A. K. Kostanyan, H. G. Manukyan, K. A. Sargsyan, G. S. Karakhanyan, H. A. Alexanyan, N. B. Knyazyan
{"title":"Composite Material Based on Oxyfluoride Barium Boron-Aluminosilicate Glass and Al2o3 for LTCC Technology","authors":"A. K. Kostanyan, H. G. Manukyan, K. A. Sargsyan, G. S. Karakhanyan, H. A. Alexanyan, N. B. Knyazyan","doi":"10.1007/s10717-025-00753-x","DOIUrl":"10.1007/s10717-025-00753-x","url":null,"abstract":"<p>This article examines the synthesis and properties of a composite ceramic material based on a glass with the composition 31.0BaO – 30.0B<sub>2</sub>O<sub>3</sub> – 15.0Al<sub>2</sub>O<sub>3</sub> – 7.0SiO<sub>2</sub> – 6.8MgO – 5.9ZnO – 4.3MgF<sub>2</sub> (mol.%) and an Al<sub>2</sub>O<sub>3</sub> filler. The composite ceramic, prepared with an initial glass-to-Al<sub>2</sub>O<sub>3</sub> mass ratio of 60 : 40 and sintered at 875°C, exhibits a relative permittivity ε<sub><i>r</i></sub> of 8.62 and a loss tangent tan δ of 12.1 × 10 <sup>–4</sup> at 1 MHz. The material demonstrates a flexural strength of 117.5 MPa, a coefficient of linear thermal expansion (CLTE) of 69.7 × 10 <sup>–7</sup> K <sup>– 1</sup>, and chemical compatibility with silver electrodes. These properties suggest its applicability in low-temperature co-fired ceramic (LTCC) technology.</p>","PeriodicalId":579,"journal":{"name":"Glass and Ceramics","volume":"82 1-2","pages":"88 - 92"},"PeriodicalIF":0.6,"publicationDate":"2025-05-16","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"144117780","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
N. A. Timofeeva, S. S. Balabanov, T. O. Evstropov, A. V. Naumova, S. V. Filofeev, R. S. Kovylin
{"title":"Hot Pressing Conditions of CVD ZnSe Powder Influence the Properties of Optical Ceramics","authors":"N. A. Timofeeva, S. S. Balabanov, T. O. Evstropov, A. V. Naumova, S. V. Filofeev, R. S. Kovylin","doi":"10.1007/s10717-025-00750-0","DOIUrl":"10.1007/s10717-025-00750-0","url":null,"abstract":"<p>This study examines the influence of vacuum hot pressing (VHP) conditions on the microstructure, density, and optical properties of ZnSe ceramics. Graphite and titanium foils, as well as alumina powder, were used to isolate the compact from the graphite mold, thereby enabling the variation in carbon contamination levels. Carbon was found to significantly affect the sintering and recrystallization of ZnSe ceramics, hindering the achievement of high density and transparency. Microstructural analysis revealed that the use of alumina as an insulating layer promotes more uniform grain growth, while minimizing abnormal grain enlargement. Spectral analysis demonstrated that maximum infrared (IR) transparency was achieved in samples with initial densities exceeding 97% after additional hot isostatic pressing (HIP). However, further enhancement of the optical properties necessitates the complete elimination of carbon contamination, which demands the replacement of graphite tooling in the VHP process.</p>","PeriodicalId":579,"journal":{"name":"Glass and Ceramics","volume":"82 1-2","pages":"67 - 73"},"PeriodicalIF":0.6,"publicationDate":"2025-05-16","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"144117779","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
{"title":"Glass Formation and Phase Transformations in the TeO2–ZnO–MoO3 System","authors":"O. A. Zamyatin, Z. K. Nosov, M. V. Krasnov","doi":"10.1007/s10717-025-00751-z","DOIUrl":"10.1007/s10717-025-00751-z","url":null,"abstract":"<p>The article examines a glass-forming region in the ternary TeO<sub>2</sub>–ZnO–MoO<sub>3</sub> system at two melt cooling rates. Glasses containing up to 80 mol.% molybdenum trioxide were obtained with varying TeO<sub>2</sub>/ZnO ratios. X-ray diffraction (XRD) was used to study the phase formation in the batch and glass samples under thermal treatment. No significant interaction between the initial binary oxides was observed in the temperature range of 20 – 300°C. However, further heating led to the formation of complex oxides of tellurium (IV), zinc, and molybdenum (VI), including Te<sub>2</sub>MoO<sub>7</sub>, Zn<sub>2</sub>Te<sub>3</sub>O<sub>8</sub>, ZnMoO<sub>4</sub>, and ZnTeMoO<sub>6</sub>. These phases were also formed during controlled glass crystallization. The transmission spectra of the glasses exhibited a redshift of the absorption edge with an increase in molybdenum trioxide content.</p>","PeriodicalId":579,"journal":{"name":"Glass and Ceramics","volume":"82 1-2","pages":"74 - 81"},"PeriodicalIF":0.6,"publicationDate":"2025-05-15","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"144117768","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
