Materials Today最新文献

Superior delamination resistant two-dimensional lamellar materials

IF 21.1 1区材料科学

Materials Today Pub Date : 2025-03-18 DOI: 10.1016/j.mattod.2025.02.011

Kaiwen Li , Lidan Wang , Feifan Chen , Jiahao Lu , Rui Guo , Yue Gao , Shiyu Luo , Xin Ming , Yue Lin , Zhen Xu , Manyi Huang , Chao Wang , Yingjun Liu , Chao Gao

{"title":"Superior delamination resistant two-dimensional lamellar materials","authors":"Kaiwen Li , Lidan Wang , Feifan Chen , Jiahao Lu , Rui Guo , Yue Gao , Shiyu Luo , Xin Ming , Yue Lin , Zhen Xu , Manyi Huang , Chao Wang , Yingjun Liu , Chao Gao","doi":"10.1016/j.mattod.2025.02.011","DOIUrl":"10.1016/j.mattod.2025.02.011","url":null,"abstract":"<div><div>Numerous 2D sheets are generally exfoliated and prevalent to be assembled into macroscopic lamellar materials. However, these highly expected materials still inherit the easy exfoliation of 2D sheets and exhibit severe delamination failure problems, despite their outstanding in-plane performances and functions. Here, we find the increasing stack order of 2D sheets inversely aggravates delamination and uncover the hidden interlayer dissipation as the dominating mechanism. We propose a strong interlayer entanglement toughening strategy to greatly improve the delamination strength of graphene oxide papers by 268%, achieving a superior delamination resistance of benchmark natural nacres. The interlayer disentanglement offers extra dissipative sites to alleviate the stress concentration of the crack tip and suppress the crack propagation. This work provides an effective structural design strategy to resolve the intrinsic delamination problem of 2D lamellar materials, paving the way to realistic applications as structural materials and durable coatings.</div></div>","PeriodicalId":387,"journal":{"name":"Materials Today","volume":"85 ","pages":"Pages 39-48"},"PeriodicalIF":21.1,"publicationDate":"2025-03-18","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"143833645","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":1,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

引用次数: 0

Strain engineering in gradient-structured metallic glasses for excellent overall water splitting

IF 21.1 1区材料科学

Materials Today Pub Date : 2025-03-16 DOI: 10.1016/j.mattod.2025.02.024

Chaoqun Pei , Shuangqin Chen , Jiuyuan Xie , Shidong Feng , Mingyuan Yu , Cheng Zhan , Yuyang Qian , Guannan Yang , Yuxuan Chen , Si Lan , Erjun Kan , Di Wang , Xiaoke Mu , Horst Hahn , Baoan Sun , Gerhard Wilde , Tao Feng

{"title":"Strain engineering in gradient-structured metallic glasses for excellent overall water splitting","authors":"Chaoqun Pei , Shuangqin Chen , Jiuyuan Xie , Shidong Feng , Mingyuan Yu , Cheng Zhan , Yuyang Qian , Guannan Yang , Yuxuan Chen , Si Lan , Erjun Kan , Di Wang , Xiaoke Mu , Horst Hahn , Baoan Sun , Gerhard Wilde , Tao Feng","doi":"10.1016/j.mattod.2025.02.024","DOIUrl":"10.1016/j.mattod.2025.02.024","url":null,"abstract":"<div><div>Metallic glasses (MGs) represent cutting-edge electrocatalysts due to their distinctive disordered atomic structure. However, enhancing the activity of MG catalysts poses a significant challenge. In this study, we present an innovative gradient structure design aimed at introducing strain effects into non-noble Ni<sub>40</sub>Fe<sub>40</sub>P<sub>20</sub> MG wires, resulting in a substantial enhancement of their water electrolysis efficiency. Our novel design strategy has been successfully implemented in various composition MG wires fabricated using the Taylor–Ulitovsky (TU) method. The gradient-structured metallic glasses (GS-MGs) enable the attainment of large and consistent surface tensile strain, which in turn modifies the electronic structure, leading to a remarkable improvement in catalytic performance. Furthermore, employing free-standing Ni<sub>40</sub>Fe<sub>40</sub>P<sub>20</sub> GS-MGs with a fully three-dimensional nanoporous structure as both cathode and anode in the overall water-splitting cell has achieved breakthrough performance in alkaline media. Notably, the cell exhibits significantly reduced potentials of only 1.378 V and 1.682 V at current densities of 10 mA cm<sup>−2</sup> and 1000 mA cm<sup>−2</sup>, respectively, surpassing precious metal catalysts and previously reported advanced electrocatalysts. This study demonstrates that strain engineering induced by gradient structures is a universal and effective strategy for enhancing the catalytic performance of MGs. It introduces a new paradigm for the development of high-efficiency water splitting applications.</div></div>","PeriodicalId":387,"journal":{"name":"Materials Today","volume":"85 ","pages":"Pages 100-111"},"PeriodicalIF":21.1,"publicationDate":"2025-03-16","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"143833639","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":1,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

