Journal of Alloys and Compounds最新文献

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Dynamic interfaces in manganese oxide-based oxygen evolution: Coupling catalyst design with electrolyte ion effects 锰基析氧的动态界面:电解液离子效应耦合催化剂设计
IF 6.2 2区 材料科学
Journal of Alloys and Compounds Pub Date : 2026-11-01 DOI: 10.1016/j.jallcom.2026.191730
Chuanbin Li,Jianpin Liu,Ling Lon,Feng Zhu,Xin Li,Qihang Dai,Xiaoshan Qian,Zhiwen Qiu,Qiliang Zhang,Yanxi Yin
{"title":"Dynamic interfaces in manganese oxide-based oxygen evolution: Coupling catalyst design with electrolyte ion effects","authors":"Chuanbin Li,Jianpin Liu,Ling Lon,Feng Zhu,Xin Li,Qihang Dai,Xiaoshan Qian,Zhiwen Qiu,Qiliang Zhang,Yanxi Yin","doi":"10.1016/j.jallcom.2026.191730","DOIUrl":"https://doi.org/10.1016/j.jallcom.2026.191730","url":null,"abstract":"","PeriodicalId":344,"journal":{"name":"Journal of Alloys and Compounds","volume":"21 1","pages":"191730"},"PeriodicalIF":6.2,"publicationDate":"2026-11-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"149208744","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":2,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Multiscale structural inheritance drives strength-ductility synergy in a 2055 Al-Cu-Li alloy via integrated ultrasonic melt treatment and thermomechanical processing 2055铝铜锂合金的多尺度结构继承通过超声熔体处理和热机械综合加工驱动强度-延性协同效应
IF 6.2 2区 材料科学
Journal of Alloys and Compounds Pub Date : 2026-11-01 DOI: 10.1016/j.jallcom.2026.191748
Li Zhang,Zhilong Du,Liguo Wang,Shaokang Guan
{"title":"Multiscale structural inheritance drives strength-ductility synergy in a 2055 Al-Cu-Li alloy via integrated ultrasonic melt treatment and thermomechanical processing","authors":"Li Zhang,Zhilong Du,Liguo Wang,Shaokang Guan","doi":"10.1016/j.jallcom.2026.191748","DOIUrl":"https://doi.org/10.1016/j.jallcom.2026.191748","url":null,"abstract":"","PeriodicalId":344,"journal":{"name":"Journal of Alloys and Compounds","volume":"62 1","pages":"191748"},"PeriodicalIF":6.2,"publicationDate":"2026-11-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"149208740","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":2,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
A review of ceramic-reinforced nickel-based superalloys: processing, properties, and applications 陶瓷增强镍基高温合金的研究进展:工艺、性能及应用
IF 6.2 2区 材料科学
Journal of Alloys and Compounds Pub Date : 2026-11-01 DOI: 10.1016/j.jallcom.2026.191712
Abdalla Elmaghraby,Sadettin Cem Altıparmak,AMM Nazmul Ahsan,Jianzhi Li
{"title":"A review of ceramic-reinforced nickel-based superalloys: processing, properties, and applications","authors":"Abdalla Elmaghraby,Sadettin Cem Altıparmak,AMM Nazmul Ahsan,Jianzhi Li","doi":"10.1016/j.jallcom.2026.191712","DOIUrl":"https://doi.org/10.1016/j.jallcom.2026.191712","url":null,"abstract":"","PeriodicalId":344,"journal":{"name":"Journal of Alloys and Compounds","volume":"63 1","pages":"191712"},"PeriodicalIF":6.2,"publicationDate":"2026-11-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"149208673","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":2,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Evaporation-induced hexagonal-to-monoclinic phase engineering in GaSexTe1-x for self-powered broadband photodetection 蒸发诱导的GaSexTe1-x自供电宽带光探测的六边形到单斜相工程
IF 6.2 2区 材料科学
Journal of Alloys and Compounds Pub Date : 2026-11-01 DOI: 10.1016/j.jallcom.2026.191767
Hüseyin Kaan Kaplan,Uygar Berke Gür,Huriye Gencal,Kadir Can Doğan,Orhan Şentürk,Ali Olkun,Mehmet Yağmurcukardeş,Umut Aydemi̇r,Sertan Kemal Akay
