Zh. T. Suleimenov, A. A. Sagyndykov, E. A. Abutalipov
{"title":"Composite Glass-Crystal Facing Materials Based on Industrial Phosphoric Waste and Cullet","authors":"Zh. T. Suleimenov, A. A. Sagyndykov, E. A. Abutalipov","doi":"10.1007/s10717-023-00620-7","DOIUrl":"10.1007/s10717-023-00620-7","url":null,"abstract":"<p>Matted glass compositions have been developed for the top layer and bottom structural layer of composite glass-crystal cladding material based on waste from the phosphoric industry: phosphoric slag, phosphorite fines, boiler dust, and cullet.</p>","PeriodicalId":579,"journal":{"name":"Glass and Ceramics","volume":"80 9-10","pages":"392 - 395"},"PeriodicalIF":0.6,"publicationDate":"2023-12-22","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"138944599","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
R. N. Rumyantsev, A. A. Kournikova, A. A. Ily’in, A. V. Afineevsky, T. N. Borisova, E. S. Severgina, D. A. Prozorov, N. N. Smirnov
{"title":"Study of the Conditions for Ceramic and Mechanochemical Synthesis of CuO/ZnO/γ-Al2O3 Composites","authors":"R. N. Rumyantsev, A. A. Kournikova, A. A. Ily’in, A. V. Afineevsky, T. N. Borisova, E. S. Severgina, D. A. Prozorov, N. N. Smirnov","doi":"10.1007/s10717-023-00617-2","DOIUrl":"10.1007/s10717-023-00617-2","url":null,"abstract":"<p>The preparation process for the composites CuO/ZnO/γ-Al<sub>2</sub>O<sub>3</sub>, which can be used as the main component of catalysts for large-tonnage methanol production and carbon monoxide conversion, was investigated by means of x-ray phase, x-ray crystalline, and synchronous thermal analysis as well as scanning electron microscopy, and low-temperature adsorption-desorption of nitrogen. The influence of the production method and the nature and intensity of processing on the phase composition of the resulting precursors and the physicochemical properties of the resulting composites was determined. The processes occurring at the stage of mechanochemical activation of a mixture of anhydrous oxides CuO/ZnO/γ-Al<sub>2</sub>O<sub>3</sub> and a mixture of oxides with ammonium carbonate and ethanedioic [oxalic] acid were studied. The optimal parameters for obtaining CuO/ZnO/γ-Al<sub>2</sub>O<sub>3</sub> composites with a developed specific surface and porous structure were determined.</p>","PeriodicalId":579,"journal":{"name":"Glass and Ceramics","volume":"80 9-10","pages":"370 - 377"},"PeriodicalIF":0.6,"publicationDate":"2023-12-22","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"138946121","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
V. Yu. Chukhlanov, N. N. Smirnova, I. A. Krasilnikova, N. V. Chukhlanova
{"title":"Ceramic-Forming Organosilicon Polymer as a Modifier of Heat-Insulating Syntactic Material","authors":"V. Yu. Chukhlanov, N. N. Smirnova, I. A. Krasilnikova, N. V. Chukhlanova","doi":"10.1007/s10717-023-00618-1","DOIUrl":"10.1007/s10717-023-00618-1","url":null,"abstract":"<p>The results of the preparation of strengthened syntactic carbon materials that can be used for industrial-grade heat insulation in conditions of heightened pressures and temperatures are presented. Strengthened syntactic carbon material is obtained by mixing hollow carbon microspheres, pre-treated with vanadium (III) chloride catalyst, with a phenol-formaldehyde binder with the addition of fine polydimethylsilane, molding the composition at low pressure, soaking the mold at 150°C for 2 h, followed by heat treatment in an inert environment at 375°C and final carbonization in combination with carbidization when the temperature rises at a rate of 100 K/h to 900°C. The physicomechanical and thermophysical characteristics were studied. Syntactic material can be used for the manufacture of heat-insulation products operating at high temperatures.</p>","PeriodicalId":579,"journal":{"name":"Glass and Ceramics","volume":"80 9-10","pages":"385 - 388"},"PeriodicalIF":0.6,"publicationDate":"2023-12-22","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"138945484","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
