Journal of Alloys and Compounds最新文献

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Rubber/BiOCl: Yb,Er composite for the enhanced degradation of methylene blue and Rhodamine B dyes under solar irradiation 橡胶/BiOCl:Yb,Er复合材料对亚甲基蓝和罗丹明B染料的强化降解
IF 5.8 2区 材料科学
Journal of Alloys and Compounds Pub Date : 2025-04-25 DOI: 10.1016/j.jallcom.2025.180625
E. Valadez-Renteria , M. Rosales , P.C. Hernandez-Del Castillo , Claramaria Rodriguez-Gonzalez , T.A. Esquivel-Castro , V. Alonso , P. Salas , J. Oliva
{"title":"Rubber/BiOCl: Yb,Er composite for the enhanced degradation of methylene blue and Rhodamine B dyes under solar irradiation","authors":"E. Valadez-Renteria ,&nbsp;M. Rosales ,&nbsp;P.C. Hernandez-Del Castillo ,&nbsp;Claramaria Rodriguez-Gonzalez ,&nbsp;T.A. Esquivel-Castro ,&nbsp;V. Alonso ,&nbsp;P. Salas ,&nbsp;J. Oliva","doi":"10.1016/j.jallcom.2025.180625","DOIUrl":"10.1016/j.jallcom.2025.180625","url":null,"abstract":"<div><div>BiOCl:Yb,Er (BiOCl) photocatalyst was synthesized by combustion method using urea or thiourea as fuel. The analysis by scanning-electron microscopy revealed that BiOCl photocatalysts made with urea and thiourea had irregular-like and rod-like shapes, respectively. The BiOCl photocatalyst synthesized with urea and thiourea degraded Methylene Blue (MB) by 90 % and 100 %, respectively, after 90 min under UV–VIS light. Interestingly, BiOCl photocatalyst made with thiourea degraded completely MB after only 60 min under solar light. Later, the BiOCl photocatalyst was supported on recycled rubber (taken from bicycle tires) and this rubber/BiOCl (R/BiOCl) composite produced 100 % degradation for MB after 90 min of photocatalytic reaction. BiOCl powder synthesized with thiourea also degraded totally Rhodamine B (RhB) dye (after 90 min using UV–VIS light and after 10 min using sunlight). The R/BiOCl composite degraded 100 % of RhB after 120 min. Thus, the R/BiOCl composite produced slower dye degradation, but it was easily removed (manually) from the clean water. BiOCl synthesized with thiourea produced the highest photocatalytic performance because: i) it had the highest absorbance in the UV–VIS range and ii) it had the highest content of defects, which promoted the photocatalytic activity. In fact, BiOCl made with thiourea induced the highest mineralization of carbon (86 %) according to the TOC analysis. Additionally, the incorporation of Er and Yb ions into the BiOCl lattice facilitated the Up-conversion process under solar irradiation, enhancing the generation of electron-hole pairs, which in turn, incremented the photocatalytic degradation of MB and RhB dyes. The main oxidizing species responsible for the degradation of MB/RhB dyes were <span><math><mrow><mi>•</mi><msubsup><mrow><mi>O</mi></mrow><mrow><mn>2</mn></mrow><mrow><mo>−</mo></mrow></msubsup></mrow></math></span> radicals according to scavenger tests. The findings of this research demonstrated the potential of rubber/BiOCl based photocatalytic floaters for the degradation of dyes. Thus, the recycled rubber can be used as support for photocatalytic powders, which also reduces the contamination of water by microplastics.</div></div>","PeriodicalId":344,"journal":{"name":"Journal of Alloys and Compounds","volume":"1027 ","pages":"Article 180625"},"PeriodicalIF":5.8,"publicationDate":"2025-04-25","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"143872244","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":2,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Microstructure and mechanical properties of Mo2FeB2-316SS cermets prepared by vacuum sintering 真空烧结制备的 Mo2FeB2-316SS 金属陶瓷的微观结构和力学性能
IF 5.8 2区 材料科学
Journal of Alloys and Compounds Pub Date : 2025-04-25 DOI: 10.1016/j.jallcom.2025.180626
Xiao-Yu Lang, Guo-Hua Zhang