引用次数: 0

Thermal diode-like metafabric with tunable asymmetric structure for continuous personal cooling

IF 21.1 1区材料科学

Materials Today Pub Date : 2025-03-12 DOI: 10.1016/j.mattod.2025.02.020

Chengfeng Ding , Yikai Jin , Yanyan Lin , Ningbo Cheng , Na Meng , Xianfeng Wang , Xia Yin , Jianyong Yu , Bin Ding

{"title":"Thermal diode-like metafabric with tunable asymmetric structure for continuous personal cooling","authors":"Chengfeng Ding , Yikai Jin , Yanyan Lin , Ningbo Cheng , Na Meng , Xianfeng Wang , Xia Yin , Jianyong Yu , Bin Ding","doi":"10.1016/j.mattod.2025.02.020","DOIUrl":"10.1016/j.mattod.2025.02.020","url":null,"abstract":"<div><div>Personal cooling textiles that can ensure human health and alleviate energy crises have been fabricated from various mechanisms including radiation, evaporation, and convection. However, there exists a significant challenge in achieving continuous cooling solely through thermal conduction especially in a changing environment. We report a novel strategy to create a thermal diode-like metafabric (TDM) with a tunable asymmetric structure that enables unidirectional thermal conductivity. The premise of the design is that the TDM dissipates body heat via the dense layer and insulates against environmental heat with the fluffy layer, making the heat dissipation function like a “thermal diode”. The resulting TDM can achieve a continuous cooling of 3.5 °C compared to cotton fabric, solely through thermal conduction. Additionally, it also integrates properties of ultrahigh air and moisture permeability, shape memory, and mechanical durability. The successful synthesis of such fascinating material may offer new perspectives on the design and advancement of thermal management materials in various fields.</div></div>","PeriodicalId":387,"journal":{"name":"Materials Today","volume":"85 ","pages":"Pages 91-99"},"PeriodicalIF":21.1,"publicationDate":"2025-03-12","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"143833638","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":1,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

引用次数: 0

Chelating diamine surface modifier enhances performance and stability of lead halide perovskite solar cells

IF 21.1 1区材料科学

Materials Today Pub Date : 2025-03-12 DOI: 10.1016/j.mattod.2025.02.015

Susana Ramos-Terrón , Luis Camacho , Juan-Pablo Correa-Baena , Carlo A.R. Perini , Gustavo de Miguel

{"title":"Chelating diamine surface modifier enhances performance and stability of lead halide perovskite solar cells","authors":"Susana Ramos-Terrón , Luis Camacho , Juan-Pablo Correa-Baena , Carlo A.R. Perini , Gustavo de Miguel","doi":"10.1016/j.mattod.2025.02.015","DOIUrl":"10.1016/j.mattod.2025.02.015","url":null,"abstract":"<div><div>Mono- or di-ammonium cations are commonly used to enhance the performance and stability of perovskite solar cells (PSCs) via surface defect passivation. However, their effectiveness is still limited by the little understanding of the structure–property-performance relationship of the capping layer/3D perovskite stack. In this work, two diamine spacers with similar chemical composition but different molecular geometry are tested: 4,4′-Dithiodianiline (<strong>2S</strong>) and 4,4′-Ethylenedianiline (<strong>ET</strong>). In <strong>2S</strong>, the two amine groups are spatially close owing to a torsion in the backbone of the molecule. Instead, in <strong>ET</strong> the amine groups are at the maximum distance. The torsion allows <strong>2S</strong> to bind to neighboring vacancy sites at the surface of the perovskite lattice, enhancing its passivation capabilities with respect to <strong>ET</strong>. The <strong>2S</strong> spacer forms a 2D metal halide phase at the perovskite surface, which offers better charge extraction properties than the 1D phase induced by <strong>ET</strong> spacer. In solar cells incorporating <strong>2S</strong>, these properties result in a power conversion efficiency (PCE) of 20.72 %, improved from the 18.36 % PCE of the reference and almost no loss of efficiency after 1000 h under constant illumination in inert atmosphere.</div></div>","PeriodicalId":387,"journal":{"name":"Materials Today","volume":"85 ","pages":"Pages 60-68"},"PeriodicalIF":21.1,"publicationDate":"2025-03-12","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"143833526","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":1,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

