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Topology-Optimized Porous Electrode Architectures for Enhanced Performance in Vanadium Redox Flow Batteries in Flow-Through Cell Designs 拓扑优化多孔电极结构,以提高钒氧化还原液流电池在流通电池设计中的性能
IF 4.7 4区 材料科学
Batteries & Supercaps Pub Date : 2026-04-04 Epub Date: 2025-11-02 DOI: 10.1002/batt.202500052
Poramet Aiemsathit, Mehrzad Alizadeh, Yossapong Laoonual, Patcharawat Charoen-amornkitt, Takahiro Suzuki, Shohji Tsushima
{"title":"Topology-Optimized Porous Electrode Architectures for Enhanced Performance in Vanadium Redox Flow Batteries in Flow-Through Cell Designs","authors":"Poramet Aiemsathit,&nbsp;Mehrzad Alizadeh,&nbsp;Yossapong Laoonual,&nbsp;Patcharawat Charoen-amornkitt,&nbsp;Takahiro Suzuki,&nbsp;Shohji Tsushima","doi":"10.1002/batt.202500052","DOIUrl":"10.1002/batt.202500052","url":null,"abstract":"<p>Herein, a comprehensive investigation is presented into the optimization of porous electrode (PE) structures in vanadium redox flow batteries (VRFBs) using topology optimization (TO) to enhance cell performance, particularly in flow-through configurations. This work builds upon prior studies by incorporating a full cell model that accounts for species transport, electrolyte flow, charge transfer, and proton transport within both positive and negative electrodes. PEs are optimized under different depths of discharge (DoD) conditions—5%, 50%, 65%, 90% and 95%—to capture the diverse requirements for reaction kinetics and mass transport under varying reactant concentrations. The optimized structures, featuring interdigitated channels on both electrodes, yield substantial improvements in mass transport and reaction rates compared to unmodified flow-through and interdigitated flow-field configurations. Performance tests, including polarization curves and charge/discharge characteristics, demonstrate superior current density and electrolyte utilization in the optimized flow-through porous electrode (OFT) designs. Among these, the OFT95% (optimized at 95% DoD) performs exceptionally well under low reactant conditions. Despite minor tradeoffs in hydraulic power loss, the optimized structures maintain competitive round-trip efficiency, showing promise for real-world applications. This study provides critical insights into electrode engineering for VRFBs, contributing to the advancement of sustainable energy storage technologies essential for achieving carbon neutrality.</p>","PeriodicalId":132,"journal":{"name":"Batteries & Supercaps","volume":"9 4","pages":""},"PeriodicalIF":4.7,"publicationDate":"2026-04-04","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"147683075","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Investigation of Degradation Pathways in Fluoroethylene Carbonate Based Electrolytes via Chromatographic Techniques 用色谱技术研究碳酸氟乙烯基电解质的降解途径
IF 4.7 4区 材料科学
Batteries & Supercaps Pub Date : 2026-04-04 Epub Date: 2025-11-02 DOI: 10.1002/batt.202500610
Nick Fehlings, Matthias Weiling, Jakob Hesper, Maximilian Kubot, Martin Winter, Simon Wiemers-Meyer, Sascha Nowak
{"title":"Investigation of Degradation Pathways in Fluoroethylene Carbonate Based Electrolytes via Chromatographic Techniques","authors":"Nick Fehlings,&nbsp;Matthias Weiling,&nbsp;Jakob Hesper,&nbsp;Maximilian Kubot,&nbsp;Martin Winter,&nbsp;Simon Wiemers-Meyer,&nbsp;Sascha Nowak","doi":"10.1002/batt.202500610","DOIUrl":"10.1002/batt.202500610","url":null,"abstract":"<p>For enhancing battery key performance indicators, like high voltage, safety, or lifetime, tailored electrolytes are crucial. Additives enable modifications of the solid electrolyte interphase (SEI) improving its electrochemical stability or mechanical strength. The formation and composition of the SEI still require further optimization. During operation, various side reactions of the electrolyte occur, resulting in continuous consumption of active material. The clarification of degradation mechanisms helps in understanding