Advanced Energy Materials最新文献

Synergistic Hole-Selective Contact Enabling Highly Efficient Perovskite/Organic Tandem Solar Cells 协同孔选择接触实现高效钙钛矿/有机串联太阳能电池

IF 27.8 1区材料科学

Advanced Energy Materials Pub Date : 2026-04-27 DOI: 10.1002/aenm.70945

Mengqi Chi, Xinyue Cui, Guanshui Xie, Jun Fang, Dan Ouyang, Yuqi Wang, Qiumin Kong, Longbin Qiu, Zhishan Bo, Yuqiang Liu

{"title":"Synergistic Hole-Selective Contact Enabling Highly Efficient Perovskite/Organic Tandem Solar Cells","authors":"Mengqi Chi, Xinyue Cui, Guanshui Xie, Jun Fang, Dan Ouyang, Yuqi Wang, Qiumin Kong, Longbin Qiu, Zhishan Bo, Yuqiang Liu","doi":"10.1002/aenm.70945","DOIUrl":"https://doi.org/10.1002/aenm.70945","url":null,"abstract":"Efficiency improvements in organic solar cells (OSCs), perovskite solar cells (PSCs), and tandem solar cells (TSCs) critically depend on optimized hole-selective interfacial contacts. Co-assembled self-assembled monolayers (co-SAMs) offer an effective route to enhance hole extraction. However, their practical design is limited by the absence of universal material selection rules, often leading to incompatible molecular packing and suboptimal interfaces. Here, we propose a synergistic co-SAM strategy that enables high-quality hole-selective contacts across OSCs, PSCs, and TSCs. By co-assembling carbazole-based phosphonic acids with chain length-matched phosphonic acid derivatives, we reveal that rational molecular pairing governs the synergistic behavior of co-adsorbates. PAC2Br shows optimal compatibility with 2PACz, while PAC4Br matches well with 4PACz, resulting in homogeneous molecular distribution, compact surface coverage, and favorable energy-level alignment. These synergistic interfaces effectively suppress interfacial recombination and enhance charge extraction. Consequently, co-SAM-modified devices achieve power conversion efficiencies of 19.60% in OSCs. Demonstrating the universality of the co-SAM strategy, the co-SAM pairing yields PSCs with efficiencies up to 25.78%, and further enables a champion PCE of 26.06% for perovskite/organic TSCs. This work establishes synergistic co-SAMs as a general and effective interfacial design principle for high-efficiency photovoltaic devices.","PeriodicalId":111,"journal":{"name":"Advanced Energy Materials","volume":"1 1","pages":""},"PeriodicalIF":27.8,"publicationDate":"2026-04-27","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"147753400","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":1,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

引用次数: 0

Taming Free Water Activity via Ethylene Glycol for Durable and Fast-Charging Rechargeable Seawater Batteries 通过乙二醇抑制游离水活性，用于耐用和快速充电的可充电海水电池

IF 27.8 1区材料科学

Advanced Energy Materials Pub Date : 2026-04-27 DOI: 10.1002/aenm.71008

Usman Ali, Maoyu Sun, Yueqi Xu, Qi Zhang, Muhammad Sajid, Wei Liu, Sami Ur Rahman, Lu Li, Chungang Wang, Bingqiu Liu

