Journal of Porous Materials最新文献

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Adsorption of antibiotics using fly ash-based NaP1 zeolite modified with lanthanides via ion exchange and wet impregnation 镧系修饰飞灰型NaP1沸石离子交换湿浸渍对抗生素的吸附研究
IF 3 4区 材料科学
Journal of Porous Materials Pub Date : 2026-07-10 DOI: 10.1007/s10934-026-01942-x
Agata Jankowska, Rafał Panek, Joanna Goscianska
{"title":"Adsorption of antibiotics using fly ash-based NaP1 zeolite modified with lanthanides via ion exchange and wet impregnation","authors":"Agata Jankowska,&nbsp;Rafał Panek,&nbsp;Joanna Goscianska","doi":"10.1007/s10934-026-01942-x","DOIUrl":"10.1007/s10934-026-01942-x","url":null,"abstract":"<div><p>The increase in global population, extended life expectancy, and the potential of pandemic occurrence substantially elevate antibiotics consumption, thereby exacerbating concerns related to drug resistance and their toxic effects on ecosystems. Consequently, developing effective materials capable of removing antibiotics from water has attracted significant attention. This research focused on lanthanum and cerium modifications of fly ash-based NaP1 zeolite via ion exchange and wet impregnation, aiming to enhance its performance as an adsorbent for ciprofloxacin and tetracycline. Lanthanum and cerium were selected as modifiers due to their low toxicity, abundance, and cost-effectiveness. Their incorporation into NaP1 material was confirmed by structural and compositional changes. The results showed that using lanthanum for modification is more beneficial than cerium, and ion-exchanged samples yielded greater effectiveness compared to wet-impregnated ones. According to EDS elemental mapping, ion exchange promoted a homogeneous distribution of lanthanides, implying uniform formation of active sites. The adsorption of antibiotics occurred through electrostatic and cation-π interactions, ion exchange, hydrogen bonding, and coordination complexes formation. The highest sorption capacities were attained for the sample modified with lanthanum via ion exchange (235 and 190 mg g<sup>-1</sup> for ciprofloxacin and tetracycline), which can be attributed e.g., to faster adsorption rates of La-modified adsorbents. The reusability tests showed that materials can be used five times, which is important for minimizing secondary pollution and enhancing sustainability. These findings highlight the potential of lanthanide modification of fly ash-based zeolite as an effective approach for reducing antibiotic contamination, helping to ensure environmental safety and public health protection.</p></div>","PeriodicalId":660,"journal":{"name":"Journal of Porous Materials","volume":"33 4","pages":"1311 - 1325"},"PeriodicalIF":3.0,"publicationDate":"2026-07-10","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://link.springer.com/content/pdf/10.1007/s10934-026-01942-x.pdf","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"148782348","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"OA","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
In-silico & in-vitro evaluation of Hesperetin enhanced sodium alginate/ gelatin/ hydroxyapatite scaffold for bone tissue engineering applications 橙皮素增强海藻酸钠/明胶/羟基磷灰石骨组织工程支架的硅内和体外评价
IF 3 4区 材料科学
Journal of Porous Materials Pub Date : 2026-06-29 DOI: 10.1007/s10934-026-01938-7
Shifana Begum Jamal Mohamed, Saranya Srinivasan, Ashwathi Vijayalekha, Suresh Kumar Anandasadagopan, Ashok Kumar Pandurangan
