Journal of Porous Materials最新文献

{"title":"Retraction Note: Evaluation of antimicrobial activity of different silver-exchanged nano and micronized zeolites prepared by microwave technique","authors":"H. F. Youssef, M.S Abdel-Aziz, F. K. Fouda","doi":"10.1007/s10934-025-01873-z","DOIUrl":"10.1007/s10934-025-01873-z","url":null,"abstract":"","PeriodicalId":660,"journal":{"name":"Journal of Porous Materials","volume":"32 6","pages":"2497 - 2497"},"PeriodicalIF":3.2,"publicationDate":"2025-10-21","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"145493326","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

{"title":"Chitosan-reinforced carbon aerogels from oil palm fronds for enhanced oil absorption and silver nanowires loaded as antimicrobial activity","authors":"Bernadeta Ayu Widyaningrum,&nbsp; Sudarmanto,&nbsp;Lu’lu’ Qurrotul ‘Ain Hariri,&nbsp; Hendrawati,&nbsp;Riska Surya Ningrum,&nbsp;Dwi Ajias Pramasari,&nbsp;Andrew Nosakhare Amenaghawon,&nbsp;Noureddine El Messaoudi,&nbsp;Tonni Agustiono Kurniawan,&nbsp;Handoko Darmokoesoemo,&nbsp;Heri Septya Kusuma","doi":"10.1007/s10934-025-01865-z","DOIUrl":"10.1007/s10934-025-01865-z","url":null,"abstract":"<div>\u0000 \u0000 <p>This study explores the development of carbon aerogels (CA) derived from oil palm fronds (OPF) with chitosan (CS) reinforcement and silver nanowires (AgNWs) incorporation for oil absorption and antimicrobial applications. Cellulose nanofibrils (CNF) were extracted from OPF and mixed with CS in varying mass ratios (2:1, 1:1, 1:2, and 1:3) before undergoing freeze-drying and carbonization at temperatures of 300 °C. The resulting carbon aerogels (CAn) were further functionalized with AgNWs (CAn-x) using a dip-coating technique. The CAn-x samples were observed low density (&lt; 0.0318 g/cm3), high porosity (&gt; 92%), specific surface areas (&gt; 43 m²/g), selectivity for oils and superhydrophobicity (WCA &gt; 176^◦). In addition, the CAn-x exhibited absorption capacity for marine fuel oil (MFO), palm oil (PO), and high-speed diesel oil (HSD) ranged from 20 to 76 g/g with reusable until 26 times, influenced by the aerogel’s pore structure. The CS improved the aerogel’s structural integrity, enhancing reusability over multiple absorption-desorption cycles. AgNWs loading imparted strong antimicrobial activity, particularly against Gram-negative bacteria (<i>E. coli</i> and <i>S. typhi</i>), as demonstrated by the agar diffusion method. The results suggest that CA-AgNWs composites exhibit excellent oil absorption performance, selectivity, and reusability, along with broad-spectrum antimicrobial properties. These findings highlight the potential of OPF-derived carbon aerogels as multifunctional materials for environmental and medical applications. This research demonstrates a sustainable approach to utilizing biomass waste for creating high-performance absorbents with tailored properties. Future work may focus on optimizing the composition and processing conditions for enhanced application efficiency.</p>\u0000 </div>","PeriodicalId":660,"journal":{"name":"Journal of Porous Materials","volume":"33 1","pages":"213 - 230"},"PeriodicalIF":3.2,"publicationDate":"2025-10-19","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"146091011","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

{"title":"Effect of Y zeolite mesoporousity on the catalytic cracking of vacuum gas oil (VGO)","authors":"Mohammed I. Rashied,&nbsp;Rana Th. Abd Alrubaye,&nbsp;Samer G. Abdulridha,&nbsp;Radhaa N. Saeed","doi":"10.1007/s10934-025-01858-y","DOIUrl":"10.1007/s10934-025-01858-y","url":null,"abstract":"<div><p>Mesoporous hierarchical Y zeolites were synthesized through a sequential process involving dealumination with ethylenediaminetetraacetic acid (EDTA) or oxalic acid (OX), followed by desilication using sodium hydroxide (NaOH). Characterization of the materials, employing X-ray diffraction (XRD), nitrogen adsorption–desorption, and scanning electron microscopy (SEM), confirmed significant structural modifications, an increase in mesoporosity, and an enhancement in external surface area. The OX–NaOH route demonstrated superior efficiency, achieving stable mesopores with surface areas exceeding 110 m²/g in shorter treatment times compared to the EDTA pathway. Catalytic testing in vacuum gas oil cracking at 420 °C revealed that the modified zeolite (DSY-OX3) yielded 41.1 vol% gasoline, a substantial improvement over the 18.4 vol% obtained with the parent Y zeolite. These findings suggest that the OX–NaOH method is a time- and energy-efficient approach for producing thermally stable mesoporous zeolites, making it a promising strategy for fluidized catalytic cracking (FCC) applications.</p></div>","PeriodicalId":660,"journal":{"name":"Journal of Porous Materials","volume":"33 1","pages":"199 - 212"},"PeriodicalIF":3.2,"publicationDate":"2025-10-17","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"146091007","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

