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Novel ultralight carbon foam reinforced carbon aerogel composites with low volume shrinkage and excellent thermal insulation performance 具有低体积收缩和优异隔热性能的新型超轻碳泡沫增强碳气凝胶复合材料
IF 10.5 2区 材料科学
Carbon Pub Date : 2024-11-14 DOI: 10.1016/j.carbon.2024.119826
Ruyi Sha , Bingzhu Wang , Jixiang Dai , Jianjun Sha
{"title":"Novel ultralight carbon foam reinforced carbon aerogel composites with low volume shrinkage and excellent thermal insulation performance","authors":"Ruyi Sha ,&nbsp;Bingzhu Wang ,&nbsp;Jixiang Dai ,&nbsp;Jianjun Sha","doi":"10.1016/j.carbon.2024.119826","DOIUrl":"10.1016/j.carbon.2024.119826","url":null,"abstract":"<div><div>Lightweight carbon aerogels are attractive for thermal insulation due to their low thermal conductivity and excellent high-temperature resistance under extreme environments. However, the preparation of monolithic carbon aerogels from phenolic resin precursor always faces the problem of large volumetric shrinkage during the drying and carbonization processes, thus resulting in the increasing density and thermal conductivity of aerogels. Here, to solve such issues, ultralight and rigid carbon foam was designed and synthesized as the reinforcement to fabricate carbon aerogel composites (CACs), which could significantly enhance the shrinkage resistance of monolithic carbon aerogels. The high rigidity of the carbon foam reinforcements (CFRs) was achieved through a pre-carbonization process, which also endowed the CFRs with a matched shrinkage with the monolithic carbon aerogels. As a result, the obtained CACs reinforced by the rigid CFRs showed not only crack-free structures, but also quite low shrinkage, which was about 5.9 % after carbonization. The low shrinkage of CACs then endowed them with quite low density (21.5 mg cm<sup>−3</sup>) and excellent thermal insulation performance (25.9 mW m<sup>−1</sup> K<sup>−1</sup>). Furthermore, due to a highly rough nanostructure, the CACs also possessed outstanding hydrophobicity. These merits make the CACs a promising thermal insulation material even in humid environments.</div></div>","PeriodicalId":262,"journal":{"name":"Carbon","volume":null,"pages":null},"PeriodicalIF":10.5,"publicationDate":"2024-11-14","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"142656269","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":2,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
MXene-CNTs/Co dielectric-electromagnetic synergistic composites with multi-heterogeneous interfaces for microwave absorption 具有多异质界面的 MXene-CNTs/Co 微波吸收介电电磁协同复合材料
IF 10.5 2区 材料科学
Carbon Pub Date : 2024-11-13 DOI: 10.1016/j.carbon.2024.119825
Yongqi Zhao , Jingjing Wang , Danyi Yang , Zhao Du , Xinyu Zhi , Rongrong Yu , Zhonglu Guo , Chengchun Tang , Yi Fang
{"title":"MXene-CNTs/Co dielectric-electromagnetic synergistic composites with multi-heterogeneous interfaces for microwave absorption","authors":"Yongqi Zhao ,&nbsp;Jingjing Wang ,&nbsp;Danyi Yang ,&nbsp;Zhao Du ,&nbsp;Xinyu Zhi ,&nbsp;Rongrong Yu ,&nbsp;Zhonglu Guo ,&nbsp;Chengchun Tang ,&nbsp;Yi Fang","doi":"10.1016/j.carbon.2024.119825","DOIUrl":"10.1016/j.carbon.2024.119825","url":null,"abstract":"<div><div>In view of the growing concern over electromagnetic wave pollution, the evolution of efficient microwave absorbing (MA) composites has emerged as a pivotal research area for scientists and engineers. In this study, MXene-CNTs/Co (MCC) composites with tunable and efficient MA properties were successfully prepared from a structural design perspective that capitalizes on dielectric-magnetic synergy. The electromagnetic properties of the composites were effectively regulated by adjusting the length and content of the CNTs. As expected, the design of the MCC composite absorber has a minimum reflection loss (RL<sub>min</sub>) of −62.53 dB with a matched thickness of 1.59 mm. With an effective absorption bandwidth (EAB) of 4.20 GHz (12.48–16.68 GHz) and a matched thickness of 1.38 mm, the RL<sub>min</sub> remains an impressive −41.29 dB. The exceptional MA characteristics are ascribed to its distinctive three-dimensional (3D) electromagnetic network configuration, which optimizes impedance matching and augments multi-component polarization loss and reflection/scattering capabilities. The findings of this study offer novel insights and methodologies for the advancement of efficient and tunable microwave absorbing materials.