{"title":"Microstructure and mechanical properties of Mo2FeB2-316SS cermets prepared by vacuum sintering","authors":"Xiao-Yu Lang,&nbsp;Guo-Hua Zhang","doi":"10.1016/j.jallcom.2025.180626","DOIUrl":"10.1016/j.jallcom.2025.180626","url":null,"abstract":"<div><div>Mo<sub>2</sub>FeB<sub>2</sub>-316 stainless steel (316SS) cermets with varying Mo<sub>2</sub>FeB<sub>2</sub> powder contents (69.5, 75, 80.5, wt%) were prepared. The Mo<sub>2</sub>FeB<sub>2</sub> powder was first synthesized at 1000 ℃ for 1 h by reaction between ultrafine Mo powder and FeB powder, and then mixed with 316SS powder to prepare the Mo<sub>2</sub>FeB<sub>2</sub>-316SS cermets via vacuum sintering at different temperatures. The results revealed that in the cermets, some black near-spherical particles existed at the interface of the Mo<sub>2</sub>FeB<sub>2</sub> hard phase and Fe binder phase due to the oxidations of Si and Mn elements introduced through FeB and 316SS powders. The presence of Si-Mn complex oxides reduced the interfacial wettability and thereby increased porosity, which deteriorated the hardness and transverse fracture strength. Whereas, it improved the fracture toughness through crack bridging and pinning effect. The cermet with 80.5 wt% Mo<sub>2</sub>FeB<sub>2</sub> power, sintered at 1200 ℃, achieved superior comprehensive properties with Vickers hardness of 1258 HV<sub>30</sub>, transverse rupture strength (TRS) of 1735.9 MPa and fracture toughness (<em>K</em><sub>IC</sub>) of 17.5 MPa·m<sup>1/2</sup>. As the temperature increased, the hardness, fracture toughness and transverse rupture strength decreased. The growth of abnormal grains was the main reason, which was related to a two-dimensional nucleation mechanism.</div></div>","PeriodicalId":344,"journal":{"name":"Journal of Alloys and Compounds","volume":"1027 ","pages":"Article 180626"},"PeriodicalIF":5.8,"publicationDate":"2025-04-25","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"143872245","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":2,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
NiTi alloys with simultaneous equiaxed-grain strength and columnar-grain ductility manipulated by direct energy deposition 直接能量沉积制备具有等轴晶粒强度和柱状晶粒延展性的NiTi合金
IF 5.8 2区 材料科学
Journal of Alloys and Compounds Pub Date : 2025-04-25 DOI: 10.1016/j.jallcom.2025.180601
Jiaqi Lu , Chi Zhang , Yang Liu , Zhifeng Huang , Huilong Hou , Aijun Huang , Fei Chen
{"title":"NiTi alloys with simultaneous equiaxed-grain strength and columnar-grain ductility manipulated by direct energy deposition","authors":"Jiaqi Lu ,&nbsp;Chi Zhang ,&nbsp;Yang Liu ,&nbsp;Zhifeng Huang ,&nbsp;Huilong Hou ,&nbsp;Aijun Huang ,&nbsp;Fei Chen","doi":"10.1016/j.jallcom.2025.180601","DOIUrl":"10.1016/j.jallcom.2025.180601","url":null,"abstract":"<div><div>NiTi alloys prepared by additive manufacturing (AM) often have coarse columnar grains showing poor tensile superelasticity, strength, and ductility, significantly impairing part qualification and targeted applications. In this work, we used laser-engineered net shaping (LENS) to fabricate NiTi alloys with lamellar structures which consist of fine nearly equiaxed grains, columnar grains, and high-density dislocations, through periodically alternating processing parameters. This strategy can partially keep the equiaxed grains produced by the transformation from columnar grains to equiaxed grains (CET) at the top of the deposited layer, and interrupt the epitaxial growth of columnar grains in AM-ed NiTi alloys. The results show that NiTi alloys with lamellar structures exhibit an excellent combination of strength and ductility with a tensile strength of 649 MPa strain of 17.5 %, a maximum recovery strain of 5.3 %, and a stable recovery strain of 3.1 % after 20 cycles. Our findings may increase the range of adjustable microstructures and combinations of properties in NiTi alloys and provide a new idea for microstructure modification and reinforcement of AM shape memory alloy.</div></div>","PeriodicalId":344,"journal":{"name":"Journal of Alloys and Compounds","volume":"1028 ","pages":"Article 180601"},"PeriodicalIF":5.8,"publicationDate":"2025-04-25","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"143872246","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":2,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Preparation and dielectric properties of ZrO2 over-substituted barium zirconate titanate ceramics by direct writing 3D printing 通过直接写入 3D 打印技术制备 ZrO2 过度取代锆酸钛酸钡陶瓷及其介电性能