aging phenomena emerging during cycling. This article investigates different electrolytes formulations containing varying amounts fluoroethylene carbonate (FEC) for employment in high voltage applications. Long-term cycling revealed roll over effect occurring for the use of FEC and EC as cosolvents and highest capacity retention for FEC replacing EC. Subsequent <i>post mortem</i> electrolyte analysis by means of high-performance liquid chromatography coupled to quadrupole time of flight analyzer revealed the formation of FEC related degradation products. FEC undergoes subtraction of fluoride to form in situ VC which then continuously reacts with other electrolyte components. The identification of degradation products thus provides information about the degradation processes, confirmed for the first time by means of instrumental analytics.</p>","PeriodicalId":132,"journal":{"name":"Batteries & Supercaps","volume":"9 4","pages":""},"PeriodicalIF":4.7,"publicationDate":"2026-04-04","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://chemistry-europe.onlinelibrary.wiley.com/doi/epdf/10.1002/batt.202500610","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"147683076","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"OA","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Understanding Degradation Mechanisms in Water-In-Salt Electrolyte. Part 2: Impact of the Electrochemical Parameters on the Cycling Behavior of LiFePO4 versus TiS2 了解盐包水电解质的降解机制。第二部分:电化学参数对LiFePO4对TiS2循环行为的影响
IF 4.7 4区 材料科学
Batteries & Supercaps Pub Date : 2026-04-04 Epub Date: 2025-11-02 DOI: 10.1002/batt.202500678
Célia Doublet, Théo Faverge, Vincent Martin, Hiram Castillo Michel, Jean-Pascal Rueff, Marian Chatenet, Lauréline Lecarme, Claire Villevieille
{"title":"Understanding Degradation Mechanisms in Water-In-Salt Electrolyte. Part 2: Impact of the Electrochemical Parameters on the Cycling Behavior of LiFePO4 versus TiS2","authors":"Célia Doublet,&nbsp;Théo Faverge,&nbsp;Vincent Martin,&nbsp;Hiram Castillo Michel,&nbsp;Jean-Pascal Rueff,&nbsp;Marian Chatenet,&nbsp;Lauréline Lecarme,&nbsp;Claire Villevieille","doi":"10.1002/batt.202500678","DOIUrl":"10.1002/batt.202500678","url":null,"abstract":"<p>Water-in-salt electrolytes (WISE) have emerged as a promising route for the development of safe and high-voltage aqueous lithium-ion batteries, owing to their expanded electrochemical stability window (ESW) and reduced safety issue. Despite this potential, the long-term cycling performance of WISE-based cells remains hindered by multiple degradation phenomena all related to water, including hydrogen and oxygen evolution reactions, carbon corrosion, and interfacial instabilities. In this study, the electrochemical behavior and degradation mechanisms of full cells based on LiFePO<sub>4</sub> and TiS<sub>2</sub> electrodes are systematically investigated in 21 m LiTFSI electrolyte. Gas evolution is quantified using online electrochemical mass spectrometry (OEMS), while surface chemistry and morphology were analyzed via X-ray photoelectron spectroscopy (XPS), scanning electron microscopy (SEM), and synchrotron-based hard X-ray photoelectron spectroscopy (HAXPES). The results demonstrate that both electrode materials undergo significant parasitic reactions—even within the ESW—leading to the formation of a LiF-rich but unstable solid electrolyte interphase and progressive accumulation of salt decomposition products. The degradation is further influenced by electrochemical parameters such as C-rate, electrode balancing, and voltage window.</p>","PeriodicalId":132,"journal":{"name":"Batteries & Supercaps","volume":"9 4","pages":""},"PeriodicalIF":4.7,"publicationDate":"2026-04-04","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://chemistry-europe.onlinelibrary.wiley.com/doi/epdf/10.1002/batt.202500678","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"147683077","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"OA","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Boron-Mediated Reconfiguration of Charge Dynamics and Structural Integrity in P2-Type Layered Metal Oxide Cathodes 硼介导的p2型层状金属氧化物阴极电荷动力学重构和结构完整性