{"title":"In-silico & in-vitro evaluation of Hesperetin enhanced sodium alginate/ gelatin/ hydroxyapatite scaffold for bone tissue engineering applications","authors":"Shifana Begum Jamal Mohamed,&nbsp;Saranya Srinivasan,&nbsp;Ashwathi Vijayalekha,&nbsp;Suresh Kumar Anandasadagopan,&nbsp;Ashok Kumar Pandurangan","doi":"10.1007/s10934-026-01938-7","DOIUrl":"10.1007/s10934-026-01938-7","url":null,"abstract":"<div><p>Bone tissue engineering (BTE) has emerged as a promising alternative to traditional bone grafting methods with limitations such as donor scarcity and immunogenic complications. This study evaluated the efficacy of a Sodium Alginate/Gelatin/Hydroxyapatite scaffold enhanced with <i>Hesperetin</i>, a bioactive flavonoid, in bone regeneration. The scaffold was fabricated using the freeze-drying technique and was characterized through various physicochemical and biological evaluations to assess its suitability for tibial regeneration. In in-silico studies were incorporated to identify <i>Hesperetin’s</i> potential targets of hesperetin in bone application, revealing its interaction with key osteogenic and anti-inflammatory pathways. The results indicated that the treated scaffolds exhibited improved characteristics compared with the control group. The surface morphology of the scaffolds confirmed that the porous microstructure was advantageous for cell adhesion, whereas the MTT results revealed enhanced osteoblast viability. These findings highlight the potential of flavonoid-enhanced scaffolds in regenerative medicine, offering a biocompatible and efficacious solution to bone defects.</p><h3>Graphical abstract</h3><div><figure><div><div><picture><source><img></source></picture></div></div></figure></div></div>","PeriodicalId":660,"journal":{"name":"Journal of Porous Materials","volume":"33 4","pages":"1291 - 1310"},"PeriodicalIF":3.0,"publicationDate":"2026-06-29","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"148783471","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Sustainable synthesis of water hyacinth–derived porous activated carbon/ZnO/g-C₃N₄ Ternary composite for visible-light photocatalytic degradation of methylene blue and rhodamine B 水葫芦衍生多孔活性炭/ZnO/g-C₃N₄三元复合材料可见光催化降解亚甲基蓝和罗丹明B的可持续合成
IF 3 4区 材料科学
Journal of Porous Materials Pub Date : 2026-06-26 DOI: 10.1007/s10934-026-01940-z
Amal A. Nassar, Ayman K. El-Sawaf, A. O. Ali, M. F. Mubarak
{"title":"Sustainable synthesis of water hyacinth–derived porous activated carbon/ZnO/g-C₃N₄ Ternary composite for visible-light photocatalytic degradation of methylene blue and rhodamine B","authors":"Amal A. Nassar,&nbsp;Ayman K. El-Sawaf,&nbsp;A. O. Ali,&nbsp;M. F. Mubarak","doi":"10.1007/s10934-026-01940-z","DOIUrl":"10.1007/s10934-026-01940-z","url":null,"abstract":"<div><p>In this study, a sustainable ternary nanocomposite photocatalyst, water hyacinth-derived porous activated carbon/ZnO/g-C₃N₄ (WHR-PAC/ZnO/g-C₃N₄), was successfully fabricated for the efficient degradation of methylene blue (MB) and rhodamine B (RhB) dyes under visible light irradiation. The prepared composite was characterized using various physicochemical techniques to investigate its structural, morphological, optical, and surface properties. The results confirmed the successful integration of ZnO and g-C₃N₄ onto the WHR-PAC surface, leading to enhanced surface area and improved charge separation efficiency. The photocatalytic activity of the synthesized nanocomposite was evaluated under different experimental conditions, including catalyst dosage, pH, dye concentration, and irradiation time. The WHR-PAC/ZnO/g-C₃N₄ composite achieved maximum degradation efficiencies of 97.8 ± 2.9% for MB within 75 min and 95.4 ± 2.9% for RhB within 90 min under visible light irradiation. Kinetic studies revealed that the degradation process followed pseudo-first-order kinetics. The enhanced photocatalytic performance was attributed to the synergistic interaction among WHR-PAC, ZnO, and g-C₃N₄, which promoted efficient charge transfer and suppressed electron–hole recombination. Furthermore, the photocatalyst exhibited excellent stability and reusability, maintaining high degradation efficiency after seven consecutive cycles. These findings demonstrate that the WHR-PAC/ZnO/g-C₃N₄ nanocomposite is a promising and environmentally friendly visible-light-driven photocatalyst for wastewater treatment applications.</p></div>","PeriodicalId":660,"journal":{"name":"Journal of Porous Materials","volume":"33 4","pages":"1271 - 1290"},"PeriodicalIF":3.0,"publicationDate":"2026-06-26","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"148783403","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Preparation and wave absorbing properties of sea urchin-like MHCM@PANI composites 海胆样MHCM@PANI复合材料的制备及其吸波性能