D. S. Vakalov, I. S. Chikulina, S. N. Skichuk, D. P. Bedrakov
{"title":"Garnet Phase Formation in Y2O3–Lu2O3–Yb2O3–Er2O3–Al2O3 System During the Synthesis of Nanocrystalline Weakly Agglomerated Ceramic Powders by Coprecipitation Method Using Ammonium Sulfate","authors":"D. S. Vakalov, I. S. Chikulina, S. N. Skichuk, D. P. Bedrakov","doi":"10.1007/s10717-025-00742-0","DOIUrl":"10.1007/s10717-025-00742-0","url":null,"abstract":"<p>For the first time, we obtained a series of ceramic powders with garnet structure, (Y<sub>1–<i>x</i></sub>Lu<sub><i>x</i></sub>)<sub>3</sub>Yb<sub>0.15</sub>Er<sub>0.03</sub>Al<sub>5</sub>O<sub>12</sub> (YLuAG), using the coprecipitation method with ammonium sulfate. The atomic ratio of Y<sup>3+</sup>/Lu<sup>3+</sup> cations was varied from 80/20 to 20/80. It was determined that the formation of the garnet phase under the synthesis conditions proceeds through the formation of intermediate phases, whose composition depends on the Y/Lu ratio in the initial salt solution. The differential thermal analysis (DTA) of precursor powders and x-ray diffraction (XRD) of (Y<sub>1–<i>x</i></sub>Lu<sub><i>x</i></sub>)<sub>3</sub>Yb<sub>0.15</sub>Er<sub>0.03</sub>Al<sub>5</sub>O<sub>12</sub> ceramic powders obtained at 800, 900, 1000, and 1150°C facilitated the identification of the temperature ranges for the formation and decomposition of intermediate crystalline phases obtained during the thermal synthesis of the garnet phase, including Y<sub>2</sub>O<sub>2</sub>SO<sub>4</sub>, Y<sub>2</sub>(SO<sub>4</sub>)<sub>3</sub>, Lu<sub>2</sub>(SO<sub>4</sub>)<sub>3</sub>, and Lu<sub>1–<i>x</i></sub>Y<sub><i>x</i></sub>AlO<sub>3</sub>.</p>","PeriodicalId":579,"journal":{"name":"Glass and Ceramics","volume":"82 1-2","pages":"23 - 27"},"PeriodicalIF":0.6,"publicationDate":"2025-05-15","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"144117767","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
L. A. Avakyan, D. V. Khizhnyak, E. A. Tretyakov, M. Z. Ziatdinova, M. P. Vetchinnikov, V. V. Kriventsov, G. Yu. Shakhgildyan, L. A. Bugaev, V. N. Sigaev
{"title":"Local Atomic Structure of Neodymium Ions in Boroaluminate and Zinc Phosphate Glasses Determined by EXAFS","authors":"L. A. Avakyan, D. V. Khizhnyak, E. A. Tretyakov, M. Z. Ziatdinova, M. P. Vetchinnikov, V. V. Kriventsov, G. Yu. Shakhgildyan, L. A. Bugaev, V. N. Sigaev","doi":"10.1007/s10717-025-00746-w","DOIUrl":"10.1007/s10717-025-00746-w","url":null,"abstract":"<p>This article examines the local atomic structure of neodymium ions introduced into boroaluminate (5 mol.% Nd<sub>2</sub>O<sub>3</sub>) and zinc phosphate (0.5 mol.% Nd<sub>2</sub>O<sub>3</sub>) glasses by extended x-ray absorption fine structure (EXAFS) spectroscopy near the Nd <i>L</i><sub>3</sub>-edge. The reference spectra of neodymium oxide recorded at both the <i>K</i>- and <i>L</i><sub>3</sub>-edges facilitated the identification of multielectron excitation features and enhanced the determination accuracy of local structural parameters. The findings revealed that, on average, neodymium ions in the boroaluminate glass are coordinated by approximately 9.6 oxygen atoms at a Nd–O distance of approximately 2.4 Å, whereas in the zinc phosphate glass, they are surrounded by approximately 6.8 oxygen atoms at approximately 2.3 Å.</p>","PeriodicalId":579,"journal":{"name":"Glass and Ceramics","volume":"82 1-2","pages":"51 - 56"},"PeriodicalIF":0.6,"publicationDate":"2025-05-14","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"144117764","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