IF 4.7 4区 材料科学
Batteries & Supercaps Pub Date : 2026-04-04 Epub Date: 2025-11-14 DOI: 10.1002/batt.202500673
Neeraja Nair, Shantikumar V. Nair, Senthilkumar Baskar
{"title":"Boron-Mediated Reconfiguration of Charge Dynamics and Structural Integrity in P2-Type Layered Metal Oxide Cathodes","authors":"Neeraja Nair,&nbsp;Shantikumar V. Nair,&nbsp;Senthilkumar Baskar","doi":"10.1002/batt.202500673","DOIUrl":"10.1002/batt.202500673","url":null,"abstract":"<p>The rational tuning of layered metal oxide cathodes is central to advancing sodium-ion battery performance, particularly under high-voltage operation. Herein, the role of light weight boron as a covalent dopant is investigated to modulate the charge dynamics and structural robustness of P2-type Na<sub>0.67</sub>Ni<sub>0.33</sub>Mn<sub>0.67</sub>O<sub>2</sub> cathodes. Through strategic boron (B) doping at the oxygen framework, a reconfiguration of local bonding environments is observed, which mitigates transition-metal migration and stabilizes the layered lattice during high-voltage cycling. Electrochemical analyses reveal a trade-off between enhanced voltage retention and marginal capacity suppression at elevated doping levels, attributed to altered Na<sup>+</sup> diffusion pathways and phase evolution dynamics. Complementary structural and spectroscopic studies indicate suppressed phase transitions due to anionic redox, underscoring the dual role of boron in reinforcing both electronic transport and structural resilience. This work delineates the nuanced impact of B-doping on layered oxide chemistry, offering insight into defect-driven performance engineering for next-generation Na-ion energy storage systems.</p>","PeriodicalId":132,"journal":{"name":"Batteries & Supercaps","volume":"9 4","pages":""},"PeriodicalIF":4.7,"publicationDate":"2026-04-04","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"147683842","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Self-Sacrificial Copper Cluster-Catalyzed Oxygen Reduction: A Paradigm Shift in Zinc-Air Battery Technology 自我牺牲铜簇催化氧还原:锌-空气电池技术的范式转变
IF 4.7 4区 材料科学
Batteries & Supercaps Pub Date : 2026-04-04 Epub Date: 2025-11-07 DOI: 10.1002/batt.202500588
Murali Punniyamoorthy, Nadar Allwyn, Kalaivanan Ramamurthy, Murugavel Kathiresan, Marappan Sathish
{"title":"Self-Sacrificial Copper Cluster-Catalyzed Oxygen Reduction: A Paradigm Shift in Zinc-Air Battery Technology","authors":"Murali Punniyamoorthy,&nbsp;Nadar Allwyn,&nbsp;Kalaivanan Ramamurthy,&nbsp;Murugavel Kathiresan,&nbsp;Marappan Sathish","doi":"10.1002/batt.202500588","DOIUrl":"10.1002/batt.202500588","url":null,"abstract":"<p>Metal-ion decorated covalent organic frameworks (M-COFs) are prepared by reacting aldehyde-terminated Cu(I) clustered monomers and amine-terminated triazine monomers through imine linkages, and the as-prepared Cu(I) cluster-based COF is analyzed and tested for its electrocatalytic activity toward oxygen reduction reactions. These M-COFs are more stable and active under adverse conditions. The annealed sample (ACu-COF) displays an increased surface area of 120 m<sup>2 </sup>g<sup>−1</sup> compared to the pristine sample Cu-COF (19 m<sup>2 </sup>g<sup>−1</sup>). Because of its larger specific surface area, and active nitrogen content, the annealed counterpart with flower morphology exhibits exceptional oxygen reduction reaction (ORR) capabilities. The ACu-COF sample demonstrates a nearly four-electron ORR process, an onset potential of 0.92 V versus reversible hydrogen electrode (RHE), and a diffusion limiting current density of 3.85 mA cm<sup>−2</sup>. It also reached a half-wave potential of 0.78 V versus RHE. After 2000 cycles, the onset potential of the ACu-COF only dips by 28 mV, demonstrating its remarkable long-term durability. Additionally, the homemade primary zinc-air battery employing ACu-COF produces a specific capacity of 747 mAh g<sup>−1</sup> and a maximum peak power density of 133 mW cm<sup>−2</sup>.