IF 3 4区 材料科学
Journal of Porous Materials Pub Date : 2026-06-25 DOI: 10.1007/s10934-026-01941-y
Xiaoqing Yin, Ziyi Zhang, Fan Zhang, Junwu Wen, Fei Yan, Yang Chen
{"title":"Preparation and wave absorbing properties of sea urchin-like MHCM@PANI composites","authors":"Xiaoqing Yin,&nbsp;Ziyi Zhang,&nbsp;Fan Zhang,&nbsp;Junwu Wen,&nbsp;Fei Yan,&nbsp;Yang Chen","doi":"10.1007/s10934-026-01941-y","DOIUrl":"10.1007/s10934-026-01941-y","url":null,"abstract":"<div><p>In this paper, silica hydrolyzed by tetraethyl orthosilicate was used as template to synthesize phenolic resin microspheres by resorcinol and formaldehyde. Then, mesoporous hollow carbon microspheres (MHCM) were obtained by etching and high-temperature calcination. The sea urchin-like MHCM@PANI composite absorbing material was prepared by in-situ polymerization of MHCM coated with polyaniline (PANI). The microwave absorption performance of MHCM@PANI composite was evaluated. The minimum reflection loss (RL<sub>min</sub>) was − 49.95dB and the maximum effective absorption bandwidth was 6.03 GHz. By adjusting the ratio of MHCM and PANI, the effective electromagnetic wave absorption of X, C and Ku bands can be achieved, and the broadband absorption can be achieved. With low dielectric constant, PANI can effectively adjust the overall dielectric properties of carbon materials, optimize impedance matching, and generate new heterogeneous interfaces, thus improving the wave absorption properties of composite materials. The excellent absorbing performance mainly comes from the combination of good impedance matching characteristics and a variety of loss mechanisms including dielectric loss, multiple reflection scattering and strong interface polarization.</p></div>","PeriodicalId":660,"journal":{"name":"Journal of Porous Materials","volume":"33 4","pages":"1261 - 1269"},"PeriodicalIF":3.0,"publicationDate":"2026-06-25","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"148783438","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
3D printed silk fibroin-bentonite-hydroxyapatite hybrid scaffold with antioxidant property for bone regeneration 3D打印丝素-膨润土-羟基磷灰石复合抗氧化骨再生支架
IF 3 4区 材料科学
Journal of Porous Materials Pub Date : 2026-06-24 DOI: 10.1007/s10934-026-01932-z
Logeshwaran A, Renold Elsen, Ashutosh D. Bagde, Sunita Nayak
{"title":"3D printed silk fibroin-bentonite-hydroxyapatite hybrid scaffold with antioxidant property for bone regeneration","authors":"Logeshwaran A,&nbsp;Renold Elsen,&nbsp;Ashutosh D. Bagde,&nbsp;Sunita Nayak","doi":"10.1007/s10934-026-01932-z","DOIUrl":"10.1007/s10934-026-01932-z","url":null,"abstract":"<div><p>For bone tissue regeneration, 3D printing ceramic materials is beneficial, however material synthesis and commercially accessible composites raise demand and decrease cost-effectiveness. Implementing more composite materials to the defective site may triggers oxidative stress to the surrounding cells. This study focuses on the development of 3D printed Bentonite- Hydroxyapatite (BEN-HAP) scaffold infilled with flavonoids conjugated silk fibroin for bone tissue replacement for controlling oxidative stress during tissue regeneration. The silk fibroin (SF) infilled regions in the scaffold showed a sponge-like fibre matrix that facilitates cell adhesion and