{"title":"Ceramic Artifacts of Kyrgyzstan: Integrative Investigation","authors":"G. T. Oruzbaeva, V. P. Borisov","doi":"10.1007/s10717-023-00619-0","DOIUrl":"10.1007/s10717-023-00619-0","url":null,"abstract":"<p>The application of an integrated research approach to the reconstruction of ceramic production technology on the territory of the Kyrgyz Republic is considered based on the results obtained by modern methods. For the first time, the results of studying physicomechanical and physicochemical properties are summarized and an attempt is made to open up methods of technical analysis of ceramic artifacts. A unified scientific approach has been developed to the ceramics of various periods ranging from the 2nd millennium BC to our era up to the 10th – 12th centuries, and excavated in Kyrgyzstan, so as to determine the relationship between their microstructure and physical and mechanical properties. Ceramic technology, like no other industry, requires this kind of research because of the specificity of technical information associated with both natural and social factors. The lack of solid knowledge in the field of ceramics technology prevents the acquisition of important information about the history, culture, and economy of Kyrgyzstan as a nation-building entity. However, a comprehensive study of production techniques, types, compositions, and quality of ceramics would open up completely new prospects for confirming the antiquity of Kyrgyzstan.</p>","PeriodicalId":579,"journal":{"name":"Glass and Ceramics","volume":"80 9-10","pages":"389 - 391"},"PeriodicalIF":0.6,"publicationDate":"2023-12-22","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"138946976","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
T. M. Volobueva, O. Yu. Sorokin, G. N. Golovkin, B. Yu. Kuznetsov
{"title":"Synthesis and Study of the Properties of Corundum-Mullite Ceramic as a Component of Ceramic Composite Materials","authors":"T. M. Volobueva, O. Yu. Sorokin, G. N. Golovkin, B. Yu. Kuznetsov","doi":"10.1007/s10717-023-00615-4","DOIUrl":"10.1007/s10717-023-00615-4","url":null,"abstract":"<p>The conditions for the synthesis of mullite-corundum ceramic prepared on the basis of Al<sub>2</sub>O<sub>3</sub> and SiO<sub>2</sub> powders were investigated. The composition of mullite-corundum ceramic with Al<sub>2</sub>O<sub>3</sub> < 80 wt.%, which affords the best thermomechanical compatibility with molybdenum, was determined. The possibility of obtaining a composite material based on a mullite-corundum matrix and molybdenum, as well as its use as a barrier layer at the Mo–Si-containing ceramic interface, was confirmed. It was ascertained that the use of a barrier layer substantially reduces the likelihood of thermal stresses arising at the interface between two phases. It is demonstrated that the technological parameters of the process of preparing Al<sub>2</sub>O<sub>3</sub>–SiO<sub>2</sub> powder mixtures require elaboration in order to increase the thermochemical compatibility of molybdenum with mullite-corundum ceramic.</p>","PeriodicalId":579,"journal":{"name":"Glass and Ceramics","volume":"80 9-10","pages":"357 - 363"},"PeriodicalIF":0.6,"publicationDate":"2023-12-21","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"138952865","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
{"title":"Glass and Ceramics Volume 80, Number 7","authors":"","doi":"10.1007/s10717-023-00595-5","DOIUrl":"10.1007/s10717-023-00595-5","url":null,"abstract":"","PeriodicalId":579,"journal":{"name":"Glass and Ceramics","volume":"80 7-8","pages":"265 - 266"},"PeriodicalIF":0.6,"publicationDate":"2023-11-14","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"134796434","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
{"title":"Glass and Ceramics Volume 80, Number 8","authors":"","doi":"10.1007/s10717-023-00603-8","DOIUrl":"10.1007/s10717-023-00603-8","url":null,"abstract":"","PeriodicalId":579,"journal":{"name":"Glass and Ceramics","volume":"80 7-8","pages":"305 - 306"},"PeriodicalIF":0.6,"publicationDate":"2023-11-14","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"134796433","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Sh. M. Shamuratova, Dj. I. Alimdjanova, Z. T. Matkarimov