</p>","PeriodicalId":132,"journal":{"name":"Batteries & Supercaps","volume":"9 4","pages":""},"PeriodicalIF":4.7,"publicationDate":"2026-04-04","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"147683440","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Simultaneous Catalytic Construction of Closed-Pore-Rich Hard Carbon Anode and Generation of Na0.67Ni0.2Fe0.2Mn0.6O2 Cathode for Sodium-Ion Batteries 钠离子电池富闭孔硬碳阳极的同步催化构建及Na0.67Ni0.2Fe0.2Mn0.6O2阴极的制备
IF 4.7 4区 材料科学
Batteries & Supercaps Pub Date : 2026-04-04 Epub Date: 2025-11-03 DOI: 10.1002/batt.202500715
Tianzhuo Wen, Shimin Yan, Liangyu Li, Yan Ding, Jing Li, Zhongxue Chen
{"title":"Simultaneous Catalytic Construction of Closed-Pore-Rich Hard Carbon Anode and Generation of Na0.67Ni0.2Fe0.2Mn0.6O2 Cathode for Sodium-Ion Batteries","authors":"Tianzhuo Wen,&nbsp;Shimin Yan,&nbsp;Liangyu Li,&nbsp;Yan Ding,&nbsp;Jing Li,&nbsp;Zhongxue Chen","doi":"10.1002/batt.202500715","DOIUrl":"10.1002/batt.202500715","url":null,"abstract":"<p>Sodium-ion battery (SIB) has been regarded as a promising electrochemical device for stationary energy storage, whereas its widespread application is still hindered by relatively lower energy density and unredeemed cost-effectiveness. High-capacity anode materials are one of the bottlenecks limiting the improvement of energy density of SIBs, while tuning the closed porous structure is the most efficient approach to boost the plateau capacity. Unfortunately, simple and practical closed-pore-forming strategies remain scarce. Herein, a transition metal oxide catalytic strategy to prepare closed-pore-rich hard carbon anode for the first time while simultaneously transforming the catalyst into layered oxide cathode is reported. The abundant closed-pore structure provides an augmented array of sites for sodium ion storage, thereby contributing to a heightened plateau capacity and Coulombic efficiency. Hence, the obtained anode delivers a reversible capacity of 301.6 mAh g<sup>−1</sup> with a high initial coulombic efficiency of 92.3%. Note that a capacity retention of 98.4% is achieved after 300 cycles. In particular, a full cell constructed by the above closed-pore-rich hard carbon anode and layered oxide cathode demonstrates favorable energy density and cycling stability. This work is believed to provide a green and sustainable route for achieving high-performance SIB electrode materials.</p>","PeriodicalId":132,"journal":{"name":"Batteries & Supercaps","volume":"9 4","pages":""},"PeriodicalIF":4.7,"publicationDate":"2026-04-04","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"147683190","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Design Strategies for Electrolytes in Lithium Metal Batteries: Insights into Liquid and Solid-State Systems 锂金属电池中电解质的设计策略:对液体和固态系统的见解
IF 4.7 4区 材料科学
Batteries & Supercaps Pub Date : 2026-04-04 Epub Date: 2025-11-05 DOI: 10.1002/batt.202500550
Un Hwan Lee, Seonhye Park, Joonhee Kang
{"title":"Design Strategies for Electrolytes in Lithium Metal Batteries: Insights into Liquid and Solid-State Systems","authors":"Un Hwan Lee,&nbsp;Seonhye Park,&nbsp;Joonhee Kang","doi":"10.1002/batt.202500550","DOIUrl":"10.1002/batt.202500550","url":null,"abstract":"<p>Lithium metal anodes are considered indispensable for next-generation high-energy batteries, but their practical application is severely hampered by interfacial instabilities that lead to uncontrolled dendrite growth and continuous electrolyte consumption. This review systematically addresses these challenges by evaluating state-of-the-art electrolyte engineering strategies for both liquid and solid-state systems. In liquid electrolytes, key approaches are analyzed, including high-concentration/localized