</div></div>","PeriodicalId":262,"journal":{"name":"Carbon","volume":null,"pages":null},"PeriodicalIF":10.5,"publicationDate":"2024-11-13","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"142656267","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":2,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Synergistic NH2-MIL-88B/Ta4C3TX/graphene aerogels for sustainable wastewater treatment and thermal energy storage 用于可持续废水处理和热能储存的 NH2-MIL-88B/Ta4C3TX/ 石墨烯协同气凝胶
IF 10.5 2区 材料科学
Carbon Pub Date : 2024-11-13 DOI: 10.1016/j.carbon.2024.119823
Jiarong Zhang , Long Yu , Ya'nan Zhao , Tianran Zhao , Yi'na Yang , Chunna Yu , Chang Zhao , Guangjian Xing
{"title":"Synergistic NH2-MIL-88B/Ta4C3TX/graphene aerogels for sustainable wastewater treatment and thermal energy storage","authors":"Jiarong Zhang ,&nbsp;Long Yu ,&nbsp;Ya'nan Zhao ,&nbsp;Tianran Zhao ,&nbsp;Yi'na Yang ,&nbsp;Chunna Yu ,&nbsp;Chang Zhao ,&nbsp;Guangjian Xing","doi":"10.1016/j.carbon.2024.119823","DOIUrl":"10.1016/j.carbon.2024.119823","url":null,"abstract":"<div><div>The urgent need for multifunctional, high-performance materials is critical in addressing environmental pollution and energy shortages faced by contemporary society. This research presents innovative NH<sub>2</sub>-MIL-88B/Ta<sub>4</sub>C<sub>3</sub>T<sub>X</sub>/graphene aerogels that exhibit exceptional capabilities in photocatalysis and thermal energy storage utilizing solar energy. Synthesized through a combination of hydrothermal and freeze-drying methods, these aerogels feature unique structural characteristics, including a hierarchical porous structure, low density, and a large specific surface area. Furthermore, the synergistic effects of NH<sub>2</sub>-MIL-88B, Ta<sub>4</sub>C<sub>3</sub>T<sub>X</sub> MXene, and the aerogel matrix contribute to remarkable physicochemical properties, such as high sunlight absorptivity and an optimal optical band gap that aligns well with the solar spectrum. These attributes enable the aerogels to photodegrade various dye and antibiotic drug solutions with high concentrations. The photodegradation efficiencies achieved were 75.57 % for Congo red, 61.56 % for methylene blue, and 58.57 % for tetracycline hydrochloride. Additionally, these aerogels exhibit significant adsorption capacities for various dyes and drugs. Moreover, when the phase change material polyethylene glycol is successfully integrated into the aerogels, they exhibit excellent thermal energy storage performance with leak-proof capabilities. A high photothermal conversion efficiency of 90.15 %, a phase enthalpy of 202.13 J g<sup>−1</sup>, and an enthalpy efficiency of 98.55 % provide evidence for this. This work provides valuable insights into the development of multifunctional aerogels aimed at addressing the challenges of wastewater treatment and energy shortages.</div></div>","PeriodicalId":262,"journal":{"name":"Carbon","volume":null,"pages":null},"PeriodicalIF":10.5,"publicationDate":"2024-11-13","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"142656266","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":2,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Hierarchical core-shell transitional metal chalcogenides Co9S8/ CoSe2@C nanocube embedded into porous carbon for tunable and efficient microwave absorption 嵌入多孔碳中的分层核壳过渡金属卤化物 Co9S8/ CoSe2@C 纳米管用于可调高效微波吸收
IF 10.5 2区 材料科学
Carbon Pub Date : 2024-11-12 DOI: 10.1016/j.carbon.2024.119824
Nian Wang , Yikun Chen , Huichao Rao , Yujia Zou , Kai Nan , Yan Wang