{"title":"Taming Free Water Activity via Ethylene Glycol for Durable and Fast-Charging Rechargeable Seawater Batteries","authors":"Usman Ali, Maoyu Sun, Yueqi Xu, Qi Zhang, Muhammad Sajid, Wei Liu, Sami Ur Rahman, Lu Li, Chungang Wang, Bingqiu Liu","doi":"10.1002/aenm.71008","DOIUrl":"https://doi.org/10.1002/aenm.71008","url":null,"abstract":"Aqueous seawater-based batteries (ASWBs) are promising for low-cost, sustainable energy storage but are limited by highly reactive free water in pure seawater (PSW), which leads to electrode degradation and poor cycling stability. Herein, we address this bottleneck by an entropy-enhanced cosolvent approach using an eco-friendly, low-cost modified seawater (MSW) electrolyte (ethylene glycol as the cosolvent) for ASWBs. EG molecules increase the short-range entropy of the MSW, forming discrete, small clusters that increase Na+ mobility and reduce free water activity by disrupting the native H-bonding network of PSW. Combining this MSW electrolyte with a high-entropy hexacyanoferrate (HEHCF) cathode results in exceptional cycling lifespan (>20,000 cycles) at a high current density of 7000 mA g−1, with 96.50% capacity retention and full charge–discharge in 35–39 s. This outstanding performance stems from a pseudocapacitive-dominant charge-storage mechanism, reversible monoclinic↔cubic phase transitions in HEHCF, and suppressed parasitic reactions. This work provides a cost-effective, scalable electrolyte-engineering strategy to unlock stable ASWBs, advancing their potential for grid-scale and marine energy-storage applications.","PeriodicalId":111,"journal":{"name":"Advanced Energy Materials","volume":"26 1","pages":""},"PeriodicalIF":27.8,"publicationDate":"2026-04-27","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"147753555","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":1,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

引用次数: 0

Redox-Mediated Aluminum–Air Fuel Cells With Suppressed Hydrogen Evolution for Durable Power Generation 氧化还原介导的铝-空气燃料电池与抑制氢释放持久发电

IF 27.8 1区材料科学

Advanced Energy Materials Pub Date : 2026-04-27 DOI: 10.1002/aenm.71004

Yuxi Song, Hang Zhang, Zhongheng Fu, Zeyun Gu, Lingchao Xia, Haoyang Guo, Jiahao Zhuang, Yizhuo He, Linghang Meng, Zhi Wei Javier Ang, Qing Wang

{"title":"Redox-Mediated Aluminum–Air Fuel Cells With Suppressed Hydrogen Evolution for Durable Power Generation","authors":"Yuxi Song, Hang Zhang, Zhongheng Fu, Zeyun Gu, Lingchao Xia, Haoyang Guo, Jiahao Zhuang, Yizhuo He, Linghang Meng, Zhi Wei Javier Ang, Qing Wang","doi":"10.1002/aenm.71004","DOIUrl":"https://doi.org/10.1002/aenm.71004","url":null,"abstract":"Aluminum (Al) is a promising anode material for metal–air systems owing to its exceptional theoretical capacity, earth abundance, and environmental compatibility. However, its practical development in alkaline media is hindered by parasitic corrosion and surface passivation arising from the thermodynamically favored hydrogen evolution reaction (HER), resulting in low Faradaic efficiency. Herein, we introduce a redox-mediated aluminum–air fuel cell (RM-AAFC) in which HER is kinetically suppressed by a soluble redox mediator, 7,8-dihydroxy-2-phenazine sulfonic acid (DHPS), which forms a competitive electron transfer pathway at the Al–electrolyte interface, boosting Faradaic efficiency from 36.1% to 92.5% without compromising the reaction kinetics. When integrated with precipitation- and complexation- based aluminate extraction strategies, the system delivers a peak power density of 210 mW cm−2 and a volumetric capacity of 403.2 Ah L−1 during sustained operation. These findings highlight redox-mediated chemistry as a general and scalable strategy for mitigating interfacial parasitic reactions in aqueous metal–air energy systems.","PeriodicalId":111,"journal":{"name":"Advanced Energy Materials","volume":"18 1","pages":""},"PeriodicalIF":27.8,"publicationDate":"2026-04-27","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"147753557","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":1,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

引用次数: 0

Improving the Electrocatalytic Activity of a High-Entropy Ruddlesden–Popper Perovskite Air Electrode for Solid Oxide Cells Through Composition Regulation 通过成分调控提高高熵Ruddlesden-Popper钙钛矿空气电极对固体氧化物电池的电催化活性

IF 27.8 1区材料科学

Advanced Energy Materials Pub Date : 2026-04-27 DOI: 10.1002/aenm.70992

Jian Zhang, Penghui Yao, Jinpeng Zhang, Tianqi Shao, Zifan Niu, Xuehua Zhang, Dehe Lin, Beibei Yang, Yicheng Zhao, Yongdan Li