{"title":"Defect-rich porous CeO2-based materials with adjustable acid-base properties for direct synthesis of carbonates from CO2 and alcohol","authors":"Wei Dong,&nbsp;Bin Hua,&nbsp;Xingzhuang Ren,&nbsp;Nannan Liang,&nbsp;Aizhong jia","doi":"10.1007/s10934-025-01867-x","DOIUrl":"10.1007/s10934-025-01867-x","url":null,"abstract":"<div><p>The effective transformation of CO₂ sources is one of the potential strategies to promote carbon neutrality strategic goals. A series of efficient Zr_<i>x</i>-CeO₂ catalysts with high surface oxygen vacancies and tunable acid-basic sites for direct synthesis of dialkyl carbonate (DAC) have been prepared by using xanthan gum (XG) as a template through the hydrothermal method, and were further characterized with SEM, XRD, NH₃-TPD, CO₂-TPD, XPS, and N₂ adsorption-desorption. The effect of Zr-doping on the crystal structure, oxygen vacancies, and acid-basic sites was investigated in detail, and their catalytic performances were further evaluated with direct synthesis DAC through the reaction between CO₂ and alcohol, in which multiple carbonates can be simultaneously synthesized in one pot. A possible synergistic catalytic mechanism was proposed. The obtained conclusions and discoveries provide a new insight and reference for related research.</p></div>","PeriodicalId":660,"journal":{"name":"Journal of Porous Materials","volume":"33 1","pages":"187 - 197"},"PeriodicalIF":3.2,"publicationDate":"2025-10-15","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"146091030","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

{"title":"Synergistic trimetallic FeCoW/rGO nanocomposite as a durable and high-performance electrode for advanced supercapacitors","authors":"Ali B. M. Ali,&nbsp;Ammar Yasir Ahmed,&nbsp;Premkumar R.,&nbsp;Badri Narayan Sahu,&nbsp;T. Gomathi,&nbsp;Gaganjot Kaur,&nbsp;Bekzod Matyakubov,&nbsp;Doniyor Jumanazarov,&nbsp;Mumtaj Shah,&nbsp;M. A. Diab,&nbsp;P. D. Jangir","doi":"10.1007/s10934-025-01862-2","DOIUrl":"10.1007/s10934-025-01862-2","url":null,"abstract":"<div><p>Developing advanced electrode materials with both high energy density and outstanding long-term stability is essential for next-generation supercapacitors. In this work, a novel FeCoW/rGO nanocomposite was synthesized via a one-pot hydrothermal method and thoroughly characterized, revealing hierarchical flower-like FeCoW nanospheres uniformly anchored on reduced graphene oxide to form a highly porous, three-dimensional architecture. The electrode displayed a high specific capacitance of 525.16 F g⁻¹ at 1 A g⁻¹, a notable energy density of 26.25 Wh kg⁻¹, and remarkable cycling stability, retaining 94.48% of its initial capacitance over 5000 cycles. This superior performance arises from the synergistic redox activity of Fe, Co, and W, the conductive rGO framework, and the unique hierarchical structure, which collectively promote abundant active sites, facilitate rapid ion/electron transport, and alleviate mechanical stress during cycling. These results establish FeCoW/rGO as a promising and durable electrode material for advanced energy storage applications.</p></div>","PeriodicalId":660,"journal":{"name":"Journal of Porous Materials","volume":"33 1","pages":"171 - 186"},"PeriodicalIF":3.2,"publicationDate":"2025-10-15","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"146090993","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

