Applied Surface Science最新文献

Microstructure and property regulation of IN718/FeCrNiAlCu reinforced 316 L SS composite coatings via laser-directed energy deposition 激光定向能沉积IN718/FeCrNiAlCu增强316 L SS复合涂层的组织与性能调控

IF 6.6 2区材料科学

Applied Surface Science Pub Date : 2026-10-14 DOI: 10.1016/j.apsusc.2026.168678

Senao Gao, Huakai Mao, Haitao Duan, Nian Liu, Guodong Zhang

{"title":"Microstructure and property regulation of IN718/FeCrNiAlCu reinforced 316 L SS composite coatings via laser-directed energy deposition","authors":"Senao Gao, Huakai Mao, Haitao Duan, Nian Liu, Guodong Zhang","doi":"10.1016/j.apsusc.2026.168678","DOIUrl":"10.1016/j.apsusc.2026.168678","url":null,"abstract":"<div><div>Conventional 316 L stainless steel (316 L SS) coatings face inherent microstructural and performance drawbacks that limit their service reliability. Herein, an INHEA alloy consisting of 25 wt% Inconel 718 superalloy and 75 wt% FeCrNiAlCu high-entropy alloy was introduced as an integrated reinforcing constituent to fabricate INHEA-reinforced 316 L SS composite coatings by laser-directed energy deposition (LDED), and their phase composition, microstructure, and property evolution were systematically investigated. The results reveal that increasing INHEA content transforms the 316 L composite coating from a single FCC phase into a mixed structure with coexisting FCC, BCC and secondary phases. Laves and core–shell structured phases precipitate when the INHEA content exceeds 15 wt%, alongside notable grain refinement. The 45 wt% INHEA-reinforced 316 L coating delivers the optimal overall performance: its hardness is 85.76% higher than pure 316 L SS (surpassing Inconel 718), and wear volume decreases by 66.67%. The enhanced hardness is primarily attributed to the synergistic effects of second-phase, solid-solution, and dislocation strengthening mechanisms. Furthermore, 45 wt% INHEA addition significantly enhances corrosion resistance by thickening the passive film, raising corrosion and pitting potentials, increasing polarization resistance by one order of magnitude, and reducing corrosion current density.</div></div>","PeriodicalId":247,"journal":{"name":"Applied Surface Science","volume":"755 ","pages":"Article 168678"},"PeriodicalIF":6.6,"publicationDate":"2026-10-14","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"149213950","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":2,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

引用次数: 0

Microscopic competitive adsorption characteristics of CH4–CO2 on coal surface CH4-CO2在煤表面的微观竞争吸附特性

IF 6.7 2区材料科学

Applied Surface Science Pub Date : 2026-10-05 DOI: 10.1016/j.apsusc.2026.168611

Xia Yan, Shouya Wu, Zhaomin Li

{"title":"Microscopic competitive adsorption characteristics of CH4–CO2 on coal surface","authors":"Xia Yan, Shouya Wu, Zhaomin Li","doi":"10.1016/j.apsusc.2026.168611","DOIUrl":"https://doi.org/10.1016/j.apsusc.2026.168611","url":null,"abstract":"To clarify microscopic competitive adsorption characteristics of methane (CH<ce:inf loc=\"post\">4</ce:inf>) and carbon dioxide (CO<ce:inf loc=\"post\">2</ce:inf>) on coal surfaces, a constitutive model for CO<ce:inf loc=\"post\">2</ce:inf>–CH<ce:inf loc=\"post\">4</ce:inf> competitive adsorption on coal surfaces is derived based on the Lennard-Jones intermolecular potential theory. The model accuracy has verified against both molecular dynamics simulation results and competitive adsorption experimental data. Model analysis results reveal that: the densities of CO<ce:inf loc=\"post\">2</ce:inf> and CH<ce:inf loc=\"post\">4</ce:inf> both increase initially and then decrease with decreasing distance from coal surface. The location of maximum CO<ce:inf loc=\"post\">2</ce:inf> density is closer to the surface than that of CH<ce:inf loc=\"post\">4</ce:inf>, which is a characteristic parameter characterizing the CO<ce:inf loc=\"post\">2</ce:inf> competitive adsorption superiority. The average molar fraction of CO<ce:inf loc=\"post\">2</ce:inf> in adsorption region is significantly higher than that in the free phase. The CO<ce:inf loc=\"post\">2</ce:inf> competitive adsorption selectivity coefficient decreases by a power law and gradually approaches 1 with increasing CO<ce:inf loc=\"post\">2</ce:inf> mole fraction in free region. The CO<ce:inf loc=\"post\">2</ce:inf> competitive adsorption superiority weakens significantly when the CO<ce:inf loc=\"post\">2</ce:inf> mole fraction in free region exceeds 40%. During pressurization below 10 megapascal (MPa), the free CO<ce:inf loc=\"post\">2</ce:inf> gradually transforms into the adsorbed state, and CO<ce:inf loc=\"post\">2</ce:inf> competitive adsorption superiority is enhanced. The CO<ce:inf loc=\"post\">2</ce:inf> competitive adsorption selectivity coefficients show linearly upward trend with increasing pressure and power-law downward trend with increasing temperature.","PeriodicalId":247,"journal":{"name":"Applied Surface Science","volume":"21 1","pages":""},"PeriodicalIF":6.7,"publicationDate":"2026-10-05","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"149123691","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":2,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