{"title":"Hierarchical core-shell transitional metal chalcogenides Co9S8/ CoSe2@C nanocube embedded into porous carbon for tunable and efficient microwave absorption","authors":"Nian Wang ,&nbsp;Yikun Chen ,&nbsp;Huichao Rao ,&nbsp;Yujia Zou ,&nbsp;Kai Nan ,&nbsp;Yan Wang","doi":"10.1016/j.carbon.2024.119824","DOIUrl":"10.1016/j.carbon.2024.119824","url":null,"abstract":"<div><div>In the domain of electromagnetic (EM) wave absorbing materials, the selection of suitable components and microstructures is an effective approach for designing the intense coupling of wave impedance and EM dissipation. In this study, we have successfully fabricated a double-carbon modified Co<sub>9</sub>S<sub>8</sub>/CoSe<sub>2</sub> nanocube, where the core-shell Co<sub>9</sub>S<sub>8</sub>/CoSe<sub>2</sub>@C cube was anchored onto porous carbon (PC). The existence of three-dimensional (3D) porous carbon and the fabrication of Co<sub>9</sub>S<sub>8</sub>/CoSe<sub>2</sub>@C distributed on carbon nanosheets contribute to the improvement of conduction, magnetic losses, and the optimization of impedance matching. Substantial heterogeneous interfaces are generated between Co<sub>9</sub>S<sub>8</sub>, CoSe<sub>2</sub>, carbon shells, and PC, leading to extensive interfacial polarization and facilitating the transformation of EM energy into thermal energy. The abundant defects, S and Se vacancies in carbon component can act as polarization centers, inducing dipolar polarization and thus increasing the electromagnetic wave (EMW) loss. The Co<sub>9</sub>S<sub>8</sub>/CoSe<sub>2</sub>@C@PC exhibits the best microwave absorption properties, with a minimum reflection loss (RL<sub>min</sub>) of −64.1 dB at 2.5 mm and an effective absorption bandwidth (EAB) of 6.3 GHz. The High-Frequency Structure Simulator results indicate the RCS values of the samples within the range of −90 °C &lt; θ &lt; 90 °C are lower than −20 dB m<sup>2</sup>, which can achieve almost full-angle coverage in the actual environment. This research offers inspiration and strategies for the design and synthesis of multi-component magneto-electric composites based on transitional metal chalcogenides.</div></div>","PeriodicalId":262,"journal":{"name":"Carbon","volume":null,"pages":null},"PeriodicalIF":10.5,"publicationDate":"2024-11-12","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"142655844","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":2,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Coating carbon cloth with Cu3Se2 by electrodeposition for pressure sensing and enhanced EMI shielding 通过电沉积在碳布上镀上 Cu3Se2,用于压力传感和增强电磁干扰屏蔽
IF 10.5 2区 材料科学
Carbon Pub Date : 2024-11-10 DOI: 10.1016/j.carbon.2024.119814
Peng-an Zong , Mengran Chen , Xia Wang , Heng Liu , Zhengxi He , Yixiang Ou , Chuan Sun
{"title":"Coating carbon cloth with Cu3Se2 by electrodeposition for pressure sensing and enhanced EMI shielding","authors":"Peng-an Zong ,&nbsp;Mengran Chen ,&nbsp;Xia Wang ,&nbsp;Heng Liu ,&nbsp;Zhengxi He ,&nbsp;Yixiang Ou ,&nbsp;Chuan Sun","doi":"10.1016/j.carbon.2024.119814","DOIUrl":"10.1016/j.carbon.2024.119814","url":null,"abstract":"<div><div>Functional films with electromagnetic interference (EMI) shielding capabilities and pressure sensing functions epitomize the intersection of materials science and electronics. These films not only protect against electromagnetic interference but also provide essential data on mechanical stresses, thus improving the reliability, performance, and safety of electronic devices and structures. Carbon cloth (CC) offer excellent air and moisture permeability, ensuring long-term comfort when in contact with human skin; however, they face challenges in achieving highly effective EMI shielding. In this study, a Cu<sub>3</sub>Se<sub>2</sub> coated CC based composite film was fabricated using a facile electrodeposition method. The EMI shielding effectiveness was significantly enhanced from 15 dB to 63 dB, a more than fourfold improvement. The Cu<sub>3</sub>Se<sub>2</sub>/CC film also demonstrated distinctive resistance variation and high sensitivity when used as pressure sensors to detect human motions, including finger bending, wrist flexion, knee movement, and elbow swing. Additionally, the Cu<sub>3</sub>Se<sub>2</sub>-modified textile exhibited flame retardancy, excellent flexibility, and breathability. This work highlights the potential for cost-effective, high-EMI-shielding textile sensors and paves the way for the development of multifunctional wearable electronics.