proliferation which were observed under FESEM. Also, flake-shaped appetite formation with increased Ca: P ratio (13.21:9.11) was observed in SF-infilled scaffolds, confirming the calcium and phosphate mineralization layer. The scaffolds showed improved surface properties that facilitated slow water permeation and absorption compared with BEN-HAP scaffold. The biocompatibility results showed no toxic effect on human Wharton’s jelly mesenchymal stem cells (hWJ-MSCs), additionally, the quercetin and hesperetin loaded SF-BEN-HAP scaffold showed more than 60% closure promoting a high cell migration rate at 10 µM concentration in scratch test assay. And a maximum reduction in Reactive oxygen species (ROS) activity in hWJ-MSCs was observed when treated with 20 µM flavonoids, as a result, the scaffold provides better environmental niche for cell growth, inhibiting the oxidative stress, suitable for bone tissue repair.</p></div>","PeriodicalId":660,"journal":{"name":"Journal of Porous Materials","volume":"33 4","pages":"1247 - 1260"},"PeriodicalIF":3.0,"publicationDate":"2026-06-24","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"148783458","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Silicalite-1 hollow fiber zeolite membranes for hydrogen separation from CO₂ under humid conditions 硅石-1中空纤维沸石膜,用于在潮湿条件下从CO₂中分离氢
IF 3 4区 材料科学
Journal of Porous Materials Pub Date : 2026-06-19 DOI: 10.1007/s10934-026-01937-8
Seyed Mojtaba Mirfendereski, Tayebeh Mazaheri
{"title":"Silicalite-1 hollow fiber zeolite membranes for hydrogen separation from CO₂ under humid conditions","authors":"Seyed Mojtaba Mirfendereski,&nbsp;Tayebeh Mazaheri","doi":"10.1007/s10934-026-01937-8","DOIUrl":"10.1007/s10934-026-01937-8","url":null,"abstract":"<div><p>This work introduces four mutually reinforcing synthesis routes to prepare hydrophobic silicalite-1 zeolite membranes tailored for H₂/CO₂ separation in the presence of moisture. In combination, sequential zirconia intermediate layer, dual-sized seeding, variable-temperature hydrothermal crystallization, and cationic-linker-assisted seeding limit Al leaching from the support, promote the order arrangement of seeds, and drive the formation of continuous, defect-free crystals. Structural and morphological analyses, together with gas permeation tests, verify that the resulting films are dense, highly crystalline, and strongly water-repellent. The best-performing membrane shows a Si/Al ratio of 211 (values commonly reported for Al-containing MFI membranes Si/Al &lt; 100), a water contact angle of 155° (vs. &lt; 120° for conventional layers), and an H₂/CO₂ selectivity of 6.4 while maintaining high permeance. The observed separation behavior closely follows the degree of hydrophobicity, highlighting the critical roles of suppressing Al incorporation and eliminating intercrystalline voids. Overall, the proposed scalable synthesis route yields mechanically robust membranes suitable for post-Water Gas Shift hydrogen upgrading and integration into high-temperature membrane reactors.</p></div>","PeriodicalId":660,"journal":{"name":"Journal of Porous Materials","volume":"33 4","pages":"1229 - 1246"},"PeriodicalIF":3.0,"publicationDate":"2026-06-19","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"148782639","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Experimental investigation on the water vapor adsorption performance of MOF-801 and its composite adsorbent MOF-801及其复合吸附剂的水蒸气吸附性能实验研究
IF 3 4区 材料科学
Journal of Porous Materials Pub Date : 2026-06-19 DOI: 10.1007/s10934-026-01935-w
Huizhong Z. Zhao, Chunbo Miao, Chengfeng Liu, Qingge Wang, Zhihao Xi