IF 5.8 2区 材料科学
Journal of Alloys and Compounds Pub Date : 2025-04-25 DOI: 10.1016/j.jallcom.2025.180634
Zhuohao Qiu , Gaoyuan Chen , Xixi Bao , Jitao Xu , Chengyi Chu , Guangjian Peng , Jianjun Guo , Yuchuan Cheng , Aihua Sun
{"title":"Preparation and dielectric properties of ZrO2 over-substituted barium zirconate titanate ceramics by direct writing 3D printing","authors":"Zhuohao Qiu ,&nbsp;Gaoyuan Chen ,&nbsp;Xixi Bao ,&nbsp;Jitao Xu ,&nbsp;Chengyi Chu ,&nbsp;Guangjian Peng ,&nbsp;Jianjun Guo ,&nbsp;Yuchuan Cheng ,&nbsp;Aihua Sun","doi":"10.1016/j.jallcom.2025.180634","DOIUrl":"10.1016/j.jallcom.2025.180634","url":null,"abstract":"<div><div>Barium titanate ceramics exhibit great potential in ceramic capacitors due to their excellent dielectric properties. However, with the highly integrated advancement in electronic components, the preparation of high-capacitance ceramic capacitors with complex structural design has been the focus in current research. In this study, the complex structural barium zirconium titanate is first prepared through direct ink writing (DIW) technique. Subsequently, based on the regulation of zirconium substitution on the phase transition temperature of barium titanate, we reasonably designed zirconium-substituted barium titanate ceramics with varying stoichiometric ratios to regulate the three-phase transition temperatures of zirconium titanate ceramics, and following optimized the sintering temperature of the over-substituted barium zirconium titanate, thus improving the dielectric properties of the barium titanate. The results demonstrate that the solid content of 65 % exhibited the optimal forming precision and the highest densification. Additionally, the over-substituted zirconia alter the phase structure of barium titanate, increasing the proportion of tetragonal phase and subsequently elevating the dielectric constant of the specimens. Notably, among all sintering temperatures tested, the specimen sintered at 1400 °C display the highest proportion of tetragonal zirconia-barium titanate and an optimal dielectric constant. This research offers valuable technical and theoretical insights for the preparation and utilization of zirconium-substituted barium titanate ceramics with intricate structures.</div></div>","PeriodicalId":344,"journal":{"name":"Journal of Alloys and Compounds","volume":"1027 ","pages":"Article 180634"},"PeriodicalIF":5.8,"publicationDate":"2025-04-25","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"143872292","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":2,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Ca3TeO6:Er3+: A green phosphor for bifunctional applications in non-contact optical thermometry and w-LEDs Ca3TeO6:Er3+:用于非接触式光学测温和w- led双功能应用的绿色荧光粉
IF 5.8 2区 材料科学
Journal of Alloys and Compounds Pub Date : 2025-04-25 DOI: 10.1016/j.jallcom.2025.180622
Ya Yang , Mengxue Zhang , Di Gao , Mengkun Zhang , Yu Zhang , Yue Yang , Yufeng Du , Houteng Zhao , Xianchao Du , Ruijin Yu
{"title":"Ca3TeO6:Er3+: A green phosphor for bifunctional applications in non-contact optical thermometry and w-LEDs","authors":"Ya Yang ,&nbsp;Mengxue Zhang ,&nbsp;Di Gao ,&nbsp;Mengkun Zhang ,&nbsp;Yu Zhang ,&nbsp;Yue Yang ,&nbsp;Yufeng Du ,&nbsp;Houteng Zhao ,&nbsp;Xianchao Du ,&nbsp;Ruijin Yu","doi":"10.1016/j.jallcom.2025.180622","DOIUrl":"10.1016/j.jallcom.2025.180622","url":null,"abstract":"<div><div>The green Ca<sub>3</sub>TeO<sub>6</sub>:Er<sup>3+</sup> phosphors were prepared by means of solid-state reaction at a high temperature. The crystalline phase, elemental mapping, photoluminescence (PL) spectra, and Commission International de L’Eclairage (CIE) chromaticity coordinates of the synthesized compounds were employed to characterize the materials comprehensively. The bandgap energy (<em>E</em><sub>g</sub>) of Ca<sub>3</sub>TeO<sub>6</sub> was calculated to be 3.007 eV using Density Functional Theory (DFT). Analysis of the diffuse reflection spectra (DRS) further demonstrated its suitability as a phosphor host matrix. The Ca<sub>3</sub>TeO<sub>6</sub>:Er<sup>3+</sup> phosphor exhibited strong excitation