formulations, fluorinated components, and functional additives designed to form robust and stable solid electrolyte interphases. For solid-state electrolytes, advances in polymer, inorganic, and composite systems are surveyed, aimed at enhancing ionic conductivity while mechanically suppressing dendrites. Finally,a forward-looking perspective is proposed, highlighting that the integration of multiscale simulation, machine learning, and data-driven screening will be key to the rational design and rapid discovery of advanced electrolytes. This integrated approach is expected to overcome a critical bottleneck, paving the way for the realization of safe and high-performance lithium metal batteries.</p>","PeriodicalId":132,"journal":{"name":"Batteries & Supercaps","volume":"9 4","pages":""},"PeriodicalIF":4.7,"publicationDate":"2026-04-04","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://chemistry-europe.onlinelibrary.wiley.com/doi/epdf/10.1002/batt.202500550","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"147683214","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"OA","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Modification of the Solid Electrolyte Interphase on SiGr Electrodes by a Prelithiation Method Using Passivated Lithium Metal Powder 钝化金属锂粉预锂化法修饰SiGr电极固体电解质界面
IF 4.7 4区 材料科学
Batteries & Supercaps Pub Date : 2026-04-04 Epub Date: 2025-11-04 DOI: 10.1002/batt.202500514
Ekin Esen, Iratxe de Meatza, Martin Schmuck, Mohsen Padervand, Martin Winter, Elie Paillard, Masoud Baghernejad
{"title":"Modification of the Solid Electrolyte Interphase on SiGr Electrodes by a Prelithiation Method Using Passivated Lithium Metal Powder","authors":"Ekin Esen,&nbsp;Iratxe de Meatza,&nbsp;Martin Schmuck,&nbsp;Mohsen Padervand,&nbsp;Martin Winter,&nbsp;Elie Paillard,&nbsp;Masoud Baghernejad","doi":"10.1002/batt.202500514","DOIUrl":"10.1002/batt.202500514","url":null,"abstract":"<p>Negative electrode materials with high specific energy, such as SiGr, are essential to decrease battery cell weight and volume while allowing improved range and design flexibilities for electric vehicles. Among different SiGr anode prelithiation methods, the use of passivated lithium metal powder is discussed in terms of cell impedance and its effects on the interphase film formation on SiGr and LiNi<sub>0.8</sub>Mn<sub>0.1</sub>Co<sub>0.1</sub>O<sub>2</sub> (NMC-811) electrodes with high mass loadings. Electrochemical impedance spectroscopy analyses show that a less resistive and more effective solid electrolyte interphase (SEI) forms upon prelithiation which also benefits the charge transfer at the SiGr electrode. Scanning electron microscopy images show a thicker interphase layer with less interstitial porosity on the prelithiated SiGr electrodes and a thinner cathode electrolyte interphase on NMC-811 electrode as a result of the lower average cathode potential attained throughout cycling, in comparison with the cells without prelithiation. A more diverse SEI layer, richer in beneficial components such as LiF, is promoted by the prelithiation method as shown by X-ray photoelectron spectroscopy with a sputtering depth of 100 nm. Finally, it is shown that the more robust SEI layer forming upon prelithiation requires less electrolyte consumption for repairing the SEI layer throughout long-term cycling.</p>","PeriodicalId":132,"journal":{"name":"Batteries & Supercaps","volume":"9 4","pages":""},"PeriodicalIF":4.7,"publicationDate":"2026-04-04","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://chemistry-europe.onlinelibrary.wiley.com/doi/epdf/10.1002/batt.202500514","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"147683268","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"OA","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Recent Advances in Current Collectors for Anode-Free Lithium Metal Batteries 无阳极锂金属电池集流器研究进展
IF 4.7 4区 材料科学
Batteries & Supercaps Pub Date : 2026-04-04 Epub Date: 2025-11-02 DOI: 10.1002/batt.202500417