{"title":"Experimental investigation on the water vapor adsorption performance of MOF-801 and its composite adsorbent","authors":"Huizhong Z. Zhao,&nbsp;Chunbo Miao,&nbsp;Chengfeng Liu,&nbsp;Qingge Wang,&nbsp;Zhihao Xi","doi":"10.1007/s10934-026-01935-w","DOIUrl":"10.1007/s10934-026-01935-w","url":null,"abstract":"<div><p>Metal-organic frameworks (MOFs) represent a sophisticated class of crystalline materials characterized by metal ions coordinated with organic ligands, resulting in highly porous structures. Among them, MOF-801, a zirconium-based framework, stands out due to its exceptional surface area and customizable pore architecture. In this study, MOF-801 was synthesized by a solvothermal method, and an impregnation technique was utilized to composite it with the hygroscopic salt LiCl. This process yielded three composite adsorbents (ML-1, ML-2, ML-3) with varying LiCl mass fractions. The morphological characteristics of MOF-801 and its composite materials were examined by scanning electron microscopy (SEM), X-ray diffraction (XRD), and nitrogen adsorption measurements. The influence of hygroscopic salt content on the adsorption performance of the composite adsorbents was analyzed, and the desorption performance of MOF-801 and its composites was evaluated under various temperature conditions. The experiments demonstrated that composite adsorbents containing LiCl exhibited commendable adsorption performance, desorption capabilities, and cyclic stability. The composite adsorbent ML-3, featuring a 30% LiCl mass fraction, achieved an equilibrium adsorption capacity of 0.6788 g/g after 25 adsorption-desorption cycles at 25 °C and 50% RH, representing a 168% increase compared to pure MOF-801. Additionally, ML-3 exhibited significantly enhanced desorption rates and speeds, indicating its potential applicability in atmospheric water harvesting (AWH).</p></div>","PeriodicalId":660,"journal":{"name":"Journal of Porous Materials","volume":"33 4","pages":"1201 - 1212"},"PeriodicalIF":3.0,"publicationDate":"2026-06-19","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"148782638","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Carbon foam based microporous Pd(0) catalyst: the rapid and efficient reduction of organic pollutants 碳泡沫基微孔Pd(0)催化剂:快速高效还原有机污染物
IF 3 4区 材料科学
Journal of Porous Materials Pub Date : 2026-06-19 DOI: 10.1007/s10934-026-01934-x
Zehra Özçifçi, Nuray Yılmaz Baran, Hakkı Türker Akçay, Kaan Karaoğlu, Talat Baran
{"title":"Carbon foam based microporous Pd(0) catalyst: the rapid and efficient reduction of organic pollutants","authors":"Zehra Özçifçi,&nbsp;Nuray Yılmaz Baran,&nbsp;Hakkı Türker Akçay,&nbsp;Kaan Karaoğlu,&nbsp;Talat Baran","doi":"10.1007/s10934-026-01934-x","DOIUrl":"10.1007/s10934-026-01934-x","url":null,"abstract":"<div><p>In the present work, we report the synthesis of a low-cost microporous sucrose-based carbon foam (ACF) with a specific surface area of 591.29 m<sup>2</sup>/g, which was used as support for the preparation of a palladium-based (ACF-Pd) heterogeneous catalyst. The prepared ACF-Pd heterogeneous catalyst was characterized using BET, Raman, XPS, XRD, TEM, SEM and EDS methods. The catalytic reduction/decolorization capacity of microporous ACF-Pd was investigated for the reduction of various nitroarenes (2-nitroaniline, 4-nitroaniline, 4-nitrophenol and 4-nitro-o-phenylenediamine) and organic dyes (methyl orange, methylene blue and rhodamine B) by UV-Vis spectroscopy in an aqueous medium, with NaBH<sub>4</sub> as the reducing agent at room temperature. The advantages of this method include short reaction times, mild reaction conditions, high yields, easy separation and excellent chemical stability of the catalyst due to its reusability. The results of the catalytic tests showed that the reduction/discoloration reactions of both nitro compounds and organic dyes were successfully carried out within 0–100 s, owing to the strong catalytic ability of ACF-Pd. Moreover, the catalytic reduction of 2-nitroaniline was carried out five times in consecutive run without both noticeable decrease in the catalytic and any change in the morphology of the catalyst, confirming that it is a sustainable and robust nano catalyst.