{"title":"Improving the Electrocatalytic Activity of a High-Entropy Ruddlesden–Popper Perovskite Air Electrode for Solid Oxide Cells Through Composition Regulation","authors":"Jian Zhang, Penghui Yao, Jinpeng Zhang, Tianqi Shao, Zifan Niu, Xuehua Zhang, Dehe Lin, Beibei Yang, Yicheng Zhao, Yongdan Li","doi":"10.1002/aenm.70992","DOIUrl":"https://doi.org/10.1002/aenm.70992","url":null,"abstract":"One major challenge to the application of solid oxide cell technology is the poor catalytic activity and stability of air electrodes. High-entropy engineering has been considered as a promising strategy to improve the activity and durability of perovskite-derived air electrodes. However, the understanding of the individual contributions of configurational entropy and specific elemental composition to the performance improvement is still insufficient. Herein, the effects of A-site elements and configurational entropy on the performance of Ruddlesden–Popper-structured (La/Sr/Pr/Ba/Ca)2Ni0.5Fe0.5O4±δ electrodes are investigated. The results demonstrate that the electrocatalytic activity of the electrode is highly related to the reactivity of lattice oxygen. The polarization resistance of the electrode is negatively correlated with the content of Sr and the configurational entropy, and a Sr-rich Sr0.8La0.3Pr0.3Ba0.3Ca0.3Ni0.5Fe0.5O4±δ electrode with a sub-high entropy exhibits the lowest polarization resistance of 0.044 Ω cm2 at 700°C. A protonic ceramic cell with that air electrode achieves a peak power density of 2.15 W cm−2 in the fuel cell mode and a current density of 2.88 A cm−2 for H2O electrolysis under 1.3 V at 700°C. Meanwhile, the air electrode exhibits high stability in CO2 and H2O atmospheres.","PeriodicalId":111,"journal":{"name":"Advanced Energy Materials","volume":"60 1","pages":""},"PeriodicalIF":27.8,"publicationDate":"2026-04-27","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"147753556","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":1,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

引用次数: 0

Ultralow-Overpotential CO Production from Electroreduction of CO2 on a Hydroxyl-Enriched Heterojunction 富羟基异质结上CO2电还原产生超低过电位CO

IF 27.8 1区材料科学

Advanced Energy Materials Pub Date : 2026-04-27 DOI: 10.1002/aenm.71003

Huan Xie, Yan Zheng, Wenzheng Nie, Linglan Men, Huihui Bao, Yingchun Liu, Chuangwei Liu, Jingwei Liu, Changlei Xia

{"title":"Ultralow-Overpotential CO Production from Electroreduction of CO2 on a Hydroxyl-Enriched Heterojunction","authors":"Huan Xie, Yan Zheng, Wenzheng Nie, Linglan Men, Huihui Bao, Yingchun Liu, Chuangwei Liu, Jingwei Liu, Changlei Xia","doi":"10.1002/aenm.71003","DOIUrl":"https://doi.org/10.1002/aenm.71003","url":null,"abstract":"Electrochemical CO2 reduction (eCO2R) to valuable chemicals or fuels offers an effective solution to alleviate the energy crisis and environmental challenges. Reducing the overpotential of a desired product for eCO2R is paramount to achieving high energy efficiency. Herein, CuO/In2O3 (Cu4.2In1) nanosheets (NSs) p-n heterojunction with the built-in electric field which enhances the surficial hydroxyl coverage achieving the greatly decreased overpotential for CO production by eCO2R. The Faraday efficiency of CO attains 96.5% under an impressively low overpotential (130 mV), which is one of the lowest among the reported catalysts for CO production. Additionally, the eCO2R system integrates with a commercial triple-junction solar cell exhibiting an average solar-to-CO conversion energy efficiency of 7.9%, with the CO production rate of 0.73 mmol h−1 cm−2. The built-in electric field between the CuO/In2O3 (Cu4.2In1) NSs heterojunction increases the oxidation states of Cu ions (Cuδ+, δ = 2.14), which enhances the surficial hydroxyl coverage by the strong electrostatic attraction at low overpotentials, consequently stabilizing *COOH intermediate and facilitating the desorption of *CO. This work provides a new solution to achieve energy efficient eCO2R by the surficial hydroxyl coverage manipulation.","PeriodicalId":111,"journal":{"name":"Advanced Energy Materials","volume":"54 1","pages":""},"PeriodicalIF":27.8,"publicationDate":"2026-04-27","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"147751546","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":1,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