</div></div>","PeriodicalId":262,"journal":{"name":"Carbon","volume":null,"pages":null},"PeriodicalIF":10.5,"publicationDate":"2024-11-10","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"142656207","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":2,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Metal-free carbon catalysis of toluene on activated coke and its active sources 活性焦炭上的无金属碳催化甲苯及其活性来源
IF 10.5 2区 材料科学
Carbon Pub Date : 2024-11-09 DOI: 10.1016/j.carbon.2024.119788
Le Huang , Caiting Li , Xuan Liu , Shanhong Li , Lei Gao , Xueyu Du , Youcai Zhu , Jungang Zhao , Kuang Yang , Ziang Zhang , Ying Zhang
{"title":"Metal-free carbon catalysis of toluene on activated coke and its active sources","authors":"Le Huang ,&nbsp;Caiting Li ,&nbsp;Xuan Liu ,&nbsp;Shanhong Li ,&nbsp;Lei Gao ,&nbsp;Xueyu Du ,&nbsp;Youcai Zhu ,&nbsp;Jungang Zhao ,&nbsp;Kuang Yang ,&nbsp;Ziang Zhang ,&nbsp;Ying Zhang","doi":"10.1016/j.carbon.2024.119788","DOIUrl":"10.1016/j.carbon.2024.119788","url":null,"abstract":"<div><div>In this work, toluene removal by activated coke (ACK) was investigated. For the first time, metal-free carbon catalytic oxidation of toluene on ACK was experimentally demonstrated. On this basis, the active sources of carbon catalytic oxidation of toluene on ACK, including surface defects, pore grading degree (V<span><math><msub><mrow></mrow><mrow><mi>m</mi><mi>e</mi><mi>s</mi><mo>+</mo><mi>m</mi><mi>a</mi><mi>c</mi></mrow></msub></math></span>/V<span><math><msub><mrow></mrow><mrow><mi>t</mi></mrow></msub></math></span>), and surface oxygen functional groups, were identified in combination with characterization tests. The catalytic effects of different oxygen-containing functional groups (C=O, COO-, C-O-) on toluene oxidation were analyzed. The carbon catalytic oxidation reaction path of toluene on ACK has been determined as follows: toluene <span><math><mo>→</mo></math></span> benzyl alcohol <span><math><mo>→</mo></math></span> benzaldehyde <span><math><mo>→</mo></math></span> benzoic acid <span><math><mo>→</mo></math></span> maleic anhydride <span><math><mo>→</mo></math></span> carbon dioxide and water. It can be divided into three steps: initial oxidation of toluene to benzyl alcohol and benzaldehyde on C=O; deep non-mineralized oxidation of benzyl alcohol and benzaldehyde on C=O, COO-, C-O-; and mineralized oxidation of intermediate products on C-O- to produce CO<span><math><msub><mrow></mrow><mrow><mn>2</mn></mrow></msub></math></span>. The gradual oxidation of toluene promotes the interconversion of C=O, COO-, and C-O-, with the assistance of O<span><math><msub><mrow></mrow><mrow><mn>2</mn></mrow></msub></math></span> and reactive oxygen species (O<span><math><msup><mrow></mrow><mrow><mo>∗</mo></mrow></msup></math></span>) generated by activation of O<span><math><msub><mrow></mrow><mrow><mn>2</mn></mrow></msub></math></span> and adsorbed water.</div></div>","PeriodicalId":262,"journal":{"name":"Carbon","volume":null,"pages":null},"PeriodicalIF":10.5,"publicationDate":"2024-11-09","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"142656270","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":2,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
CTAB@Ti3C2Tx/laser-induced graphene for the detection of veterinary drugs in micro-droplet 用于检测微滴中兽药的 CTAB@Ti3C2Tx/ 激光诱导石墨烯
IF 10.5 2区 材料科学
Carbon Pub Date : 2024-11-09 DOI: 10.1016/j.carbon.2024.119815
Tao Wang , Ruizheng Zhong , Yimeng Fu , Chidan Wan , Xin Zhou , Zhiyong He , Mei Liu , Can Wu , Yong Tang