{"title":"Evaporation-induced hexagonal-to-monoclinic phase engineering in GaSexTe1-x for self-powered broadband photodetection","authors":"Hüseyin Kaan Kaplan,Uygar Berke Gür,Huriye Gencal,Kadir Can Doğan,Orhan Şentürk,Ali Olkun,Mehmet Yağmurcukardeş,Umut Aydemi̇r,Sertan Kemal Akay","doi":"10.1016/j.jallcom.2026.191767","DOIUrl":"https://doi.org/10.1016/j.jallcom.2026.191767","url":null,"abstract":"","PeriodicalId":344,"journal":{"name":"Journal of Alloys and Compounds","volume":"35 1","pages":"191767"},"PeriodicalIF":6.2,"publicationDate":"2026-11-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"149208654","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":2,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Microstructure evolution and corrosion mechanisms of silica refractory in a pure hydrogen atmosphere at high temperature 高温纯氢气氛中二氧化硅耐火材料的组织演变及腐蚀机理
IF 6.7 2区 材料科学
Journal of Alloys and Compounds Pub Date : 2026-10-16 DOI: 10.1016/j.jallcom.2026.191787
Wenhui Nie, Tiantian Gu, Yanyan Liu, Yusheng Lu, Jianming Dan, Ding Chen, Shaofei Li
{"title":"Microstructure evolution and corrosion mechanisms of silica refractory in a pure hydrogen atmosphere at high temperature","authors":"Wenhui Nie,&nbsp;Tiantian Gu,&nbsp;Yanyan Liu,&nbsp;Yusheng Lu,&nbsp;Jianming Dan,&nbsp;Ding Chen,&nbsp;Shaofei Li","doi":"10.1016/j.jallcom.2026.191787","DOIUrl":"10.1016/j.jallcom.2026.191787","url":null,"abstract":"<div><div>The safety of hydrogen at high temperatures depends on the lining refractories, however research on their corrosion behavior in a pure hydrogen environment is still in its infancy. In light of their extensive use in high-temperature industries and the potential hydrogen corrosion risk associated with their high SiO<sub>2</sub> content, the corrosion behavior of coke oven silica bricks in a pure hydrogen environment at 1200–1450 °C, along with their macroscopic physical properties, microstructure, and phase evolution, were systematically investigated in this work. The results indicate that higher temperatures and smaller sample sizes accelerated material weight loss. Although corrosion generally degrades mechanical properties, an anomalous relative strength recovery was observed after exposure at 1450°C for 4<!--> <!-->h compared with specimens corroded at lower temperatures. Microstructural analysis suggests that this recovery may be associated with the in‑situ formation of SiO<sub>2</sub> fibers via disproportionation reactions, with fiber growth governed by both the “vapor‑liquid‑solid” (VLS) and “vapor‑solid” (VS) mechanisms. By elucidating the corrosion behavior and the relative strength recovery phenomenon, this study provides a theoretical basis for selecting and designing refractory materials for hydrogen service at high temperature.</div></div>","PeriodicalId":344,"journal":{"name":"Journal of Alloys and Compounds","volume":"1083 ","pages":"Article 191787"},"PeriodicalIF":6.7,"publicationDate":"2026-10-16","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"149204275","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":2,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Advances in Photo-Supercapacitor Technologies for Integrated Energy Harvesting and Storage 集成能量收集与存储的光-超级电容器技术研究进展
IF 6.7 2区 材料科学
Journal of Alloys and Compounds Pub Date : 2026-10-15 DOI: 10.1016/j.jallcom.2026.191670
Nadiya Ayu Astarini, Andrei Bernadette, Hairus Abdullah, Meng-Lin Tsai, Mika Sillanpää
