":"10.1002/smll.202570201","DOIUrl":"https://doi.org/10.1002/smll.202570201","url":null,"abstract":"<p><b>Heterojunction Transistors</b></p><p>In article number 2407497, Jun-Gyu Choi, Sungjun Park, and co-workers illustrate a wafer-scale array of solution-processed heterojunction transistors fabricated via SAM-assisted selective patterning. This novel strategy highlights a promising alternative to conventional photolithography by effectively addressing the challenges posed by partially overlapped junction structures. A magnified junction interface showcases efficient carrier transport, enabled by the partially overlapped architecture of the metal oxide heterojunction.\u0000\u0000 <figure>\u0000 <div><picture>\u0000 <source></source></picture><p></p>\u0000 </div>\u0000 </figure></p>","PeriodicalId":228,"journal":{"name":"Small","volume":"21 26","pages":""},"PeriodicalIF":13.0,"publicationDate":"2025-07-04","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://onlinelibrary.wiley.com/doi/epdf/10.1002/smll.202570201","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"144551169","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":2,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"OA","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
SmallPub Date : 2025-07-04DOI: 10.1002/smll.202505121
Sourav Paul, Amal Gain, Ashadul Adalder, Sayan Pal, Samir H Mushrif, Uttam Kumar Ghorai
{"title":"Morphology Dependent N<sub>2</sub> Reduction on Cu<sub>2</sub>O: Combined Experimental and Computational Study for Efficient Ammonia Electrocatalytic Synthesis.","authors":"Sourav Paul, Amal Gain, Ashadul Adalder, Sayan Pal, Samir H Mushrif, Uttam Kumar Ghorai","doi":"10.1002/smll.202505121","DOIUrl":"https://doi.org/10.1002/smll.202505121","url":null,"abstract":"<p><p>Tailoring morphology to alter catalyst performance offers a promising approach to enhance electrocatalytic nitrogen reduction reaction (NRR) for ammonia electrosynthesis. In this work, the structure-dependent performance of Cu<sub>2</sub>O nanocrystals with distinct cubic and octahedral morphologies is investigated. Experimental results demonstrate the structure-dependent activity, wherein Cu<sub>2</sub>O with nanooctahedral morphology shows enhanced NRR performance achieving NH<sub>3</sub> yield of 182.1 µg h<sup>-1</sup> mg<sub>cat</sub> <sup>-1</sup> and Faradaic efficiency (FE) of 35.8% at -0.5 V versus RHE, surpassing its cubic counterpart. To gain mechanistic insights, density functional theory calculations are performed with Hubbard correction (DFT + U). The results indicate thermodynamically favorable nitrogen reduction pathway on the exposed (111) facets of Cu<sub>2</sub>O. Furthermore, charge transfer analysis provides insights into the redistribution of electron density during NRR. The synergy between experimental results and theoretical insights highlights the importance of morphological tuning in designing efficient Cu<sub>2</sub>O-based catalysts for electrocatalytic ammonia synthesis.</p>","PeriodicalId":228,"journal":{"name":"Small","volume":" ","pages":"e2505121"},"PeriodicalIF":13.0,"publicationDate":"2025-07-04","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"144558571","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":2,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
SmallPub Date : 2025-07-04DOI: 10.1002/smll.202504084
Xiao Liu, Zhen Shi, Mingxuan Bu, Xusheng Wang, Wensheng Yan, Xiaodong Pi
{"title":"4H-SiC Homojunction Photogated Synapses Enabling High-Temperature Neuromorphic Computing.","authors":"Xiao Liu, Zhen Shi, Mingxuan Bu, Xusheng Wang, Wensheng Yan, Xiaodong Pi","doi":"10.1002/smll.202504084","DOIUrl":"https://doi.org/10.1002/smll.202504084","url":null,"abstract":"<p><p>Ultraviolet optoelectronic synapses (UVOSs) that can simultaneously perceive, memorize, and preprocess UV light signals hold great promise for applications in secure communication, fire warning, and planetary exploration. However, the thermal instability of current UVOSs significantly hinders their practical applications in harsh environments. In this