{"title":"Improving stability and regenerability of nano-sized ZSM-5 zeolite in MTP reaction: toward a reliable industrial catalyst","authors":"Amirhossein Javdani,&nbsp;Javad Ahmadpour,&nbsp;Fereydoon Yaripour","doi":"10.1007/s10934-025-01861-3","DOIUrl":"10.1007/s10934-025-01861-3","url":null,"abstract":"<div><p>High silica ZSM-5 is a promising catalyst for the methanol to propylene (MTP) process but requires improved stability and regenerability on an industrial scale. Here, we prepared a nano-sized ZSM-5 via the seeding technique and developed its physiochemical characteristics using combined desilication and phosphorus modification. This approach combines the advantages of the above-mentioned methods and can be easily scaled up to an industrial level. The resulting catalyst exhibited a prolonged catalytic lifetime (77 days; about three times that of conventional ZSM-5) with high regenerability (70% restored catalytic activity in the second reaction cycle) and also produced a high amount of propylene from converted methanol (<span>(:{text{A}}_{{text{C}}_{text{3}}{text{H}}_{text{6}}})</span>) at lifetime per gram of zeolite catalysts (293.9 <span>(:{text{g}}_{{text{C}}_{text{3}}{text{H}}_{text{6}}}text{/}{text{g}}_{text{cat}})</span> in the first reaction cycle and 203.1 <span>(:{text{g}}_{{text{C}}_{text{3}}{text{H}}_{text{6}}}text{/}{text{g}}_{text{cat}})</span> in the second reaction cycle). It could be concluded that shortening the diffusion path, mesoporization, and moderating the acidity are responsible for such high stability and regenerability.</p></div>","PeriodicalId":660,"journal":{"name":"Journal of Porous Materials","volume":"33 1","pages":"117 - 131"},"PeriodicalIF":3.2,"publicationDate":"2025-10-13","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"146091028","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

{"title":"Construction of an interpenetrating network structure based on skeleton reconstruction of melamine foam and ultrafine glass fiber and property investigations","authors":"Kai Xu,&nbsp;Zhiyu Zhang,&nbsp;Zhaofeng Chen,&nbsp;Chengqian Bian,&nbsp;Yongjie Li,&nbsp;Ximiao Wei","doi":"10.1007/s10934-025-01864-0","DOIUrl":"10.1007/s10934-025-01864-0","url":null,"abstract":"<div><p>In response to escalating demands for energy-efficient and acoustically optimized materials, this study develops a lightweight interpenetrating network (IPN) composite felt via skeleton fragmentation reconstruction of melamine foam (MF) and ultrafine glass fibers (UGF). Utilizing a scalable wet-laid sheet forming technique, MF was mechanically fragmented and uniformly integrated with UGF at controlled mass ratios (M7G3-M3G7). Comprehensive characterization revealed that the hybrid architecture simultaneously enhances thermal insulation and acoustic performance. Microstructural analysis confirmed a dual bonding mechanism-bridging and interpenetration-between MF trident-like skeletons and UGF, forming tortuous micropores (2–25 μm). Optimal thermal insulation was achieved with M3G7 (30.83 mW/m·K), leveraging synergistic hindrance from organic–inorganic heat transfer mismatches and suppressed convection in narrowed pores. Mechanically, M5G5 exhibited superior compressive strength (&gt; 900 N at 5 mm displacement) due to fiber reinforcement, while M7G3 showed high elasticity (75% rebound). Acoustic testing demonstrated broadband sound absorption (up to 0.8 at 4000–6000 Hz) and frequency-dependent insulation (6–18 dB), attributed to pore-mediated wave scattering and viscous dissipation. This work has addressed the “sound-heat-force” performance trade-off issue existing in multi-functional composite materials, enabling the exploration of next-generation sustainable solutions for global energy conservation and reduction of noise pollution. It also paves the way for subsequent in-depth component proportion optimization to achieve balanced high-performance multi-functional materials.</p></div>","PeriodicalId":660,"journal":{"name":"Journal of Porous Materials","volume":"33 1","pages":"87 - 97"},"PeriodicalIF":3.2,"publicationDate":"2025-10-13","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"146091027","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

{"title":"Design and fabrication of a novel, recoverable, and heterogeneous magnetic composite based on Melamine-Functionalized SBA-15 for catalytic synthesis of Quinazoline compounds","authors":"Mohammad Reza Naimi-Jamal,&nbsp;Nazanin Mohassel Yazdi","doi":"10.1007/s10934-025-01857-z","DOIUrl":"10.1007/s10934-025-01857-z","url":null,"abstract":"<div><p>A mesoporous SBA-15 compound was mogenous composite was thoroughly characterized using various techniques, including Infrared spectroscopy (FT-IR), Energy dispersive X-ray (EDX) for elemental analysis, scanning electron microscopy (SEM) for investigating surface morphology, thermogravimetric analysis (TGA), X-ray diffraction (XRD), transmission electron microscopy (TEM) and, N₂ adsorption–desorption isotherms (BET). Vibrating-sample magnetometry (VSM) technique is used to measure magnetic properties of SBA-15/Fe₃O₄@MEL. The catalytic performance of the nanocomposite was then evaluated in the synthesis of quinazolinone compounds, yielding electron-withdrawing and electron-donating groups in high yield. Many of these derivatives exhibit important properties, including biological activity. These materials are known, and their identification has been reported through comparison of their spectral data with the literature.</p></div>","PeriodicalId":660,"journal":{"name":"Journal of Porous Materials","volume":"33 1","pages":"149 - 167"},"PeriodicalIF":3.2,"publicationDate":"2025-10-13","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"146091029","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