under 378 nm irradiation, displaying three characteristic emission peaks. The dominant emission peaks were observed at 523 nm and 545 nm, which align with the characteristic electronic transitions of Er<sup>3+</sup> ions at <sup>2</sup>H<sub>11/2</sub>-<sup>4</sup>I<sub>15/2</sub> and <sup>4</sup>S<sub>3/2</sub>-<sup>4</sup>I<sub>15/2</sub>, respectively. A regular concentration quenching behavior was observed, with the optimum Er<sup>3+</sup> doping concentration determined to be 5.0 mol%. The prepared phosphors demonstrated significant temperature sensitivity over the range of 300–480 K when utilizing the fluorescence intensity ratio (FIR) technology. A maximum relative sensor sensitivity was 1.18 % K<sup>−1</sup> at 300 K indicating excellent potential for non-contact thermometry applications. Furthermore, the prepared white light-emitting diode (w-LED) exhibited outstanding performance, characterized by a high color rendering index (<em>R</em><sub>a</sub>) of 92. Overall, these results indicate that Ca<sub>3</sub>TeO<sub>6</sub>:Er<sup>3+</sup> phosphors hold significant potential for use in solid-state lighting as well as in non-contact temperature sensing.</div></div>","PeriodicalId":344,"journal":{"name":"Journal of Alloys and Compounds","volume":"1028 ","pages":"Article 180622"},"PeriodicalIF":5.8,"publicationDate":"2025-04-25","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"143876182","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":2,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Study on the behavior of randomly distributed Al-Cu nanopowders by laser shock dynamic compaction 激光冲击动态压实随机分布Al-Cu纳米粉体的性能研究
IF 5.8 2区 材料科学
Journal of Alloys and Compounds Pub Date : 2025-04-25 DOI: 10.1016/j.jallcom.2025.180577
Maomao Cui , Yu Zhou , Minggang Wang , Hongchen Liu , Xiao Wang , Huixia Liu
{"title":"Study on the behavior of randomly distributed Al-Cu nanopowders by laser shock dynamic compaction","authors":"Maomao Cui ,&nbsp;Yu Zhou ,&nbsp;Minggang Wang ,&nbsp;Hongchen Liu ,&nbsp;Xiao Wang ,&nbsp;Huixia Liu","doi":"10.1016/j.jallcom.2025.180577","DOIUrl":"10.1016/j.jallcom.2025.180577","url":null,"abstract":"<div><div>To address the unique challenges presented by the dynamic compaction of realistically distributed nanopowders under laser shock, which differs from the compaction process of regularly arranged powders. A study investigates the laser shock dynamic compaction (LSDC) behavior of randomly distributed nano Al-Cu powders. The aim was to investigate the microstructural evolution and densification of randomly distributed nano Al-Cu powders during LSDC and to assess the effect of varying nano Cu content on the density and mechanical properties of Al-Cu nanopowder compacts. Using a self-developed LSDC platform, nano aluminum and nano copper powders were uniformly mixed in mass ratios of 5 %, 10 %, and 15 %, producing compacts with a density of 95.36 %. A model was established via the Gurney energy equation to link laser energy to upper punch velocity, and the compaction response of the nanopowders at different velocities was simulated. Molecular dynamics (MD) modeling, constructed using Atomsk and LAMMPS software, closely represented actual conditions, allowing characterization of crystal structure changes, dislocation evolution, and other behaviors during laser shock compaction. Results indicated that increasing nano Cu content led to a gradual decrease in the microhardness of Al-Cu compacts. Across shock velocities from 500 to 1500 m/s, the material exhibited three stages: solid non-densification, solid densification, and liquid densification. The study quantified temperature distribution and dislocation density during laser shock, clarifying compaction mechanisms at various shock velocities. These findings reveal the microstructural evolution, temperature distribution, and densification processes in the laser dynamic compaction of randomly distributed nano Al-Cu powders, providing theoretical support for LSDC technology applications in nanomaterial development.</div></div>","PeriodicalId":344,"journal":{"name":"Journal of Alloys and Compounds","volume":"1027 ","pages":"Article 180577"},"PeriodicalIF":5.8,"publicationDate":"2025-04-25","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"143869861","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":2,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Achieving excellent soft magnetic performance in FeCoBSiCu alloy through composition-processing regulation 通过成分加工调控,实现了FeCoBSiCu合金优异的软磁性能