work, high-temperature-resistant synaptic devices based on the p-n 4H-SiC homojunctions are demonstrated. The efficient separation of the photogenerated carriers at the homojunction interface induces a pronounced photogating effect, enabling robust light-stimulated synaptic behavior even at 350 °C in ambient air without any encapsulation. The maximum operating temperature of these devices notably exceeds that reported for other UVOSs. Leveraging an array of these devices, information encryption and image learning-memory are emulated at 350 °C. Moreover, the 4H-SiC photogated synapse array recognizes handwritten digits with up to 95% accuracy in artificial neural network (ANN) simulations. This study provides a simple yet effective strategy for developing UVOSs for high-temperature neuromorphic computing.</p>","PeriodicalId":228,"journal":{"name":"Small","volume":" ","pages":"e2504084"},"PeriodicalIF":13.0,"publicationDate":"2025-07-04","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"144558639","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":2,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
SmallPub Date : 2025-07-04DOI: 10.1002/smll.202411730
Pragati Kishore Prasad, Suraj Toraskar, Suman Khan, Tom Granot, Yael Fridmann Sirkis, Eliane Hadas Yardeni, Shira Albeck, Tamar Unger, Ekaterina Petrovich-Kopitman, Yoseph Addadi, Rakesh Raigawali, Saurabh Anand, Sharath S Vishweshwara, Chethan D Shanthamurthy, Noa Oppenheimer-Low, Raghavendra Kikkeri, Ori Avinoam, Leila Motiei, David Margulies
{"title":"Low-Background His-Tag-Targeting Probes for Turn-On Fluorescence Detection of Cell Surface Proteins and Their Binding Interactions.","authors":"Pragati Kishore Prasad, Suraj Toraskar, Suman Khan, Tom Granot, Yael Fridmann Sirkis, Eliane Hadas Yardeni, Shira Albeck, Tamar Unger, Ekaterina Petrovich-Kopitman, Yoseph Addadi, Rakesh Raigawali, Saurabh Anand, Sharath S Vishweshwara, Chethan D Shanthamurthy, Noa Oppenheimer-Low, Raghavendra Kikkeri, Ori Avinoam, Leila Motiei, David Margulies","doi":"10.1002/smll.202411730","DOIUrl":"https://doi.org/10.1002/smll.202411730","url":null,"abstract":"<p><p>Turn-on fluorescent probes consisting of dye-ligand conjugates serve as a powerful tool for detecting cell surface proteins (CSPs) and their interactions with binding partners. However, generating such probes from protein-based ligands remains challenging. This challenge became particularly evident during the COVID-19 pandemic, which highlighted the need for assays to evaluate inhibitors of the interaction between the SARS-CoV-2 virus receptor-binding domain (RBD) and the angiotensin-converting enzyme 2 (ACE2) receptor. To sense this interaction in a cellular environment using turn-on probes, a tri-nitrilotriacetic acid (tri-NTA) unit was conjugated to quinoline-based cyanine (QBC) dyes. This design leverages the high affinity of tri-NTA for His-tag, along with the low-background and confinement-sensitive optical responses of QBC dyes, to create probes that fluoresce upon binding to His-tagged proteins on cell surfaces. Herein, it is shown that this approach enables the development of an exceptionally simple cell-based assay with which inhibitors of the RBD-ACE2 interaction can be readily sensed by combining a turn-on probe, His-tagged RBD, ACE2-expressing cells, and recording changes in the probe's emission spectra. The potential of this method is further demonstrated by using such probes to detect lectin binding to cell surface glycans and to image a bacterial CSP under wash-free conditions.</p>","PeriodicalId":228,"journal":{"name":"Small","volume":" ","pages":"e2411730"},"PeriodicalIF":13.0,"publicationDate":"2025-07-04","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"144558569","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":2,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