Yang Liu, Lina Pan, Peng Huang
{"title":"Recent Advances in Current Collectors for Anode-Free Lithium Metal Batteries","authors":"Yang Liu,&nbsp;Lina Pan,&nbsp;Peng Huang","doi":"10.1002/batt.202500417","DOIUrl":"10.1002/batt.202500417","url":null,"abstract":"<p>Lithium metal anodes are promising for next-generation batteries due to their ultrahigh theoretical capacity (3860 mAh g<sup>−1</sup>) and low redox potential. Anode-free lithium metal batteries offer enhanced energy density by eliminating prelithiated anodes. However, lithium's high reactivity causes dendrite growth, risking short circuits, while the unstable solid electrolyte interphase consumes active lithium and electrolyte, reducing cycle life and Coulombic efficiency (CE). Commercial copper foil current collectors, though conductive, promote uneven lithium deposition due to their smooth surfaces.Therefore, the modification of the Cu-based current collectors to reduce local current density, inhibit dendrite growth, and improve CE has been widely studied and reported. Herein, methods for modifying Cu-based current collectors are systematically summarized to guide the rational design of these modifications.</p>","PeriodicalId":132,"journal":{"name":"Batteries & Supercaps","volume":"9 4","pages":""},"PeriodicalIF":4.7,"publicationDate":"2026-04-04","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"147683073","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Conformal and Nanoscale Poly(pyrrole) Coating on Li3VO4 Surface Enabling High Performance Lithium-Ion Batteries Li3VO4表面保形纳米级聚吡咯涂层实现高性能锂离子电池
IF 4.7 4区 材料科学
Batteries & Supercaps Pub Date : 2026-04-04 Epub Date: 2025-11-04 DOI: 10.1002/batt.202500575
Mini Pothanadu Antony, Dona Susan Baji, Shantikumar Nair, Dhamodaran Santhanagopalan
{"title":"Conformal and Nanoscale Poly(pyrrole) Coating on Li3VO4 Surface Enabling High Performance Lithium-Ion Batteries","authors":"Mini Pothanadu Antony,&nbsp;Dona Susan Baji,&nbsp;Shantikumar Nair,&nbsp;Dhamodaran Santhanagopalan","doi":"10.1002/batt.202500575","DOIUrl":"10.1002/batt.202500575","url":null,"abstract":"<p>Lithium vanadium oxide (Li<sub>3</sub>VO<sub>4</sub>) shows great promise as an anode for high-efficiency Li-ion batteries (LIBs). However, its application is hindered by poor electronic conductivity and high charge transfer resistance caused by a thick and unstable solid electrolyte interface layer. A two-step approach aimed at improving the electrochemical performance of the LVO anode for high-rate and long-cycle LIBs is reported. This involves the hydrothermal synthesis of crystalline LVO, followed by a conformal coating of polypyrrole (Ppy) via vapor-phase polymerization. The conductive Ppy layer facilitates electron transport and enhances lithium-ion diffusion, mitigating the limitations of pristine LVO. Among the tested samples, [email protected] (0.5 indicates coating time in hours) exhibited the highest reversible capacity of 605 mAh g<sup>−1</sup>, nearly three times that of pristine LVO with an initial Coulombic efficiency of 87% upon chemical prelithiation. The rate capability studies revealed stable performance, with 78% capacity retention over 500 cycles at 10C. Electrochemical impedance spectroscopy reveals that the [email protected] electrode exhibits high Li-ion diffusivity, reduced interfacial layer resistance, and enhanced charge transfer kinetics. Ex situ surface chemical analysis confirms the formation of a stable solid–electrolyte interphase layer on [email protected]. Conformal Ppy coating on LVO is a promising strategy for developing high-performance LIB anode.</p>","PeriodicalId":132,"journal":{"name":"Batteries & Supercaps","volume":"9 4","pages":""},"PeriodicalIF":4.7,"publicationDate":"2026-04-04","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"147683271","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
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