IF 5.8 2区 材料科学
Journal of Alloys and Compounds Pub Date : 2025-04-25 DOI: 10.1016/j.jallcom.2025.180585
Wenhui Guo , Lingxiang Shi , You Wu , Jili Jia , Ranbin Wang , Hengtong Bu , Xinglong Yang , Zongfan Zhu , Siqi Xiang , Yunshuai Su , Yang Shao , Kefu Yao
{"title":"Achieving excellent soft magnetic performance in FeCoBSiCu alloy through composition-processing regulation","authors":"Wenhui Guo ,&nbsp;Lingxiang Shi ,&nbsp;You Wu ,&nbsp;Jili Jia ,&nbsp;Ranbin Wang ,&nbsp;Hengtong Bu ,&nbsp;Xinglong Yang ,&nbsp;Zongfan Zhu ,&nbsp;Siqi Xiang ,&nbsp;Yunshuai Su ,&nbsp;Yang Shao ,&nbsp;Kefu Yao","doi":"10.1016/j.jallcom.2025.180585","DOIUrl":"10.1016/j.jallcom.2025.180585","url":null,"abstract":"<div><div>The overwhelming evolution of electronic devices has put forward more urgent performance demands for soft magnetic materials, especially for the higher saturation magnetic induction intensity (<em>B</em><sub>s</sub>) and the lower coercivity (<em>H</em><sub>c</sub>). Nevertheless, there is extremely rare material candidate satisfying the <em>B</em><sub>s</sub> approaching 2 T and the <em>H</em><sub>c</sub> below 10 A/m. In this study, we adopted three composition modulation strategies (<em>i.e.</em>, replacing Si with Fe/B/Cu) on FeCoBSiCu alloy to systematically perform crystallization thermal processing with magnetic field assistance, and ultimately achieved the controllable transition of structure-performance from amorphous to nanocrystalline alloys. Especially, the newly developed Fe<sub>68.4</sub>Co<sub>17.5</sub>B<sub>13</sub>Si<sub>0.3</sub>Cu<sub>0.8</sub> (<em>B</em><sub>s</sub> = 1.99 T, <em>H</em><sub>c</sub> = 8.1 A/m) characterized as a glassy matrix with relatively high crystallization volume fraction of <em>α</em>-Fe(Co) nanocrystals, owns ultra-high <em>B</em><sub>s</sub> approaching the performance of ultra-fast annealing alloys, and Fe<sub>68.2</sub>Co<sub>17.5</sub>B<sub>13.4</sub>Si<sub>0.1</sub>Cu<sub>0.8</sub> (<em>B</em><sub>s</sub> = 1.91 T, <em>H</em><sub>c</sub> = 0.9 A/m) dominated by amorphous structure, possesses the highest <em>B</em><sub>s</sub> on the premise of <em>H</em><sub>c</sub> below 1 A/m. The ideas of composition-processing regulation are anticipated to efficiently guide and accelerate the development of novel soft magnetic materials with excellent performance.</div></div>","PeriodicalId":344,"journal":{"name":"Journal of Alloys and Compounds","volume":"1027 ","pages":"Article 180585"},"PeriodicalIF":5.8,"publicationDate":"2025-04-25","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"143876355","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":2,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Optimization of microstructure and properties of new Al-Ce-Sc alloy wires in drawn state 新型Al-Ce-Sc合金拉丝组织与性能的优化
IF 5.8 2区 材料科学
Journal of Alloys and Compounds Pub Date : 2025-04-25 DOI: 10.1016/j.jallcom.2025.180623
Jinrong Xiao , Jieyun Ye , Peilong Li , Shiqi Jiang , Fusheng Zhu , Zhigang Wang
{"title":"Optimization of microstructure and properties of new Al-Ce-Sc alloy wires in drawn state","authors":"Jinrong Xiao ,&nbsp;Jieyun Ye ,&nbsp;Peilong Li ,&nbsp;Shiqi Jiang ,&nbsp;Fusheng Zhu ,&nbsp;Zhigang Wang","doi":"10.1016/j.jallcom.2025.180623","DOIUrl":"10.1016/j.jallcom.2025.180623","url":null,"abstract":"<div><div>The current aluminum alloy conductor still has contradictions in conductivity, heat resistance, and strength that cannot be resolved simultaneously, and it cannot meet the requirements of large-capacity transmission lines. In this work, Al-RE alloy wires with a composite addition of Ce and Sc elements were prepared by extrusion and drawing. The effects of the composite addition of Ce and Sc on the