{"title":"CTAB@Ti3C2Tx/laser-induced graphene for the detection of veterinary drugs in micro-droplet","authors":"Tao Wang ,&nbsp;Ruizheng Zhong ,&nbsp;Yimeng Fu ,&nbsp;Chidan Wan ,&nbsp;Xin Zhou ,&nbsp;Zhiyong He ,&nbsp;Mei Liu ,&nbsp;Can Wu ,&nbsp;Yong Tang","doi":"10.1016/j.carbon.2024.119815","DOIUrl":"10.1016/j.carbon.2024.119815","url":null,"abstract":"<div><div>The design and construction of novel micro-droplet electrochemical sensor is crucial for the development of electrochemical analysis. The core of micro-droplet electrochemical sensors lies in fabricating effective electrode substrate materials and surface-active materials. MXene have been widely used for electrochemical sensors due to its high conductivity and excellent hydrophilicity. However, MXene-based materials are rarely used for the fabrication of micro-droplet electrochemical sensors. Besides, pure MXene materials often fall short of meeting trace detection requirements for specific substances, which necessitates the surface modification of these MXene materials. This work aims at fabricating novel MXene-based micro-droplet electrochemical sensor for veterinary drug residues detection. In order to achieve this purpose, cationic surfactant cetyltrimethylammonium bromide (CTAB) was intercalated into the interlayers of Ti<sub>3</sub>C<sub>2</sub>T<sub>x</sub> nanosheets, enlarging its interlayer spacing. Meanwhile, CTAB molecules were also bonded on the surface of Ti<sub>3</sub>C<sub>2</sub>T<sub>x</sub> nanosheets through electrostatic adsorption, inducing the assembly of small-sized Ti<sub>3</sub>C<sub>2</sub>T<sub>x</sub> nanosheets into larger ones (CTAB@Ti<sub>3</sub>C<sub>2</sub>T<sub>x</sub>) and endowing Ti<sub>3</sub>C<sub>2</sub>T<sub>x</sub> nanosheets with positively charged surface. Compared with pristine Ti<sub>3</sub>C<sub>2</sub>T<sub>x</sub> nanosheets, the hydrophilicity and adsorption capacity of CTAB@Ti<sub>3</sub>C<sub>2</sub>T<sub>x</sub> were effectively boosted. After then, CTAB@Ti<sub>3</sub>C<sub>2</sub>T<sub>x</sub> were modified on the surface of integrated laser-induced graphene (LIG) electrodes. As a result, CTAB@Ti<sub>3</sub>C<sub>2</sub>T<sub>x</sub>/LIG showed enhanced electrochemical activity and rapid, sensitive micro-droplet electrochemical detection for paracetamol and fenbendazole veterinary drug residues were achieved. Finally, the constructed CTAB@Ti<sub>3</sub>C<sub>2</sub>T<sub>x</sub>/LIG micro-droplet electrochemical sensor was employed for the detection of paracetamol and fenbendazole in pork and milk samples, exhibiting satisfactory detection accuracy.</div></div>","PeriodicalId":262,"journal":{"name":"Carbon","volume":null,"pages":null},"PeriodicalIF":10.5,"publicationDate":"2024-11-09","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"142656204","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":2,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Innovative fabrication of CNT/SiC composite fibers via impregnation-wet twisting-pyrolysis: Advancements in strength, conductivity, and EMI shielding 通过浸渍-湿法加捻-热解创新性地制造出 CNT/SiC 复合纤维:强度、导电性和电磁干扰屏蔽方面的进步
IF 10.5 2区 材料科学
Carbon Pub Date : 2024-11-09 DOI: 10.1016/j.carbon.2024.119812
Lingzhi Cheng , Kang Cheng , Shuxuan Qu , Xinrong Jiang , Xin Sui , Munan Lu , Weibang Lyu
{"title":"Innovative fabrication of CNT/SiC composite fibers via impregnation-wet twisting-pyrolysis: Advancements in strength, conductivity, and EMI shielding","authors":"Lingzhi Cheng ,&nbsp;Kang Cheng ,&nbsp;Shuxuan Qu ,&nbsp;Xinrong Jiang ,&nbsp;Xin Sui ,&nbsp;Munan Lu ,&nbsp;Weibang Lyu","doi":"10.1016/j.carbon.2024.119812","DOIUrl":"10.1016/j.carbon.2024.119812","url":null,"abstract":"<div><div>Floating catalyst chemical vapor deposition (FCCVD) is a key method for synthesizing high-strength, electrically conductive carbon nanotube (CNT) fibers. However, the high porosity of FCCVD CNT fibers limits the full utilization of the intrinsic performance of CNTs. It remains a challenge to assemble and continuous fabricate high-performance CNT fibers. Herein, this study proposed an impregnation-wet twisting-pyrolysis process to fabricate continuous