引用次数: 0

A Transferable Aqueous KCl–OPLT Co‐Treatment for Buried‐Interface Regulation in SnO 2 ‐Based Perovskite Solar Cells 可转移水相KCl-OPLT Co -处理对SnO - 2基钙钛矿太阳能电池埋藏界面调节的影响

IF 27.8 1区材料科学

Advanced Energy Materials Pub Date : 2026-04-27 DOI: 10.1002/aenm.70991

Jia Xu, Shuduo Ma, Jiale Chen, Qianzheng Shi, Yilin Ren, Xueqi Zhang, Mengting Miao, Xingyu Gao, Yahan Wu, Xu Pan, Jianxi Yao

{"title":"A Transferable Aqueous KCl–OPLT Co‐Treatment for Buried‐Interface Regulation in SnO 2 ‐Based Perovskite Solar Cells","authors":"Jia Xu, Shuduo Ma, Jiale Chen, Qianzheng Shi, Yilin Ren, Xueqi Zhang, Mengting Miao, Xingyu Gao, Yahan Wu, Xu Pan, Jianxi Yao","doi":"10.1002/aenm.70991","DOIUrl":"https://doi.org/10.1002/aenm.70991","url":null,"abstract":"Regulating the SnO 2 /perovskite buried interface is critical for suppressing interfacial recombination and J–V hysteresis in n–i–p perovskite solar cells, yet many treatments remain formulation‐dependent or fail to establish a confined and reproducible interface after deposition. Here, we report a one‐step aqueous ion–molecule co‐treatment that forms a KCl–O‐phospho‐L‐tyrosine (OPLT) interlayer on solution‐processed SnO 2 without altering the perovskite precursor or fabrication process. In a representative rigid hybrid device, the champion power conversion efficiency (PCE) increases from 24.44% to 26.10%, with an improved open‐circuit ( V OC ) from 1.156 to 1.196 V and reduced hysteresis ( HI ) from 8.4% to 2.7%. Across four additional SnO 2 ‐based platforms, including rigid/flexible and hybrid/all‐inorganic devices, this strategy consistently delivers PCE gains of 1.44–1.75%, V OC increases of 20–50 mV, and suppressed hysteresis. Depth‐resolved characterization reveals preferential SnO 2 ‐side localization of the interlayer. Combined spectroscopic, electrostatic, and theoretical analyses indicate a cooperative interfacial reconfiguration driven by the coupled K + –phosphonate environment, leading to reduced defects, more uniform electrostatics, and improved energetics. These effects enable more efficient electron extraction, faster V OC build‐up, and reduced photovoltage decay. This work provides a modular and transferable aqueous strategy for regulating buried interfaces in high‐performance perovskite solar cells.","PeriodicalId":111,"journal":{"name":"Advanced Energy Materials","volume":"26 1","pages":""},"PeriodicalIF":27.8,"publicationDate":"2026-04-27","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"147751547","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":1,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

引用次数: 0

Solar-Driven Photothermal Hydrogen Production: Recent Advances and Future Perspectives 太阳能驱动的光热制氢：最新进展和未来展望

