Batteries & Supercaps最新文献_第10页

Dry-Pressed Fabrication of Lithium-Ion Electrodes Over 500 μm Thick 干压制造厚度超过 500 微米的锂离子电极

IF 5.1 4区材料科学

Batteries & Supercaps Pub Date : 2024-08-20 DOI: 10.1002/batt.202400301

Kedi Hu, William Fu, Alan C. West, Daniel A. Steingart

引用次数: 0

Metal Coordination Compounds for Organic Redox Flow Batteries 用于有机氧化还原流动电池的金属配位化合物

IF 5.1 4区材料科学

Batteries & Supercaps Pub Date : 2024-08-17 DOI: 10.1002/batt.202400434

Jiayi Gao, Lixing Xia, Miaoning Ou, Zhan'ao Tan

{"title":"Metal Coordination Compounds for Organic Redox Flow Batteries","authors":"Jiayi Gao, Lixing Xia, Miaoning Ou, Zhan'ao Tan","doi":"10.1002/batt.202400434","DOIUrl":"10.1002/batt.202400434","url":null,"abstract":"Along with the continuous optimization of the energy structure, more and more electricity come from intermittent renewable energy sources such as wind and solar energy. Redox flow batteries (RFBs) have the advantage that energy and power can be regulated independently, so they are widely used in large-scale energy storage. Redox active materials are the important components of RFBs, which determine the performance of the battery and the cost of energy storage. Some metal coordination compounds (MCCs) and their derivatives have been considered redox active materials that can replace metal-based redox flow batteries due to their properties such as tunability, high abundance and sustainability. MCCs can provide higher energy density because they are highly soluble both in the initial state and in any charged state during the battery cycling process. MCCs have also attracted a lot of attention from researchers because of their high economic value, low toxicity, and wide availability. This review provides an overview of the recent development of soluble metal coordination compounds, such as Ferrocene, and concludes with an in-depth discussion of the prospects of metal coordination compounds for application in organic redox flow batteries.","PeriodicalId":132,"journal":{"name":"Batteries & Supercaps","volume":"7 12","pages":""},"PeriodicalIF":5.1,"publicationDate":"2024-08-17","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"142185137","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

引用次数: 0

The Effect of Mud Cracking on the Performance of Thick Li-Ion Electrodes 泥浆裂解对厚锂离子电极性能的影响

IF 5.1 4区材料科学

Batteries & Supercaps Pub Date : 2024-08-17 DOI: 10.1002/batt.202400260

Will J. Dawson, Andrew R. T. Morrison, Francesco Iacoviello, Adam M. Boyce, Gargi Giri, Juntao Li, Thomas S. Miller, Paul Shearing

引用次数: 0

Electrolyte Developments for All-Solid-State Lithium Batteries: Classifications, Recent Advances and Synthesis Methods 全固态锂电池电解质的发展：分类、最新进展和合成方法

IF 5.1 4区材料科学

Batteries & Supercaps Pub Date : 2024-08-16 DOI: 10.1002/batt.202400432

Cheuk Hei Chan, Hon Ho Wong, Shipeng Liang, Mingzi Sun, Tong Wu, Qiuyang Lu, Lu Lu, Baian Chen, Bolong Huang

{"title":"Electrolyte Developments for All-Solid-State Lithium Batteries: Classifications, Recent Advances and Synthesis Methods","authors":"Cheuk Hei Chan, Hon Ho Wong, Shipeng Liang, Mingzi Sun, Tong Wu, Qiuyang Lu, Lu Lu, Baian Chen, Bolong Huang","doi":"10.1002/batt.202400432","DOIUrl":"10.1002/batt.202400432","url":null,"abstract":"The developments of all-solid-state lithium batteries (ASSLBs) have become promising candidates for next-generation energy storage devices. Compared to conventional lithium batteries, ASSLBs possess higher safety, energy density, and stability, which are determined by the nature of the solid electrolyte materials. In particular, various types of solid electrolyte materials have been developed to achieve similar or even superior ionic conductivity to the organic liquid electrolyte at room temperature. Although tremendous efforts have been devoted to the mechanistic understanding of solid electrolyte materials, the unsatisfactory electrochemical and mechanical performances limit the commercialization and practical application of ASSLBs. To further improve their performances, the current developments of different advanced solid electrolytes and their performances are highly significant. In this review, we summarize the comprehensive performance of the common solid electrolytes and their fabrication strategies, including inorganic-based solid electrolytes, solid polymer electrolytes, and composite solid electrolytes. The performances of the ASSLBs constructed by different solid electrolytes have been systematically compared. The practical challenges of ASSLBs will also be summarized in this review. This review aims to provide a comprehensive review of the current developments of solid electrolytes in ASSLBs and discuss the strategies for advanced solid electrolytes to facilitate the future commercialization of ASSLBs.","PeriodicalId":132,"journal":{"name":"Batteries & Supercaps","volume":"7 12","pages":""},"PeriodicalIF":5.1,"publicationDate":"2024-08-16","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://onlinelibrary.wiley.com/doi/epdf/10.1002/batt.202400432","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"142185140","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"OA","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