引用次数: 0

Fine-tuning the electrochemical deposition of Ag nanoparticles on TiO2 nanotube array films for Surface-Enhanced Raman Scattering 纳米银纳米颗粒在TiO2纳米管阵列薄膜上的电化学沉积，用于表面增强拉曼散射

IF 6.7 2区材料科学

Applied Surface Science Pub Date : 2026-10-02 DOI: 10.1016/j.apsusc.2026.168581

Martín I. Broens, Omar E. Linarez Pérez

{"title":"Fine-tuning the electrochemical deposition of Ag nanoparticles on TiO2 nanotube array films for Surface-Enhanced Raman Scattering","authors":"Martín I. Broens, Omar E. Linarez Pérez","doi":"10.1016/j.apsusc.2026.168581","DOIUrl":"https://doi.org/10.1016/j.apsusc.2026.168581","url":null,"abstract":"In this work, we report the controlled electrodeposition of Ag nanoparticles on anodic TiO<ce:inf loc=\"post\">2</ce:inf> nanotube films (TiO<ce:inf loc=\"post\">2</ce:inf>-NTFs) for their application as Surface-Enhanced Raman Scattering (SERS) platforms. The influence of TiO<ce:inf loc=\"post\">2</ce:inf> crystallinity, AgNO<ce:inf loc=\"post\">3</ce:inf> precursor concentration, and the number of galvanostatic deposition cycles was systematically investigated to achieve fine control over nanoparticle size, surface density, and distribution. Morphological analysis revealed that amorphous and anatase TiO<ce:inf loc=\"post\">2</ce:inf>-NTFs promoted uniform, high-density Ag nanoparticle deposition. In contrast, the mixed anatase–rutile film exhibited lower Ag nanoparticle coverage and cookie-type aggregates, which may be associated with its higher wall resistivity. At low AgNO<ce:inf loc=\"post\">3</ce:inf> concentrations, uniform and nanosized Ag particles were obtained, whereas higher concentrations led to localized nucleation and the formation of microcrystals. The resulting TiO<ce:inf loc=\"post\">2</ce:inf>-NTF/Ag films displayed strong SERS activity toward 2-mercaptopyridine, with responses that, under some conditions, exceeded those reported for similar photoreduction-based platforms. Notably, the SERS performance depends on the balance among nanoparticle size, surface density, and spatial distribution, highlighting the importance of precise electrochemical control in tailoring high-performance SERS substrates.","PeriodicalId":247,"journal":{"name":"Applied Surface Science","volume":"27 1","pages":""},"PeriodicalIF":6.7,"publicationDate":"2026-10-02","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"149123732","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":2,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

引用次数: 0

Superatom-assembled B6C monolayer for sensitive NO, NO2, and NH3 sensing with rapid room-temperature recovery: a first-principles study 超原子组装B6C单层用于快速室温恢复的NO， NO2和NH3敏感传感：第一性原理研究

IF 6.7 2区材料科学

Applied Surface Science Pub Date : 2026-10-01 DOI: 10.1016/j.apsusc.2026.168592

Tao Peng,Kaidong Shen,Jing Xie,Chang Xu,Longjiu Cheng

引用次数: 0

Aptes-regulated interfacial loading of n-octadecane/SiO2 phase change nanocapsules on PU/PEG fibrous membranes for stable thermal management aptes调节正十八烷/SiO2相变纳米胶囊在PU/PEG纤维膜上的界面负载，用于稳定热管理

IF 6.7 2区材料科学

Applied Surface Science Pub Date : 2026-10-01 DOI: 10.1016/j.apsusc.2026.168556

Yanlan Zhou, Ruishuo Guo, Huijia Wang, Xin Xu, Zhiqiang Li, Zhuolu Li, Xile Chen, Ni Li