</p></div>","PeriodicalId":660,"journal":{"name":"Journal of Porous Materials","volume":"33 4","pages":"1213 - 1227"},"PeriodicalIF":3.0,"publicationDate":"2026-06-19","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://link.springer.com/content/pdf/10.1007/s10934-026-01934-x.pdf","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"148782640","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"OA","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Dual-functional Bi₂(Se₀0.8 S₀.₂)₃@C composite for high-performance supercapacitors and visible-light photocatalytic MB degradation 双功能Bi₂(Se 0 0.8 S 0)。₂)₃@C复合材料用于高性能超级电容器和可见光光催化MB降解
IF 3 4区 材料科学
Journal of Porous Materials Pub Date : 2026-06-15 DOI: 10.1007/s10934-026-01933-y
A. Parveen, N. Surumbarkuzhali, D. Anitha Kumari, R. Kanimozhi, Arumugam Krishnan Arulmozhi
{"title":"Dual-functional Bi₂(Se₀0.8 S₀.₂)₃@C composite for high-performance supercapacitors and visible-light photocatalytic MB degradation","authors":"A. Parveen,&nbsp;N. Surumbarkuzhali,&nbsp;D. Anitha Kumari,&nbsp;R. Kanimozhi,&nbsp;Arumugam Krishnan Arulmozhi","doi":"10.1007/s10934-026-01933-y","DOIUrl":"10.1007/s10934-026-01933-y","url":null,"abstract":"<div><p>The development of stable, high-density electrode materials for use in advanced electrochemical energy storage systems is of utmost importance. This study presents a simple one-step chemical precipitation approach for the fabrication of Bi₂(Se₀.<sub>8</sub>S₀.₂)₃@C, a sulfur-modified bismuth selenide solid solution coupled with amorphous carbon. The presence of crystalline bismuth selenosulfide was verified through structural investigation. Morphological analysis revealed a network of nanosheets embedded within a carbon matrix, facilitating enhanced charge transfer and providing abundant electroactive sites. Electrochemical testing in a 3 M KOH electrolyte showed that the Bi₂(Se₀.₈S₀.₂)₃@C electrode achieved a specific capacitance of 950 F g⁻¹ at 1 A g⁻¹ and exhibited excellent cycling stability, retaining 98% of its capacitance after 5000 cycles with nearly 100% efficiency. An asymmetric supercapacitor device, using activated carbon as the negative electrode and Bi₂(Se₀.<sub>8</sub>S₀.₂)₃@C as the positive electrode, delivered a maximum energy density of 65 Wh kg⁻¹ at 877 W kg⁻¹ and 35 Wh kg⁻¹ at 3117 W kg⁻¹. Furthermore, after just 20 s of charging, two ASC coin cells connected in series were able to power multiple LEDs for approximately 10 min, demonstrating excellent power delivery and rapid energy storage capability. These results indicate that asymmetric supercapacitors based on sulfur-modified bismuth selenide–carbon composite electrodes can be highly effective. In addition, Bi₂(Se₀0.8 S₀.₂)₃@C shows enhanced photocatalytic performance with ~ 92% MB degradation, higher rate constant (0.0761 min⁻¹), and excellent stability over five cycles due to improved charge separation.</p></div>","PeriodicalId":660,"journal":{"name":"Journal of Porous Materials","volume":"33 4","pages":"1185 - 1199"},"PeriodicalIF":3.0,"publicationDate":"2026-06-15","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"148782467","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Electrochemical evaluation of honeycomb-structured activated carbon prepared from Maranta arundinacea bagasse fiber for supercapacitor applications 甘蔗渣纤维制备蜂窝状活性炭在超级电容器中的电化学性能
IF 3 4区 材料科学
Journal of Porous Materials Pub Date : 2026-06-12 DOI: 10.1007/s10934-026-01927-w
Lekshmi Sunil, Manik Clinton Franklin, Akshaya Sisubalan, Shilpa Alaparambil Sudhakaran, Hemalatha Kuzhandaivel, Vijayakumar Elayappan, Karthick Sivalingam Nallathambi
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