{"title":"MXene-Mediated Charge Modulation in Plasmonic Metal-Semiconductor Heterojunctions for Photo-Induced Enhanced Raman Spectroscopy.","authors":"Ruchi Singh, Aditya Thakur, Rabindranath Lo, Kolleboyina Jayaramulu, Soumik Siddhanta","doi":"10.1002/smll.202503180","DOIUrl":"https://doi.org/10.1002/smll.202503180","url":null,"abstract":"<p><p>The smart integration of nanoparticles with tailored semiconductors, followed by UV illumination prior to Raman measurements, activates photo-induced enhanced Raman spectroscopy (PIERS), enabling ultrasensitive detection. This photo-mediated modulation of charge transfer is a special case of surface-enhanced Raman spectroscopy (SERS), where enhancement is tuned via chemical-interaction-induced charge transfer between the analyte and substrate. Herein, photoinduced charge transfer dynamics are explored by tuning the work function of the supporting material embedding plasmonic nanostructures and creating an interfacial light-mediated charge-transfer system. Using two distinct nanoparticles supported on a two-dimensional material revealed directional charge transport behaviour, reflecting Fermi-level equilibration at heterojunctions. Titanium carbide-based MXene (Ti<sub>3</sub>C<sub>2</sub>Tx; Tx = -OH, -F) is introduced as a charge-transfer modulator due to its tunable work function, significantly influencing carrier transport direction and efficiency. Notably, Au-based hybrids exhibit PIERS enhancement upto five orders of magnitude, unlike Ag-based hybrids that show quenching. This confirms that optimized nanoparticle-MXene hybrids facilitate hot electron movement across interfaces, leading to differential PIERS responses. Additionally, density functional theory calculations elucidate electronic structures and photogenerated electron migration. This study provides valuable insights into photo-induced charge transfer, emphasizing its pivotal role in enhancing chemical contributions in SERS, advancing future optical sensing and molecular recognition platforms.</p>","PeriodicalId":228,"journal":{"name":"Small","volume":" ","pages":"e2503180"},"PeriodicalIF":13.0,"publicationDate":"2025-07-04","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"144558573","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":2,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
{"title":"ReS<sub>2</sub>/MoSe<sub>2</sub> Van der Waals Heterostructure Photodetectors for Polarization Imaging and Polarization-Encoded Optical Communication.","authors":"Yufan Wang, Zijie Lai, Senyao Tang, Jiaxuan Wang, Qiyuan Zhou, Shuhan Li, Weiqi Wang, Huijuan Zhao, Yuanfang Yu, Li Gao","doi":"10.1002/smll.202503599","DOIUrl":"https://doi.org/10.1002/smll.202503599","url":null,"abstract":"<p><p>Two dimensional (2D) materials with anisotropic optoelectronic properties provide a feasible solution for polarization photodetectors, however, it is challenging to achieve simultaneous high responsivity, fast photoresponse, and good anisotropic ratio of the photocurrent (I<sub>ph-max</sub>/I<sub>ph-min</sub>). In this work, a polarization-sensitive photodetector based on ReS<sub>2</sub>/MoSe<sub>2</sub> van der Waals heterostructures is constructed for type-II energy band alignment with a clean contact interface. Under 532 nm laser irradiation, the photodetector has both high responsivity (89.4 A W<sup>-1</sup>), high-speed response (≈30.5 µs/≈36.2 µs), and high anisotropy ratio of 3.23. The performance of the device has been enhanced for multifunctional applications, including single-pixel polarization imaging and encrypted optical communication by combining Morse code with polarization encoding, demonstrating its potential in polarization-related optical information applications.</p>","PeriodicalId":228,"journal":{"name":"Small","volume":" ","pages":"e2503599"},"PeriodicalIF":13.0,"publicationDate":"2025-07-04","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"144558577","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":2,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
SmallPub Date : 2025-07-04DOI: 10.1002/smll.202410360
Radha Bhardwaj, Martin Pumera