microstructure, mechanical properties, electrical conductivity, and heat resistance of industrial pure aluminum alloys were studied. Results show that the grain refinement of the alloy with a compound addition of 0.1 wt% Ce and 0.2 wt% Sc was better, with an average grain size of 7.2 μm. The comprehensive performance of Al-0.1Ce-0.2Sc alloy wire is the best, with UTS of 218.9 MPa, YS of 215.6 MPa, EL of 5.1 %, and electrical conductivity (EC) of 60.68 % IACS. The fine coherent nano-Al<sub>3</sub>Sc phases precipitated during hot extrusion and drawing have excellent strengthening effects and high thermal stability, which can significantly enhance the strength and heat resistance of the alloy. The addition of the element Ce results in the formation of the phases Al<sub>13</sub>Fe<sub>3</sub>Ce and AlCeSiFe, which significantly reduces the concentration of Fe and Si atoms in the aluminum matrix, thereby reducing the scattering of electrons and increasing the EC of the alloy. The Al-0.1Ce-0.2Sc alloy wire showed a tensile strength residual of up to 96.8 % after a heat resistance test at 230°C × 1 h. The damping properties of several alloys were also evaluated, among which the Al-0.1Ce-0.2Sc alloy wire has excellent high-temperature damping properties with an internal dissipation value of up to 0.25. The Al-0.1Ce-0.2Sc alloy conductor simultaneously possesses high-strength, high-conductivity, high-heat-resistance, and high-damping properties, which provides a data reference for the subsequent design of heat-resistant aluminum conductor materials with both strength and conductivity.</div></div>","PeriodicalId":344,"journal":{"name":"Journal of Alloys and Compounds","volume":"1027 ","pages":"Article 180623"},"PeriodicalIF":5.8,"publicationDate":"2025-04-25","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"143872293","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":2,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Design Methods of High-Entropy Alloys: Current Status and Prospects 高熵合金的设计方法:现状与前景
IF 6.2 2区 材料科学
Journal of Alloys and Compounds Pub Date : 2025-04-25 DOI: 10.1016/j.jallcom.2025.180638
Lingxin Li, Zhengdi Liu, Xulong An, Wenwen Sun
{"title":"Design Methods of High-Entropy Alloys: Current Status and Prospects","authors":"Lingxin Li, Zhengdi Liu, Xulong An, Wenwen Sun","doi":"10.1016/j.jallcom.2025.180638","DOIUrl":"https://doi.org/10.1016/j.jallcom.2025.180638","url":null,"abstract":"High-entropy alloys (HEAs), with their outstanding comprehensive properties, hold significant potential for applications in aerospace, energy, and military fields. However, due to the vast compositional space of HEAs, the traditional trial-and-error approach not only consumes considerable resources but also suffers from low efficiency, severely hindering the development of these alloys. In recent years, the rapid advancements in high-throughput experiments, computational materials science, and machine learning have offered new opportunities for the design of HEAs. This paper aims to explore the design methods for HEAs, including those based on high-throughput experiments, computational materials science, materials science, and machine learning. It discusses the current state of research on these four design methods, analyzing the advantages and limitations of each. Finally, the paper addresses the future trends in the development of design methods for HEAs.","PeriodicalId":344,"journal":{"name":"Journal of Alloys and Compounds","volume":"42 1","pages":""},"PeriodicalIF":6.2,"publicationDate":"2025-04-25","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"143872294","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":2,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Enhancing linearity of open-loop parallel fluxgate sensors via induced anisotropy in amorphous wires 利用非晶线诱导各向异性提高开环并联磁通门传感器的线性度
IF 5.8 2区 材料科学
Journal of Alloys and Compounds Pub Date : 2025-04-25 DOI: 10.1016/j.jallcom.2025.180636
Chunyang Mu , Lining Pan , Haoran Ma , Mengran Su , Aina He , Yaqiang Dong , Qikui Man , Deren Li , Jiawei Li
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