引用次数: 0

The rise of lithium bis(fluorosulfonyl) imide: An efficient alternative to LiPF6 and functional additive in electrolytes

IF 21.1 1区材料科学

Materials Today Pub Date : 2025-03-11 DOI: 10.1016/j.mattod.2025.02.018

Liqiong Tong , Jingqin Ji , Yanlan Zhao , Li Wang , Xiangming He

{"title":"The rise of lithium bis(fluorosulfonyl) imide: An efficient alternative to LiPF6 and functional additive in electrolytes","authors":"Liqiong Tong , Jingqin Ji , Yanlan Zhao , Li Wang , Xiangming He","doi":"10.1016/j.mattod.2025.02.018","DOIUrl":"10.1016/j.mattod.2025.02.018","url":null,"abstract":"<div><div>Lithium bis (fluorosulfonyl) imide (LiFSI), as a potential replacement for lithium hexafluorophosphate (LiPF<sub>6</sub>) and as an electrolyte additive for lithium-ion batteries, is attracting attention due to its advantages in low-temperature performance, multiplication capacity and cycle life. LiFSI exhibits superior performance compared to LiPF<sub>6</sub>, especially as an additive in high-power applications. However, it still faces challenges such as collector corrosion and complex production processes. Researchers are actively exploring solutions to face these challenges, primarily by optimizing electrolyte formulations to enhance LiFSI performance, improving synthesis processes to reduce costs and increase yields, and scaling up production to meet market demand. Despite the challenges, research and applications of LiFSI are increasing, and its performance, cost-effectiveness, and environmental benefits make it a strong contender for future battery technology. Continuous research and development will be the key to determining the scope of its integration and improvement in the battery industry.</div></div>","PeriodicalId":387,"journal":{"name":"Materials Today","volume":"85 ","pages":"Pages 282-303"},"PeriodicalIF":21.1,"publicationDate":"2025-03-11","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"143833531","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":1,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

引用次数: 0

A molecular review on weakly solvating electrolytes for lithium batteries

IF 21.1 1区材料科学

Materials Today Pub Date : 2025-03-11 DOI: 10.1016/j.mattod.2025.02.021

Yao-Peng Chen , Xiang Chen , Nan Yao , Zhao Zheng , Legeng Yu , Yu-Chen Gao , Han-Bing Zhu , Chao-Long Wang , Jin-Hao Yao , Qiang Zhang

{"title":"A molecular review on weakly solvating electrolytes for lithium batteries","authors":"Yao-Peng Chen , Xiang Chen , Nan Yao , Zhao Zheng , Legeng Yu , Yu-Chen Gao , Han-Bing Zhu , Chao-Long Wang , Jin-Hao Yao , Qiang Zhang","doi":"10.1016/j.mattod.2025.02.021","DOIUrl":"10.1016/j.mattod.2025.02.021","url":null,"abstract":"<div><div>Carbonate-based electrolytes have significantly advanced the practical applications of lithium batteries (LBs) in various fields. However, commercial carbonate-based electrolytes exhibit sluggish desolvation behavior, resulting in poor performance of LBs under fast-charging and low-temperature conditions. In contrast, weakly solvating electrolytes (WSEs) have demonstrated rapid desolvation due to relatively weak Li<sup>+</sup>–solvent interactions. This review summarizes the recent progress of molecular design strategies for WSEs. First, the origins and characteristics of WSEs are analyzed. The dielectric constant (<em>ε</em>) and donor number (DN) of solvents affect the interactions among Li<sup>+</sup>, solvents, and anions, which are critical for the formation of WSEs. Both theoretical calculations and experimental characterizations are introduced to afford qualitative or quantitative WSE investigation. The solvent molecule design strategies for WSEs are summarized, including increasing steric hindrance, reducing the number of donor atoms, and reducing the negative charge on donor atoms. Finally, insightful perspectives are proposed to advance the development of WSEs in practical LBs.</div></div>","PeriodicalId":387,"journal":{"name":"Materials Today","volume":"85 ","pages":"Pages 304-318"},"PeriodicalIF":21.1,"publicationDate":"2025-03-11","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"143833652","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":1,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