{"title":"Aptes-regulated interfacial loading of n-octadecane/SiO2 phase change nanocapsules on PU/PEG fibrous membranes for stable thermal management","authors":"Yanlan Zhou, Ruishuo Guo, Huijia Wang, Xin Xu, Zhiqiang Li, Zhuolu Li, Xile Chen, Ni Li","doi":"10.1016/j.apsusc.2026.168556","DOIUrl":"https://doi.org/10.1016/j.apsusc.2026.168556","url":null,"abstract":"Polyethylene glycol (PEG)-based phase change fibrous membranes are promising flexible thermal management materials, but their performance is often limited by melting-induced deformation, low heat-transfer efficiency, and insufficient cycling stability. In this study, an APTES-regulated interfacial loading strategy was developed by loading amino-functionalized n-octadecane/SiO<ce:inf loc=\"post\">2</ce:inf> phase change nanocapsules (N<ce:inf loc=\"post\">x</ce:inf>-PCNCs) onto electrospun PU/PEG fibrous membranes. The effect of APTES concentration on the capsule loading state and thermal management performance was systematically investigated. Moderate APTES modification improved the loading and dispersion of PCNCs on the fiber. Among the samples, PU/PEG/N<ce:inf loc=\"post\">20</ce:inf>-PCNCs showed a relatively uniform particle distribution and a thermal conductivity of 0.129 ± 0.015 W · m⁻<ce:sup loc=\"post\">1</ce:sup> · K⁻<ce:sup loc=\"post\">1</ce:sup>. The composite fibrous membrane maintained stable phase-change behavior after 200 melting–crystallization cycles and 20 water-treatment cycles, demonstrating good cycling stability under the tested conditions. Moreover, PU/PEG/N<ce:inf loc=\"post\">20</ce:inf>-PCNCs exhibited an average solar reflectance of approximately 95 ± 0.8% and reduced the surface temperature by 9.2 and 2.3 °C compared with PU and PU/PEG fibrous membranes under simulated solar irradiation. These results demonstrate that APTES-regulated interfacial loading of PCNCs is an effective strategy for improving the thermal storage, stability, and temperature-buffering performance of PU/PEG phase change fibrous membranes.","PeriodicalId":247,"journal":{"name":"Applied Surface Science","volume":"28 1","pages":""},"PeriodicalIF":6.7,"publicationDate":"2026-10-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"149123638","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":2,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

引用次数: 0

Adsorption of amine-, carboxylic acid-, phosphonic acid-, and thiol-terminated long-chain aliphatic molecules on metal oxide nanoparticles and facile preparation of superhydrophobic surfaces 胺-、羧酸-、磷酸-和巯基端长链脂肪分子在金属氧化物纳米颗粒上的吸附和超疏水表面的制备

IF 6.7 2区材料科学

Applied Surface Science Pub Date : 2026-10-01 DOI: 10.1016/j.apsusc.2026.168551

Josue Moreno-Arceo,Margaret M.A. Peters,Saurabh Karande,Yuqing Cozzens,Curtis L. Wright,James E. Whitten

引用次数: 0

Corrigendum to “H2 gas sensing of co-incorporated metal-organic frameworks” [Appl. Surf. Sci. 523 (2020) 146487] “共掺入金属-有机框架的H2气体传感”的勘误表[苹果]。冲浪。科学通报。523 (2020)146487]

IF 6.7 2区材料科学

Applied Surface Science Pub Date : 2026-10-01 DOI: 10.1016/j.apsusc.2026.168568

Duy-Khoi Nguyen,Jae-Hyoung Lee,Tan Le-Hoang Doan,Thanh-Binh Nguyen,Sungkyun Park,Sang Sub Kim,Bach Thang Phan

引用次数: 0

Homogeneous N-polar AlScN sputtered films using a single AlSc alloy target and in-situ AlSc template 采用单一AlSc合金靶和原位AlSc模板制备均匀n极AlScN溅射膜

IF 6.7 2区材料科学

Applied Surface Science Pub Date : 2026-10-01 DOI: 10.1016/j.apsusc.2026.168566

SeongUk Yun,Dohyun Go,Xinyu Wang,Ping-Che Lee,Prabhakar R. Bandaru,Andrew C. Kummel

引用次数: 0

Electrical conduction and oxidation of ultra-thin chromium films 超薄铬膜的导电和氧化

IF 6.7 2区材料科学

Applied Surface Science Pub Date : 2026-10-01 DOI: 10.1016/j.apsusc.2026.168609

Vicente de la Barra,Leonardo Vergara,Javiera Martinez,Gabriel Gray,Fernando Álvarez-Asencio,Valeria del Campo,Patricio Häberle,Claudio Gonzalez-Fuentes,Rodrigo Segura,Douglas Olivares,Denise Criado,Marcos Flores,Ricardo Henríquez

引用次数: 0

BF4⁻ surface treatment enhancing stability of CsPbBr3 nanocrystals for Rec. 2020 ultra-wide color gamut green perovskite LEDs 用于Rec. 2020超宽色域绿色钙钛矿led的CsPbBr3纳米晶体稳定性的表面处理

IF 6.7 2区材料科学

Applied Surface Science Pub Date : 2026-10-01 DOI: 10.1016/j.apsusc.2026.168585

Ke Xing,Weibin Chen,Yusheng Song,Yijie Wang,Lei Song,Sihang Ji,Jialong Zhao,Xi Yuan,Yu Zhang

引用次数: 0