{"title":"Advances in Photo-Supercapacitor Technologies for Integrated Energy Harvesting and Storage","authors":"Nadiya Ayu Astarini,&nbsp;Andrei Bernadette,&nbsp;Hairus Abdullah,&nbsp;Meng-Lin Tsai,&nbsp;Mika Sillanpää","doi":"10.1016/j.jallcom.2026.191670","DOIUrl":"10.1016/j.jallcom.2026.191670","url":null,"abstract":"<div><div>The production of sustainable energy through clean energy technology has a crucial intention to overcome the limitations of conventional energy sources and environmental damage. A significant number of solar energy devices have been developed because of their abundant supply. However, the performance of single-photovoltaic energy systems is strongly influenced by weather conditions, geographic location, and illumination duration. Therefore, they require support from complementary energy sources within the overall energy system. To address this limitation, integrating a solar cell with a supercapacitor enables direct photo-charging, providing an alternative photo-rechargeable energy solution without generating harmful pollutants. The novel photo-supercapacitor system offers many potential advantages, such as high energy densities, storing harvested solar energy, quick response time, fast charge and discharge rates, a wide operating temperature range, stabilizing power systems, and environmental sustainability. Furthermore, a synergy of photoactive semiconductors and capacitive compounds can be helpful in the fabrication of both stimulus-responsive materials. This allows the photo-generated carrier device to be an effective and ideal renewable energy technology. In this study, we provide a broad overview of the design configuration, working mechanism, and fabrication of various compact system forms of photo-supercapacitor devices. A comparative analysis of innovative materials and electrochemical characterization is specifically explained to evaluate comprehensive energy conversion performance. Herein, this review summarizes all of the advances in photo-supercapacitors for these next-generation energy harvesting and storage, including potential, opportunities, and challenges to build sustainable energy systems as the pioneers of green energy production.</div></div>","PeriodicalId":344,"journal":{"name":"Journal of Alloys and Compounds","volume":"1083 ","pages":"Article 191670"},"PeriodicalIF":6.7,"publicationDate":"2026-10-15","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"149204562","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":2,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Fabrication of ultrahigh mass-loaded flexible self-supported electrodes for high-performance supercapacitors 高性能超级电容器用超高质量负载柔性自支撑电极的制备
IF 6.7 2区 材料科学
Journal of Alloys and Compounds Pub Date : 2026-10-15 DOI: 10.1016/j.jallcom.2026.191639
Xinpu Yang, Zhanwen Wang, Yuan He, Siqi Chen, Gang Wang, Xiping Yang, Mingxia Lu
{"title":"Fabrication of ultrahigh mass-loaded flexible self-supported electrodes for high-performance supercapacitors","authors":"Xinpu Yang,&nbsp;Zhanwen Wang,&nbsp;Yuan He,&nbsp;Siqi Chen,&nbsp;Gang Wang,&nbsp;Xiping Yang,&nbsp;Mingxia Lu","doi":"10.1016/j.jallcom.2026.191639","DOIUrl":"10.1016/j.jallcom.2026.191639","url":null,"abstract":"&lt;div&gt;&lt;ul&gt;&lt;li&gt;&lt;span&gt;•&lt;/span&gt;&lt;span&gt;&lt;div&gt;A binder-free 3D interpenetrating conductive network (CNT/GO) network is constructed on carbon cloth serve as stable scaffold for high-loading PANI deposition.&lt;/div&gt;&lt;/span&gt;&lt;/li&gt;&lt;li&gt;&lt;span&gt;•&lt;/span&gt;&lt;span&gt;&lt;div&gt;The optimized electrode achieves ultrahigh mass loading of 22&lt;!--&gt; &lt;!--&gt;mg&lt;!--&gt; &lt;!--&gt;cm&lt;sup&gt;–2&lt;/sup&gt; and exhibits outstanding areal capacitance and remarkable rate capability.&lt;/div&gt;&lt;/span&gt;&lt;/li&gt;&lt;li&gt;&lt;span&gt;•&lt;/span&gt;&lt;span&gt;&lt;div&gt;The electrode delivers a high areal capacitance of 4116 mF⋅cm&lt;sup&gt;–2&lt;/sup&gt; at 5&lt;!--&gt; &lt;!--&gt;mg⋅cm&lt;sup&gt;–2&lt;/sup&gt;.