H. Alhalabi, D. V. Marasanov, N. V. Nikonorov, M. A. Sinyakova, G. G. Chernik
{"title":"Ion Exchange Strengthening of Sodium-Calcium-Magnesium Silicate Glass Using a Silicon-Phosphorus-Antimony Cation Exchanger in Potassium Nitrate Melt","authors":"H. Alhalabi, D. V. Marasanov, N. V. Nikonorov, M. A. Sinyakova, G. G. Chernik","doi":"10.1007/s10717-025-00752-y","DOIUrl":"10.1007/s10717-025-00752-y","url":null,"abstract":"<p>This article examines the influence of the potassium form of silicon-phosphorus-antimony cation exchangers (K:SPA-cation exchangers) added to a potassium nitrate melt on the compressive stresses on the surface of sodium-calcium-magnesium silicate glass. Compressive stresses are induced by low-temperature ion exchange between Na<sup>+</sup> ions in the glass and K<sup>+</sup> ions in the molten salt. We compared two types of potassium nitrate: technical grade B and chemically pure grade CP. The distribution of compressive stresses in the surface layer of the glass was analyzed using waveguide spectroscopy; we determined the birefringence profile to calculate the stress profile. Microhardness was measured using a PMT-3 microhardness tester. The addition of a K:SPA-cation exchanger into the potassium nitrate melt was shown to improve ion exchange conditions for both types of nitrate compared to the salt melt without a cation exchanger, leading to an increase in compressive stress, depth of the ion-exchanged layer, and microhardness. Following ion exchange with the addition of a cation exchanger, an increase in compressive stress relative to the initial glass was 155 MPa and 450 MPa for grade B and grade CP, respectively. Microhardness increased by 120% and 240% for grade B and grade CP, respectively. The cation exchanger significantly improves ion exchange conditions for technical-grade potassium nitrate (grade B). The introduction of cation exchangers into the salt bath melt holds promise for advancing ion exchange technology, which is used to enhance the mechanical and thermal strength of glass products. The potential of this method is particularly relevant in glass strengthening production, where cheaper technical-grade potassium nitrate is used.</p>","PeriodicalId":579,"journal":{"name":"Glass and Ceramics","volume":"82 1-2","pages":"82 - 87"},"PeriodicalIF":0.6,"publicationDate":"2025-05-14","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"144117763","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
{"title":"Laser Modification of Thermal Spray Coatings Obtained by HVOF Spraying. A Review","authors":"S. I. Yaresko, I. A. Antoshin","doi":"10.1007/s10717-025-00745-x","DOIUrl":"10.1007/s10717-025-00745-x","url":null,"abstract":"<p>This review summarizes research findings on the laser modification of coatings produced by high-velocity oxygen fuel (HVOF) spraying, with a primary focus on the laser post-treatment of tungsten carbide-based coatings. We discuss the main types of laser systems used for additional thermal processing of coatings. The results demonstrate that laser post-treatment significantly influences the microstructure of coatings, leading to higher density, a 4 – 6-fold reduction in porosity and dispersion, and the ability to control the distribution and magnitude of residual stresses. The review further demonstrates that laser post-treatment increases the micro- hardness of coatings by 20 – 50%, improves adhesion strength between the coating and the metallic substrate, enhances wear and corrosion resistance, and reduces the friction coefficient by 20 – 65%. The underlying mechanisms of the observed variations in structural and mechanical properties of remelted coatings are discussed.</p>","PeriodicalId":579,"journal":{"name":"Glass and Ceramics","volume":"82 1-2","pages":"39 - 50"},"PeriodicalIF":0.6,"publicationDate":"2025-05-13","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"144117759","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