引用次数: 0

A Review on the Role of Hydrogen Bonds in Organic Electrode Materials 综述氢键在有机电极材料中的作用

IF 5.1 4区材料科学

Batteries & Supercaps Pub Date : 2024-08-15 DOI: 10.1002/batt.202400440

Yonghui Wang, Yuxuan Zhao, Xinlei Xu, Weizhe Gao, Qichun Zhang, Weiwei Huang

引用次数: 0

Metal-Organic Framework Materials as Bifunctional Electrocatalyst for Rechargeable Zn-Air Batteries 金属有机框架材料作为可充电锌-空气电池的双功能电催化剂

IF 5.1 4区材料科学

Batteries & Supercaps Pub Date : 2024-08-15 DOI: 10.1002/batt.202400402

Fangqing Liu, Xiaoyi Lu, Chenglong Shi, Zhipeng Sun

引用次数: 0

Li6.25Al0.25La3Zr1.75Nb0.25O12 Nanofiber Fillers Reinforced PVDF-HFP-Based Bilayer Composite Solid-State Electrolytes 锂6.25Al0.25La3Zr1.75Nb0.25O12纳米纤维填料增强PVDF-HFP双层复合固态电解质

IF 5.1 4区材料科学

Batteries & Supercaps Pub Date : 2024-08-14 DOI: 10.1002/batt.202400379

Minghua Chen, Wannian Liu, Yixin Wu, Yulong Liu, Yang Wang, Zhen Chen

{"title":"Li6.25Al0.25La3Zr1.75Nb0.25O12 Nanofiber Fillers Reinforced PVDF-HFP-Based Bilayer Composite Solid-State Electrolytes","authors":"Minghua Chen, Wannian Liu, Yixin Wu, Yulong Liu, Yang Wang, Zhen Chen","doi":"10.1002/batt.202400379","DOIUrl":"10.1002/batt.202400379","url":null,"abstract":"Composite solid-state electrolytes (CSEs) combining the advantages of polymer and ceramic electrolytes, are regarded as highly promising candidates for solid-state lithium metal batteries (SSLMBs). However, selecting appropriate polymer and ceramic materials, along with an effective combination method, is crucial in determining the performance of CSEs. To address the challenges of lithium dendrite inhibition and compatibility with cathodes simultaneously, herein, we have constructed a bilayer CSE based on poly(vinylidene fluoride)-hexafluoropropylene (PVDF-HFP). Al/Nb co-doped Li6.25Al0.25La3Zr1.75Nb0.25O12 (LALZNO) nanofibers prepared by an electrostatic spinning technique, are incorporated as fillers to create high-throughput Li+ transport pathways and enhance the overall performance of the CSE. Furthermore, polypropylene carbonate is introduced on the anode side of the CSE to enhance the wettability of lithium metal/CSE interface, thus improving the stability of lithium upon cycling. On the cathode side, succinonitrile is added to inhibit the crystallization of PVDF-HFP and facilitate the fast Li+ transport. Consequently, the Li||Li cells demonstrate stable plating-stripping performance at 0.1 mA cm−2 for >520 h. In addition, the Li||LiFePO4 full cells show improved cycling and rate performance. This work validates the effectiveness of developing bilayer CSEs and showcases their potential application in SSLMBs.","PeriodicalId":132,"journal":{"name":"Batteries & Supercaps","volume":"8 2","pages":""},"PeriodicalIF":5.1,"publicationDate":"2024-08-14","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"142185141","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

引用次数: 0

Sustainable Hard Carbon as Anode Materials for Na-Ion Batteries: From Laboratory to Upscaling 可持续硬碳作为钠离子电池的阳极材料：从实验室到扩大规模

IF 5.1 4区材料科学

Batteries & Supercaps Pub Date : 2024-08-14 DOI: 10.1002/batt.202400428

Zhenyu Guo, Kaitian Zheng, Mengnan Wang, Yichen Huang, Yuanzhu Zhao, Heather Au, Maria-Magdalena Titirici

{"title":"Sustainable Hard Carbon as Anode Materials for Na-Ion Batteries: From Laboratory to Upscaling","authors":"Zhenyu Guo, Kaitian Zheng, Mengnan Wang, Yichen Huang, Yuanzhu Zhao, Heather Au, Maria-Magdalena Titirici","doi":"10.1002/batt.202400428","DOIUrl":"10.1002/batt.202400428","url":null,"abstract":"Sodium-ion batteries (NIBs) are an alternative to lithium-ion batteries (LIBs), particularly in applications where cost, availability, and sustainability are more critical. Hard carbon is emerging as a promising anode material for NIBs, however, the scale up remains in developmental stages. In this study, we focus on the development and potential upscaling of sustainable hard carbon materials as anodes for NIBs. The synthesis of hard carbon starts from D-glucose, a scalable and environmentally benign precursor. A facile process combining hydrothermal carbonisation and subsequent pyrolysis at 1500 °C allows the hard carbon to become an industrially viable material. The resulting hard carbon demonstrates competitive performance metrics including a high initial Coulombic efficiency, high reversible capacity, long-term cycling stability, and rate capability. This study concludes with a discussion of the techno-economic analysis of adopting such sustainable materials in the battery industry, highlighting the potential for significant advancements in energy storage technologies.","PeriodicalId":132,"journal":{"name":"Batteries & Supercaps","volume":"8 2","pages":""},"PeriodicalIF":5.1,"publicationDate":"2024-08-14","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://onlinelibrary.wiley.com/doi/epdf/10.1002/batt.202400428","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"142185143","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"OA","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