IF 27.8 1区材料科学

Advanced Energy Materials Pub Date : 2026-04-27 DOI: 10.1002/aenm.70941

Jian Xu, Ce Fu, Zhong-Yong Yuan, Zhangxing Chen, Heng Zhao

{"title":"Solar-Driven Photothermal Hydrogen Production: Recent Advances and Future Perspectives","authors":"Jian Xu, Ce Fu, Zhong-Yong Yuan, Zhangxing Chen, Heng Zhao","doi":"10.1002/aenm.70941","DOIUrl":"https://doi.org/10.1002/aenm.70941","url":null,"abstract":"Photothermal hydrogen production has emerged as a promising solar-to-hydrogen (STH) conversion strategy that integrates photon and thermal energy harvesting to overcome the intrinsic limitations of conventional photocatalysis. This review provides a comprehensive overview of recent advances in photothermal hydrogen production, emphasizing how light absorption, charge carrier relaxation, and nonradiative heat generation synergistically enable efficient catalytic conversion. The structural and interfacial engineering strategies, including nanoscale modulation, core–shell and hollow architectures, and plasmonic coupling, that enhance light-heat conversion and optimize carrier dynamics are highlighted. Beyond material-level design, the emerging concept of thermal environment engineering is discussed, which reconstructs reaction interfaces from liquid-solid to gas-solid phases through “evaporation-conversion” coupling, thereby improving energy utilization and hydrogen evolution kinetics. Mechanistic insights are further connected to recent developments in machine learning-assisted catalyst discovery, which offers a data-driven pathway toward intelligent design of photothermal systems. Finally, the review outlines the challenges and future opportunities for achieving high-efficiency, stable, and scalable solar-driven photothermal hydrogen production, providing a conceptual framework that bridges fundamental understanding with practical implementation.","PeriodicalId":111,"journal":{"name":"Advanced Energy Materials","volume":"1 1","pages":""},"PeriodicalIF":27.8,"publicationDate":"2026-04-27","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"147753558","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":1,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

引用次数: 0

Self‐Heating and Thermal Gradient in Solid‐State Batteries: Friend or Foe? 固态电池的自加热和热梯度：是敌是友？

IF 27.8 1区材料科学

Advanced Energy Materials Pub Date : 2026-04-25 DOI: 10.1002/aenm.70978

Abhinand Ayyaswamy, Bairav S. Vishnugopi, Partha P. Mukherjee

{"title":"Self‐Heating and Thermal Gradient in Solid‐State Batteries: Friend or Foe?","authors":"Abhinand Ayyaswamy, Bairav S. Vishnugopi, Partha P. Mukherjee","doi":"10.1002/aenm.70978","DOIUrl":"https://doi.org/10.1002/aenm.70978","url":null,"abstract":"Solid‐state batteries (SSBs) are poised to tackle the growing demands of electrified mobility due to their superior energy and power density with enhanced safety. Realizing their potential necessitates overcoming fundamental mechanistic challenges, including solid–solid point contacts, chemo–mechanical interactions, and interfacial instability. Here, we uncover the underpinning origins of dynamic thermo‐electrochemical gradients and intrinsic heat generation during operation. By harnessing their self‐heating signature under thermally modulated environments, we delineate design spaces that integrate materials, electrode configurations, and operational regimes, enabling performance improvements through enhanced thermal responsiveness. The directionality of thermal gradients is critically informed by the cathode architecture and correlates to the resulting temperature profiles, gradients, and interface stability. Further, we present a compelling case for transitioning to anode‐free SSBs that yield greater thermal utilization and performance benefits from self‐heating. Our novel Generate‐Retain‐Intensify‐Direct (GRID) workflow based on a mechanism‐centric SSB design, highlights its intrinsic thermal signature as a key lever for high‐power applications.","PeriodicalId":111,"journal":{"name":"Advanced Energy Materials","volume":"20 1","pages":""},"PeriodicalIF":27.8,"publicationDate":"2026-04-25","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"147739536","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":1,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

引用次数: 0

Triple Active Sites in Prussian Blue Analogues for High-Capacity Aqueous and Seawater Ammonium Ion Batteries 大容量水溶液和海水铵离子电池中普鲁士蓝类似物的三活性位点

IF 27.8 1区材料科学

Advanced Energy Materials Pub Date : 2026-04-24 DOI: 10.1002/aenm.70988

Chao Geng, Jianqi Zhang, Xiaobin Liao, Jin-Ming Wu, Minhua Cao, Quanquan Pang, Zhenyu Zhang, Yijun Shen, Wei Wen