{"title":"Development of copper embedded silica reinforced ordered mesoporous carbonaceous material for non-enzymatic biomarker sensor","authors":"Sakthivel Elamaran Chandru,&nbsp;Riya Das,&nbsp;Lakshi Saikia,&nbsp;Paneerselvam Yuvaraj,&nbsp;G. Gnana Kumar,&nbsp;Kodirajan Selvakumar","doi":"10.1007/s10934-025-01856-0","DOIUrl":"10.1007/s10934-025-01856-0","url":null,"abstract":"<div><p>A systematic approach was developed for synthesizing a copper quantum dot embedded, silica reinforced, and hierarchically ordered, porous biogenic carbonaceous (HPC) material from pre-activated carbon of the <i>Mimosa pudica</i> plant <i>via</i> sol-gel and alcothermal processes. The substantial functional entities on the partially activated carbon enabled an organized interaction with silica, copper oxide and a polymer template, resulting in a Cu-doped silica reinforced ordered mesoporous carbon material (Cu-SOMC) from the crude plant. The meso-phases (2θ values and h, l, k values 22.08^o and 9.48^o), crystalline structure and the oxidation state of Cu in Cu-SOMC are characterized by XRD, XPS analysis and TEM-SAED patterns. SEM, TEM and SEM-EDAX analysis revealed the silica reinforcement, a hierarchically ordered arrangement of carbon layers, uniform distribution of Cu₂O (3–6 nm), pore size distribution (0.106 cm³/g) and chemical composition of the synthesized material. The modified Cu-SOMC/GC electrode fabricated from Cu-SOMC exhibited good selectivity and sensitivity against the mammalian metabolic biomarker creatinine (CA). The electrode showed a wide range of concentrations (10–100 µM), a broad scan rate range (10–100 mVs⁻¹) and a low detection limit at 2 nm <i>via</i> the electrochemical method.</p></div>","PeriodicalId":660,"journal":{"name":"Journal of Porous Materials","volume":"33 1","pages":"133 - 148"},"PeriodicalIF":3.2,"publicationDate":"2025-10-13","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"146091006","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

{"title":"Sustainable activated carbon derived from Parthenium hysterophorus for levofloxacin removal and supercapacitor applications","authors":"Vishal,&nbsp; Sahil,&nbsp;Ritika Sharma,&nbsp;Ramesh Kumar,&nbsp;Dharmender Singh Rana,&nbsp;Neeraj Gupta,&nbsp;Dilbag Singh","doi":"10.1007/s10934-025-01860-4","DOIUrl":"10.1007/s10934-025-01860-4","url":null,"abstract":"<div>\u0000 \u0000 <p>This study explores the synthesis of oxygen rich activated carbon (AC) material derived from a toxic and inexpensive weed <i>Parthenium hysterophorus</i>. The synthesized carbon material (AC) was used for dual applications: removal of Levofloxacin (LEV) from wastewater and as an electrode material for supercapacitor. The AC was characterized by FESEM, HRTEM, BET, XRD and FTIR techniques. Morphological investigations revealed irregular, stacked graphitic flakes and amorphous nature of AC, whereas elemental mapping verified a carbon-rich composition (78.2%) with integrated oxygen (21.8%). A pore width of 3.4 nm and a surface area of 1.043 m²/g were identified by BET analysis consistent with type III isotherm. FTIR analysis verified the existence of different functional groups enhancing the interaction with LEV by π–π, hydrogen bonding and electrostatic interactions. The adsorption dose experiment displayed that 7 mg dose of AC effectively remove 77% of LEV drug (0.018 g/L). Furthermore, the specific capacitance obtained at 10 mV/s is 1718 F/g. The excellent specific capacitance proves the high storage capacity of AC. Further in case of device, the specific capacitance for first cycle is 6.25 Fg⁻¹. Further, from the twoelectrode system, the device retained 80% its original efficiency. Langmuir and Freundlich models were found to be applicable by isotherm studies, indicating monolayer and multilayer adsorption mechanisms. <i>Parthenium hysterophorus</i> offers a viable path for energy storage and environmental remediation. It can also be used as a cost-effective and eco-friendly raw material for producing functionalized activated carbon.</p>\u0000 </div>","PeriodicalId":660,"journal":{"name":"Journal of Porous Materials","volume":"33 1","pages":"99 - 115"},"PeriodicalIF":3.2,"publicationDate":"2025-10-13","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"146091005","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}