{"title":"Mechanical Strength Control of Safety Glasses for Ground Transportation During the Production Process","authors":"E. R. Khorosheva, R. I. Makarov","doi":"10.1007/s10717-025-00747-9","DOIUrl":"10.1007/s10717-025-00747-9","url":null,"abstract":"<p>This study investigates the influence of tempering parameters on the mechanical strength of safety glass products. We examined the effects of press configuration and temperature settings within the chambers of tunnel furnace on the fracture patterns of glass during strength testing. A logistic regression model was developed to predict fracture behavior during mechanical strength testing of produced glass, facilitating real-time adjustments to the tempering process. This approach aims to enhance quality control and optimize production efficiency.</p>","PeriodicalId":579,"journal":{"name":"Glass and Ceramics","volume":"82 1-2","pages":"57 - 58"},"PeriodicalIF":0.6,"publicationDate":"2025-05-13","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"144117760","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
L. I. Podzorova, V. P. Sirotinkin, A. S. Baikin, A. A. Il’icheva, N. A. Michaylina, E. S. Morokov, O. I. Pen’kova, T. R. Chueva
{"title":"Physical and Mechanical Characteristics of Ceramic Materials Based on Systems ZrO2–Sm2O3 with Two-Phase Composition","authors":"L. I. Podzorova, V. P. Sirotinkin, A. S. Baikin, A. A. Il’icheva, N. A. Michaylina, E. S. Morokov, O. I. Pen’kova, T. R. Chueva","doi":"10.1007/s10717-025-00749-7","DOIUrl":"10.1007/s10717-025-00749-7","url":null,"abstract":"<p>This study investigates the physical and mechanical properties of ceramic materials with compositions 97ZrO<sub>2</sub>–3Sm<sub>2</sub>O<sub>3</sub> and 94ZrO<sub>2</sub>–6Sm<sub>2</sub>O<sub>3</sub> (mol.%), fabricated from initial nanopowders. The ceramics exhibit a two-phase structure comprising tetragonal and cubic solid solutions based on ZrO<sub>2</sub>. The Sm<sub>2</sub>O<sub>3</sub> content is shown to significantly influence the phase ratio, thereby affecting the grain structure and properties of the material. An increase in the volume fraction of the tetragonal ZrO<sub>2</sub>-based solid solution from 46 to 85 vol.% leads to an enhancement in mechanical strength from 600 to 850 MPa and in fracture toughness <i>K</i><sub>1<i>c</i></sub> from 8.0 to 10.5 MPa · m<sup>1/2</sup>.</p>","PeriodicalId":579,"journal":{"name":"Glass and Ceramics","volume":"82 1-2","pages":"62 - 66"},"PeriodicalIF":0.6,"publicationDate":"2025-05-13","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"144117761","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
V. A. Lapin, A. A. Kravtsov, V. A. Tarala, V. E. Suprunchuk, F. F. Malyavin, D. S. Vakalov
{"title":"Preparation of YAG:Ce Ceramics with High Luminescent Properties","authors":"V. A. Lapin, A. A. Kravtsov, V. A. Tarala, V. E. Suprunchuk, F. F. Malyavin, D. S. Vakalov","doi":"10.1007/s10717-025-00740-2","DOIUrl":"10.1007/s10717-025-00740-2","url":null,"abstract":"<p>This study examines the synthesis of YAG:Ce precursor powder and luminescent ceramics by reverse chemical co-precipitation. We investigated the effects of sintering additives (CaO, MgO, and TEOS), Ce<sup>3+</sup> activator concentration, vacuum sintering temperature, and the temperature of air annealing on the luminescent properties of YAG:Ce ceramics. The optimal parameters for achieving high luminescence efficiency were defined: sintering additive concentration of 0.01 wt.%, TEOS as the sintering additive, vacuum sintering temperature of 1800°C, and air annealing temperature of 600°C for TEOS-containing samples. A ceramic sample exhibiting a luminescence efficiency of 319 lm/W was achieved under laser radiation with a power of 190 mW and a spot diameter of approximately 5 mm.</p>","PeriodicalId":579,"journal":{"name":"Glass and Ceramics","volume":"82 1-2","pages":"11 - 18"},"PeriodicalIF":0.6,"publicationDate":"2025-05-10","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"144117680","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}