{"title":"Triple Active Sites in Prussian Blue Analogues for High-Capacity Aqueous and Seawater Ammonium Ion Batteries","authors":"Chao Geng, Jianqi Zhang, Xiaobin Liao, Jin-Ming Wu, Minhua Cao, Quanquan Pang, Zhenyu Zhang, Yijun Shen, Wei Wen","doi":"10.1002/aenm.70988","DOIUrl":"https://doi.org/10.1002/aenm.70988","url":null,"abstract":"Aqueous ammonium-ion battery has recently gained attention as a safe, high-power, and cost-effective energy storage device; yet the development in cathode materials that can simultaneously deliver high capacity, high potential, and stable cycling performance is limited. Herein, a Prussian blue analog with three redox-active sites (Co, Mn, and Fe) as a high-performance cathode material for aqueous ammonium-ion batteries by a dual function doping strategy is reported. It achieves a high reversible capacity of 153 mAh g−1 and superior cycling stability over 2500 cycles with negligible capacity decay. Density functional theory calculations and electrochemical analysis reveal that Mn activates the redox activity of Co via the enhanced electron depletion, while Co effectively suppresses the Jahn–Teller effect through splitting the degenerate orbitals of Mn, preserving the long-range structural integrity of the framework. Paring this cathode with the VOx@polypyrrole anode, a high specific energy of 145.7 Wh kg−1 can be achieved at a high specific power of 810.9 W kg−1. This work offers a viable design strategy for the optimization of electrode materials through unlocking multiple active sites and stabilizing lattice frameworks.","PeriodicalId":111,"journal":{"name":"Advanced Energy Materials","volume":"20 1","pages":""},"PeriodicalIF":27.8,"publicationDate":"2026-04-24","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"147739525","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":1,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

引用次数: 0

Suppressing Dissolution of Solid Electrolyte Interphase Enables Highly Stable Sodium‐Ion Batteries 抑制固体电解质间相溶解使钠离子电池高度稳定

IF 27.8 1区材料科学

Advanced Energy Materials Pub Date : 2026-04-23 DOI: 10.1002/aenm.70981

Zhigao Chen, Shengjie Cui, Chenyang Liu, Chao Shen, Ting Jin, Keyu Xie

{"title":"Suppressing Dissolution of Solid Electrolyte Interphase Enables Highly Stable Sodium‐Ion Batteries","authors":"Zhigao Chen, Shengjie Cui, Chenyang Liu, Chao Shen, Ting Jin, Keyu Xie","doi":"10.1002/aenm.70981","DOIUrl":"https://doi.org/10.1002/aenm.70981","url":null,"abstract":"Maintaining the integrity of solid electrolyte interphase (SEI) is pivotal for ensuring the cycling stability of sodium‐ion batteries (SIBs). However, conventional SEIs exhibit subtle yet persistent dissolution during electrochemical cycling, accelerating battery performance degradation. Meanwhile, the correlation between SEI solubility, composition evolution, and cycling reversibility remains ambiguous. Herein, we construct a robust, inorganic‐rich SEI layer via boron‐containing ion‐induced interfacial chemistry, which effectively suppresses SEI dissolution by minimizing electrode–electrolyte contact and inhibiting the repeated generating‐dissolving process of organic components. We further elucidate the correlation between SEI components and its solubility, and quantify that the average capacity loss caused by the dissolution of organic‐rich SEI is 1.36 times that of inorganic‐rich SEI. Benefiting from the stabilized SEI, the hard carbon (HC) anode delivers excellent cycling stability, retaining 81.9% capacity after 400 cycles even at 60°C. Moreover, the HC||O3‐NaNi 1/3 Fe 1/3 Mn 1/3 O 2 (NNFMO) full cell achieves 78.6% capacity retention over 300 cycles. This study provides fundamental insights into SEI dissolution mechanisms and presents an effective strategy to enhance the durability of SIBs.","PeriodicalId":111,"journal":{"name":"Advanced Energy Materials","volume":"81 1","pages":""},"PeriodicalIF":27.8,"publicationDate":"2026-04-23","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"147733700","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":1,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

引用次数: 0