CNT/SiC composite fibers to enhance the mechanical and electrical properties by reducing pore sizes and improving the interaction between CNTs. The resulting compact structure and enhanced interfacial interactions of the CNT/SiC fibers exhibited both high strength (2015.27 MPa) and high electrical conductivity (7.2 × 10<sup>5</sup> S/m), representing increases of 130.8 % and 69.9 % compared to pristine CNT fibers. The unidirectional laminates assembled by continuous CNT/SiC fibers demonstrated high electromagnetic interference (EMI) shielding effectiveness of 66.33 dB. This innovative continuous process holds significant potential for the industrial utilization of CNT/SiC fibers.</div></div>","PeriodicalId":262,"journal":{"name":"Carbon","volume":null,"pages":null},"PeriodicalIF":10.5,"publicationDate":"2024-11-09","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"142656205","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":2,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Chemical changes from N-doped graphene and Metal-Organic Frameworks to N-G/MOF composites for improved electrocatalytic activity 从掺杂 N 的石墨烯和金属有机框架到 N-G/MOF 复合材料的化学变化,以提高电催化活性
IF 10.5 2区 材料科学
Carbon Pub Date : 2024-11-09 DOI: 10.1016/j.carbon.2024.119816
Niladri Talukder , Yudong Wang , Xiao Tong , Eon Soo Lee
{"title":"Chemical changes from N-doped graphene and Metal-Organic Frameworks to N-G/MOF composites for improved electrocatalytic activity","authors":"Niladri Talukder ,&nbsp;Yudong Wang ,&nbsp;Xiao Tong ,&nbsp;Eon Soo Lee","doi":"10.1016/j.carbon.2024.119816","DOIUrl":"10.1016/j.carbon.2024.119816","url":null,"abstract":"<div><div>Integrating N-doped graphene (N-G) with Metal-Organic Frameworks (MOFs) enhances catalytic activity for oxygen reduction reaction (ORR), often exceeding both the performances of their precursors and, in some cases, even Platinum group metal (PGM)-based catalysts. However, the factors driving this improved catalytic activity in N-G/MOF composites remain unexplored, particularly from the perspective of the chemical changes. To investigate the chemical changes in N-G and MOF upon their integration and the implications of these changes on ORR catalytic activity, an N-G/MOF was synthesized from N-G with a MOF (ZIF-8) following a mechanochemical wet ball milling process. The N-G, ZIF-8, and N-G/MOF samples were examined for changes in elemental composition, chemical state of carbon, different nitrogen and carbon bonds, and other chemical interactions. In the N-G/MOF catalyst, compared to its N-G and ZIF-8 precursors, the relative oxygen content increased, indicating the formation of additional oxygen-containing groups. The C 1s peak shifted to a lower binding energy in N-G/MOF, suggesting changes in the overall chemical or oxidation state of the carbon atoms. Besides, the increase in pyridinic-N functional groups in N-G/MOF points to the formation of additional active sites. Furthermore, the formation of C–Zn bonds in N-G/MOF suggests the probable emergence of single-atom Zn sites, while the increase in C<img>O bonds points to the formation of carboxyl or carbonyl groups. These chemical changes could be linked to the enhanced electrocatalytic activity of the N-G/MOF composite for ORR. This study may also be beneficial for other research focused on developing composite catalysts involving various N-G and MOFs-based materials.</div></div>","PeriodicalId":262,"journal":{"name":"Carbon","volume":null,"pages":null},"PeriodicalIF":10.5,"publicationDate":"2024-11-09","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"142656262","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":2,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Construction of flexible magnetic carbon nanofibers by core-shell MOF derivatives for optimizing microwave absorption 利用核壳 MOF 衍生物构建柔性磁性纳米碳纤维以优化微波吸收
IF 10.5 2区 材料科学
Carbon Pub Date : 2024-11-09 DOI: 10.1016/j.carbon.2024.119817
Luyao Han, Haibo Yang, Zhixin Cai, Ying Lin
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