&lt;/div&gt;&lt;/span&gt;&lt;/li&gt;&lt;li&gt;&lt;span&gt;•&lt;/span&gt;&lt;span&gt;&lt;div&gt;It retains 81% of initial capacitance after 10,000 cycles at 40&lt;!--&gt; &lt;!--&gt;mA⋅cm&lt;sup&gt;–2&lt;/sup&gt;.&lt;/div&gt;&lt;/span&gt;&lt;/li&gt;&lt;/ul&gt;&lt;/div&gt;&lt;div&gt;&lt;div&gt;The rapid advancement of flexible and wearable electronics has intensified the demand for energy storage devices that combine high-mass-loading active materials with superior rate performance. However, high-mass-loading electrodes often suffer from slow ion diffusion and inefficient electron conduction, which severely limit their rate capability and practical application. To overcome these limitations, we construct a binder-free three-dimensional (3D) interconnected network on functionalized carbon cloth (FCC) by integrating one-dimensional (1D) carbon nanotubes (CNTs) and two-dimensional (2D) graphene oxide (GO). This architecture serves as a robust scaffold to enable efficient polyaniline (PANI) deposition. Experimental results reveal that 1D CNTs function as conductive interlinks bridging 2D GO nanosheets and the FCC substrate, effectively lowering the charge transfer resistance (&lt;em&gt;R&lt;/em&gt;&lt;sub&gt;&lt;em&gt;ct&lt;/em&gt;&lt;/sub&gt;) and establishing unobstructed transport channels for both electrons and electrolyte ions. Owing to this hierarchical structural design, the electrode achieved an ultrahigh mass loading of 22&lt;!--&gt; &lt;!--&gt;mg⋅cm⁻&lt;sup&gt;2&lt;/sup&gt; after 3600&lt;!--&gt; &lt;!--&gt;s electrodeposition. Electrochemical measurements in a three-electrode configuration delivered a remarkable areal capacitance of 4116 mF⋅cm⁻&lt;sup&gt;2&lt;/sup&gt; at a current density of 5&lt;!--&gt; &lt;!--&gt;mA⋅cm⁻&lt;sup&gt;2&lt;/sup&gt;. Notably, it maintains a capacitance retention of 85.2% even at an ultrahigh current density of 100&lt;!--&gt; &lt;!--&gt;mA⋅cm⁻&lt;sup&gt;2&lt;/sup&gt;, demonstrating excellent rate performance. A symmetric flexible solid-state supercapacitor (FSSC) assembled using this electrode exhibits a high areal capacitance of 1123 mF⋅cm⁻&lt;sup&gt;2&lt;/sup&gt; at 5&lt;!--&gt; &lt;!--&gt;mA⋅cm⁻&lt;sup&gt;2&lt;/sup&gt; with 83.5% capacitance retention at 100&lt;!--&gt; &lt;!--&gt;mA⋅cm⁻&lt;sup&gt;2&lt;/sup&gt;, along with a maximum areal energy density of 190.83 μWh⋅cm⁻&lt;sup&gt;2&lt;/sup&gt; and a power density of 2000 μW⋅cm⁻&lt;sup&gt;2&lt;/sup&gt;. These results highlight the great potential of the proposed electrode for high-performance flexible energy storage applications.&lt;/div&gt;&lt;/div&gt;&lt;div&gt;The rapid advancement of flexible and wearable electronics has intensified the demand for energy storage devices that combine high-mass-loading active materials with superior rate","PeriodicalId":344,"journal":{"name":"Journal of Alloys and Compounds","volume":"1083 ","pages":"Article 191639"},"PeriodicalIF":6.7,"publicationDate":"2026-10-15","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"149204838","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":2,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Research on dimensional instability control of aluminum alloy thin-walled components based on droplet + arc additive manufacturing 基于液滴+电弧增材制造的铝合金薄壁件尺寸不稳定性控制研究
IF 6.7 2区 材料科学
Journal of Alloys and Compounds Pub Date : 2026-10-14 DOI: 10.1016/j.jallcom.2026.191594
Wang Xin, Gao Xinxin, Han Leng, Bai Yin, Wang Shuxian, Chen Junqiao, Liu Yaru