引用次数: 0

Development and Upscaling of a Waterborne Formulation for High-Energy Density NMC811 Cathodes 开发和升级用于高能量密度 NMC811 阴极的水性配方

IF 5.1 4区材料科学

Batteries & Supercaps Pub Date : 2024-08-13 DOI: 10.1002/batt.202400358

Dr. Susan Sananes-Israel, Idoia Urdampilleta, Galyna Kvasha, Imanol Landa-Medrano, Iratxe de Meatza

{"title":"Development and Upscaling of a Waterborne Formulation for High-Energy Density NMC811 Cathodes","authors":"Dr. Susan Sananes-Israel, Idoia Urdampilleta, Galyna Kvasha, Imanol Landa-Medrano, Iratxe de Meatza","doi":"10.1002/batt.202400358","DOIUrl":"10.1002/batt.202400358","url":null,"abstract":"The pursuit of high-energy lithium-ion cells has led to an increase in the fraction of nickel in the LiNixMnyCozO2 (NMC, with x+y+z=1) layered oxide, a state-of-the-art cathode material in electric vehicles. NMC is usually processed using organic solvents that are non-sustainable. Nevertheless, increasing the Ni fraction entails a decrease in the electrode stability and the processability of this material in water. In this work, high-nickel NMC materials have been subjected to water processing. In an initial stage, water sensitivity of the materials has been studied. Then, the formulation has been adapted to enhance the NMC fraction without penalizations in the electrochemical performance and compared to an organic solvent-based formulation. The recipe developed, consisting of 93 % of NMC, has been successfully upscaled to a semi-industrial coating line. The pH buffering has been observed as a critical step to mitigate lithium leaching and implement this process in an industrial environment. The obtained electrodes have been tested in single-layer pouch cells using silicon-based negative electrodes, also processable in water-based slurries. The resulting cells provide limited cycling life due to the low cyclability of the negative electrode but evidence that it is industrially viable to manufacture high-energy cells consisting only of water-processed electrodes.","PeriodicalId":132,"journal":{"name":"Batteries & Supercaps","volume":"7 12","pages":""},"PeriodicalIF":5.1,"publicationDate":"2024-08-13","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://onlinelibrary.wiley.com/doi/epdf/10.1002/batt.202400358","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"142185146","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"OA","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

引用次数: 0

Pore-Filling Induced Solid Electrolyte Failure of Ti-Doped Na3Zr2Si2PO12 Characterized by Operando Synchrotron X-Ray Tomography** 通过操作同步辐射 X 射线断层扫描表征掺钛 Na3Zr2Si2PO12 的孔隙填充诱导固态电解质失效

IF 5.1 4区材料科学

Batteries & Supercaps Pub Date : 2024-08-13 DOI: 10.1002/batt.202400429

Mengya Li, Marm Dixit, Pavel Shevchenko, Francesco De Carlo, Mahalingam Balasubramanian, Ilias Belharouak

{"title":"Pore-Filling Induced Solid Electrolyte Failure of Ti-Doped Na3Zr2Si2PO12 Characterized by Operando Synchrotron X-Ray Tomography**","authors":"Mengya Li, Marm Dixit, Pavel Shevchenko, Francesco De Carlo, Mahalingam Balasubramanian, Ilias Belharouak","doi":"10.1002/batt.202400429","DOIUrl":"10.1002/batt.202400429","url":null,"abstract":"Solid-state batteries (SSBs), particularly those utilizing sodium metal, are emerging as a promising technology due to their potential for enhanced safety, higher energy density, and longer cycle life. NASICON (Na superionic conductor) materials, known for their robust crystalline structure and high ionic conductivity, are pivotal in the development of efficient sodium all-solid-state batteries. These materials exhibit high room-temperature ionic conductivity and electrochemical stability, making them ideal for various applications. Research has focused on improving NASICON's ionic conductivity and stability through doping, interface regulation, and composite anode design. Recent advancements include Ti-doped Na3Zr2Si2PO12 (Ti-NZSP), which demonstrates improved surface stability, higher ionic conductivity, and increased critical current density. However, challenges such as Na dendrite formation and mechanical integrity under operational conditions persist. Advanced imaging techniques like operando synchrotron X-ray tomography have provided insights into failure mechanisms, revealing that pore-filling and dendrite growth are significant issues. Understanding these processes is essential for enhancing the performance and safety of Na-based SSBs. This study underscores the need for continued research to address these challenges and develop reliable, high-performance solid-state electrolytes for future energy storage solutions.","PeriodicalId":132,"journal":{"name":"Batteries & Supercaps","volume":"8 2","pages":""},"PeriodicalIF":5.1,"publicationDate":"2024-08-13","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"142185145","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

引用次数: 0