{"title":"Electroporcelain Based on Raw Materials of Uzbekistan","authors":"Sh. M. Shamuratova, Dj. I. Alimdjanova, Z. T. Matkarimov","doi":"10.1007/s10717-023-00610-9","DOIUrl":"10.1007/s10717-023-00610-9","url":null,"abstract":"<div><div><p>The results of investigations of the preparation of electrical porcelain based on available customary raw materials of Uzbekistan are presented. It is shown that in conditions of a shortage of high-grade mineral raw materials for the preparation of electrical porcelain it is advisable to introduce about half of the kaolin in a pre-calcined state into the mixture. In addition the products of firing primary and secondary Angrenskoe kaolins at 1350°C allow us to consider them as a mullite-containing component that subsequently imparts high physicomechanical and dielectric properties to the porcelain material. The phase composition of the resulting porcelain is represented mainly by new crystalline components — mullite and cristobalite, which allows it to be classified as an electric porcelain of the mullite-type.</p></div></div>","PeriodicalId":579,"journal":{"name":"Glass and Ceramics","volume":"80 7-8","pages":"337 - 341"},"PeriodicalIF":0.6,"publicationDate":"2023-11-10","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"134795966","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
A. N. Smirnov, S. A. Krylova, D. A. Gorlenko, E. E. Kuzmina, D. I. Alekseev
{"title":"Magnesium Oxide Based Structural–Mechanical Properties of Samples Formed on Organic Binder Polymerization: A Study","authors":"A. N. Smirnov, S. A. Krylova, D. A. Gorlenko, E. E. Kuzmina, D. I. Alekseev","doi":"10.1007/s10717-023-00602-9","DOIUrl":"10.1007/s10717-023-00602-9","url":null,"abstract":"<div><div><p>The influence of humidity and oxygen on the formation of the structure and strength properties of manufactured products based on magnesium oxide and the organic binder SFPR-054 was studied. It was ascertained that conduction of the polymerization process at 25°C without access to air effects approximately five-fold higher sample strength compared to the samples polymerized in dry form at 300°C. The data obtained suggest that an increase in the structural and mechanical properties of manufactured products on the basis of magnesium oxide contributes to moistening of the batch, retention of the pressed product and the polymerization process in an oxygen-free environment or in an atmosphere of water vapors.</p></div></div>","PeriodicalId":579,"journal":{"name":"Glass and Ceramics","volume":"80 7-8","pages":"300 - 304"},"PeriodicalIF":0.6,"publicationDate":"2023-11-08","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"134795817","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
V. A. Kjutvitsky, I. A. Romanova, E. V. Mironova, V. V. Borisova, O. I. Ostanina, F. N. Karachevtsev
{"title":"Bismuthate Glass as Backing for Gas Sensors","authors":"V. A. Kjutvitsky, I. A. Romanova, E. V. Mironova, V. V. Borisova, O. I. Ostanina, F. N. Karachevtsev","doi":"10.1007/s10717-023-00607-4","DOIUrl":"10.1007/s10717-023-00607-4","url":null,"abstract":"<div><div><p>Bismuthate-borate glasswas synthesized with the compositions (wt.%) 70 Bi<sub>2</sub>O<sub>3</sub>, 2 GeO<sub>2</sub>, 25 B<sub>2</sub>O<sub>3</sub>, 3 MoO<sub>3</sub>; 70 Bi<sub>2</sub>O<sub>3</sub>, 17 GeO<sub>2</sub>, 10 B<sub>2</sub>O<sub>3</sub>, 3 MoO<sub>3</sub> and 80 Bi<sub>2</sub>O<sub>3</sub>, 4 GeO<sub>2</sub>, 5 MoO<sub>3</sub>, 11 SiO<sub>2</sub>; 80 Bi<sub>2</sub>O<sub>3</sub>, 8 GeO<sub>2</sub>, 8.5 SiO<sub>2</sub>, 3.5 MoO<sub>3</sub>. Methods were developed for forming a receptor layer on the resulting glass by means of ultrasonic spraying of the interacting components and applying a water-insoluble polymer film obtained via a chemical reaction between the polymer poly-N,N-dimethyl-3,4-dimethylenepyrrolidinium chloride and the modifier potassium hexacyanoferrate (II). The sensors prepared based on these glasses make it possible to determine to within2– 4% the content of hydrogen sulfide and water vapor in air.</p></div></div>","PeriodicalId":579,"journal":{"name":"Glass and Ceramics","volume":"80 7-8","pages":"317 - 321"},"PeriodicalIF":0.6,"publicationDate":"2023-11-06","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"134795704","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}