{"title":"Research on dimensional instability control of aluminum alloy thin-walled components based on droplet + arc additive manufacturing","authors":"Wang Xin,&nbsp;Gao Xinxin,&nbsp;Han Leng,&nbsp;Bai Yin,&nbsp;Wang Shuxian,&nbsp;Chen Junqiao,&nbsp;Liu Yaru","doi":"10.1016/j.jallcom.2026.191594","DOIUrl":"10.1016/j.jallcom.2026.191594","url":null,"abstract":"<div><div>Although droplet + arc additive manufacturing technology has significant advantages in the efficiency of producing metal components but faces challenges in achieving dimensional accuracy during forming processes. This article addresses these challenges through a structured approach. To this end, a mathematical model is developed to predict the flight distance of molten droplets. Based on this model, displacement compensation is designed to ensure precise initial positioning during single-layer deposition. Secondly, thermal accumulation characteristics within the forming system during layer-by-layer deposition are analyzed. This involves integrating process parameters with temperature monitoring data between deposition layers to establish an energy balance relationship. Thirdly, secondary deposition is conducted on a 10-layer thin-walled component to explore the relationship between arc energy density and deposition layer size under conditions of two-dimensional heat dissipation. The results highlight the importance of controlling arc energy density in droplet + arc additive manufacturing to customize thin-walled dimensions, optimize thermal accumulation effects, and enhance the stability of sample formation.</div></div>","PeriodicalId":344,"journal":{"name":"Journal of Alloys and Compounds","volume":"1083 ","pages":"Article 191594"},"PeriodicalIF":6.7,"publicationDate":"2026-10-14","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"149204563","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":2,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Selective laser melting of in-situ formed nano SiC-reinforced AlSi10Mg composite: Microstructural and mechanical properties 原位成形纳米sic增强AlSi10Mg复合材料的选择性激光熔化:显微组织和力学性能
IF 6.7 2区 材料科学
Journal of Alloys and Compounds Pub Date : 2026-10-14 DOI: 10.1016/j.jallcom.2026.191746
QiFeng Shi, Yi Xiong, Chao Zhang, Kaikai Xu, Wanli Ling, Dongsheng Wang, Huishu Wu
{"title":"Selective laser melting of in-situ formed nano SiC-reinforced AlSi10Mg composite: Microstructural and mechanical properties","authors":"QiFeng Shi,&nbsp;Yi Xiong,&nbsp;Chao Zhang,&nbsp;Kaikai Xu,&nbsp;Wanli Ling,&nbsp;Dongsheng Wang,&nbsp;Huishu Wu","doi":"10.1016/j.jallcom.2026.191746","DOIUrl":"10.1016/j.jallcom.2026.191746","url":null,"abstract":"<div><div>In this work, a chemical reduction method was developed to produce AlSi10Mg powders uniformly coated with a graphene-oxide-derived carbon layer (rGO/AlSi10Mg powders, where rGO denotes partially reduced graphene oxide). The composite (designated as SiC-AlSi10Mg) was then fabricated using selective laser melting (SLM). The microstructure of the as-built composite is remarkably refined, its average grain size decreases to approximately 5.1 μm, compared with the heterogeneous, coarser-grain structure of the SLM AlSi10Mg alloy (featuring coarse grains reaching 15–20 μm). During SLM, combined evidence from XRD, Raman spectroscopy, EDS and HRTEM suggests the possible in-situ formation of minor nanoscale SiC, with carbon originating from partially reduced graphene oxide and silicon from the AlSi10Mg alloy. These potentially in-situ formed SiC particles tend to segregate at grain boundaries, correlating with increased dislocation density. The SLM SiC-AlSi10Mg alloy delivers a superior combination of mechanical properties: its tensile strength (ultimate tensile strength ~467<!--> <!-->MPa, yield strength ~383<!--> <!-->MPa) and microhardness (161.2 HV0.1) significantly exceed those of the SLM AlSi10Mg alloy (~401<!