引用次数: 0

A review of cyclodextrins polymers in solid-phase (micro)extraction

IF 21.1 1区材料科学

Materials Today Pub Date : 2025-03-11 DOI: 10.1016/j.mattod.2025.02.013

Yingying Wang , Lan He , Weijie Wei , Xiaqing Zhang , Jiang Wang , Jin Li , Zhuwei Gao

引用次数: 0

Photonic structures in multispectral camouflage: From static to dynamic technologies

IF 21.1 1区材料科学

Materials Today Pub Date : 2025-03-10 DOI: 10.1016/j.mattod.2025.02.016

Chunyun Cheng , Jingchong Liu , Fuqiang Wang , Cunhai Wang

{"title":"Photonic structures in multispectral camouflage: From static to dynamic technologies","authors":"Chunyun Cheng , Jingchong Liu , Fuqiang Wang , Cunhai Wang","doi":"10.1016/j.mattod.2025.02.016","DOIUrl":"10.1016/j.mattod.2025.02.016","url":null,"abstract":"<div><div>Ubiquitous camouflage phenomena in natural inspire and promote the development of modern camouflage technologies. Currently, the combination of detectors working across different wavebands has posed severe threats to camouflage technologies working within single/narrow wavebands, creating an urgent demand for advanced multispectral camouflage technologies. However, due to distinct or even incompatible requirements of thermal properties at different wavelengths, achieving multispectral camouflage via the same structure still remains tremendously challenging. Benefiting from the micro/nanomanufacturing technologies, various photonic structures that enable precise manipulation of electromagnetic waves emerge, and they have been successfully applied to multispectral camouflage. In contrast, a systematic review of photonic engineered structures in multispectral camouflage technologies is still lacking. Herein, we present the state-of-the-art review of advanced photonic structures in multispectral camouflage technologies. This review commences with the elucidation of spectral detection principles and corresponding requirements for multispectral camouflage, summarizes exceptional photonic structures for static infrared compatible multi-band camouflage application, continuous with innovative photonic structures integrated with dynamically reconfigurable materials for adaptive multispectral camouflage, and ultimately ends with challenges and perspectives for the future development of photonic structures in multispectral camouflage technologies. This review can serve as guidance for designing and applying photonic structures in multispectral camouflage technologies.</div></div>","PeriodicalId":387,"journal":{"name":"Materials Today","volume":"85 ","pages":"Pages 253-281"},"PeriodicalIF":21.1,"publicationDate":"2025-03-10","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"143833530","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":1,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

引用次数: 0

Crystal engineering strategies for advanced electrocatalysts in lithium-sulfur batteries