{"title":"Surface-Engineered 2D Nanomaterials in Gas Sensors: Advancement and Challenges.","authors":"Radha Bhardwaj, Martin Pumera","doi":"10.1002/smll.202410360","DOIUrl":"https://doi.org/10.1002/smll.202410360","url":null,"abstract":"<p><p>2D nanomaterials liketransition metal dichalcogenides (TMDs), MXene, nitrides, and black phosphorus-based gas sensors have garnered extensive attention in recentdecades. The extraordinary physicochemical and electrical properties of 2D nanomaterials make them highly sensitive toward gas molecules at roomtemperature. However, despite their potential, the current gas sensingtechnology suffers from inadequate selectivity, inaccurate detection and environmentalinstability. This review provides an overview of recent developments in surface-engineering routes to improve the sensing properties of 2D nanomaterials-based gas sensors. First, it covers emerging 2D nanomaterials, their synthesis routes, and gas-sensing mechanisms. Lateron, thoroughly explores renowned surface-engineering strategies such as defectmodulation, nanoparticle functionalization, and heteroatom doping to enhancethe gas sensing performance. Metal intercalation and partial surface oxidation/reductionapproaches are also discussed to tune the sensing characteristics. Furthermore, single-atom catalyst engineering highlights the anchoring of metalatoms on 2D nanomaterials to achieve enhanced atom utilization, leading tobetter catalytic sensing activities. The engineering techniques introduceeffective surface sensitization, modulated carrier concentration in 2D materials. This review outlines the key objectives of surface-engineeringstrategies to overcome the limitations of hybrid materials and pave the way fornext-generation sensors with enhanced sensing performance toimpact a wide range of applications.</p>","PeriodicalId":228,"journal":{"name":"Small","volume":" ","pages":"e2410360"},"PeriodicalIF":13.0,"publicationDate":"2025-07-04","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"144558581","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":2,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
{"title":"Biomimetic Design of Capillary-Driven Photothermal Fabric for Efficient Interface Evaporation.","authors":"Dongnan Zhang, Zijian Bai, Jianyu Jiang, Chenhao Ma, Jing Guo, Fengyu Quan, Hong Zhang, Yue Yu","doi":"10.1002/smll.202504092","DOIUrl":"https://doi.org/10.1002/smll.202504092","url":null,"abstract":"<p><p>Solar vapor generation (SVG) offers a promising solution to freshwater scarcity; however, current solar evaporators suffer from limitations in water transport, salt resistance, and scalability, hindering their commercial application. To address these challenges, this study introduces a biomimetic capillary-driven photothermal fabric. Using sodium alginate (SA) as the matrix, vinyl silicon-based nanoparticles (VSNP) and reduced graphene oxide (rGO) are integrated to form a multi-hybrid structure with interconnected flexible dynamic hydrogen bonds and rigid ionic cross-links. This configuration imparts the fibers with high strength (2.972 cN/dtex) and toughness (8.856% elongation at break). The alginate-based fabric, produced via wet spinning and weaving, retains outstanding mechanical and structural stability. Inspired by plant water transport mechanisms, the photothermal fabric efficiently channels water to the evaporation interface through its porous structure and capillary action. The rGO's π-π conjugation enhances the fabric's light absorption and photothermal conversion. Under 1 kW m<sup>-2</sup> solar irradiation, the fabric's surface temperature reaches 118.5 °C, with an evaporation rate of 2.886 kg m<sup>-2</sup> h<sup>-1</sup>, 6.87 times higher than pure water, and an evaporation efficiency of 118.95%. Additionally, the fabric exhibits excellent salt resistance, stable cyclic performance, and scalability for mass production, offering new potential for solar-driven evaporation technologies.</p>","PeriodicalId":228,"journal":{"name":"Small","volume":" ","pages":"e2504092"},"PeriodicalIF":13.0,"publicationDate":"2025-07-04","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"144558640","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":2,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}