--> <!-->MPa, ~275<!--> <!-->MPa, and ~116.9 HV0.1, respectively). Notably, such property improvement is not achieved at the expense of ductility; instead, the elongation increase from 8.6% to 16.1%. The concurrent enhancement of strength and ductility arises from the combined contributions of dislocation generation, grain refinement, the potential formation of trace SiC, and residual graphene‑derived phases.</div></div>","PeriodicalId":344,"journal":{"name":"Journal of Alloys and Compounds","volume":"1083 ","pages":"Article 191746"},"PeriodicalIF":6.7,"publicationDate":"2026-10-14","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"149204409","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":2,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Structural, Optical and Photodiode Characteristics of Cu-Doped In2O3 Thin Films Prepared by Jet Nebulizer Spray Pyrolysis 喷射雾化器喷雾热解法制备cu掺杂In2O3薄膜的结构、光学和光电二极管特性
IF 6.7 2区 材料科学
Journal of Alloys and Compounds Pub Date : 2026-10-10 DOI: 10.1016/j.jallcom.2026.191597
M. Nithyaroja, D. Selleswari, R. Marnadu, Deepa Jananakumar, Mohamed Saad
{"title":"Structural, Optical and Photodiode Characteristics of Cu-Doped In2O3 Thin Films Prepared by Jet Nebulizer Spray Pyrolysis","authors":"M. Nithyaroja,&nbsp;D. Selleswari,&nbsp;R. Marnadu,&nbsp;Deepa Jananakumar,&nbsp;Mohamed Saad","doi":"10.1016/j.jallcom.2026.191597","DOIUrl":"10.1016/j.jallcom.2026.191597","url":null,"abstract":"<div><div>Cu-doped In<sub>2</sub>O<sub>3</sub> thin films with different Cu concentrations were prepared by the jet nebulizer spray pyrolysis (JNSP) technique, and their structural, optical, electrical and photoelectrical properties were systematically investigated. X-ray diffraction analysis confirmed the crystalline nature of the deposited films with the cubic bixbyite structure of In<sub>2</sub>O<sub>3</sub>. The average crystallite size exhibited a concentration-dependent variation with Cu incorporation, decreasing from 6.54<!--> <!-->nm for pristine In<sub>2</sub>O<sub>3</sub> to 2.96<!--> <!-->nm at 1.5<!--> <!-->wt.% Cu and subsequently increasing to 3.69 and 7.04<!--> <!-->nm at 3.0 and 4.5<!--> <!-->wt.% Cu, respectively. EDX and XPS analyses confirmed the presence of Cu in the deposited films; however, the specific crystallographic site occupied by Cu could not be established from the present measurements. Optical analysis revealed a progressive reduction in the optical bandgap from 3.60<!--> <!-->eV for pristine In<sub>2</sub>O<sub>3</sub> to 3.35<!--> <!-->eV for the 4.5<!--> <!-->wt.% Cu-doped film, accompanied by concentration-dependent changes in the optical response. The temperature-dependent I-V measurements demonstrated systematic variations in the electrical transport behaviour with Cu incorporation. Cu:In<sub>2</sub>O<sub>3</sub>/n-Si heterojunction photodiodes were fabricated and investigated under dark and illuminated conditions, revealing concentration-dependent photoelectrical characteristics. The results demonstrate that Cu incorporation provides an effective approach for tuning the structural, optical, electrical and photoelectrical properties of JNSP-derived In<sub>2</sub>O<sub>3</sub> thin films for potential photodetection applications.</div></div>","PeriodicalId":344,"journal":{"name":"Journal of Alloys and Compounds","volume":"1083 ","pages":"Article 191597"},"PeriodicalIF":6.7,"publicationDate":"2026-10-10","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"149214188","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":2,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
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