IF 21.1 1区材料科学

Materials Today Pub Date : 2025-03-10 DOI: 10.1016/j.mattod.2025.02.022

Lucheng Cai, Hangjun Ying, Wei-Qiang Han

{"title":"Crystal engineering strategies for advanced electrocatalysts in lithium-sulfur batteries","authors":"Lucheng Cai, Hangjun Ying, Wei-Qiang Han","doi":"10.1016/j.mattod.2025.02.022","DOIUrl":"10.1016/j.mattod.2025.02.022","url":null,"abstract":"<div><div>Lithium-sulfur batteries (LSBs) have captured considerable interest from both academia and industry due to their exceptional energy density. Nevertheless, the inherent sluggish redox kinetics of sulfur species and the shuttle effect instigated by lithium polysulfides (LiPSs) have impeded the progress of LSBs, severely compromising their overall performance. The application of catalytic materials is deemed a promising approach to enhance these kinetics. In recent years, the manipulation of the crystal lattice of catalysts has been demonstrated to enhance their catalytic performance. Given the lack of comprehensive overviews on the development of this strategy and the concomitant performance optimization techniques, we propose a crystal engineering strategy for electrocatalysts in lithium-sulfur batteries and review the relevant research progress. The crystal engineering strategy we proposed for electrocatalysts in lithium-sulfur batteries comprises the following four aspects: (1) Phase transition: alterations in atomic configurations; (2) Crystalline and amorphous states: disorder of atomic arrangements; (3) Lattice distortion: optimization of lattice parameters; (4) Preferential crystal facet exposure: variations among crystal faces. Finally, we discuss the challenges and obstacles encountered in implementing this strategy. This review aims to guide future research efforts toward optimizing LSBs performance through advanced crystal engineering techniques.</div></div>","PeriodicalId":387,"journal":{"name":"Materials Today","volume":"85 ","pages":"Pages 319-346"},"PeriodicalIF":21.1,"publicationDate":"2025-03-10","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"143833651","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":1,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

引用次数: 0

Boosting ammonia electrosynthesis via interfacial tandem nitrate reduction enabled by an amorphous@crystalline electrocatalyst

IF 21.1 1区材料科学

Materials Today Pub Date : 2025-03-08 DOI: 10.1016/j.mattod.2025.02.012

Zeyu Li , Qing Wang , Lixiang Zhong , Chunshuang Yan , Zichen Shi , Yinggang Ou , Yaru Shang , Chu Zhang , Shengji Tian , Hengjie Liu , Daobin Liu , Pin Song , Zeming Qi , Li Song , Chade Lv

{"title":"Boosting ammonia electrosynthesis via interfacial tandem nitrate reduction enabled by an amorphous@crystalline electrocatalyst","authors":"Zeyu Li , Qing Wang , Lixiang Zhong , Chunshuang Yan , Zichen Shi , Yinggang Ou , Yaru Shang , Chu Zhang , Shengji Tian , Hengjie Liu , Daobin Liu , Pin Song , Zeming Qi , Li Song , Chade Lv","doi":"10.1016/j.mattod.2025.02.012","DOIUrl":"10.1016/j.mattod.2025.02.012","url":null,"abstract":"<div><div>Electrocatalytic ammonia synthesis through the nitrate to ammonia (NRA) technique is of energy and environmental sustainability for the nitrogen cycle. Nevertheless, the nitrite (*NO<sub>2</sub>) intermediate may desorb, which would reduce the productivity of ammonia and the of Faradaic efficiency. Here, a heterostructured electrocatalyst consisting of amorphous CuO and crystalline CeO<sub>2</sub> is prepared for efficient NH<sub>3</sub> production through the interface tandem [2 + 6]-electron electrocatalysis approach. In alkaline medium, the NH<sub>3</sub> yield and Faradaic efficiency reach 8.6 mg h<sup>−1</sup> mg<sub>cat</sub><sup>−1</sup> and 96 %, respectively. As evidenced by the <em>in situ</em> experiments and theoretical calculations, the amorphous@crystalline interfacial local unsaturated Cu-Ce bimetallic site configuration endows the heterostructured electrocatalyst with strong *NO<sub>2</sub> adsorption abilities and sufficient *H supply, which synergistically catalyze NH<sub>3</sub> production through the [2 + 6]-electron NRA process. Furthermore, the Zn-NO<sub>3</sub><sup>−</sup> battery devices, constructed with amorphous-CuO@crystalline-CeO<sub>2</sub> as electrode materials, demonstrate outstanding application results. This work suggests an achievable route for promoting the NRA activity, enabling simultaneous ammonia production, electricity generation, and wastewater treatment, and holds great potential for the development of new heterostructured electrocatalysts for NH<sub>3</sub> production.</div></div>","PeriodicalId":387,"journal":{"name":"Materials Today","volume":"85 ","pages":"Pages 49-59"},"PeriodicalIF":21.1,"publicationDate":"2025-03-08","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"143833525","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":1,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

引用次数: 0